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    Catalytic olefin block copolymers with controlled block sequence distribution
    54.
    发明授权
    Catalytic olefin block copolymers with controlled block sequence distribution 有权
    具有受控块序列分布的催化烯烃嵌段共聚物

    公开(公告)号：US08053529B2

    公开(公告)日：2011-11-08

    申请号：US12066879

    申请日：2006-09-14

    Applicant: Edmund M. Carnahan ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

    Inventor： Edmund M. Carnahan ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Timothy T. Wenzel

    IPC: C08F297/00 ,  C08F2/00 ,  C08L23/00 ,  C08F4/643

    CPC classification number: C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08F2410/01 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/08 ,  C08F4/64048 ,  C08F4/64193 ,  C08F4/64148 ,  C08F4/64144 ,  C08F2/001

    Abstract: A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer products, said process comprising: 1) contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions in a reactor or reactor zone with a composition comprising at least one olefin polymerization catalyst and a cocatalyst and characterized by the formation of polymer chains from said monomer or monomers; 2) transferring the reaction mixture to a second reactor or reactor zone and optionally adding one or more additional reactants, catalysts, monomers or other compounds prior to, commensurate with, or after said transfer; and 3) causing polymerization to occur in said second reactor or reactor zone to form polymer chains that are differentiated from the polymer chains formed in step 1); said process being characterized by addition of a chain shuttling agent to the reaction mixture prior to, during, or subsequent to step 1) such that at least some of the resulting polymer molecules from step 3) comprise two or more chemically or physically distinguishable blocks or segments.

    Abstract translation: 一种用于聚合一种或多种可加聚单体和所得聚合物产物的方法，所述方法包括：1）在反应器或反应器区中的加成聚合条件下将加成聚合单体或单体混合物与包含至少一种 烯烃聚合催化剂和助催化剂，其特征在于由所述单体或单体形成聚合物链; 2）将反应混合物转移到第二反应器或反应器区，并任选地在所述转移之前，之后或之后加入一种或多种另外的反应物，催化剂，单体或其它化合物; 和3）在所述第二反应器或反应器区域中引起聚合以形成与步骤1）中形成的聚合物链不同的聚合物链; 所述方法的特征在于在步骤1）之前，期间或之后向反应混合物中加入链穿梭剂，使得来自步骤3）的所得聚合物分子中的至少一些包含两个或多个化学或物理上可区分的嵌段或 细分。

    Olefin polymerization catalysts
    57.
    发明授权
    Olefin polymerization catalysts 有权
    烯烃聚合催化剂

    公开(公告)号：US07718566B2

    公开(公告)日：2010-05-18

    申请号：US12313854

    申请日：2008-11-25

    Applicant: Timothy T. Wenzel ,  Zondra Dee Dixon

    Inventor： Timothy T. Wenzel ,  Zondra Dee Dixon

    IPC: C08F4/60 ,  C08F4/606 ,  B01J31/22

    CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F210/16 ,  C08F210/14 ,  C08F4/64148

    Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 15 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.

    Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式αa和bgr;bγgMXn表示，其中M是金属; X是卤代芳氧基; ＆bgr 并且γ是各自包含至少一个15族原子的基团; α是连接部分，其形成与每个化合物的化学键; 和γ; a，b，g和n分别为1〜4的整数。

    Olefin polymerization catalysts
    59.
    发明申请
    Olefin polymerization catalysts 有权
    烯烃聚合催化剂

    公开(公告)号：US20090082195A1

    公开(公告)日：2009-03-26

    申请号：US12313854

    申请日：2008-11-25

    Applicant: Timothy T. Wenzel ,  Zondra Dee Dixon

    Inventor： Timothy T. Wenzel ,  Zondra Dee Dixon

    IPC: C08F4/72 ,  C07F17/00 ,  B01J31/12

    CPC classification number: C08F10/00 ,  C07F7/003 ,  C08F210/16 ,  C08F210/14 ,  C08F4/64148

    Abstract: A catalyst composition and method for olefin polymerization are provided. In one aspect, the catalyst composition is represented by the formula αaβbγgMXn wherein M is a metal; X is a halogenated aryloxy group; β and γ are groups that each comprise at least one Group 15 atom; α is a linking moiety that forms a chemical bond to each of β and γ; and a, b, g, and n are each integers from 1 to 4.

    Abstract translation: 提供了一种用于烯烃聚合的催化剂组合物和方法。 在一个方面，催化剂组合物由式alphamatabgammagMXn表示，其中M是金属; X是卤代芳氧基; β和γ是各自包含至少一个15族原子的基团; α是与β和γ各自形成化学键的连接部分; a，b，g和n分别为1〜4的整数。

    Catalytic Olefin Block Copolymers with Controlled Block Sequence Distribution
    60.
    发明申请
    Catalytic Olefin Block Copolymers with Controlled Block Sequence Distribution 有权
    具有受控块序列分布的催化烯烃嵌段共聚物

    公开(公告)号：US20080269412A1

    公开(公告)日：2008-10-30

    申请号：US12066879

    申请日：2006-09-14

    Applicant: Edmund M. Carnahan ,  Phillip D. Hustad ,  Roger L. Kuhiman ,  Timothy T. Wenzel

    Inventor： Edmund M. Carnahan ,  Phillip D. Hustad ,  Roger L. Kuhiman ,  Timothy T. Wenzel

    IPC: C08F297/00 ,  C08F2/01

    CPC classification number: C08F297/08 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08F2410/01 ,  C08F4/65912 ,  C08F2/38 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/12 ,  C08F2500/08 ,  C08F4/64048 ,  C08F4/64193 ,  C08F4/64148 ,  C08F4/64144 ,  C08F2/001

    Abstract: A process for the polymerization of one or more addition polymerizable monomers and the resulting polymer products, said process comprising: 1) contacting an addition polymerizable monomer or mixture of monomers under addition polymerization conditions in a reactor or reactor zone with a composition comprising at least one olefin polymerization catalyst and a cocatalyst and characterized by the formation of polymer chains from said monomer or monomers; 2) transferring the reaction mixture to a second reactor or reactor zone and optionally adding one or more additional reactants, catalysts, monomers or other compounds prior to, commensurate with, or after said transfer; and 3) causing polymerization to occur in said second reactor or reactor zone to form polymer chains that are differentiated from the polymer chains formed in step 1); said process being characterized by addition of a chain shuttling agent to the reaction mixture prior to, during, or subsequent to step 1) such that at least some of the resulting polymer molecules from step 3) comprise two or more chemically or physically distinguishable blocks or segments.

    Abstract translation: 一种用于聚合一种或多种可加聚单体和所得聚合物产物的方法，所述方法包括：1）在反应器或反应器区中的加成聚合条件下将加成聚合单体或单体混合物与包含至少一种 烯烃聚合催化剂和助催化剂，其特征在于由所述单体或单体形成聚合物链; 2）将反应混合物转移到第二反应器或反应器区，并任选地在所述转移之前，之后或之后加入一种或多种另外的反应物，催化剂，单体或其它化合物; 和3）在所述第二反应器或反应器区域中引起聚合以形成与步骤1）中形成的聚合物链不同的聚合物链; 所述方法的特征在于在步骤1）之前，期间或之后向反应混合物中加入链穿梭剂，使得来自步骤3）的所得聚合物分子中的至少一些包含两个或多个化学或物理上可区分的嵌段或 细分。

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