公开(公告)号：US20180030218A1

公开(公告)日：2018-02-01

申请号：US15552833

申请日：2016-02-17

Applicant: BASF SE

Inventor： Tina Mark ,  Thomas Daniel ,  Erich Lutz ,  Stefan Molter ,  Anna Kowalski

IPC: C08J3/24 ,  C08F6/16 ,  A61L15/24 ,  C08F6/18 ,  C08F120/06 ,  A61L15/60

CPC classification number: C08J3/245 ,  A61L15/24 ,  A61L15/42 ,  A61L15/60 ,  C08F2/14 ,  C08F2/18 ,  C08F6/16 ,  C08F6/18 ,  C08F120/06 ,  C08F220/06 ,  C08F2810/20 ,  C08J2333/02 ,  C08L101/14 ,  C08F222/385

Abstract: A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the agglomerated base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 140 to 220° C.

公开(公告)号：US20160280825A1

公开(公告)日：2016-09-29

申请号：US15032333

申请日：2014-10-20

Applicant: BASF SE

Inventor： Stephan Bauer ,  Tina Mark ,  Lydia König ,  Yvonne Hagen ,  Thomas Daniel

IPC: C08F220/06 ,  A61F13/53 ,  A61F13/534 ,  A61L15/60 ,  A61L15/24

Abstract: A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.

Abstract translation: 通过悬浮聚合和热表面后交联制造吸水性聚合物颗粒的方法，其中通过悬浮聚合获得的基础聚合物具有至少37g / g的离心保留能力，并且热表面后交联在100至190℃下进行 。

公开(公告)号：US20160272745A1

公开(公告)日：2016-09-22

申请号：US14442501

申请日：2013-11-11

Applicant: BASF SE

Inventor： Thomas Daniel ,  Norbert Herfert ,  Stephan Bauer ,  Katrin Baumann ,  Birgit Reinhard ,  Jürgen Freiberg ,  Rudolf Schliwa

IPC: C08F220/06 ,  B01J20/28 ,  B01J20/26 ,  A61L15/24 ,  A61L15/60

CPC classification number: C08F220/06 ,  A61L15/22 ,  A61L15/24 ,  A61L15/42 ,  A61L15/60 ,  B01J20/267 ,  B01J20/28023 ,  B01J20/2805 ,  C08F6/005 ,  C08L33/02 ,  C08L33/08 ,  C08F2222/1013

Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution comprising less than 0.3% by weight of persulfate and at least 0.05% by weight of azo initiator and thermal aftertreatment of the formed polymer particles at less than 100° C. in a fluidized bed for 60 to 300 minutes.

Abstract translation: 本发明涉及通过聚合包含小于0.3重量％的过硫酸盐和至少0.05重量％的偶氮引发剂的单体溶液的液滴制备吸水性聚合物颗粒的方法，并且所形成的聚合物颗粒的热后处理少 在流化床中超过100℃，持续60至300分钟。

公开(公告)号：US09126186B2

公开(公告)日：2015-09-08

申请号：US13672129

申请日：2012-11-08

Applicant: BASF SE

Inventor： Joerg Belack ,  Thomas Daniel ,  Christophe Bauduin

IPC: B01J20/26 ,  A61L15/60 ,  C08J3/24 ,  A61L15/24

CPC classification number: B01J20/267 ,  A61L15/24 ,  A61L15/60 ,  C08J3/245 ,  C08J2333/02 ,  C08L33/08

Abstract: A process for producing thermally surface postcrosslinked water-absorbing polymer particles, wherein the water-absorbing polymer particles are coated before, during or after the thermal surface postcrosslinking with at least one complex consisting of a polyvalent metal salt and a 2-hydroxycarboxamide.

Abstract translation: 一种制备热表面后交联吸水性聚合物颗粒的方法，其中吸水聚合物颗粒在与至少一种由多价金属盐和2-羟基甲酰胺组成的络合物进行热表面后交联之前，期间或之后被涂覆。

公开(公告)号：US09073040B2

公开(公告)日：2015-07-07

申请号：US13870599

申请日：2013-04-25

Applicant: BASF SE

Inventor： Rainer Dobrawa ,  Thomas Daniel ,  Uwe Stueven ,  Marco Krüger ,  Francisco Javier Lopez Villanueva ,  Norbert Herfert ,  Karin Flore ,  Stefan Blei ,  Michael A. Mitchell

IPC: B32B5/16 ,  C08L31/02 ,  C08L33/04 ,  B01J20/26 ,  A61L15/60 ,  C08F2/10 ,  C08F220/06 ,  B01J20/30 ,  C08F222/10

CPC classification number: B01J20/26 ,  A61L15/60 ,  B01J20/264 ,  B01J20/3085 ,  C08F2/10 ,  C08F220/06 ,  C08F222/1006 ,  Y10T428/249958 ,  Y10T428/249981 ,  Y10T428/254 ,  Y10T428/2982 ,  Y10T428/31935

Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, wherein the temperature of the gas leaving the polymerization chamber is 130° C. or less, the gas velocity inside the polymerization chamber is at least 0.5 m/s, and the droplets are generated by using a droplet plate having a multitude of bores.

