公开(公告)号：US07449685B2

公开(公告)日：2008-11-11

申请号：US11336989

申请日：2006-01-23

申请人： Yasuaki Takada ,  Masao Suga ,  Hisashi Nagano ,  Izumi Waki ,  Hidehiro Okada ,  Tatsuo Nojiri ,  Yasuo Seto ,  Yasuhiro Sano ,  Shigeharu Yamashiro ,  Isaac Ohsawa

发明人： Yasuaki Takada ,  Masao Suga ,  Hisashi Nagano ,  Izumi Waki ,  Hidehiro Okada ,  Tatsuo Nojiri ,  Yasuo Seto ,  Yasuhiro Sano ,  Shigeharu Yamashiro ,  Isaac Ohsawa

IPC分类号： H01J49/00

CPC分类号： H01J49/04 ,  Y10T436/16

摘要： A gas monitoring apparatus includes a sample introducing portion, a measurement portion, an ionization portion, a mass analysis portion, a data processing portion and a display. The sample introducing portion introduces a sample gas including an object material to be measured. The measurement portion measures a concentration of a predetermined coexisting material, which coexists with the object material in the sample gas. The ionization portion ionizes the sample gas. The mass analysis portion analyzes mass of an ion produced by the ionization portion. The data processing portion analyzes signals detected by the mass analysis portion to calculate a concentration of the object material. And the display displays results of analysis conducted by the data processing portion. The data processing portion includes an adjustment portion which adjusts the concentration of the object material according to the concentration of the predetermined coexisting material.

摘要翻译： 气体监测装置包括样品引入部分，测量部分，电离部分，质量分析部分，数据处理部分和显示器。 样品引入部分引入包括待测量物体的样品气体。 测量部分测量与样品气体中的目标材料共存的预定共存材料的浓度。 电离部分使样品气体离子化。 质量分析部分分析由电离部分产生的离子的质量。 数据处理部分分析由质量分析部检测出的信号，计算出物体的浓度。 并且显示器显示由数据处理部分进行的分析结果。 数据处理部包括调整部，其根据预定的共存材料的浓度来调整被检体的浓度。

公开(公告)号：US07397025B2

公开(公告)日：2008-07-08

申请号：US11517334

申请日：2006-09-08

申请人： Takashi Baba ,  Hiroyuki Satake ,  Yasuaki Takada

发明人： Takashi Baba ,  Hiroyuki Satake ,  Yasuaki Takada

IPC分类号： B01D59/44 ,  H01J49/00

CPC分类号： H01J49/145 ,  H01J49/0095 ,  H01J49/063

摘要： A mass spectrometer having an ion source section capable of creating positive ions and negative ions at high efficiency. The ion source is comprised of an ion source section for creating ions of a sample gas, a mass spectrometric section for conducting mass separation of created ions, linear RF generating multipole electrodes, magnetic fields generation means, a sample gas introduction system, a reaction gas introduction system and an electron source in which the linear RF generating multipole electrodes generate linear RF multipole electric fields. A static magnetic fields is applied in parallel on the center axis where the linear RF multipole electric fields are zero. A sample gas and a reagent gas are introduced into the ion source section. Electrons are injected for creating reaction of the positive ions or negative ions.

摘要翻译： 具有能够以高效率产生正离子和负离子的离子源部的质谱仪。 离子源包括用于产生样品气体的离子的离子源部分，用于导出所产生的离子的质量分离的质谱部分，线性RF产生多极电极，磁场产生装置，样品气体引入系统，反应气体 引入系统和电子源，其中线性RF产生多极电极产生线性RF多极电场。 在线性RF多极电场为零的中心轴上并行施加静态磁场。 样品气体和反应气体被引入离子源部分。 注入电子以产生正离子或负离子的反应。

