Transparent substrate and method of manufacturing the same
    51.
    发明授权
    Transparent substrate and method of manufacturing the same 失效
    透明基材及其制造方法

    公开(公告)号:US06521334B1

    公开(公告)日:2003-02-18

    申请号:US09570264

    申请日:2000-05-12

    IPC分类号: B32B700

    摘要: At least one monomolecule film is formed on a transparent substrate surface directly or via a protective film. The monomolecule film is formed with chemical coupling of chlorosilane surface active compound, for example, of the formula: F(CF2)m(CH2)nSiRqX3−q where m is an integer of from 1 to 15, n is an integer of from 0 to 15 provided that the total of m and n is an integer of from 10 to 30 and R is an alkyl or an alkoxyl group, or F(CF2)m′(CH2)n′A(CH2)pSiRqX3−q where m represents an integer ranging from 1 to 8, n′ represents an integer ranging from 0 to 2, p represents an integer ranging from 5 to 25, q represents an integer ranging from 0 to 2, X represents a halogen atom or an alkoxyl group, R represents an alkyl or an alkoxyl group, and A represents O, a —COO— or —Si(CH3)2—. The transparent substrate such as glass is made hydrophobic and free of contamination.

    摘要翻译: 至少一个单分子膜直接或通过保护膜形成在透明基板表面上。 单分子膜由氯硅烷表面活性化合物的化学偶合形成,例如下式:其中m为1至15的整数,n为0至15的整数,条件是m和n的总和为 10〜30的整数,R为烷基或烷氧基,m表示1〜8的整数,n'表示0〜2的整数,p表示5〜25的整数,q表示 表示0〜2的整数,X表示卤素原子或烷氧基,R表示烷基或烷氧基,A表示O,-COO-或-Si(CH 3)2 - 。 透明基板如玻璃被制成疏水性并且没有污染。

    Chemically adsorbed film and method of manufacturing the same

    公开(公告)号:US06410152B1

    公开(公告)日:2002-06-25

    申请号:US09892530

    申请日:2001-06-28

    IPC分类号: B32B904

    摘要: A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

    Latent image, preparation and development thereof and articles with the
image
    54.
    发明授权
    Latent image, preparation and development thereof and articles with the image 失效
    潜在的形象,准备和发展以及形象的文章

    公开(公告)号:US5906871A

    公开(公告)日:1999-05-25

    申请号:US645773

    申请日:1996-05-14

    IPC分类号: B41M3/00 B44F1/02

    摘要: A latent image comprising a first substance formed on a substrate of a second substance having a surface tension different from a surface tension of the first substance, the first substance and the substrate having a difference of 0.1 to 100 nm in height from each other. The latent image is formed by a method comprising the-step of subjecting a substrate of a first substance to a chemical treatment or a physical treatment to form a surface of a second substance which has a surface tension different from a surface tension of the first substance and has a difference of 0.1 to 100 nm in height from the substrate on part of the substrate. The latent image is developed by a method comprising the steps of contacting a latent image comprising a first substance formed on a substrate of a second substance having a surface tension different from a surface tension of the first substance with a third substance different from the first substance and the second substance, and applying a developing ray to the latent image.

    摘要翻译: 一种潜像,其包括形成在第二物质的基底上的第一物质,所述第二物质的表面张力不同于所述第一物质的表面张力,所述第一物质和所述基底的高度彼此的差异为0.1〜100nm。 该潜像通过包括以下步骤的方法形成:将第一物质的基材进行化学处理或物理处理以形成具有与第一物质的表面张力不同的表面张力的第二物质的表面的方法 并且在基板的一部分上与基板的高度差为0.1〜100nm。 通过包括以下步骤的方法显影潜像:将形成在第一物质的表面张力不同于第一物质的第二物质的基板上形成的第一物质的潜像与不同于第一物质的第三物质 和第二物质,并将显影射线施加到潜像上。

    Self lubricating device
    55.
    发明授权
    Self lubricating device 失效
    自润滑装置

    公开(公告)号:US5876801A

    公开(公告)日:1999-03-02

    申请号:US936024

    申请日:1997-09-23

    摘要: A chemically adsorbed film having a surface layer containing fluorine groups and a stem layer chemically bonded by siloxane bonds to a substrate is formed on the surface of a frictional portion of a machine part such as a gear or a bearing or on the surface of a game ball. An excellently self-lubricating low frictional resistance machine part or game ball thus can be obtained. A frictional portion of a gear or the like, made of SiO.sub.2 or like ceramic material, is dipped and held in a solution containing a surface active material, e.g., CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 dissolved in a non-aqueous solvent. A hydrochloric acid removal reaction is brought about between SiCl groups of the material, which contains a fluorocarbon and a chlorosilane group, and hydroxyl groups numerously present on the SiO2 surface, thus forming bonds ofCF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si (O--).sub.3over the entire frictional portion surface. A fluorine-containing monomolecular film thus is formed, which is chemically bonded to the substrate and has a thickness of about 1.5 nm.

