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    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays
    62.
    发明授权
    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays 失效
    3-亚苄基 - 樟脑，其制备方法及其在防紫外线中的应用

    公开(公告)号：US4654434A

    公开(公告)日：1987-03-31

    申请号：US825932

    申请日：1986-02-04

    Applicant: Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    Inventor： Gerard Lang ,  Madeleine Leduc ,  Alain Malaval

    IPC: A61K8/35 ,  A61K8/46 ,  A61Q17/04 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86 ,  C07C309/25 ,  C07C69/76 ,  C07C143/52

    CPC classification number: A61K8/466 ,  A61K8/35 ,  A61Q17/04 ,  C07C255/00 ,  C07C309/00 ,  C07C45/68 ,  C07C45/74 ,  C07C49/683 ,  C07C49/697 ,  C07C49/753 ,  C07C59/86

    Abstract: The invention relates to new 3-benzylidene-camphor derivatives of the formula: ##STR1## in which R.sub.1 denotes H or SO.sub.3.sup..crclbar. M.sup..sym., with M=H, an alkali metal or N.sup..sym. (R.sub.3).sub.4, with R.sub.3 =H or C.sub.1 -C.sub.4 alkyl or hydroxyalkyl; R.sub.2 denotes C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and n=0-4; and Z denotes ##STR2## in which R.sub.4 has the same meaning as R.sub.1 and can be identical or different, or alternatively ##STR3## in which R.sub.5 denotes H, optionally substituted aryl, C.sub.1 -C.sub.4 alkyl, --CN, --C00R7 or ##STR4## and R.sub.6 denotes --COOR.sub.8 or ##STR5## in which R.sub.7 and R.sub.8, which are identical or different, denote alkyl, alkenyl, cycloalkyl or aralkyl and R.sub.9 and R.sub.10, which are identical or different, denote H, alkyl, alkenyl or cycloalkyl; if R.sub.5 =H, alkyl or aryl, R.sub.6 can represent --COO.sup..crclbar. M.sup..sym. ; the methylidene-camphor radical, on the one hand, and the radical Z, on the other hand, are in the meta or para position. These derivatives act as sun filters.

    Abstract translation: 本发明涉及下式的新的3-亚苄基 - 樟脑衍生物：其中R 1表示H或SO 3（ - ）M（+），其中M = H，碱金属或N（+）（ R3）4，其中R3 = H或C1-C4烷基或羟烷基; R2表示C1-C4烷基或C1-C4烷氧基，n = 0-4; 并且Z表示其中R 4具有与R 1相同的含义并且可以相同或不同，或者其中R 5表示H，任选取代的芳基，C 1 -C 4烷基，-CN，-COOR 7或

    Quaternized polymers; process for preparing the same; and cosmetic compositions containing the same
    64.
    发明授权
    Quaternized polymers; process for preparing the same; and cosmetic compositions containing the same 失效
    季铵化聚合物; 制备方法; 和含有它们的化妆品组合物

    公开(公告)号：US4608250A

    公开(公告)日：1986-08-26

    申请号：US490852

    申请日：1983-05-02

    Applicant: Bernard Jacquet ,  Gerard Lang

    Inventor： Bernard Jacquet ,  Gerard Lang

    IPC: C08L79/00 ,  A61K8/00 ,  A61K8/84 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/10 ,  C08G73/00 ,  C08G73/02 ,  A61K7/06 ,  A45D7/00 ,  A61K7/09

    CPC classification number: C08G73/0226 ,  A61K8/84 ,  A61Q5/00 ,  A61Q5/10 ,  A61K2800/5426 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/12

    Abstract: A quaternized polymer having recurring units of the formula ##STR1## wherein X.sup..crclbar. represents an anion derived from an organic or mineral acid;R'.sub.2 is an aliphatic radical having a maximum of 20 carbon atoms;R'.sub.1 is an aliphatic, alicyclic or arylaliphatic radical containing a minimum of 2 carbon atoms and a maximum of 20 carbon atoms, or R'.sub.1 and R'.sub.2 together with the nitrogen atom to which they are attached form a ring capable of containing a second heteroatom other than said nitrogen;A represents a divalent group of the formula ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 and being such that the sum (x+y+t) is greater than or equal to 0 and less than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms;B represents a divalent group of the formula ##STR3## --CH.sub.2 --CHOH--CH.sub.2 --, --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n -- or ##STR4## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z, and u are whole numbers ranging from 0 to 11, two of them being able to be simultaneously equal to 0 such that the sum (v+z+u) is greater than or equal to 1 and lower than 18, and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, and n is a whole number equal to 2 or 3.The polymers are usefully employed in cosmetic compositions for application to the hair or skin.

