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    Butadiene/sytrene block copolymers having an asymmetric structure, their preparation and their use as molding materials
    52.
    发明授权
    Butadiene/sytrene block copolymers having an asymmetric structure, their preparation and their use as molding materials 失效
    具有不对称结构的丁二烯/ sytrene嵌段共聚物，其制备及其作为模塑材料的用途

    公开(公告)号：US4891410A

    公开(公告)日：1990-01-02

    申请号：US184068

    申请日：1988-04-20

    申请人： Klaus Bronstert ,  Daniel Wagner ,  Horst Schuch

    发明人： Klaus Bronstert ,  Daniel Wagner ,  Horst Schuch

    IPC分类号： C08F297/04

    CPC分类号： C08F297/04

    摘要： In block copolymers of the general formula A--B--A' which have a molecular weight of less than 300,000 and consist of from 18 to 40% by weight of a vinylaromatic hydrocarbon and from 60 to 82% by weight of one or more partially or completely hydrogenated hydrocarbons and in which A and A' are each a polymer block of a vinylaromatic hydrocarbon and B is a polymer block of a diene hydrocarbon, the weight ratio of the polymer blocks A to A' is less than or equal to 1:5 and greater than 1:10 and the mean molecular weight of polymer block A is from 2,000 to 20,000 and that of the polymer block A' is from 10,000 to 110,000 and the molecular weight of the B block is not less than 18,000. The block copolymers are prepared by a process in which, in a first polymerization stage, the vinylaromatic hydrocarbon is completely polymerized to form the A or A' block, in the second polymerization stage the diene hydrocarbon is completely converted to form the B block and thereafter the second portion of the vinylaromatic hydrocarbon is polymerized on to form the A or A' block, the portion of a vinylaromatic compound for the preparation of the A' block being not less than five times, and not more than 10 times, the weight used to form the A block. The block copolymers are used for the preparation of molding materials.

    摘要翻译： 通式ABA'的嵌段共聚物，其分子量小于300,000，由18至40重量％的乙烯基芳族烃和60至82重量％的一种或多种部分或完全氢化的烃和 其中A和A'各自为乙烯基芳族烃的聚合物嵌段，B为二烯烃的聚合物嵌段，聚合物嵌段A与A'的重量比小于或等于1:5且大于1 10，聚合物嵌段A的平均分子量为2,000〜20,000，聚合物嵌段A'的平均分子量为10,000〜110,000，B嵌段的分子量为18000以上。 嵌段共聚物通过以下方法制备，其中在第一聚合阶段，乙烯基芳族烃完全聚合以形成A或A'嵌段，在第二聚合阶段中，二烯烃完全转化成B嵌段，此后 将乙烯基芳族烃的第二部分聚合形成A或A'嵌段，用于制备A'嵌段的乙烯基芳族化合物部分不小于所用重量的5倍，而不超过10倍 形成A块。 嵌段共聚物用于制备模塑材料。

    Preparation of polyfunctional initiators for anionic polymerization, oligomeric polyfunctional initiators, use of the resulting polymers for the preparation of unfunctionalized or functionalized polymers and as prepolymers for other resins
    53.
    发明授权
    Preparation of polyfunctional initiators for anionic polymerization, oligomeric polyfunctional initiators, use of the resulting polymers for the preparation of unfunctionalized or functionalized polymers and as prepolymers for other resins 失效
    用于阴离子聚合的多官能引发剂的制备，低聚多官能引发剂，所得聚合物用于制备未官能化或官能化聚合物以及用作其它树脂的预聚物

    公开(公告)号：US4822530A

    公开(公告)日：1989-04-18

    申请号：US176680

    申请日：1988-04-01

    申请人： Klaus Bronstert ,  Siegbert Bohnet

    发明人： Klaus Bronstert ,  Siegbert Bohnet

    IPC分类号： C07F1/02 ,  C08C19/44 ,  C08F2/38 ,  C08F4/00 ,  C08F4/42 ,  C08F4/48 ,  C08F8/00 ,  C08F12/00 ,  C08F36/00 ,  C08F36/04 ,  C08F297/04

    CPC分类号： C08F297/04 ,  C07F1/02 ,  C08F36/04

    摘要： Oligomeric polyfunctional initiators for anionic polymerization of dienes and/or alkenylaromatics are prepared by a process in which a mixture of dialkenylaromatics and alkenylaromatics in a molar ratio of from 1:4 to 1:100, in an inert solvent, is run, at from 25.degree. to 100.degree. C., continuously or in small portions, with thorough mixing, into an initially taken mixture which contains from 1.2 to 3.0 molar equivalents, based on the dialkenylaromatics, of one or more organolithium compounds and an inert solvent, and is polymerized completely. The resulting oligomeric initiators are used for the preparation of unfunctionalized or functionalized polymers or block copolymers from dienes and/or alkenylaromatics, and the functionalized polymers thus prepared are used as prepolymers for other resins.

