摘要:
The present invention is directed to a composition of matter useful as a multifunctional viscosity improver-dispersant for oleaginous compositions, particularly lubricating oil compositions, comprising at least one adduct or reaction product of (A) ethylene copolymer, preferably ethylene propylene copolymer of at least 15,000 number average molecular weight grafted with monounsaturated mono- or dicarboxylic acid material; (B) amido-amine or thioamido-amine comprising reaction product of at least one amine, preferably polyamine, and an alpha, beta-unsaturated compound represented by the formula ##STR1## wherein X is sulfur or oxygen, Y is --OR.sup.4, --SR.sup.4, or ##STR2## and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently selected from hydrogen, hydrocarbyl, and substituted hydrocarbyl, and (D) viscosity stabilizing effective amount of C.sub.12 to about C.sub.18 hydrocarbyl substituted dicarboxylic anhydride. The present invention is also directed to oleaginous compositions and concentrates, particularly lubricating oil compositions and concentrates, containing said adduct whereby said compositions exhibit improved viscosity stability for extended periods of time.
摘要:
The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 10,000 number average molecular weight substituted with thiocarboxylic acid producing moieties (preferably acid or anhydride moieties), wherein the terminal unsaturation comprises ethenylidene unsaturation. The thiocarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.
摘要:
A material useful as a dispersant additive in oleaginous compositions selected from fuels and lubricating oils comprising the reaction products of:(i) at least one intermediate adduct comprised of the reaction products of(a) at least one polyepoxide, and(b) at least one member selected from the group consisting of polyamines, polyols, and amino alcohols; and(ii) at least one of (a) hydrocarbyl substituted C.sub.3 -C.sub.10 monocarboxylic or C.sub.4 -C.sub.10 dicarboxylic acid producing material; (b) an aldehyde and a hydrocarbyl substituted hydroxy aromatic compound; or (c) an aldehyde and the reaction product of a hydrocarbyl substituted C.sub.3 -C.sub.10 monocarboxylic or C.sub.4 -C.sub.10 dicarboxylic acid or anhydride and an amine substituted hydroxy aromatic compound.Also included is a process for preparing said material and an oleaginous composition containing said material.
摘要:
C.sub.5 -C.sub.9 lactone based adduct materials are made by reacting a C.sub.5 -C.sub.9 lactone with a polyol to form a lactone adduct intermediate, and thereafter reacting the intermediate with an aliphatic hydrocarbyl saturated or unsaturated, straight chain or branched chain monocarboxylic or dicarboxylic acylating agent having from about one to about 165 total carbon atoms in said straight or branched chain to insure that the resulting lactone adduct is hydrocarbon soluble. The resulting adduct material are useful per se, as oil soluble dispersant additives, and are useful in fuel and lubricating oil compositions including concentrates containing the additives.
摘要:
An oil soluble dispersant comprising the reaction products of:(1)(i) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides; (ii) long chain hydrocarbon having a polyamine attached directly thereto; (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyamine; and (iv) Mannich condensation product formed by reacting long chain hydrocarbyl substituted mono or dicarboxylic acids or their anhydrides with an aminophenol, which may be optionally hydrocarbyl substituted, to form a long chain hydrocarbyl substituted amide or imide-containing phenol intermediate adduct, and condensing said long chain hydrocarbyl substituted amide or imide-containing phenol adduct with aldehyde and polyamine; said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2) at least one polythioepoxide. Also disclosed are oleaginous compositions, particularly lubricating oil compositions, containing said dispersant.
摘要:
An oil soluble dispersant comprising the reaction products of:(1) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides; (ii) long chain hydrocarbon having a polyamine attached directly thereto; (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyalkylene polyamine; and (iv) Mannich condensation product formed by reacting long chain hydrocarbyl substituted mono or dicarboxylic acids or their anhydrides with an aminophenol, which may be optionally hydrocarbyl substituted, to form a long chain hydrocarbyl substituted amide or imide-containing phenol intermediate adduct, and condensing said long chain hydrocarbyl substituted amide or imide-containing phenol adduct with aldehyde and polyamine; said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2) at least one polyepoxide.
摘要:
Poly (C.sub.5 -C.sub.9 lactone) modified Mannich base adducts are made by reacting a C.sub.5 -C.sub.9 lactone, an amine, an aldehyde, an N-hydroxyarylamine, and a hydrocarbyl substituted C.sub.4 -C.sub.10 monounsaturated dicarboxylic acid producing material, e.g., a polyisobutenyl, succinic anhydride, which, in turn, preferably is made by reacting a polymer of a C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 700 to 10,000 with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are about 0.7 to 2.00 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting adducts are useful per se as oil soluble dispersant additives. They are also useful in fuel and lubricating oil compositions, as well as in concentrates and additive packages.
摘要:
C.sub.5 -C.sub.9 lactone based adduct materials are made by reacting a C.sub.5 -C.sub.9 lactone with a polyamine, a polyol or an amino alcohol to form a lactone adduct intermediate, and thereafter reacting the intermediate with a hydrocarbyl substituted C.sub.4 -C.sub.10 monounsaturated dicarboxylic acid producing material, e.g., a polyisobutenyl succinimide, which, in turn, preferably was made by reacting a polymer of a C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 300 to 10,000 with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 0.7 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting adduct material are useful per se, as oil soluble dispersant additives, and are useful in fuel and lubricating oil compositions including concentrates containing the additives.
摘要:
Hydroxyl terminated polymeric C.sub.5 -C.sub.9 lactone adducts are made by reacting a C.sub.5 -C.sub.9 lactone with the reaction product of a C.sub.2 -C.sub.10 olefin polymer or a halogenated derivative thereof having a number average molecular weight of 300 to about 10,000, with an amine containing from 2 to 60 total carbon atoms and from 1 to 12 nitrogen atoms. The resulting adducts are useful per se as oil soluble dispersant additives. They are also useful in fuel and lubricating oil compositions, as well as in concentrates and additive packages.
摘要:
Oil soluble viscosity index improving additives comprising ethylene compolymers such as copolymers of ethylene and propylene; and ethylene, propylene and diolefin; etc. reacted or grafted with ethylenically unsaturated carboxylic acid moieties, preferably maleic anhydride moieties, and reacted with amines having two or more primary amine groups or at least one primary amine group and at least one secondary amine group and a carboxylic acid component, preferably alkylene polyamine and with alkenyl succinic anhydride such as polyisobutenyl succinic anhydride, are improved by being further reacted with a lactone, preferably a lactone having at least 6 atoms in the lactone ring. The resulting lactone modified products are useful per se as oil soluble V.I. additives in fuel and lubricating compositions including concentrates containing the additives.