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公开(公告)号:US20120049167A1
公开(公告)日:2012-03-01
申请号:US13145718
申请日:2010-01-21
CPC分类号: C07D213/18 , C07D233/58 , C08G61/02 , C08G61/10 , C08G61/12 , C08G2261/312 , C08G2261/3142 , C08G2261/3162 , C08G2261/5242 , C09K11/06 , C09K2211/1029 , C09K2211/1044 , C09K2211/1466 , C09K2211/188 , H01L51/0035 , H01L51/0037 , H01L51/004 , H01L51/0091 , H01L51/5012 , H05B33/14
摘要: An organic electroluminescent device in which an organic layer containing a metal coordination compound represented by the following formula (1) is sandwiched between the pair of electrodes composed of an anode and a cathode, MLaXb (1) wherein M is an ion of a metal of Group 11 of the Periodic Table, L is a ligand represented by the formula (2) shown below, X is an anion, and a and b are defined in the specification, wherein A is a divalent group formed by removing two hydrogen atoms from the formula (3) or (4) shown below, and D1, k1, m1, A, D1, Q1, and Q2 are defined in the specification, wherein X1, X2, X3, X4, X5, R1, R5, R6, and R9 are defined in the specification.
摘要翻译: 一种有机电致发光器件,其中含有由下式(1)表示的金属配位化合物的有机层夹在由阳极和阴极组成的一对电极之间,MLaXb(1)其中M是金属的离子 L是由下述式(2)表示的配体,X是阴离子,a和b在本说明书中定义,其中A是通过除去二个氢原子而形成的二价基团 在本说明书中定义了D1,k1,m1,A,D1,Q1和Q2,其中X1,X2,X3,X4,X5,R1,R5,R6和 R9在本说明书中定义。
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公开(公告)号:US20120021897A1
公开(公告)日:2012-01-26
申请号:US13202858
申请日:2010-02-19
IPC分类号: B01J31/22 , C07F15/06 , C07D487/22 , C07F1/08 , C07F3/06 , C07D471/22 , C07D498/22 , C07F15/04
CPC分类号: C07D471/22 , B01J31/2243 , B01J2231/70 , B01J2531/0216 , B01J2531/0241 , B01J2531/16 , B01J2531/26 , B01J2531/845 , B01J2531/847 , C07D487/22 , C07D498/22 , C07D513/22 , H01L51/0083 , H01L51/009 , H01L51/0091 , H01L51/0092 , H01M4/9008
摘要: A compound represented by the following formula (1): wherein, Y1, Y2, Y3 and Y4 represent a group represented by any of the above formulae; P1, P2, P3 and P4 are an atomic group required for forming an aromatic heterocyclic ring; P5 and P6 are an atomic group required for forming an aromatic ring; Z1 and Z2 represent ORα, —SRα or —NRα2, wherein Rα represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; Q1 and Q2 represent a direct bond or a linking group; a P1-containing ring and a P2-containing ring are bonded to form Q1-containing fused structure; a P3-containing ring and a P4-containing ring are bonded to form Q2-containing fused structure; can be used as a ligand of a metal complex, and the metal complex is useful for a catalyst.
摘要翻译: 由下式(1)表示的化合物:其中,Y1,Y2,Y3和Y4表示由上述任何一个表示的基团; P1,P2,P3和P4是形成芳族杂环所需的原子团; P5和P6是形成芳环所需的原子团; Z1和Z2表示ORα,-SRα或-NRα2,其中Rα表示氢原子或具有1至4个碳原子的烷基; Q1和Q2表示直接键或连接基团; 键合含有P1的环和含有P2的环,形成含有Q1的稠合结构; 键合含有P3的环和含有P4的环,形成含有Q2的稠合结构; 可以用作金属络合物的配体,并且金属络合物可用于催化剂。
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公开(公告)号:US20100219399A1
公开(公告)日:2010-09-02
申请号:US12159143
申请日:2006-12-25
CPC分类号: C08L53/00 , C08G61/00 , C08G61/10 , C08G61/12 , C08G61/124 , C08G61/125 , C08G61/126 , C09K11/06 , C09K2211/14 , H01L51/0026 , H01L51/0035 , H01L51/0036 , H01L51/0037 , H01L51/0039 , H01L51/0043 , H01L2251/308 , H05B33/14 , C08L2666/02
摘要: A block copolymer comprising two or more of blocks of the following formula (1), wherein at least two of a plurality of m's present in the copolymer represent a number of 5 or more, Ar's in adjacent two blocks in the copolymer are mutually different, and the copolymer has two Ar's when composed of 2 blocks of the formula (1), has two or more Ar's when composed of 3 blocks of the formula (1) and has four or more Ar's when composed of 4 or more blocks of the formula (1): (in the formula (1), Ar represents a conjugative divalent group and represents the same divalent group in an identical block, and m represents a number of 1 or more showing the number average polymerization degree of Ar present in one block.).