公开(公告)号：US07129478B2

公开(公告)日：2006-10-31

申请号：US11126218

申请日：2005-05-11

申请人： Takashi Baba ,  Hiroyuki Satake ,  Yasuaki Takada

发明人： Takashi Baba ,  Hiroyuki Satake ,  Yasuaki Takada

IPC分类号： B01D59/44 ,  H01J49/00

CPC分类号： H01J49/145 ,  H01J49/0095 ,  H01J49/063

摘要： A mass spectrometer having an ion source section capable of creating positive ions and negative ions at high efficiency. The ion source is comprised of an ion source section for creating ions of a sample gas, a mass spectrometric section for conducting mass separation of created ions, linear RF generating multipole electrodes, magnetic fields generation means, a sample gas introduction system, a reaction gas introduction system and an electron source in which the linear RF generating multipole electrodes generate linear RF multipole electric fields. A static magnetic fields is applied in parallel on the center axis where the linear RF multipole electric fields are zero. A sample gas and a reagent gas are introduced into the ion source section. Electrons are injected for creating reaction of the positive ions or negative ions.

摘要翻译： 具有能够以高效率产生正离子和负离子的离子源部的质谱仪。 离子源包括用于产生样品气体的离子的离子源部分，用于导出所产生的离子的质量分离的质谱部分，线性RF产生多极电极，磁场产生装置，样品气体引入系统，反应气体 引入系统和电子源，其中线性RF产生多极电极产生线性RF多极电场。 在线性RF多极电场为零的中心轴上并行施加静态磁场。 样品气体和反应气体被引入离子源部分。 注入电子以产生正离子或负离子的反应。

公开(公告)号：US20060226358A1

公开(公告)日：2006-10-12

申请号：US11296317

申请日：2005-12-08

申请人： Masaki Ishikawa ,  Masaki Matsumoto ,  Yoshihiro Nishikawa ,  Yasuaki Takada ,  Hisashi Nagano ,  Masami Sakamoto

发明人： Masaki Ishikawa ,  Masaki Matsumoto ,  Yoshihiro Nishikawa ,  Yasuaki Takada ,  Hisashi Nagano ,  Masami Sakamoto

IPC分类号： G01N23/00

CPC分类号： G01N1/2214 ,  G01N1/24 ,  G01N33/22 ,  G01N2001/024 ,  G01N2001/028 ,  H01J49/004

摘要： Firstly, the following check chip is set up into a heater: A check chip onto which a sample has been picked up by wiping out the surface of a check target, or a check chip formed by absorbing and collecting the sample into a filter. Here, the filter has been set up in a vibration-type or heating-type portable-type absorption probe in an attachment/detachment-capable manner. Secondly, a sample gas generated from the heated check chip is analyzed using a tandem-type mass spectrometer. This makes it possible to simplify the sample pick-up from various types of check targets, and to shorten the pick-up time and the checking time.

公开(公告)号：US07015464B2

公开(公告)日：2006-03-21

申请号：US10780880

申请日：2004-02-19

申请人： Hisashi Nagano ,  Izumi Waki ,  Yasuaki Takada

发明人： Hisashi Nagano ,  Izumi Waki ,  Yasuaki Takada

IPC分类号： H01J44/04 ,  G01N24/00

CPC分类号： H01J49/0027 ,  H01J49/0077 ,  Y10T436/24

摘要： An apparatus for detecting chemical substances which is high in sensitivity and selectivity is provided. An organic acid or an organic acid salt is used to generate an organic acid gas from an organic acid gas generator to be mixed with a sample gas for introduction into an ion source for ionization, thereby obtaining a mass spectrum by a mass analysis region. A data processor determines the detection or non-detection of a specific m/z of an organic acid adduct ion obtained by adding a molecule generated from the organic acid to a molecule with specific m/z generated from a target chemical substance to be detected based on the obtained mass spectrum. When there is an ion peak with the m/z of the organic acid adduct ion, the presence of the target chemical substance to be detected is determined, and an alarm is sounded. False detection can be prevented.

