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公开(公告)号：US20190127864A1
公开(公告)日：2019-05-02
申请号：US16196199
申请日：2018-11-20
申请人： Calera Corporation
摘要： Disclosed herein are ion exchange membranes, electrochemical systems, and methods that relate to various configurations of the ion exchange membranes and other components of the electrochemical cell.
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公开(公告)号：US20190119186A1
公开(公告)日：2019-04-25
申请号：US16135357
申请日：2018-09-19
申请人： Calera Corporation
发明人： Margarete K. Leclerc , Emily A. Cole , Thomas A. Albrecht , Michael Kostowskyj , Ryan J. Gilliam , Michael J. Weiss , Kyle Self
摘要： There are provided methods and systems related to use of one or more lanthanide halides in an electrochemical oxidation of metal halide in anolyte where the metal ion is oxidized from lower oxidation state to higher oxidation state at an anode; and then further use of the one or more lanthanide halides and the metal halide with the metal ion in the higher oxidation state in a halogenation reaction of an unsaturated hydrocarbon or a saturated hydrocarbon to form one or more products comprising halohydrocarbon.
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公开(公告)号：US10161050B2
公开(公告)日：2018-12-25
申请号：US15071648
申请日：2016-03-16
申请人： Calera Corporation
摘要： Disclosed herein are ion exchange membranes, electrochemical systems, and methods that relate to various configurations of the ion exchange membranes and other components of the electrochemical cell.
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公开(公告)号：US20180347056A1
公开(公告)日：2018-12-06
申请号：US15992422
申请日：2018-05-30
申请人： Calera Corporation
摘要： There are provided methods and systems to form propylene chlorohydrin by hydrolysis of 1,2-dichloropropane and to further form propylene oxide from propylene chlorohydrin.
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65.发明申请公开(公告)号：US20180245223A1
公开(公告)日：2018-08-30
申请号：US15963637
申请日：2018-04-26
申请人： Calera Corporation
IPC分类号： C25B3/06 , C07D301/24 , C07D303/04 , C07C29/64 , C07C31/36
CPC分类号： C25B3/06 , C07C17/08 , C07C29/64 , C07C31/36 , C07D301/24 , C07D303/04 , C07C19/01 , C07C19/045
摘要： Disclosed herein are methods and systems that relate to various configurations of electrochemical oxidation, chlorine oxidation, oxychlorination, chlorination, and epoxidation reactions to form propylene oxide or ethylene oxide.
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公开(公告)号：US09957623B2
公开(公告)日：2018-05-01
申请号：US14919281
申请日：2015-10-21
申请人： CALERA CORPORATION
发明人： Ryan J Gilliam , Bryan Boggs , Kyle Self , Margarete K Leclerc , Alexander Gorer , Michael J Weiss , John H Miller , Samaresh Mohanta
CPC分类号： C25B9/00 , C25B1/00 , C25B1/02 , C25B1/20 , C25B11/035 , C25B11/0442 , C25B15/08
摘要： There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.
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公开(公告)号：US09957621B2
公开(公告)日：2018-05-01
申请号：US14855262
申请日：2015-09-15
申请人： Calera Corporation
发明人： Thomas A. Albrecht , Dennis Solas , Margarete K. Leclerc , Michael Joseph Weiss , Ryan J. Gilliam , Kyle Self
CPC分类号： C25B3/06 , C25B1/02 , C25B3/02 , C25B9/06 , C25B9/203 , C25B11/00 , C25B11/0405 , C25B11/0478 , C25B11/0489 , C25B15/08
摘要： There are provided electrochemical methods and systems to form one or more organic compounds or enantiomers thereof selected from the group consisting of substituted or unsubstituted dioxane, substituted or unsubstituted dioxolane, dichloroethylether, dichloromethyl methyl ether, dichloroethyl methyl ether, chloroform, carbon tetrachloride, phosgene, and combinations thereof.
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公开(公告)号：US20180044267A1
公开(公告)日：2018-02-15
申请号：US15793250
申请日：2017-10-25
申请人： Calera Corporation
发明人： Michael Joseph Weiss , Ryan J. Gilliam , Kyle Self , Gal Mariansky , Margarete K. Leclerc , Riyaz Mohammed Shipchandler , Jacob Nagar
摘要： There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with an unsaturated hydrocarbon and/or a saturated hydrocarbon to form products. Separation and/or purification of the products as well as of the metal ions in the lower oxidation state and the higher oxidation state, is provided herein.
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公开(公告)号：US09880124B2
公开(公告)日：2018-01-30
申请号：US14937751
申请日：2015-11-10
申请人： Calera Corporation
发明人： Ryan J. Gilliam , Hong Zhao
IPC分类号： G01N27/38 , G01N27/49 , G01N27/28 , G01N33/20 , G01N27/401
CPC分类号： G01N27/38 , G01N27/401 , G01N27/49 , G01N33/20 , Y10T436/255
摘要： Disclosed herein are systems and methods that relate to use of ultramicroelectrodes (UME) in measurement of ion concentration in presence of one or more organic compound(s).
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公开(公告)号：US20170121832A1
公开(公告)日：2017-05-04
申请号：US15338235
申请日：2016-10-28
申请人： Calera Corporation
摘要： Disclosed herein are methods and systems that relate to electrochemically oxidizing metal halide with a metal ion in a lower oxidation state to a higher oxidation state; halogenating an unsaturated hydrocarbon or a saturated hydrocarbon with the metal halide with the metal ion in the higher oxidation state; and oxyhalogenating the metal halide with the metal ion from a lower oxidation state to a higher oxidation state in presence of an oxidant. In some embodiments, the oxyhalogenation is in series with the electrochemical oxidation, the electrochemical oxidation is in series with the oxyhalogenation, the oxyhalogenation is parallel to the electrochemical oxidation, and/or the oxyhalogenation is simultaneous with the halogenation.
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