公开(公告)号：US20120171579A1

公开(公告)日：2012-07-05

申请号：US13339384

申请日：2011-12-29

Applicant: Li-Duan Tsai ,  Yueh-Wei Lin ,  Chia-Chen Fang ,  Cheng-Liang Cheng ,  Jing-Pin Pan ,  Tsung-Hsiung Wang

Inventor： Li-Duan Tsai ,  Yueh-Wei Lin ,  Chia-Chen Fang ,  Cheng-Liang Cheng ,  Jing-Pin Pan ,  Tsung-Hsiung Wang

IPC: H01M10/056

CPC classification number: H01M10/0525 ,  H01M4/405 ,  H01M4/581 ,  H01M4/5815 ,  H01M4/587 ,  H01M4/621 ,  H01M4/625 ,  H01M4/626 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235 ,  H01M2300/0025 ,  Y02E60/122

Abstract: A non-aqueous electrolyte including a lithium salt, an organic solvent, and an electrolyte additive is provided. The electrolyte additive is a meta-stable state nitrogen-containing polymer formed by reacting Compound (A) and Compound (B). Compound (A) is a monomer having a reactive terminal functional group. Compound (B) is a heterocyclic amino aromatic derivative as an initiator. A molar ratio of Compound (A) to Compound (B) is from 10:1 to 1:10. A lithium secondary battery containing the non-aqueous electrolyte is further provided. The non-aqueous electrolyte of this disclosure has a higher decomposition voltage than a conventional non-aqueous electrolyte, such that the safety of the battery during overcharge or at high temperature caused by short-circuit current is improved.

Abstract translation: 提供了包含锂盐，有机溶剂和电解质添加剂的非水电解质。 电解质添加剂是通过使化合物（A）和化合物（B）反应而形成的间位稳定状态的含氮聚合物。 化合物（A）是具有反应性末端官能团的单体。 化合物（B）是作为引发剂的杂环氨基芳族衍生物。 化合物（A）与化合物（B）的摩尔比为10:1至1:10。 还提供含有非水电解质的锂二次电池。 本公开的非水电解质具有比常规的非水电解质更高的分解电压，从而提高了由于短路电流引起的过充电或高温下电池的安全性。

公开(公告)号：US08137838B2

公开(公告)日：2012-03-20

申请号：US11976557

申请日：2007-10-25

Applicant: Chang-Rung Yang ,  Jing-Pin Pan ,  Chien-An Chen ,  Jung-Mu Hsu

Inventor： Chang-Rung Yang ,  Jing-Pin Pan ,  Chien-An Chen ,  Jung-Mu Hsu

IPC: H01M4/62 ,  H01M4/13

CPC classification number: H01M4/62 ,  H01M4/131 ,  H01M4/133 ,  H01M4/136 ,  H01M4/139 ,  H01M4/624 ,  H01M10/0525

Abstract: A battery electrode paste composition containing modified maleimide(s) is provided, which has an electrode active material, a conductive additive, a binder and modified maleimide(s) as dispersant. The modified maleimide as the dispersant in the battery electrode paste composition has dendrimer-like hyperbranched structures, which can form a stable complex with the electrode active material. Therefore, owing to the excellent compatibility of the modified maleimide with the solvent in the electrode paste, the storage stability of the paste is increased. Furthermore, through formation of stable bonding between the modified maleimide and the current-collecting metal substrate, the adhesive force between the electrode film and the current-collecting metal substrate is enhanced and the cycling life of the battery product is extended.

