公开(公告)号：US07261954B2

公开(公告)日：2007-08-28

申请号：US11353338

申请日：2006-02-13

Applicant: Mark E. Thompson ,  Xiaofan Ren ,  Vadim Adamovich ,  Steven R Cordero ,  Brian Wendell D'Andrade ,  Bert Alleyne ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Xiaofan Ren ,  Vadim Adamovich ,  Steven R Cordero ,  Brian Wendell D'Andrade ,  Bert Alleyne ,  Stephen R. Forrest

IPC: H01L51/54 ,  H05B33/12

CPC classification number: H01L51/5096 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0037 ,  H01L51/005 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0077 ,  H01L51/0079 ,  H01L51/0081 ,  H01L51/0082 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/5016 ,  H01L51/5048 ,  Y10S428/917 ,  Y10T428/24942

Abstract: Light emitting devices having blocking layers comprising one or more metal complexes are provided. The blocking layers may serve to block electrons, holes, and/or excitons. Preferably, the devices further comprise a separate emissive layer in which charge and/or excitons are confined. Metal complexes suitable for blocking layers can be selected by comparison of HOMO and LUMO energy levels of materials comprising adjacent layers in devices of the present invention.

Abstract translation: 提供具有包含一种或多种金属络合物的阻挡层的发光器件。 阻挡层可用于阻挡电子，空穴和/或激子。 优选地，所述器件还包括单独的发射层，其中电荷和/或激子被限制在其中。 可以通过比较本发明的装置中包含相邻层的材料的HOMO和LUMO能级来选择适合于阻挡层的金属络合物。

公开(公告)号：US07230269B2

公开(公告)日：2007-06-12

申请号：US11150143

申请日：2005-06-13

Applicant: Barry P. Rand ,  Stephen R. Forrest ,  Mark E. Thompson

Inventor： Barry P. Rand ,  Stephen R. Forrest ,  Mark E. Thompson

IPC: H01L29/08 ,  H01L21/00 ,  H01L51/40

CPC classification number: B82Y10/00 ,  H01L51/0046 ,  H01L51/0062 ,  H01L51/0078 ,  H01L51/0086 ,  H01L51/4246 ,  H01L2251/308 ,  Y02E10/549

Abstract: A photosensitive cell includes an anode and a cathode; a donor-type organic material and an acceptor-type organic material forming a donor-acceptor junction connected between the anode and the cathode; and an exciton blocking layer connected between the acceptor-type organic material of the donor-acceptor junction and the cathode, the blocking layer consisting essentially of a material that has a hole mobility of at least 10−7 cm2/V-sec or higher, where a HOMO of the blocking layer is higher than or equal to a HOMO of the acceptor-type material.

Abstract translation: 光敏电池包括阳极和阴极; 供体型有机材料和形成连接在阳极和阴极之间的供体 - 受体结的受主型有机材料; 以及连接在供体 - 受体结的受主型有机材料和阴极之间的激子阻挡层，该阻挡层基本上由具有至少10 -7 cm的空穴迁移率的材料组成 2秒/ V秒以上，其中阻挡层的HOMO高于或等于受主型材料的HOMO。

公开(公告)号：US07009338B2

公开(公告)日：2006-03-07

申请号：US10144419

申请日：2002-05-13

Applicant: Brian D'Andrade ,  Mark E. Thompson ,  Stephen R. Forrest

Inventor： Brian D'Andrade ,  Mark E. Thompson ,  Stephen R. Forrest

IPC: H05B33/14 ,  H05B33/00

CPC classification number: C09K11/06 ,  C09K2211/1029 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/5016 ,  H01L51/5036 ,  H01L51/5088 ,  H01L51/5096 ,  Y10S428/917 ,  Y10T428/24942

Abstract: The present invention relates to efficient organic light emitting devices (OLEDs) doped with multiple light-emitting dopants, at least one dopant comprising a phosphorescent emitter, in a thin film emissive layer or layers. The present invention is directed to an efficient phosphorescent organic light emitting device utilizing a plurality of emissive dopants in an emissive region, wherein at least one of the dopants is a phosphorescent material. Thus, the present invention provides an organic light emitting device comprising an emissive region, wherein the emissive region comprises a host material, and a plurality of emissive dopants, wherein the emissive region is comprised of a plurality of bands and each emissive dopant is doped into a separate band within the emissive region, and wherein at least one of the emissive dopants emits light by phosphorescence.