摘要翻译： 提供一种用于检测灵敏度和选择性高的化学物质的装置。 使用有机酸或有机酸盐从有机酸性气体发生器产生有机酸气体，并与用于引入离子源的样品气体混合，从而通过质量分析区域获得质谱。 数据处理器确定通过将由有机酸产生的分子加入到由待检测的目标化学物质产生的特定m / z的分子获得的有机酸加合物的特定m / z的检测或非检测基础上 在获得的质谱上。 当存在有机酸加合离子的m / z的离子峰时，确定要检测的目标化学物质的存在，并发出报警。 可以防止误检。

公开(公告)号：US20050067565A1

公开(公告)日：2005-03-31

申请号：US10873107

申请日：2004-06-23

申请人： Yasuaki Takada ,  Hisashi Nagano

发明人： Yasuaki Takada ,  Hisashi Nagano

IPC分类号： G01N27/62 ,  H01J49/42

CPC分类号： H01J49/424 ,  H01J49/0063 ,  H01J49/428

摘要： A mass spectrometer capable of analysis at high speed and high accuracy comprising a device for applying a high frequency signal not containing resonance frequencies for plural precursor ions but containing resonance frequencies of other ions, and having different amplitudes on every frequencies to an electrode constituting the mass spectrometer thereby controlling the selection for the plural precursor ions, and a device for applying a high frequency signal having amplitudes set individually on every resonance frequencies of the plural precursor ions and superimposed with the resonance frequencies for the plural precursor ions to the electrode constituting the mass spectrometer thereby controlling the dissociation of the plural precursor ions, and judging the presence or absence of the aimed chemical substance based on the mass spectra of the obtained by dissociating the plural fragment ions.

摘要翻译： 能够以高速，高精度进行分析的质谱仪，其特征在于，包括用于施加不包含多个前体离子的共振频率但含有其他离子的共振频率的高频信号的装置，并且在构成所述质量的电极的每个频率上具有不同的振幅 光谱仪，从而控制多个前体离子的选择，以及用于施加具有单独设置在多个前体离子的每个共振频率上的振幅的高频信号并与多个前体离子的共振频率叠加到构成质量的电极的装置 从而控制多个前体离子的解离，并且基于通过解离多个片段离子获得的质谱来判断目标化学物质的存在或不存在。

公开(公告)号：US06770877B2

公开(公告)日：2004-08-03

申请号：US10457426

申请日：2003-06-10

申请人： Toshihiko Ohta ,  Kenji Kusumoto ,  Yasuaki Takada ,  Hisashi Nagano

发明人： Toshihiko Ohta ,  Kenji Kusumoto ,  Yasuaki Takada ,  Hisashi Nagano

IPC分类号： H01J4910

CPC分类号： H01J49/145

摘要： A method and apparatus for analyzing vapors generated from explosives in which vapors containing nitrogen monoxide and/or nitrogen dioxide are generated by decomposing explosives by increasing the temperature of the explosives, primary ions and neutral molecules are generated from air. The generated primary ions and the nitrogen monoxide and/or nitrogen dioxide contained in the generated vapors are allowed to react with each other in an area inhibited or prevented from being penetrated by the generated neutral molecules, and the nitrogen monoxide and/or nitrogen dioxide contained in the generated vapors is ionized. The ionized nitrogen monoxide and/or nitrogen dioxide is subjected to mass spectrometry, and an amount of the nitrogen monoxide and/or nitrogen dioxide contained in the generated vapors by decomposing the explosives is determined.

摘要翻译： 用于分析由爆炸物产生的蒸汽的方法和装置，其中通过从空气中产生爆炸物，初级离子和中性分子的温度来分解包含一氧化氮和/或二氧化氮的蒸气而产生的蒸气。 产生的初级离子和产生的蒸气中含有的一氧化氮和/或二氧化氮在被产生的中性分子渗透的区域中彼此反应，并且含有一氧化氮和/或二氧化氮 在产生的蒸气中电离。 对离子化的一氧化氮和/或二氧化氮进行质谱分析，并确定通过分解爆炸物而产生的蒸汽中所含的一氧化氮和/或二氧化氮的量。