    摘要翻译: 在机械部件例如齿轮或轴承的摩擦部分的表面上或游戏表面上形成具有含氟基团的表面层和通过硅氧烷键合到基材上的茎层的化学吸附膜 球。 因此可以获得优异的自润滑低摩擦阻力机器部件或游戏球。 将由SiO 2或类似陶瓷材料制成的齿轮等的摩擦部分浸渍并保持在含有溶解在非水溶剂中的表面活性物质例如CF 3(CF 2)7(CH 2)2 ClCl 3)的溶液中。 在含有碳氟化合物和氯硅烷的材料的SiCl基团和SiO 2表面上大量存在的羟基之间产生盐酸去除反应,从而形成CF 3(CF 2)7(CH 2)2 Si(O- )3在整个摩擦部分表面上。 因此,形成与基板化学键合并且具有约1.5nm的厚度的含氟单分子膜。

    Self-lubricating device
    56.
    发明授权
    Self-lubricating device 失效
    自润滑装置

    公开(公告)号:US5836827A

    公开(公告)日:1998-11-17

    申请号:US935551

    申请日:1997-09-23

    摘要: A chemically adsorbed film having a surface layer containing fluorine groups and a stem layer chemically bonded by siloxane bonds to a substrate is formed on the surface of a frictional portion of a machine part such as a gear or a bearing or on the surface of a game ball. An excellently self-lubricating low frictional resistance machine part or game ball thus can be obtained. A frictional portion of a gear or the like, made of SiO.sub.2 or like ceramic material, is dipped and held in a solution containing a surface active material, e.g., CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 dissolved in a non-aqueous solvent. A hydrochloric acid removal reaction is brought about between SiCl groups of the material, which contains a fluorocarbon and a chlorosilane group, and hydroxyl groups numerously present on the SiO.sub.2 surface, thus forming bonds of CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si (O--).sub.3 over the entire frictional portion surface. A fluorine-containing monomolecular film thus is formed, which is chemically bonded to the substrate and has a thickness of about 1.5 nm.

    摘要翻译: 在机械部件例如齿轮或轴承的摩擦部分的表面上或游戏表面上形成具有含氟基团的表面层和通过硅氧烷键合到基材上的茎层的化学吸附膜 球。 因此可以获得优异的自润滑低摩擦阻力机器部件或游戏球。 将由SiO 2或类似陶瓷材料制成的齿轮等的摩擦部分浸渍并保持在含有溶解在非水溶剂中的表面活性物质例如CF 3(CF 2)7(CH 2)2 SiCl 3)的溶液中 。 在含有碳氟化合物和氯硅烷的材料的SiCl基团和SiO 2表面上大量存在的羟基之间产生盐酸去除反应,从而形成CF 3(CF 2)7(CH 2)2 Si(O - )3在整个摩擦部分表面上。 因此,形成与基板化学键合并且具有约1.5nm的厚度的含氟单分子膜。

    Self-lubricating device
    57.
    发明授权
    Self-lubricating device 失效
    自润滑装置

    公开(公告)号:US5731077A

    公开(公告)日:1998-03-24

    申请号:US458703

    申请日:1995-06-02

    摘要: A chemically adsorbed film having a surface layer containing fluorine groups and a stem layer chemically bonded by siloxane bonds to a substrate is formed on the surface of a frictional portion of a machine part such as a gear or a bearing or on the surface of a game ball. An excellently self-lubricating low frictional resistance machine part or game ball thus can be obtained. A frictional portion of a gear or the like, made of SiO.sub.2 or like ceramic material, is dipped and held in a solution containing a surface active material, e.g., CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 dissolved in a non-aqueous solvent. A hydrochloric acid removal reaction is brought about between SiCl groups of the material, which contains a fluorocarbon and a chlorosilane group, and hydroxyl groups numerously present on the SiO2 surface, thus forming bonds of CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si(O--).sub.3 over the entire frictional portion surface. A fluorine-containing monomolecular film thus is formed, which is chemically bonded to the substrate and has a thickness of about 1.5 nm.