摘要翻译: 包含两个或更多个下式(1)的嵌段的嵌段共聚物,其中共聚物中存在的多个m中的至少两个表示5个或更多个,共聚物中相邻的两个嵌段中的Ar相互不同, 并且当由2个式(1)的嵌段组成时,该共聚物具有两个Ar,当由3个式(1)的嵌段组成时具有两个或更多个Ar,并且当由4个或更多个式 (1)表示(式(1)中,Ar表示共轭二价基,在同一嵌段中表示相同的二价基,m表示一个嵌段中存在Ar的数均聚合度的1以上的数 。)。
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公开(公告)号:US20100086823A1
公开(公告)日:2010-04-08
申请号:US12530378
申请日:2008-03-10
CPC分类号: H01M8/1004 , H01M4/9008 , H01M8/1048 , H01M8/1067
摘要: A membrane-electrode assembly, containing an electrode catalyst containing a base metal complex, in which exchange current density i0 obtained from a Tafel plot, which is related to current density and voltage, is 5.0×10−4 Acm−2 or more, and in which a Tafel slope obtained from the Tafel plot is 450 mV/decade or less; anda membrane-electrode assembly, containing catalyst layers each containing an electrode catalyst on both sides of an electrolyte membrane, in which at least one of the catalyst layers comprises a non-noble metal-based electrode catalyst, and in which the electrolyte membrane is a hydrocarbon-based electrolyte membrane.
摘要翻译: 包含与电流密度和电压相关的由Tafel图获得的交换电流密度i0的含有贱金属络合物的电极催化剂的膜 - 电极组件为5.0×10 -4 Acm-2以上, 其中从塔菲尔图获得的塔菲尔斜率为450mV / 10或更小; 以及膜 - 电极组件,其含有在电解质膜的两面均含有电极催化剂的催化剂层,其中至少一个所述催化剂层包含非贵金属基电极催化剂,其中所述电解质膜为 烃类电解质膜。
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公开(公告)号:US20090096355A1
公开(公告)日:2009-04-16
申请号:US11921766
申请日:2006-06-09
CPC分类号: H01L51/5012 , C08G61/00 , C08G61/02 , C08G61/12 , C08G2261/1434 , C08G2261/3142 , C08G2261/3162 , C08G2261/411 , C08G2261/5222 , C08G2261/77 , C08G2261/92 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/5048
摘要: An aromatic graft polymer containing one or more kinds of repeating units represented by the following formula (1). (In the formula, Ar1 represents a divalent residue of a π-conjugated cyclic compound having a side chain represented by the following formula (2), the side chain being bonded to a carbon atom which is included in the ring structure of the divalent π-conjugated-cyclic-compound residue represented by Ar1 and has an sp2 hybrid orbital: (wherein Ar2 represents a divalent group having a residue of a π-conjugated cyclic compound; X1 represents a direct bond or a divalent group selected from the group consisting of NQ1-, —PQ2-, and —BQ3-, wherein Q1 to Q3 each independently represents a substituent; Z represents a direct bond or a divalent connecting group; k is an integer of 3 or larger; and E1 represents hydrogen, halogeno, or a monovalent organic group, provided that when two or more Ar2's, X1's, and Z's are present, then they each may be the same or different and when two or more side chains represented by the formula (2) are present, then they may be the same or different.))