    摘要翻译： 用于二烯和/或链烯基芳族化合物阴离子聚合的低聚多官能引发剂通过以下方法制备：其中惰性溶剂中摩尔比为1:4至1:100的二烯基芳烃和链烯基芳烃的混合物在25℃ DEG至100℃，连续或少量，充分混合，形成初始混合物，该混合物含有基于二烯基芳烃的1.2至3.0摩尔当量的一种或多种有机锂化合物和惰性溶剂，并且被聚合 完全 所得的低聚引发剂用于从二烯和/或链烯基芳族化合物制备未官能化或官能化的聚合物或嵌段共聚物，并且由此制备的官能化聚合物用作其它树脂的预聚物。

    Polymers containing amino groups, and their preparation
    54.
    发明授权
    Polymers containing amino groups, and their preparation 失效
    含有氨基的聚合物及其制备方法

    公开(公告)号：US4753991A

    公开(公告)日：1988-06-28

    申请号：US889372

    申请日：1986-07-25

    申请人： Klaus Bronstert

    发明人： Klaus Bronstert

    IPC分类号： C08F8/00 ,  C08C19/44 ,  C08F8/12 ,  C08F8/30 ,  C08F8/42 ,  C08F8/32

    CPC分类号： C08F8/30 ,  C08C19/44 ,  C08F8/42

    摘要： Homopolymers, copolymers and/or block copolymers which are obtained from vinylaromatics and/or dienes, are modified with functional amino groups and contain functional groups of the formula (I) or (II) ##STR1## where N is nitrogen, R.sup.1 and R.sup.2 are each alkyl or aryl, A is an unsubstituted or substituted one-membered carbon bridge, Me is an alkali metal and B is a 2-membered to 12-membered carbon bridge in which at least the members adjacent to the nitrogen atoms consists of --C(R.sup.3,R.sup.4) radicals, where R.sup.3 and R.sup.4 can be identical or different and are each hydrogen, alkyl, cycloalkyl or aryl, and the more remote members can be not only --C(R.sup.3 R.sup.4) radicals but also ether or N-alkyl- or N-arylimino groups, a process for the preparation of the polymers from the corresponding living anionically polymerized polymers, or polymers metallized with an alkali metal, and the coresponding hydrazine derivatives, and the use of the polymers for the preparation of similar polymers possessing functional groups of the general formula (V) or (VI) ##STR2## by reaction with an equivalent amount of water, or of similar polymers possessing the functional groups of the general formula (VII) or (VIII) ##STR3## by reaction with an excess of water.

    摘要翻译： 由乙烯基芳烃和/或二烯获得的均聚物，共聚物和/或嵌段共聚物用官能氨基修饰，并含有式（I）或（II）的官能团。 ）其中N是氮，R 1和R 2各自是烷基或芳基，A是未取代或取代的一元碳桥，Me是碱金属，B是2元至12元碳桥，其中至少 与氮原子相邻的成员由-C（R 3，R 4）基团组成，其中R 3和R 4可以相同或不同，并且各自为氢，烷基，环烷基或芳基，较远的成员不仅可以是-C（R 3 R 4） ）基团，还有醚或N-烷基 - 或N-芳基亚氨基，用于由相应的活性阴离子聚合聚合物或用碱金属金属化的聚合物制备聚合物的方法和相应的肼衍生物，以及使用 用于制备类似聚合物的聚合物具有 通过与等量的水或具有通式（VII）的官能团的类似聚合物反应，通式（V）或（VI）的化合物（V）或（VI） ）或（VIII）通过与过量的水反应制备（VII）或（VIII）或（VIII）化合物。

    Continuous preparation of isobutylene polymers
    55.
    发明授权
    Continuous preparation of isobutylene polymers 失效
    连续制备异丁烯聚合物

    公开(公告)号：US4558104A

    公开(公告)日：1985-12-10

    申请号：US566292

    申请日：1983-12-28

    申请人： Klaus Bronstert ,  Johann Nickl ,  Hans-Joachim Krause ,  Werner Schmitt

    发明人： Klaus Bronstert ,  Johann Nickl ,  Hans-Joachim Krause ,  Werner Schmitt

    IPC分类号： C08F2/00 ,  C08F2/04 ,  C08F2/06 ,  C08F8/00 ,  C08F10/10

    CPC分类号： C08F10/10

    摘要： Isobutylene polymers are prepared continuously, in aliphatic C.sub.3 -C.sub.6 -hydrocarbons in the presence of soluble cationic polymerization initiators and coinitiators at from -40.degree. to 40.degree. C. and under from 0.01 to 10 bar, and the solvents and monomers vaporized during the polymerization are recycled, by a process in which the liquid stream of the monomer solution, containing 40-95, in particular 50-85, percent by weight of the monomers, the liquid streams of the recycle and of the coinitiator solution and the separate stream of the initiator solution are combined in a first zone containing the polymerization zone, and the resulting polymer solution is taken off continuously through a second zone vertically below the first zone. The liquid streams of the monomer solution, the coinitiator solution and the recycle can furthermore be fed into the first zone separately from one another.