Abstract translation: 本发明涉及一种通过在周围加热气相中聚合单体溶液的液滴并使气体并流通过聚合室流过气体聚合物颗粒的方法，其中离开聚合室的气体的温度为130℃ 聚合室内的气体速度为至少0.5m / s，通过使用具有多个孔的液滴板产生液滴。

公开(公告)号：US20150119531A1

公开(公告)日：2015-04-30

申请号：US14407490

申请日：2013-06-21

Applicant: BASF SE

Inventor： Christophe Bauduin ,  Thomas Daniel ,  Asif Karim

IPC: C08J3/24 ,  A61L15/42 ,  A61L15/24

CPC classification number: C08J3/245 ,  A61L15/22 ,  A61L15/24 ,  A61L15/42 ,  A61L15/60 ,  C08F6/008 ,  C08J2333/02

Abstract: The present invention relates to a process for producing water-absorbing polymer particles having an improved profile of properties, comprising thermal surface postcrosslinking in the presence of a salt of a polyvalent metal cation and a complexing anion and subsequent aftertreatment, the aftertreatment comprising coating with a salt of a polyvalent metal cation and a non-complexing anion, and remoisturization with further drying.

Abstract translation: 本发明涉及具有改进的性能特征的吸水性聚合物颗粒的制造方法，其包括在多价金属阳离子的盐和络合阴离子存在下的热表面后交联和随后的后处理，后处理包括用 多价金属阳离子和非络合阴离子的盐，并进一步干燥进行再润湿。

公开(公告)号：US20150090934A1

公开(公告)日：2015-04-02

申请号：US14563546

申请日：2014-12-08

Applicant: BASF SE

Inventor： Volker Braig ,  Thomas Daniel ,  Rupert Kohradi ,  Herbert Platsch ,  Bettina Sobotka ,  Axel Jentzsch

IPC: A61L15/18 ,  A61L15/46 ,  A61L15/26 ,  A61L15/60

CPC classification number: A61L15/18 ,  A61F13/8405 ,  A61L15/26 ,  A61L15/46 ,  A61L15/60 ,  A61L2300/102 ,  A61L2300/11

Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.

Abstract translation: 本发明涉及包含吸水性聚合物颗粒和金属过氧化物的气味抑制组合物及其制备。

公开(公告)号：US20130331260A1

公开(公告)日：2013-12-12

申请号：US13908332

申请日：2013-06-03

Applicant: BASF SE

Inventor： Olaf Hoeller ,  Volker Braig ,  Thomas Daniel ,  Patrick Hamilton

IPC: B01J20/22 ,  A61L15/46 ,  A61L15/20 ,  B01J20/26

CPC classification number: B01J20/22 ,  A61L15/20 ,  A61L15/46 ,  A61L15/60 ,  B01J20/267 ,  C08F220/06 ,  C08K5/5399 ,  C08L33/02 ,  C08L33/08 ,  C08F2222/1013

Abstract: Superabsorbents comprising fluorofamide exhibit superior odour control without being biocides.

Abstract translation: 包含氟代酰胺的超吸收剂表现出优异的气味控制而不是杀生物剂。

公开(公告)号：US20130281594A1

公开(公告)日：2013-10-24

申请号：US13870599

申请日：2013-04-25

Applicant: BASF SE

Inventor： Rainer Dobrawa ,  Thomas Daniel ,  Uwe Stueven ,  Marco Krüger ,  Francisco Javier Lopez Villanueva ,  Norbert Herfert ,  Michael A. Mitchell

IPC: B01J20/26 ,  B01J20/30

CPC classification number: B01J20/26 ,  A61L15/60 ,  B01J20/264 ,  B01J20/3085 ,  C08F2/10 ,  C08F220/06 ,  C08F222/1006 ,  Y10T428/249958 ,  Y10T428/249981 ,  Y10T428/254 ,  Y10T428/2982 ,  Y10T428/31935

Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, wherein the temperature of the gas leaving the polymerization chamber is 130° C. or less, the gas velocity inside the polymerization chamber is at least 0.5 m/s, and the droplets are generated by using a droplet plate having a multitude of bores.

Abstract translation: 本发明涉及一种通过在周围加热气相中聚合单体溶液的液滴并使气体并流通过聚合室流过气体聚合物颗粒的方法，其中离开聚合室的气体的温度为130℃ 聚合室内的气体速度为至少0.5m / s，通过使用具有多个孔的液滴板产生液滴。

公开(公告)号：US20130260988A1

公开(公告)日：2013-10-03

申请号：US13853457

申请日：2013-03-29

Applicant: BASF SE

Inventor： Norbert Herfert ,  Thomas Daniel

IPC: B01J20/22 ,  B01J20/30

CPC classification number: B01J20/223 ,  A61L15/60 ,  B01J20/265 ,  B01J20/3085 ,  C08F8/40 ,  C08F8/42 ,  C08F220/06 ,  C08J3/128 ,  C08J3/245 ,  C08K3/00 ,  C08K3/22 ,  C08K5/00 ,  C08K5/5317 ,  C08K5/5353 ,  C08K2201/013

Abstract: A superabsorbent having surfaces complexed with polyvalent metal ions and which contains at least one phosphonic acid derivative, and the molar ratio between polyvalent metal and phosphonic acid derivative is at most 1.2/n, where n is the number of phosphonic acid groups in the phosphonic acid derivative. The superabsorbent exhibits good stability against discoloration and a surprisingly low caking tendency without any significant impairment of its performance properties.

Abstract translation: 具有与多价金属离子络合的表面并含有至少一种膦酸衍生物的超吸收体，多价金属与膦酸衍生物的摩尔比为1.2以下，n为膦酸中的膦酸基数 衍生物。 超吸收剂表现出良好的抗变色稳定性和令人惊讶的低结块倾向，而其性能特性没有任何显着的损害。