Abstract translation: 提供含有改性马来酰亚胺的电池电极糊剂组合物，其具有电极活性材料，导电添加剂，粘合剂和改性马来酰亚胺作为分散剂。 在电池电极糊料组合物中作为分散剂的改性马来酰亚胺具有树枝状大分子超支化结构，其可以与电极活性材料形成稳定的络合物。 因此，由于改性马来酰亚胺与电极糊中的溶剂的相溶性优异，因此糊料的保存稳定性提高。 此外，通过形成改性马来酰亚胺和集电金属基材之间的稳定结合，电极膜和集电金属基板之间的粘合力增强，电池产品的循环寿命延长。

公开(公告)号：US08124282B2

公开(公告)日：2012-02-28

申请号：US11964772

申请日：2007-12-27

Applicant: Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

Inventor： Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

IPC: H01M6/18

CPC classification number: H01M10/0567 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235

Abstract: A nonaqueous electrolyte having maleimide additives and rechargeable cells employing the same are provided. The nonaqueous electrolyte having maleimide additives comprises an alkali metal electrolyte, a nonaqueous solvent, and maleimide additives. Specifically, the maleimide additives comprise maleimide monomer, bismaleimide monomer, bismaleimide oligomer, or mixtures thereof. The maleimide additives comprise functional groups, such as a maleimide double bond, phenyl group carboxyl, or imide, enhancing the charge-discharge efficiency, safety, thermal stability, chemical stability, flame-resistance, and lifespan of the secondary cells of the invention.

Abstract translation: 提供具有马来酰亚胺添加剂的非水电解质和使用该非水电解质的可充电电池。 具有马来酰亚胺添加剂的非水电解质包括碱金属电解质，非水溶剂和马来酰亚胺添加剂。 具体地，马来酰亚胺添加剂包括马来酰亚胺单体，双马来酰亚胺单体，双马来酰亚胺低聚物或其混合物。 马来酰亚胺添加剂包括官能团，例如马来酰亚胺双键，苯基羧基或酰亚胺，提高本发明的二次电池的充电 - 放电效率，安全性，热稳定性，化学稳定性，阻燃性和寿命。

公开(公告)号：US20110033773A1

公开(公告)日：2011-02-10

申请号：US12623642

申请日：2009-11-23

Applicant: Chung-Liang Chang ,  Ya-Ting Hsu ,  Jing-Pin Pan

Inventor： Chung-Liang Chang ,  Ya-Ting Hsu ,  Jing-Pin Pan

IPC: H01M8/10 ,  B01J41/12 ,  B05D5/12

CPC classification number: B01D67/0006 ,  B01D71/32 ,  B01D71/64 ,  B01D71/76 ,  B01D71/82 ,  B01D2323/38 ,  B01D2325/26 ,  C08J5/2237 ,  C08J2327/18 ,  C08J2381/06 ,  C08J2400/202 ,  H01M8/1023 ,  H01M8/103 ,  H01M8/1039 ,  H01M8/1041 ,  H01M8/1081 ,  Y02P70/56

Abstract: A proton exchange membrane comprising modified hyper-branched polymer is disclosed. The proton exchange membrane includes 85-90 wt % of sulfonated tetrafluorethylene copolymer and 15-10 wt % of modified hyper-branched polymer. The modified hyper-branched polymer comprises the bismaleimide (BMI)-based hyper-branched polymer, and parts of the chain ends of the hyper-branched polymer are sulfonated by the sulfonic compound. Also, the modified hyper-branched polymer and sulfonated tetrafluorethylene copolymer are interpenetrated to form an interpenetrating polymer. Furthermore, the modification step could be performed before or after forming the interpenetrating polymer. For example, the sulfonation is proceeded after forming the interpenetrating polymer. Alternatively, the sulfonation of the hyper-branched polymer could be proceeded before the formation of the interpenetrating polymer.