Abstract translation: 本发明涉及掺杂有多个发光掺杂剂的有效的有机发光器件（OLED），至少一种包含磷光发射体的掺杂剂在薄膜发射层或多层中。 本发明涉及在发射区域中利用多个发射掺杂剂的有效磷光有机发光器件，其中至少一种掺杂剂是磷光材料。 因此，本发明提供了一种包括发射区域的有机发光器件，其中发射区域包括主体材料和多个发射掺杂剂，其中发射区域由多个带组成，并且每个发光掺杂剂被掺杂到 发射区域内的单独的带，并且其中至少一个发射掺杂剂通过磷光发光。

公开(公告)号：US06939624B2

公开(公告)日：2005-09-06

申请号：US09978455

申请日：2001-10-16

Applicant: Sergey Lamansky ,  Mark E. Thompson ,  Vadim Adamovich ,  Peter I. Djurovich ,  Chihaya Adachi ,  Marc A. Baldo ,  Stephen R. Forrest ,  Raymond Kwong

Inventor： Sergey Lamansky ,  Mark E. Thompson ,  Vadim Adamovich ,  Peter I. Djurovich ,  Chihaya Adachi ,  Marc A. Baldo ,  Stephen R. Forrest ,  Raymond Kwong

IPC: C07F15/00 ,  C09K11/06 ,  H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H05B33/14

CPC classification number: C09K11/06 ,  C07F15/0033 ,  C07F15/0086 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1092 ,  C09K2211/185 ,  H01L51/0084 ,  H01L51/0085 ,  H01L51/0087 ,  H01L51/5016 ,  H05B33/14 ,  Y10S428/917

Abstract: Emissive phosphorescent organometallic compounds are described that produce improved electroluminescence, particularly in the blue region of the visible spectrum. Organic light emitting devices employing such emissive phosphorescent organometallic compounds are also described. Also described is an organic light emitting layer including a host material having a lowest triplet excited state having a decay rate of less than about 1 per second; a guest material dispersed in the host material, the guest material having a lowest triplet excited state having a radiative decay rate of greater than about 1×105 or about 1×106 per second and wherein the energy level of the lowest triplet excited state of the host material is lower than the energy level of the lowest triplet excited state of the guest material.

公开(公告)号：US06333521B1

公开(公告)日：2001-12-25

申请号：US09610454

申请日：2000-07-05

Applicant: Mark E. Thompson ,  Loy Douglas ,  Diarmuid O'Brien ,  Bryan E. Koene ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Loy Douglas ,  Diarmuid O'Brien ,  Bryan E. Koene ,  Stephen R. Forrest

IPC: H01L2715

CPC classification number: H01L51/5048 ,  C07D487/22 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1074 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0053 ,  H01L51/0059 ,  H01L51/0072 ,  H01L51/0077 ,  H01L51/0078 ,  H01L51/0079 ,  H01L51/5012 ,  H01L51/5016 ,  H01L2251/5323 ,  H05B33/28 ,  Y10S428/917

Abstract: The present invention is directed to organic light emitting devices comprising a heterostructure for producing electroluminescence having a hole transporting layer with a glass structure. The hole transporting layer comprises a compound having a symmetric molecular structure. The end groups of the symmetric molecule are hole transporting amine moieties having an unsaturated linkage between two arenes.

Abstract translation: 本发明涉及包含用于产生具有玻璃结构的空穴传输层的电致发光的异质结构的有机发光器件。 空穴传输层包含具有对称分子结构的化合物。 对称分子的端基是在两个芳烃之间具有不饱和键的空穴传输胺部分。

公开(公告)号：US06303238B1

公开(公告)日：2001-10-16

申请号：US08980986

申请日：1997-12-01

Applicant: Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Yujian You ,  Andrei Shoustikov ,  Scott Sibley ,  Paul E. Burrows ,  Stephen R. Forrest

IPC: H05B3314

CPC classification number: H01L51/0084 ,  C07D487/22 ,  C09K11/06 ,  C09K2211/10 ,  C09K2211/1003 ,  C09K2211/1007 ,  C09K2211/1018 ,  C09K2211/1029 ,  C09K2211/1033 ,  C09K2211/1074 ,  C09K2211/18 ,  C09K2211/185 ,  C09K2211/186 ,  H01L51/0053 ,  H01L51/0067 ,  H01L51/0077 ,  H01L51/0081 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5221 ,  H01L51/5234 ,  H01L2251/308 ,  H01L2251/5323 ,  H05B33/14 ,  H05B33/28 ,  Y10S428/917 ,  Y10T428/24942