    Abstract translation: 具有式“IMAGE”的重复单元的季铵化聚合物，其中X（ - ）表示衍生自有机或无机酸的阴离子; R'2是具有最多20个碳原子的脂族基团; R'1是含有最少2个碳原子和最多20个碳原子的脂族，脂环族或芳基脂族基团，或者R 1和R 2与它们所连接的氮原子一起形成能够含有 除所述氮之外的第二杂原子; A表示式（1）的二价基团，其中x，y和t为0〜11的整数，并且使（x + y + t）之和大于等于0且小于18， 并且E和K表示氢或具有少于18个碳原子的脂族基团; B表示下式的二价基团：-CH 2 -CHOH-CH 2 - ， - （CH 2）n O-（CH 2）n - 或者其中D和G表示氢或具有少于18个碳原子的脂族基团 并且v，z和u是从0到11的整数，它们中的两个能够同时等于0，使得（v + z + u）大于等于1且小于18， 并且当和（x + y + t）之和等于0时，和（v + z + u）大于1，n是等于2或3的整数。聚合物可用于化妆品 适用于头发或皮肤的组合物。

    Substituted derivatives of thiamorpholinone
    65.
    发明授权
    Substituted derivatives of thiamorpholinone 失效
    噻吗啉酮的取代衍生物

    公开(公告)号：US4483983A

    公开(公告)日：1984-11-20

    申请号：US484605

    申请日：1983-04-13

    Applicant: Gerard Lang ,  Jean Maignan ,  Jean-Luc Leveque ,  Laurent Rasseneur

    Inventor： Gerard Lang ,  Jean Maignan ,  Jean-Luc Leveque ,  Laurent Rasseneur

    IPC: A61K8/00 ,  A61K8/49 ,  A61K31/54 ,  A61P17/16 ,  A61Q17/04 ,  C07D279/12 ,  A61K7/40

    CPC classification number: C07D279/12

    Abstract: A substituted derivative of thiamorpholinone, for use in the cosmetic and pharmaceutical field, has the formula ##STR1## wherein n is 0 or 1; R.sub.1 and R.sub.2 each independently represent hydrogen or lower alkyl and R.sub.3 represents hydrogen, mono or polyhydroxyalkyl containing 2-16 carbon atoms, carbamylalkyl, carboxyalkyl or alkoxycarbonylalkyl. When R.sub.3 represents hydrogen, R.sub.4 represents --CO.sub.2 R.sub.5 wherein R.sub.5 is alkyl having 3-18 carbon atoms, optionally interrupted by one or more heteroatoms, or mono or polyhydroxyalkyl having 2-18 carbon atoms. When R.sub.3 represents mono or polyhydroxyalkyl, carbamylalkyl, carboxyalkyl or alkoxycarbonylalkyl, R.sub.4 represents hydrogen or lower alkyl.

    Abstract translation: 用于化妆品和药物领域的噻吗啉酮的取代衍生物具有下式：其中n为0或1; R 1和R 2各自独立地表示氢或低级烷基，R 3表示氢，含有2〜16个碳原子的单或多羟基烷基，氨基甲酰基烷基，羧基烷基或烷氧基羰基烷基。 当R 3表示氢时，R 4表示-CO 2 R 5，其中R 5是具有3-18个碳原子的烷基，任选地被一个或多个杂原子间隔或具有2-18个碳原子的单羟基或多羟基烷基。 当R 3表示单或多羟基烷基，氨基甲酰基烷基，羧基烷基或烷氧基羰基烷基时，R 4表示氢或低级烷基。

    Cosmetic agents based on cationic polymers, cosmetic compositions containing the same and the use of said cosmetic agents
    69.
    发明授权
    Cosmetic agents based on cationic polymers, cosmetic compositions containing the same and the use of said cosmetic agents 失效
    基于阳离子聚合物的化妆品，含有它们的化妆品组合物和所述化妆品的使用

    公开(公告)号：US4390522A

    公开(公告)日：1983-06-28

    申请号：US217401

    申请日：1980-12-17

    Applicant: Bernard Jacquet ,  Gerard Lang ,  Alain Malaval ,  Serge Forestier ,  Do Le Trung

    Inventor： Bernard Jacquet ,  Gerard Lang ,  Alain Malaval ,  Serge Forestier ,  Do Le Trung

    IPC: A61K8/72 ,  A61K8/00 ,  A61K8/34 ,  A61K8/36 ,  A61K8/84 ,  A61Q3/02 ,  A61Q5/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/08 ,  A61Q5/10 ,  A61K7/00 ,  A61K7/04 ,  A61K7/06 ,  A61K7/09