Abstract translation: 公开了包含改性的超支化聚合物的质子交换膜。 质子交换膜包括85-90重量％的磺化四氟乙烯共聚物和15-10重量％的改性超支化聚合物。 改性的超支化聚合物包含基于双马来酰亚胺（BMI）的超支化聚合物，并且超支化聚合物的链端部分被磺酸化合物磺化。 此外，改性的超支化聚合物和磺化四氟乙烯共聚物被互穿以形成互穿聚合物。 此外，改性步骤可以在形成互穿聚合物之前或之后进行。 例如，在形成互穿聚合物之后进行磺化。 或者，超支化聚合物的磺化可以在形成互穿聚合物之前进行。

公开(公告)号：US07807301B2

公开(公告)日：2010-10-05

申请号：US12344074

申请日：2008-12-24

Applicant: Hung-Chun Wu ,  Fu-Ming Wang ,  Ching-Yi Su ,  Chang-Rung Yang ,  Jing-Pin Pan ,  Yu-Chan Yen ,  Nae-Lih Wu

Inventor： Hung-Chun Wu ,  Fu-Ming Wang ,  Ching-Yi Su ,  Chang-Rung Yang ,  Jing-Pin Pan ,  Yu-Chan Yen ,  Nae-Lih Wu

IPC: H01M10/40

CPC classification number: H01M10/0567 ,  H01M2/16 ,  H01M4/131 ,  H01M4/134 ,  H01M4/622 ,  H01M4/623 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569

Abstract: Disclosed is a lithium battery including a silicon negative electrode, a lithium mixed metal oxide positive electrode, a separator disposed between the negative and positive electrodes to define a reservoir region, an electrolytic solution filled in the reservoir region, and a sealant structure wrapped around the silicon negative electrode, the lithium mixed metal oxide positive electrode, the separator, and the electrolytic solution. The electrolytic solution includes an organic solvent, a lithium salt, and an additive. The additive includes a maleimide compound and vinylene carbonate. The silicon negative electrode of the lithium battery employing the described electrolytic solution has higher cycle efficiency and longer operating lifespan.

Abstract translation: 公开了一种锂电池，其包括硅负极，锂复合金属氧化物正极，设置在负极和正极之间的隔板，以限定储存区，填充在储存区中的电解液和围绕 硅负极，锂复合金属氧化物正极，隔膜和电解液。 电解液包括有机溶剂，锂盐和添加剂。 添加剂包括马来酰亚胺化合物和碳酸亚乙烯酯。 使用所述电解液的锂电池的硅负极具有更高的循环效率和更长的使用寿命。

公开(公告)号：US20100167102A1

公开(公告)日：2010-07-01

申请号：US12567048

申请日：2009-09-25

Applicant: Jing-Pin PAN ,  Yueh-Wei LIN ,  Chung-Liang CHANG ,  Li- Duan TSAI ,  Ya-Tin HSU

Inventor： Jing-Pin PAN ,  Yueh-Wei LIN ,  Chung-Liang CHANG ,  Li- Duan TSAI ,  Ya-Tin HSU

IPC: H01M8/10 ,  B05D5/12

CPC classification number: H01M8/1039 ,  C08J5/2275 ,  C08J2300/202 ,  C08J2300/208 ,  C08L27/18 ,  C08L2205/04 ,  H01M8/1023 ,  H01M8/1041 ,  H01M8/1081 ,  Y02P70/56 ,  C08L79/085

Abstract: The disclosed forms a proton exchange membrane. First, multi-maleimide and barbituric acid are copolymerized to form a hyper-branched polymer. Next, the solvent of the sulfonated tetrafluorethylene copolymer (Nafion) aqueous solution is replaced from water with dimethyl acetamide (DMAc). 10 to 20 parts by weight of the hyper-branched polymer is added to the 90 to 80 parts by weight of the Nafion in a DMAc solution, stood and heated to 50° C. to inter-penetrate the hyper-branched polymer and the Nafion. The heated solution is coated on a substrate, baked, and pre-treated to remove residue solvent for completing an inter-penetrated proton exchange membrane.