摘要翻译: 含有下述式(1)所示的一种以上的重复单元的芳香族接枝聚合物。 (式中,Ar 1表示具有由下式(2)表示的侧链的π-共轭环状化合物的二价残基,该侧链与包含在二价p 1的环结构中的碳原子键合 由Ar1表示的共轭环化合物残基,并具有sp2杂环轨道:(其中Ar2表示具有π-共轭环状化合物的残基的二价基团; X1表示直接键或选自以下的二价基团: NQ1-,-PQ2-和-BQ3-,其中Q1至Q3各自独立地表示取代基; Z表示直接键或二价连接基团; k表示3以上的整数,E1表示氢,卤素或 一个有机基团,条件是当存在两个或更多个Ar 2,X 1和Z时,它们各自可以相同或不同,并且当存在由式(2)表示的两个或更多个侧链时,则它们可以是 相同或不同)))
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公开(公告)号:US20090045725A1
公开(公告)日:2009-02-19
申请号:US11916464
申请日:2006-06-09
申请人: Daisuke Fukushima , Akihiko Okada , Takeshi Yamada , Kazuei Ohuchi , Hideyuki Higashimura , Nozomi Kogure
发明人: Daisuke Fukushima , Akihiko Okada , Takeshi Yamada , Kazuei Ohuchi , Hideyuki Higashimura , Nozomi Kogure
CPC分类号: H01L51/0035 , C08G61/02 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/104 , C09K2211/1044 , C09K2211/1048 , C09K2211/1051 , C09K2211/1059 , C09K2211/1088 , C09K2211/1092 , C09K2211/1096 , C09K2211/185 , H01L51/0039 , H01L51/5012
摘要: A high-molecular compound, characterized by containing a chain consisting of repeating units represented by the general formula (1) and having an average number of repeating units constituting the chain of 3 or above and a ratio of bonds formed between the head and the tail to all the bonds formed between repeating units of 85% or above: (1) wherein Ar1 is a divalent aromatic group whose aromatic ring is an aromatic hydrocarbon ring; R1 is a substituent on Ar1; n is an integer of 0 to 30; when n is 2 or above, plural R1's may be the same or different from each other, when the carbon atoms of a repeating unit of the general formula (1) are numbered as a divalent group according to Nomenclature of Organic Chemistry by IUPAC, between the two carbon atoms having free valencies, the carbon atom with a smaller number is defined as the head and the carbon atom with a larger number is defined as the tail; and no repeating unit of the general formula (1) has a two-fold axis of symmetry intersecting the straight line joining the head and the tail at right angles at the middle point.
摘要翻译: 一种高分子化合物,其特征在于,含有由通式(1)表示的重复单元构成的链,构成上述3以上链的重复单元的平均数以及头部和尾部之间形成的键的比例 对于85重量%以上的重复单元之间形成的全部键;(1)其中Ar1为芳香环为芳香烃环的二价芳香族基团; R1是Ar1上的取代基; n为0〜30的整数, 当n为2以上时,当通式(1)的重复单元的碳原子根据IUPAC的有机化学命名法被编号为二价基团时,多个R 1可以相同或不同,在 具有自由价的两个碳原子,具有较小数目的碳原子被定义为头部,并且具有较大数量的碳原子被定义为尾部; 并且没有通式(1)的重复单元具有与在中点处以直角连接头部和尾部的直线相交的双重对称轴。
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公开(公告)号:US10392395B2
公开(公告)日:2019-08-27
申请号:US13504820
申请日:2010-10-29
申请人: Nobuyoshi Koshino , Hideyuki Higashimura , Klaus Muellen , Christian von Malotki , Qi Su , Martin Baumgarten , Hassan Norouzi-Arasi , Lena Arnold , Ruili Liu
发明人: Nobuyoshi Koshino , Hideyuki Higashimura , Klaus Muellen , Christian von Malotki , Qi Su , Martin Baumgarten , Hassan Norouzi-Arasi , Lena Arnold , Ruili Liu
IPC分类号: C07D487/22 , B01J31/18 , C07D471/22 , H01M4/90 , H01M8/1007
摘要: To provide nitrogen-containing aromatic compounds with excellent oxygen reduction activity, metal complexes containing them, and catalysts and electrodes employing the same, the present invention provides an aromatic compound satisfying the following conditions (a) and (b): (a) It has 2 or more structures surrounded by at least 4 coordinatable nitrogen atoms (which structures may be the same or different), (b) At least one of the nitrogen atoms composing the structure is a nitrogen atom in a 6-membered nitrogen-containing heterocyclic ring.
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公开(公告)号:US09412487B2
公开(公告)日:2016-08-09
申请号:US13496611
申请日:2010-09-17
CPC分类号: H01B1/22 , B22F1/00 , B22F1/0062 , B22F1/02 , B22F9/00 , B22F9/24 , B22F2001/0092 , B82Y30/00 , C08G73/06 , C08G79/00 , C08G2261/1424 , C08G2261/1432 , C08G2261/148 , C08G2261/3142 , C08G2261/3162 , C08G2261/514 , C08G2261/95 , C08K3/08 , C08L65/00 , H01B1/00
摘要: A silver-(conjugated compound) composite comprising silver particles having a number-average Feret diameter of not more than 1,000 nm, and a conjugated compound having a weight-average molecular weight of not less than 3.0×102 adsorbed to the silver particles. The composite exhibits excellent conductivity and charge injection properties, and excellent dispersibility within non-polar solvents.
