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公开(公告)号：US4943545A
公开(公告)日：1990-07-24
申请号：US258090
申请日：1988-10-14
Applicant: Clarence D. Chang , Scott Han , Bruce P. Pelrine
Inventor： Clarence D. Chang , Scott Han , Bruce P. Pelrine
CPC classification number: B01J29/40 , B01J29/084 , B01J29/90 , B01J2229/42 , Y10S423/22 , Y10S423/23 , Y10S423/27 , Y10S423/29 , Y10S423/33 , Y10S423/36
Abstract: Zeolitic catalysts containing framework displaced aluminum, e.g., steamed or spent catalysts, are activated by contact with aqueous fluoride solution under mild conditions. The treatment can enhance catalytic activity, ion-exchange capacity and crystallinity by replacing aluminum in the zeolitic framework.
Abstract translation: 含有骨架置换铝的沸石催化剂，例如蒸汽或废催化剂，通过在温和条件下与氟化钠水溶液接触来活化。 该处理可以通过在沸石框架中代替铝来提高催化活性，离子交换容量和结晶度。
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公开(公告)号：US4912275A
公开(公告)日：1990-03-27
申请号：US310124
申请日：1989-02-15
Applicant: Clarence D. Chang , Cynthia T-W. Chu , Carol S. Lee
Inventor： Clarence D. Chang , Cynthia T-W. Chu , Carol S. Lee
CPC classification number: C10G11/05 , B01J29/40 , B01J29/90 , C10G3/49 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/65 , B01J29/70 , C10G2300/4006 , C10G2300/703 , C10G2400/30 , Y02P30/20
Abstract: Alumina-composited zeolite catalysts are activated by contact with an aqueous ammonium solution under ammonia gas pressure such that a pH of at least about 8 is maintained in the solution. The treated zeolite may thereafter be calcined without prior ammonium-exhange to provide the zeolite in the hydrogen form. Catalysts which are activated in this manner are useful for converting alcohols and/or ethers to hydrocarbons including aromatics.
Abstract translation: 通过在氨气压力下与铵水溶液接触来活化氧化铝复合沸石催化剂，使得溶液中保持至少约8的pH。 然后处理的沸石可以在没有先前的铵铵化的条件下煅烧，以提供氢形式的沸石。 以这种方式活化的催化剂可用于将醇和/或醚转化成包括芳烃的烃。
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63.发明授权Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index 失效改性结晶硅铝酸盐沸石催化剂及其在生产高黏度指数的润滑剂中的应用
公开(公告)号：US4876411A
公开(公告)日：1989-10-24
申请号：US27034
申请日：1987-03-19
Applicant: Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
Inventor： Emmerson Bowes , Clarence D. Chang , Scott Han , David S. Shihabi
IPC: C10G50/02
CPC classification number: C10G50/02
Abstract: The present invention provides a process for modifying a crystalline aluminosilicate zeolite having a Constraint Index of from about to about 12 which comprises:(a) steaming the as synthesized crytalline aluminosilicate zeolite containing organic template material to decompose at least a portion of said template material and to extract zeolitic aluminum; and,(b) contacting the zeolite resulting from step (a) in the ammonium, alkali metal or hydrogen form with a dealuminizing agent which forms a water-soluble complex with aluminum to remove a further quantity of zeolitic aluminum therefrom wherein said treated catalyst is employed in the making of lube oil from olefins.
Abstract translation: 本发明提供了一种修饰约约至约12的约束指数的结晶硅铝酸盐沸石的方法，该方法包括：（a）蒸煮含有有机模板材料的合成的胆固醇铝硅酸盐沸石，以分解所述模板材料的至少一部分，以及 提取沸石铝; 和（b）将由步骤（a）得到的沸石以铵，碱金属或氢的形式与脱铝剂接触，脱铝剂与铝形成水溶性络合物，以从中除去另外量的沸石铝，其中所述处理过的催化剂为 用于从烯烃制备润滑油。
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公开(公告)号：US4788370A
公开(公告)日：1988-11-29
申请号：US082397
申请日：1987-08-06
Applicant: Clarence D. Chang , David S. Shihabi , Paul B. Weisz
Inventor： Clarence D. Chang , David S. Shihabi , Paul B. Weisz
CPC classification number: B01J29/86 , C01B35/1009 , Y10S423/27
Abstract: A process is provided for converting feedstock comprising C.sub.2.sup.+ olefins, C.sub.2 -C.sub.7 paraffins or mixtures thereof to product comprising C.sub.5.sup.+ hydrocarbons over a catalyst comprising a siliceous zeolite prepared by the method comprising providing zeolite Beta containing boron and aluminum, treating the zeolite with silicon tetrachloride at a temperature and for a time sufficient to replace boron with silicon, and recovering the siliceous zeolite having reduced boron content but substantially preserved initial aluminum content.
Abstract translation: 提供了一种方法，用于将包含C 2 +烯烃，C 2 -C 7链烷烃或其混合物的原料转化为包含通过包括提供含硼和铝的沸石β的方法制备的硅质沸石的催化剂的包含C5 +烃的产物， 足以用硅代替硼的温度和时间，以及回收具有降低的硼含量但基本保持初始铝含量的硅质沸石。
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公开(公告)号：US4784749A
公开(公告)日：1988-11-15
申请号：US82398
申请日：1987-08-06
Applicant: Clarence D. Chang , David S. Shihabi , Paul B. Weisz
Inventor： Clarence D. Chang , David S. Shihabi , Paul B. Weisz
CPC classification number: B01J29/86 , C01B35/1009 , Y10S423/27
Abstract: A process is provided for converting feedstock comprising hydrocarbon compounds to product comprising hydrocarbon compounds of lower molecular weight than feedstock hydrocarbon compounds over a catalyst comprising a siliceous zeolite prepared by the method comprising providing zeolite Beta containing boron and aluminum, treating the zeolite with silicon tetrachloride at a temperature and for a time sufficient to replace boron with silicon, and recovering the siliceous zeolite having reduced boron content but substantially preserved initial aluminum content. In particular embodiments, the conversion is selective cracking for waxes and the process is useful for reducing the pour point of fuel oils and lubricants.