Abstract translation: 所公开的形成质子交换膜。 首先，将多马来酰亚胺和巴比妥酸共聚以形成超支化聚合物。 接着，将磺化四氟乙烯共聚物（Nafion）水溶液的溶剂用二甲基乙酰胺（DMAc）从水中取代。 将10〜20重量份的超支化聚合物加入到在DMAc溶液中的90至80重量份的Nafion中，并加热至50℃以相互渗透超支化聚合物和Nafion 。 将加热的溶液涂布在基材上，烘烤并预处理以除去残留溶剂以完成相互穿透的质子交换膜。

公开(公告)号：US20100130625A1

公开(公告)日：2010-05-27

申请号：US12418534

申请日：2009-04-03

Applicant: Chung-Liang CHANG ,  Jing-Pin PAN ,  Tsung-Hsiung WANG ,  Yueh-Wei LIN ,  Ya-Tin HSU

Inventor： Chung-Liang CHANG ,  Jing-Pin PAN ,  Tsung-Hsiung WANG ,  Yueh-Wei LIN ,  Ya-Tin HSU

IPC: C08J5/20

CPC classification number: C08G83/005 ,  C08J5/2275 ,  C08J2327/18 ,  C08J2400/202 ,  H01M8/1023 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/1072 ,  H01M8/1081 ,  Y02P70/56

Abstract: A proton exchange membrane and method for formation the same is disclosed. When forming the proton exchange membrane, first, a bismaleimide and barbituric acid are copolymerized to form a hyper-branched polymer. Next, the solvent of the sulfonated tetrafluorethylene copolymer (Nafion) aqueous solution is replaced with dimethyl acetamide (DMAc). 10 to 15 parts by weight of the hyper-branched polymer is added to 90 to 85 parts by weight of the Nafion in the DMAc solution, stood and heated to 50° C. for inter-penetration of the hyper-branched polymer and the Nafion. The heated solution is coated on a substrate, baked, and pre-treated to remove residue solvent to complete formation of the proton exchange membrane.

Abstract translation: 公开了质子交换膜及其形成方法。 当形成质子交换膜时，首先将双马来酰亚胺和巴比妥酸共聚以形成超支化聚合物。 接着，用二甲基乙酰胺（DMAc）代替磺化四氟乙烯共聚物（Nafion）水溶液的溶剂。 将10〜15重量份的超支化聚合物加入到在DMAc溶液中的90至85重量份的Nafion中，并加热至50℃，以使超支化聚合物和Nafion的相互渗透 。 将加热的溶液涂覆在基材上，烘烤并预处理以除去残留溶剂以完成质子交换膜的形成。

公开(公告)号：US07560194B2

公开(公告)日：2009-07-14

申请号：US11304708

申请日：2005-12-16

Applicant: Yueh-Wei Lin ,  Jing-Pin Pan ,  Mao-Sung Wu ,  Jyh-Tsung Lee ,  Jung-Mu Hsu ,  Jung-Cheng Lin

Inventor： Yueh-Wei Lin ,  Jing-Pin Pan ,  Mao-Sung Wu ,  Jyh-Tsung Lee ,  Jung-Mu Hsu ,  Jung-Cheng Lin

IPC: H01M10/40

CPC classification number: H01M10/0565 ,  C08J5/20 ,  C08K5/3415 ,  H01B1/122 ,  H01M10/0525 ,  H01M10/0569 ,  H01M2300/0085

Abstract: The present invention is directed to a gel polymer electrolyte for use in rechargeable polymer secondary batteries and a precursor composition thereof. The precursor composition can be injected into an aluminum shell of a battery cell, which undergoes in-situ heating polymerization by heating and forms a gel polymer electrolyte penetrating a partition membrane therein. The precursor composition contains (meth)acrylic (acrylate) monomers and a modified bismaleimide oligomer resulting from a reaction of barbituric acid and bismaleimide.