Abstract: Organic light emitting devices are disclosed which are comprised of a heterostructure for producing electroluminescence wherein the heterostructure is comprised of an emissive layer containing a phosphorescent dopant compound. For example, the phosphorescent dopant compound may be comprised of platinum octaethylporphine (PtOEP), which is a compound having the chemical structure with the formula:

Abstract translation: 公开了由用于产生电致发光的异质结构组成的有机发光器件，其中异质结构由含有磷光掺杂剂化合物的发射层组成。 例如，磷光掺杂剂化合物可以由具有以下化学结构的化合物的铂八乙基卟吩（PtOEP）组成：

公开(公告)号：US06287712B1

公开(公告)日：2001-09-11

申请号：US09058142

申请日：1998-04-10

Applicant: Vladimir Bulovic ,  Stephen R. Forrest ,  Mark E. Thompson

Inventor： Vladimir Bulovic ,  Stephen R. Forrest ,  Mark E. Thompson

IPC: H05B3314

CPC classification number: H01L51/5036 ,  C09K11/06 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/0081 ,  H01L51/5012 ,  Y10S428/917

Abstract: A method for tuning the wavelength of light emitted by an organic light emitting device. An emissive dopant molecule is selected, adapted to emit light when present as a dopant in an emissive layer of the organic light emitting device. The wavelength of light emitted by said emissive dopant molecule depends on the local dipole moment of the emissive layer. The local dipole moment of the emissive layer that would result in said emissive dopant molecule emitting a desired wavelength of light is determined, and an emissive layer is fabricated, doped with the emissive dopant molecule and having the local dipole moment that results in the emissive dopant molecule emitting the desired wavelength of light.

Abstract translation: 一种用于调谐由有机发光器件发射的光的波长的方法。 选择发射掺杂剂分子，适合于在有机发光器件的发射层中作为掺杂剂存在时发光。 由所述发射掺杂剂分子发射的光的波长取决于发射层的局部偶极矩。 确定将导致所述发射掺杂剂分子发射期望波长的光的发射层的局部偶极矩，并且制造发射层，掺杂有发射掺杂剂分子并且具有导致发射掺杂剂的局部偶极矩 发射所需波长的光的分子。

公开(公告)号：US06013982A

公开(公告)日：2000-01-11

申请号：US772333

申请日：1996-12-23

Applicant: Mark E. Thompson ,  Stephen R. Forrest

Inventor： Mark E. Thompson ,  Stephen R. Forrest

IPC: G09F9/00 ,  G09F9/30 ,  H01L27/32 ,  H01L51/50 ,  H05B33/10 ,  H05B33/12 ,  H01J1/62 ,  B32B7/00 ,  H05B33/14

CPC classification number: H05B33/12 ,  H01L27/3211 ,  H01L27/322 ,  H05B33/10 ,  H01L51/5036 ,  Y10S428/917

Abstract: The present invention concerns a multicolor display device, comprising a transparent substrate, fluorescent dye deposited in a dye layer onto the substrate by ink jet printing, and a source of radiation for illuminating said fluorescent dye. The present invention also concerns methods for creating such a device.

Abstract translation: 本发明涉及一种多色显示装置，其包括透明基板，通过喷墨打印沉积在基板上的染料层中的荧光染料以及用于照射所述荧光染料的辐射源。 本发明还涉及用于创建这种装置的方法。

公开(公告)号：US5861219A

公开(公告)日：1999-01-19

申请号：US838099

申请日：1997-04-15

Applicant: Mark E. Thompson ,  Stephen R. Forrest ,  Paul E. Burrows ,  Yujian You ,  Andrei Shoustikov

Inventor： Mark E. Thompson ,  Stephen R. Forrest ,  Paul E. Burrows ,  Yujian You ,  Andrei Shoustikov

IPC: H01L51/00 ,  H01L51/30 ,  H01L51/50 ,  H01L51/52 ,  H05B33/00

CPC classification number: H01L51/0079 ,  B82Y10/00 ,  H01L51/0081 ,  H01L51/0082 ,  H01L51/0092 ,  H01L2251/308 ,  H01L2251/5315 ,  H01L51/0046 ,  H01L51/0053 ,  H01L51/5012 ,  H01L51/5206 ,  H01L51/5281 ,  Y10S428/917

Abstract: The present invention is directed to organic light emitting devices comprised of an electroluminescent layer containing a host material comprised of a metal complex of (5-hydroxy)quinoxaline: ##STR1## wherein M is Al, Ga, In, Zn or Mg, with n=3, if M is Al, Ga or In and n=2, if M is Zn or Mg, and to a method for fabricating such devices. Further disclosed for use in the electroluminescent layer of organic light emitting devices are dopant materials comprised of a bisphenyl-squarilium compound, an indigo dye compound or a fullerene compound.