    摘要翻译: 在机械部件例如齿轮或轴承的摩擦部分的表面上或游戏表面上形成具有含氟基团的表面层和通过硅氧烷键合到基材上的茎层的化学吸附膜 球。 因此可以获得优异的自润滑低摩擦阻力机器部件或游戏球。 将由SiO 2或类似陶瓷材料制成的齿轮等的摩擦部分浸渍并保持在含有溶解在非水溶剂中的表面活性物质例如CF 3(CF 2)7(CH 2)2 ClCl 3)的溶液中。 在含有碳氟化合物和氯硅烷的材料的SiCl基团和SiO 2表面上大量存在的羟基之间产生盐酸去除反应,从而形成CF 3(CF 2)7(CH 2)2 Si(O - ) 在整个摩擦部分表面上。 因此,形成与基板化学键合并且具有约1.5nm的厚度的含氟单分子膜。

    Method of producing an organic device
    58.
    发明授权
    Method of producing an organic device 失效
    生产有机装置的方法

    公开(公告)号:US5681442A

    公开(公告)日:1997-10-28

    申请号:US565636

    申请日:1995-11-29

    摘要: A process for producing an organic device includes forming a first electrode and a second electrode on a substrate having an insulating film formed on a surface thereof, etching out the insulating film with the first electrode and the second electrode being used as masks, forming a monomolecular or built-up monomolecular film containing electrolytically polymerizable unsaturated groups directly or indirectly on the surface of the substrate by a chemical absorption method or the Langmuir-Blodgett method. The process further includes a procedure of spreading a surfactant containing the electrolytically polymerizable unsaturated groups on the surface of a water bath to form a monomolecular film, transferring at least one layer of the monomolecular film into the surface of the substrate, and chemically bonding molecules of the surfactant to form at least one layer of the monomolecular film of the surfactant containing electroconductive conjugated groups, applying a voltage between the first electrode and the second electrode to polymerize the electrolytically polymerizable unsaturated groups, and deriving a third electrode from the substrate such that the substrate acts as the third electrode.

    摘要翻译: 一种制造有机器件的方法包括:在其表面上形成有绝缘膜的基板上形成第一电极和第二电极,用第一电极和第二电极作为掩模蚀刻绝缘膜,形成单分子 或通过化学吸收法或Langmuir-Blodgett法直接或间接地在基材表面上含有电解聚合性不饱和基团的单分子膜。 该方法还包括将含有电解可聚合不饱和基团的表面活性剂扩散到水浴表面以形成单分子膜,将至少一层单分子膜转移到基材表面的方法,以及化学键合 所述表面活性剂形成至少一层含有导电共轭基团的表面活性剂的单分子膜,在所述第一电极和所述第二电极之间施加电压以聚合所述电解聚合的不饱和基团,并从所述基板导出第三电极, 衬底作为第三电极。

    Medical member and method of manufacturing the same
    59.
    发明授权
    Medical member and method of manufacturing the same 失效
    医疗会员及其制造方法

    公开(公告)号:US5578340A

    公开(公告)日:1996-11-26

    申请号:US485787

    申请日:1995-06-07

    摘要: A medical member having active hydrogen groups such as hydroxyl, amino or imino groups at its surface, is dipped, either directly or after formation of an inner layer on its surface, into a solution. The solution is prepared by dissolving a surface active material, e.g., CF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 SiCl.sub.3 in a non-aqueous solvent. A dehydrochlorination reaction is brought about between active hydrogen groups at the surface of the member and SiCl groups of the surface active material, thus producing bonds ofCF.sub.3 (CF.sub.2).sub.7 (CH.sub.2).sub.2 Si(O--).sub.3over the entire surface. A fluorine-containing monomolecular film is formed, which is chemically (or covalently) bonded to the member surface and has a thickness at the nanometer level. Since the chemically adsorbed film is covalently bonded to the member or inner layer, it is chemically stable and difficult to separate. Medical members can be obtained when the invention is applied to an artificial tooth, a joint, a bone, a blood bag, a catheter, a blood transportation tool, a dialysis equipment part, an operation thread, a medical implant and an operation tool.

    摘要翻译: 在其表面具有羟基,氨基或亚氨基的活性氢基团的医学成分在其表面上直接或内层形成后溶解成溶液。 通过将表面活性物质例如CF 3(CF 2)7(CH 2)2 ClCl 3溶解在非水溶剂中来制备溶液。 在成员表面的活性氢基团和表面活性材料的SiCl基团之间产生脱氯化氢反应,从而在整个表面上产生CF 3(CF 2)7(CH 2)2 Si(O-)3的键。 形成化学(或共价)结合到构件表面并具有纳米级厚度的含氟单分子膜。 由于化学吸附的膜共价结合到构件或内层,因此化学稳定且难以分离。 当将本发明应用于人造牙齿,关节,骨骼,血袋,导管,血液输送工具,透析设备部件,手术线,医疗植入物和操作工具时,可获得医疗部件。