摘要翻译: 包含平均Feret直径不大于1000nm的银颗粒的银 - (共轭化合物)复合物和吸附在银颗粒上的重均分子量不小于3.0×102的共轭化合物。 该复合材料具有优异的导电性和电荷注入性能,并且在非极性溶剂中具有优异的分散性。
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公开(公告)号:US09109081B2
公开(公告)日:2015-08-18
申请号:US11816195
申请日:2006-02-15
CPC分类号: C08G61/02 , B01J31/2295 , B01J31/24 , B01J2531/824 , C08G61/10 , C08G2261/312 , C08G2261/3142 , C08G2261/411
摘要: A method for producing an aromatic polymer comprising polycondensing an aromatic compound of the following formula (I) in the presence of a palladium complex containing a phosphine compound of the following formula (II): (wherein, Ar represents an aromatic ring-containing bi-functional organic group. X represents a halogen atom, nitro group or group of the formula —SO3Q (wherein, Q represents an optionally substituted hydrocarbon group). Y represents an oxygen atom, sulfur atom or the like, and n represents 0 or 1. M represents a hydrogen atom, —B(OQ1)2 or the like (Q1 represents a hydrogen atom or hydrocarbon group.) P(R1)3 (II) (wherein, R1 represents a group of the following formula (III) or a group of the following formula (IV) and three R1s may be the same or different, providing at least one of three R1s is a group of the following formula (III)) —C(R2)3 (III) (wherein, R2 represents a hydrogen atom or an optionally substituted hydrocarbon group) (wherein, R3 to R7 represent each independently a hydrogen atom, optionally substituted hydrocarbon group or the like).
摘要翻译: 一种芳香族聚合物的制造方法,其特征在于,在含有下述式(II)的膦化合物的钯络合物的存在下,使下式(I)的芳香族化合物缩聚:(式中,Ar表示含芳环的双 - X表示卤素原子,硝基或式-SO 3 Q基团(其中,Q表示任选取代的烃基),Y表示氧原子,硫原子等,n表示0或1。 M表示氢原子,-B(OQ1)2等(Q1表示氢原子或烃基)P(R1)3(Ⅱ)(式中,R1表示下式(III)的基团或 -C(R2)3(III)(其中,R2表示(R))表示的基团,可以相同或不同,提供三个R 1中的至少一个为下式(III) 氢原子或任选取代的烃基)(其中,R3至R 7独立地表示氢原子,任选取代的烃基等)。
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公开(公告)号:US20120270141A1
公开(公告)日:2012-10-25
申请号:US13504820
申请日:2010-10-29
申请人: Nobuyoshi Koshino , Hideyuki Higashimura , Klaus Muellen , Christian von Malotki , Qi Su , Martin Baumgarten , Hassan Norouzi-Arasi , Lena Arnold , Ruili Liu
发明人: Nobuyoshi Koshino , Hideyuki Higashimura , Klaus Muellen , Christian von Malotki , Qi Su , Martin Baumgarten , Hassan Norouzi-Arasi , Lena Arnold , Ruili Liu
IPC分类号: C07D487/14 , C07F15/06 , C07F15/02 , C07F13/00 , H01M8/10 , C07D471/04 , C07F7/10 , B01J31/02 , B01J31/06 , B01J31/12 , C07D487/22 , C07D471/22
CPC分类号: C07D487/22 , B01J31/183 , B01J2231/62 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07D471/22 , H01M4/9008 , H01M8/1007
摘要: To provide nitrogen-containing aromatic compounds with excellent oxygen reduction activity, metal complexes containing them, and catalysts and electrodes employing the same, the present invention provides an aromatic compound satisfying the following conditions (a) and (b): (a) It has 2 or more structures surrounded by at least 4 coordinatable nitrogen atoms (which structures may be the same or different), (b) At least one of the nitrogen atoms composing the structure is a nitrogen atom in a 6-membered nitrogen-containing heterocyclic ring.
摘要翻译: 为了提供具有优异的氧还原活性的含氮芳香族化合物,含有它们的金属络合物和使用它们的催化剂和电极,本发明提供了满足以下条件(a)和(b)的芳族化合物:(a) 由至少4个可配位的氮原子(其结构可以相同或不同)包围的2个或更多个结构,(b)构成该结构的至少一个氮原子是6元含氮杂环中的氮原子 。
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