Pearlescent pigments based on selectively absorbing layers of chalcogenide, oxychalcogenide and mixed chalcogenides
    53.
    发明申请
    Pearlescent pigments based on selectively absorbing layers of chalcogenide, oxychalcogenide and mixed chalcogenides 审中-公开
    基于选择性吸收硫族化物,氧化硫元素和混合硫属化物层的珠光颜料

    公开(公告)号:US20050001203A1

    公开(公告)日:2005-01-06

    申请号:US10768190

    申请日:2004-02-02

    摘要: The present invention relates to novel pearlescent pigments based on substrates comprising at least one selectively light absorbing layer, which consists of a chalcogenide and/or oxychalcogenide, preferably sulfides or oxysulfides. The coatings can be directly prepared by the precipitation of chalcogenides in liquid suspension onto the substrates. Preferably, metal oxides or mixed metal oxides are coated onto the substrate; the resulting precursor is transferred into a furnace and calcined under a sulfurizing gas flow to convert the oxides into oxysulfides and/or sulfides depending on the reaction parameters. The conversion to sulfides and/or oxysulfides is preferably carried out in a fluidized bed reactor. Angle-dependent optical pigments are thus produced, which are especially useful in paints, powder coatings, paper coatings, plastics, cosmetics, inks and security-enhancing features as well as ion decorative applications for foods and drugs.

    摘要翻译: 本发明涉及基于包含至少一个选择性光吸收层的基材的新型珠光颜料,其由硫族化物和/或氧化硫化物,优选硫化物或氧硫化物组成。 可以通过将液体悬浮液中的硫族化物沉淀到基底上来直接制备涂层。 优选地,将金属氧化物或混合金属氧化物涂覆在基材上; 将所得前体转移到炉中并在硫化气流下煅烧,以将氧化物转化为氧硫化物和/或硫化物,这取决于反应参数。 转化为硫化物和/或氧硫化物优选在流化床反应器中进行。 因此制造了依赖于角度的光学颜料,其特别适用于涂料,粉末涂料,纸张涂料,塑料,化妆品,油墨和安全性增强特征以及食品和药物的离子装饰应用。

    Process for packaging metal pigment powder
    55.
    发明授权
    Process for packaging metal pigment powder 有权
    包装金属颜料粉的工艺

    公开(公告)号:US6134863A

    公开(公告)日:2000-10-24

    申请号:US190836

    申请日:1998-11-12

    摘要: There is provided a process of packaging metal pigment in a substantially non-dusting manner. The process includes the step of dampening the metal pigment with a liquid which may be water or an organic solvent compatible with that pigment type. The dampened pigment is then placed into a porous container which is sealed prior to removal of the liquid. The porosity of the container is chosen to permit removal of the liquid (for example by evaporation and/or centrifugation) whilst retaining substantially all of the pigment. Suitable containers include paper bags (such as autoclave bags), woven fiber materials (optionally calendered or coated) and polymer materials. The substantially dry metal pigment can be conveniently stored or transported within the container and is in a convenient form to use in a powder coating process.

    摘要翻译: 提供了以基本上不起尘的方式包装金属颜料的方法。 该方法包括用可以是与该颜料类型相容的水或有机溶剂的液体润湿金属颜料的步骤。 然后将润湿的颜料置于多孔容器中,该多孔容器在除去液体之前被密封。 选择容器的孔隙率以允许除去液体(例如通过蒸发和/或离心),同时保持基本上所有的颜料。 合适的容器包括纸袋(例如高压釜袋),编织纤维材料(任选压延或涂覆)和聚合物材料。 基本上干燥的金属颜料可以方便地在容器内储存或运输,并且是以粉末涂料方法使用的方便形式。

    Particle having an attached stable free radical and methods of making
the same
    57.
    发明授权
    Particle having an attached stable free radical and methods of making the same 失效
    具有附着稳定自由基的颗粒及其制备方法

    公开(公告)号:US06068688A

    公开(公告)日:2000-05-30

    申请号:US968299

    申请日:1997-11-12

    摘要: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.10 represents an alkyl group or an aryl group; SFR represents a stable free radical; and n is an integer of from 1 to 3. A modified particle having an attached --SFR or --X--SFR is additionally disclosed. Also, modified particles with attached polymers are also disclosed as well as methods of making the modified products.

    摘要翻译: 公开了一种改性颗粒,其中颗粒具有具有下式的连接基团:其中Ar表示芳族基团; R1表示键,亚芳基,亚烷基,其中R4是烷基或亚烷基或芳基或亚芳基; R2和R3可以相同或不同,表示氢,烷基,芳基,-OR5,-NHR5,-NR5R5或-SR5,其中R5相同或不同,表示烷基 或芳基; SFR代表稳定的自由基。 还公开了具有下式的基团的改性颗粒或聚集体:其中CoupA表示含Si基团,含Ti基团或含Zr基团; R8和R9可以相同或不同,表示氢,烷基,芳基,-OR10,-NHR10,-NR10R10或-SR10,其中R10表示烷基或芳基; SFR代表稳定的自由基; n是1〜3的整数。另外公开了具有附着的-SFR或-X-SFR的改性粒子。 此外,还公开了具有连接的聚合物的改性颗粒以及制备改性产物的方法。