公开(公告)号：US06639215B2

公开(公告)日：2003-10-28

申请号：US10053567

申请日：2002-01-24

申请人： Yasuaki Takada ,  Masuyoshi Yamada ,  Masao Suga ,  Yuichiro Hashimoto

发明人： Yasuaki Takada ,  Masuyoshi Yamada ,  Masao Suga ,  Yuichiro Hashimoto

IPC分类号： B01D5944

CPC分类号： H01J49/168 ,  H01J49/0445

摘要： To provide a mass spectrometer having a high sensitivity to dioxins. In the mass spectrometer including: a sample supply tube for supplying a sample solution containing a sample to be measured; a nebulizer for nebulizing the sample solution supplied from the sample supply tube; an ion source having a needle electrode for ionizing the sample nebulized and vaporized in the nebulizer; and a mass analyzer for analyzing ions formed in the ion source, and a gas of a flow rate corresponding to the flow rate of the sample solution is mixed to the vaporized sample, and a moving direction of the sample is made opposite to a moving direction of ions at a tip of the needle electrode.

摘要翻译： 提供对二恶英具有高度敏感性的质谱仪。 在质谱仪中，包括：供给含有待测样品的样品溶液的样品供给管; 用于将从样品供应管提供的样品溶液雾化的雾化器; 离子源，其具有针状电极，用于将在雾化器中雾化和蒸发的样品电离; 以及用于分析在离子源中形成的离子的质量分析器，将与样品溶液的流量对应的流量的气体混合到蒸发的样品中，使样品的移动方向与移动方向相反 的针电极尖端的离子。

公开(公告)号：US08835834B2

公开(公告)日：2014-09-16

申请号：US13383371

申请日：2010-07-09

申请人： Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hisashi Nagano ,  Hideki Hasegawa ,  Yasuaki Takada ,  Masuyoshi Yamada

发明人： Masuyuki Sugiyama ,  Yuichiro Hashimoto ,  Hisashi Nagano ,  Hideki Hasegawa ,  Yasuaki Takada ,  Masuyoshi Yamada

IPC分类号： B01D59/44 ,  H01J49/00

CPC分类号： H01J49/004

摘要： An object is to measure both cations and anions with high duty cycle. In a mass spectrometer comprising an ion source (1), an ion guide part (31), and an ion trap (32), while ions are being mass-selectively ejected from the ion trap, ions having a polarity reverse to that of the ions trapped in the ion trap are introduced into the ion guide part.

摘要翻译： 一个目标是测量阳离子和阴离子高占空比。 在离子源（1），离子引导部（31）和离子阱（32）的质谱仪中，离子从离子阱中质量选择性地喷出时，具有与 捕获在离子阱中的离子被引入离子引导部。

公开(公告)号：US08284051B2

公开(公告)日：2012-10-09

申请号：US12357447

申请日：2009-01-22

申请人： Yasuaki Takada ,  Hisashi Nagano

发明人： Yasuaki Takada ,  Hisashi Nagano

IPC分类号： G08B21/00

CPC分类号： G08B21/12 ,  G08B31/00

摘要： Mass transit terrorism is prevented to construct a safe society. Individual explosive sensing devices are connected by a network to establish a security system. Information collected in the security center is compared with a database to determine a risk. When the risk exceeds a predetermined level upon determination of the risk, measures may be taken such that an alarm is activated and instructions for making a security guard carry out the parcel inspection of the person causing the risk are transmitted to the security guard. According to the present invention, the security can be enhanced while the social life is still convenient even when the explosive sensing device having a high throughput is employed at places such as mass transit where many people gather. Therefore, the terror risk on the mass transit can be reduced to contribute to construction of the safe society.

摘要翻译： 公共交通恐怖主义被阻止建设一个安全的社会。 各个爆炸传感装置通过网络连接建立安全系统。 将在安全中心收集的信息与数据库进行比较以确定风险。 当风险确定后风险超过预定水平时，可以采取措施，使得警报被激活，并且使导致该风险的人进行包裹检查的指示发送给保安人员。 根据本发明，即使在许多人聚集的地方诸如公共交通的地方使用具有高生产量的爆炸传感装置，社会生活仍然方便时，可以提高安全性。 因此，可以减少公共交通的恐怖风险，为安全社会的建设做出贡献。