Abstract translation: 提供了一种方法，用于将包含烃化合物的原料转化成包含比原料烃化合物低的原料烃化合物的烃化合物的产物，该催化剂包含通过包括提供含硼和铝的β沸石的方法制备的硅沸石，用四氯化硅处理沸石 足以用硅代替硼的温度和时间，以及回收具有降低的硼含量但基本保持初始铝含量的硅质沸石。 在具体实施方案中，该转化是蜡的选择性裂化，并且该方法可用于降低燃料油和润滑剂的倾点。
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Patent Agency Ranking66.发明授权Organic compound conversion with ammonium hydroxide and alkali metal aluminate treated zeolite 失效用氢氧化铵和碱金属铝酸盐处理的沸石的有机化合物转化
公开(公告)号：US4780194A
公开(公告)日：1988-10-25
申请号：US910244
申请日：1986-09-18
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
Abstract: This invention relates to acid catalysis, e.g. cracking, of organic compound feedstock, e.g. hydrocarbons, over catalyst material treated in a special way for increasing the acid catalytic activity thereof. In particular, a novel catalyst activation process is followed to enhance the alpha value of high-silica zeolite catalyst by contact with an ammoniacal solution of ammonium hydroxide and an alkali metal aluminate under appropriate conditions of time, temperature of pH.
Abstract translation: 本发明涉及酸催化，例如 有机化合物原料的裂化，例如。 碳氢化合物，以特殊方式处理以提高其酸催化活性的催化剂材料。 特别地，遵循新的催化剂活化方法，以在适当的时间，pH温度条件下，通过与铵氢氧化铵和碱金属铝酸盐的氨溶液接触来提高高二氧化硅沸石催化剂的α值。
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公开(公告)号：US4678763A
公开(公告)日：1987-07-07
申请号：US819944
申请日：1986-01-17
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
CPC classification number: B01J29/90
Abstract: Heat-damaged ZSM-5 type catalysts are reclaimed by hydrothermal treatment with an aqueous medium followed by base exchange with an ammonium salt.
Abstract translation: 热损坏的ZSM-5型催化剂通过用水介质进行水热处理回收，然后与铵盐进行碱交换。
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公开(公告)号：US4645864A
公开(公告)日：1987-02-24
申请号：US818968
申请日：1986-01-08
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
CPC classification number: C01B39/026 , B01J29/04 , C01B35/1009
Abstract: A method for increasing the total amount of lattice metal in the framework of a particular porous inorganic crystalline composition, its conversion to hydrogen or hydronium form and use thereof as a catalyst component having enhanced catalytic activity for conversion of oxygenates to hydrocarbons is provided.
Abstract translation: 提供了一种在特定的多孔无机结晶组合物的骨架中增加晶格金属总量的方法，其转化为氢或水合物形式，并且其用作催化剂组分的用途，其具有提高的含氧化合物转化为烃的催化活性。
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69.发明授权Process for the preparation of zeolite Beta using dibenzyldimethylammonium ions and the product produced 失效使用二苄基二甲基铵离子制备沸石β的方法和产生的产物
公开(公告)号：US4642226A
公开(公告)日：1987-02-10
申请号：US717997
申请日：1985-03-29
Applicant: Robert B. Calvert , Clarence D. Chang , Mae K. Rubin , Ernest W. Valyocsik
Inventor： Robert B. Calvert , Clarence D. Chang , Mae K. Rubin , Ernest W. Valyocsik
CPC classification number: B01J29/7007 , C01B39/48 , B01J2229/20 , B01J2229/26 , B01J2229/42 , Y10S423/27
Abstract: This invention relates to a new and improved form of crystalline silicate having the structure of zeolite Beta, to a new and useful improvement in synthesizing said crystalline silicate and to use of said crystalline silicate prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
Abstract translation: 本发明涉及一种具有β沸石结构的新型和改进形式的结晶硅酸盐，以便合成所述结晶硅酸盐的新的和有用的改进，以及使用根据本文制备的所述结晶硅酸盐作为有机化合物的催化剂。 烃化合物，转化。
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70.发明授权
公开(公告)号：US4624774A
公开(公告)日：1986-11-25
申请号：US818966
申请日：1986-01-08
Applicant: Clarence D. Chang , Joseph N. Miale
Inventor： Clarence D. Chang , Joseph N. Miale
CPC classification number: C01B39/026 , B01J29/04 , C01B35/1009
Abstract: A method for increasing the total amount of lattice metal in the framework of a particular porous inorganic crystalline composition, its conversion to hydrogen or hydronium form and use thereof as a catalyst component having enhanced catalyatic activity is provided.
Abstract translation: 提供了一种在特定的多孔无机结晶组合物的骨架中增加晶格金属的总量的方法，其转化为氢或水合物形式的方法及其作为具有增强的催化活性的催化剂组分的用途。
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