Abstract translation: 本发明涉及用于可再充电聚合物二次电池的凝胶聚合物电解质及其前体组合物。 可以将前体组合物注入电池单元的铝壳中，通过加热进行原位加热聚合，形成透过其中的隔膜的凝胶聚合物电解质。 前体组合物含有（甲基）丙烯酸（丙烯酸酯）单体和由巴比妥酸和双马来酰亚胺反应得到的改性双马来酰亚胺低聚物。

公开(公告)号：US20080160418A1

公开(公告)日：2008-07-03

申请号：US11964772

申请日：2007-12-27

Applicant: Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

Inventor： Jing-Pin Pan ,  Chang-Rung Yang ,  Tsung-Hsiung Wang ,  Yueh-Wei Lin ,  Pin-Chi Chiang ,  Jung-Mu Hsu

IPC: H01M10/40

CPC classification number: H01M10/0567 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/4235

Abstract: A nonaqueous electrolyte having maleimide additives and rechargeable cells employing the same are provided. The nonaqueous electrolyte having maleimide additives comprises an alkali metal electrolyte, a nonaqueous solvent, and maleimide additives. Specifically, the maleimide additives comprise maleimide monomer, bismaleimide monomer, bismaleimide oligomer, or mixtures thereof. The maleimide additives comprise functional groups, such as a maleimide double bond, phenyl group carboxyl, or imide, enhancing the charge-discharge efficiency, safety, thermal stability, chemical stability, flame-resistance, and lifespan of the secondary cells of the invention.

Abstract translation: 提供具有马来酰亚胺添加剂的非水电解质和使用该非水电解质的可充电电池。 具有马来酰亚胺添加剂的非水电解质包括碱金属电解质，非水溶剂和马来酰亚胺添加剂。 具体地，马来酰亚胺添加剂包括马来酰亚胺单体，双马来酰亚胺单体，双马来酰亚胺低聚物或其混合物。 马来酰亚胺添加剂包括官能团，例如马来酰亚胺双键，苯基羧基或酰亚胺，提高本发明的二次电池的充电 - 放电效率，安全性，热稳定性，化学稳定性，阻燃性和寿命。

公开(公告)号：US20080146706A1

公开(公告)日：2008-06-19

申请号：US11878099

申请日：2007-07-20

Applicant: Feng-Po Tseng ,  Jung-Mu Hsu ,  Jing-Pin Pan ,  Tzong-Ming Lee

Inventor： Feng-Po Tseng ,  Jung-Mu Hsu ,  Jing-Pin Pan ,  Tzong-Ming Lee

IPC: C08K5/3467 ,  C08G59/00

CPC classification number: C08K5/3415 ,  C08G59/4042 ,  C08K5/3462 ,  C08L63/00 ,  C09J163/00 ,  H05K1/0373 ,  H05K1/0393 ,  H05K3/386 ,  H05K2201/0209 ,  Y10T428/24917

Abstract: The invention provides a halogen-free and thermal resistant composition, including a mixture of bismaleimide and maleimide with molar ratio of 99:1-50:50; a barbituric acid, wherein the molar ratio of the mixture and the barbituric acid is 93:7-80:20; and an epoxy resin, wherein (the mixture with the barbituric acid) and the epoxy resin have a weight ratio of 5:95 to 50:50. The mixture undergoes reaction at 110-130° C. for about 2˜7 hours to form a maleimide modified epoxy resin. The procedure of forming the composition is solvent-free, thereby providing improved integrity for electronic packaging, lower curing temperature, and a simplified process.

Abstract translation: 本发明提供了一种无卤素和耐热组合物，包括摩尔比为99:1-50:50的双马来酰亚胺和马来酰亚胺的混合物; 巴比妥酸，其中混合物和巴比妥酸的摩尔比为93:7-780:20; 和环氧树脂，其中（与巴豆酸的混合物）和环氧树脂的重量比为5:95至50:50。 混合物在110-130℃下反应约2〜7小时，形成马来酰亚胺改性环氧树脂。 形成组合物的方法是无溶剂的，从而为电子包装提供改进的完整性，降低固化温度和简化的工艺。