    摘要翻译： 在可溶性阳离子聚合引发剂和共引发剂存在下，在-40℃至40℃，0.01至10巴条件下，在脂族C 3 -C 6烃中连续制备异丁烯聚合物，溶剂和单体在聚合过程中蒸发 通过一种方法回收，其中单体溶液的液体流包含40-95，特别是50-85重量％的单体，再循环液和共引发剂溶液的液体流和单体流 引发剂溶液在包含聚合区的第一区域中组合，并且所得聚合物溶液通过垂直于第一区域下方的第二区域连续取出。 单体溶液，共引发剂溶液和再循环的液体流可以进一步彼此分开地进料到第一区域中。

    Manufacture of homopolymers and copolymers of .alpha.-monoolefins
    57.
    发明授权
    Manufacture of homopolymers and copolymers of .alpha.-monoolefins 失效
    制造α-单烯烃的均聚物和共聚物

    公开(公告)号：US4208497A

    公开(公告)日：1980-06-17

    申请号：US883218

    申请日：1978-03-03

    申请人： Klaus Bronstert ,  Peter Klaerner ,  Gerhard Staiger

    发明人： Klaus Bronstert ,  Peter Klaerner ,  Gerhard Staiger

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F4/66 ,  C08F10/06

    CPC分类号： C08F10/00

    摘要： A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers at relatively low temperatures under relatively low pressures by means of a Ziegler-Natta catalyst comprising (I) a titanium trichloride component and (II) an aluminum-alkyl component, wherein the titanium trichloride component (I) employed is obtained by exposing a conventional catalyst component consisting, or substantially consisting, of titanium trichloride, to a carbon monoxide atmosphere under specific conditions. Catalysts obtained from titanium trichloride components (I) which have been treated in this way exhibit a relatively long induction period.

    摘要翻译： 通过齐格勒 - 纳塔催化剂在相对较低的温度下在相对较低的温度下聚合单体或单体来制备α-单烯烃的均聚物和共聚物的方法，该齐格勒 - 纳塔催化剂包含（I）三氯化钛组分和（II） 烷基组分，其中所用的三氯化钛组分（I）通过将由三氯化钛组成或基本上由三氯化钛组成的常规催化剂组分暴露于特定条件下的一氧化碳气氛下获得。 以这种方式处理的三氯化钛组分（I）获得的催化剂表现出较长的诱导期。

    Manufacture of homopolymers and copolymers of .alpha.-monoolefins
    58.
    发明授权
    Manufacture of homopolymers and copolymers of .alpha.-monoolefins 失效
    制造α-单烯烃的均聚物和共聚物

    公开(公告)号：US4189557A

    公开(公告)日：1980-02-19

    申请号：US901195

    申请日：1978-04-28

    申请人： Peter Klaerner ,  Klaus Bronstert ,  Gerhard Staiger

    发明人： Peter Klaerner ,  Klaus Bronstert ,  Gerhard Staiger

    IPC分类号： C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00 ,  Y10S526/903 ,  Y10S526/906 ,  Y10S526/907

    摘要： A process for the manufacture of homopolymers and copolymers of .alpha.-monoolefins by polymerizing the monomer or monomers by means of a Ziegler-Natta catalyst comprising (I) a titanium trichloride component and (II) an aluminum-alkyl component, wherein the titanium trichloride component (I) employed is obtained by (1) in a first stage moistening a suitable conventional catalyst component, consisting entirely or substantially of titanium trichloride, with a hydrocarbon mixture comprising a liquid alkane hydrocarbon and a liquid benzene hydrocarbon and (2) in a second stage drying the catalyst component, moistened with the hydrocarbon mixture, under an inert gas, with constant mechanical mixing, within a certain period, at a temperature which is from 5.degree. to 50.degree. C. above the boiling point of the highest-boiling hydrocarbon present in the hydrocarbon mixture which has been used to moisten the component. Homopolymers and copolymers having particularly advantageous morphological properties can be manufactured by the process of the invention.

    摘要翻译： 通过包含（I）三氯化钛组分和（II）铝 - 烷基组分的齐格勒 - 纳塔催化剂聚合单体或单体来制造α-单烯烃的均聚物和共聚物的方法，其中三氯化钛组分 （I）通过（1）在第一阶段中润湿合适的常规催化剂组分（其完全或基本上由三氯化钛组成）与包含液体烷烃和液体苯烃的烃混合物和（2）在第二阶段 在一定时间内，在高沸点烃的沸点以上5℃至50℃的温度下，在惰性气体下，以不断的机械混合的状态下，将烃类混合物润湿的催化剂组分进行阶段干燥 存在于用于润湿组分的烃混合物中。 可以通过本发明的方法制造具有特别有利的形态特征的均聚物和共聚物。