Abstract translation: 本发明涉及由含有由（5-羟基）喹喔啉的金属络合物构成的主体材料的电致发光层的有机发光器件：其中M为Al，Ga，In，Zn或Mg ，如果M是Al，Ga或In，n = 2，如果M是Zn或Mg，则制造这种器件的方法。 进一步公开用于有机发光器件的电致发光层的掺杂剂材料是由双苯基方酸化合物，靛蓝染料化合物或富勒烯化合物组成的掺杂剂材料。

公开(公告)号：US5703436A

公开(公告)日：1997-12-30

申请号：US613207

申请日：1996-03-06

Applicant: Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

Inventor： Stephen R. Forrest ,  Mark E. Thompson ,  Paul E. Burrows ,  Vladimir Bulovic ,  Gong Gu

IPC: H05B33/10 ,  C09K11/06 ,  C23C14/34 ,  G09G3/00 ,  H01L27/15 ,  H01L27/32 ,  H01L33/00 ,  H01L51/00 ,  H01L51/05 ,  H01L51/30 ,  H01L51/50 ,  H01L51/52 ,  H05B33/12 ,  H05B33/14 ,  H05B33/26 ,  H01J1/62

CPC classification number: H01L51/5234 ,  C09K11/06 ,  H01L27/156 ,  H01L27/3209 ,  H01L51/0077 ,  H01L51/0084 ,  H01L51/5012 ,  H01L51/5036 ,  H01L2224/24145 ,  H01L2251/5323 ,  H01L2924/01021 ,  H01L2924/01068 ,  H01L2924/12041 ,  H01L2924/12044 ,  H01L51/0034 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/0038 ,  H01L51/0042 ,  H01L51/005 ,  H01L51/0051 ,  H01L51/0059 ,  H01L51/008 ,  H01L51/0081 ,  H01L51/5048 ,  H01L51/5243 ,  H01L51/5246 ,  H01L51/5253

Abstract: A multicolor organic light emitting device employs vertically stacked layers of double heterostructure devices which are fabricated from organic compounds. The vertical stacked structure is formed on a glass base having a transparent coating of ITO or similar metal to provide a substrate. Deposited on the substrate is the vertical stacked arrangement of three double heterostructure devices, each fabricated from a suitable organic material. Stacking is implemented such that the double heterostructure with the longest wavelength is on the top of the stack. This constitutes the device emitting red light on the top with the device having the shortest wavelength, namely, the device emitting blue light, on the bottom of the stack. Located between the red and blue device structures is the green device structure. The devices are configured as stacked to provide a staircase profile whereby each device is separated from the other by a thin transparent conductive contact layer to enable light emanating from each of the devices to pass through the semitransparent contacts and through the lower device structures while further enabling each of the devices to receive a selective bias. The devices are substantially transparent when de-energized, making them useful for heads-up display applications.

Abstract translation: 多色有机发光器件采用由有机化合物制成的双异质结构器件的垂直层叠层。 垂直堆叠结构形成在具有ITO或类似金属的透明涂层的玻璃基底上以提供基底。 沉积在衬底上的是三个双异质结构器件的垂直堆叠布置，每个由异质结构器件制成，每个由合适的有机材料制成。 实施堆叠，使得具有最长波长的双异质结构位于堆叠的顶部。 这构成在顶部发射红光的装置，其中装置具有最短波长，即发射蓝光的装置，在堆叠的底部。 位于红色和蓝色的设备结构之间是绿色设备结构。 这些器件被配置为堆叠以提供阶梯轮廓，由此每个器件通过薄的透明导电接触层与另一个分离，以使来自每个器件的光能够透过半透明触点并通过下部器件结构，同时进一步启用 每个设备接收选择性偏差。 当断电时，这些器件基本上是透明的，使得它们对于平视显示器应用是有用的。