    CPC classification number: A61Q5/08 ,  A61K8/84 ,  A61Q5/02 ,  A61Q5/10 ,  A61K2800/5426 ,  Y10S424/01 ,  Y10S424/02

    Abstract: A cosmetic composition for application to the hair, skin or nails comprises in a cosmetic vehicle selected from water, a lower alkanol or a dilute lower alkanol solution, 0.01 to 15 percent by weight of a cationic polymer having units of the formula ##STR1## said polymer having a molecular weight between 1,000 and 50,000. R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each independently represent alkyl or hydroxyalkyl wherein the alkyl of each has 1-20 carbon atoms. A is alkylene, hydroxyalkylene, --(CH.sub.2).sub.n --Z--(CH.sub.2).sub.n -- wherein Z is oxygen and n is a whole number ranging from 2-10, or --EO).sub.m.sbsb.1 (DO.sub.m D.sub.1 wherein E is alkylene or hydroxyalkylene containing 1-5 carbon atoms, m.sub.1 is 0 or 1, m is 1-600 with the proviso that m is greater than 1 when m.sub.1 =0. D.sub.1 represents E when m.sub.1 =1 and D.sub.1 represents D when m.sub.1 =0. B represents --EO).sub.m.sbsb.1 (DO).sub.m D.sub.1 wherein E, D, D.sub.1, m and m.sub.1 are defined above X.sup..crclbar. represents a halide anion.

    Abstract translation: 用于头发，皮肤或指甲的化妆品组合物包含选自水，低级链烷醇或稀低级链烷醇溶液的化妆品载体，0.01至15重量％的具有下式单元的阳离子聚合物： 聚合物的分子量在1000至50,000之间。 R 1，R 2，R 3和R 4各自独立地表示烷基或羟烷基，其中各自的烷基具有1-20个碳原子。 A是亚烷基，羟基亚烷基， - （CH2）nZ-（CH2）n-，其中Z是氧，n是整数，范围是2-10或-EO）m1（DOm D1，其中E是含1- 5个碳原子，m1为0或1，m为1-600，条件是当m1 = 0时，m大于1，当m1 = 1时，D1表示E，当m1 = 0时，D1表示D，B表示-EO） m1（DO）m D1其中E，D，D1，m和m1如上定义，X​​（ - ）表示卤素阴离子。

    Cosmetic composition for imparting to human skin a coloration resembling a natural tan
    70.
    发明授权
    Cosmetic composition for imparting to human skin a coloration resembling a natural tan 失效
    用于赋予人类皮肤类似天然棕褐色的着色的化妆品组合物

    公开(公告)号：US4228151A

    公开(公告)日：1980-10-14

    申请号：US793317

    申请日：1977-05-03

    Applicant: Gerard Lang ,  Serge Forestier

    Inventor： Gerard Lang ,  Serge Forestier

    IPC: A61K8/49 ,  A61K31/495 ,  A61Q17/04 ,  A61K7/42 ,  A61K7/021 ,  A61K7/44

    CPC classification number: A61Q17/04 ,  A61K8/494

    Abstract: A cosmetic composition for imparting to human skin after exposure to sunlight a coloration resembling a natural tan comprises a cosmetic vehicle suitable for topical application to the skin and an effective amount of at least one compound of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently represent hydrogen, an aliphatic radical having 1-18 carbon atoms, carbalkoxy having 2-5 carbon atoms, acyl having 2-5 carbon atoms, aryl, aryl substituted by alkyl having 1-4 carbon atoms or hydroxy, a heterocycle containing 4-6 members, substituted or not by alkyl having 1-4 carbon atoms, halogen or hydroxy, or R.sub.1 and R.sub.2 together form a saturated ring containing 4-12 chains, optionally substituted by alkyl having 1-4 carbon atoms, halogen or hydroxy, or bridged and containing a heteroatom selected from N, O or S; and R.sub.3 represents hydrogen, a lower aliphatic group containing 1-6 carbon atoms, lower alkoxy containing 1-4 carbon atoms or halogen, with the proviso that R.sub.1, R.sub.2 and R.sub.3 are not hydrogen simultaneously; and an acid addition salt thereof.

    Abstract translation: 一种化妆品组合物，用于在暴晒于阳光后赋予人体皮肤的着色是类似于天然棕褐色的化妆品，其包含适合局部施用于皮肤的化妆品载体和有效量的至少一种下式的化合物，其中R1和R2各自独立地 表示氢，具有1-18个碳原子的脂族基团，具有2-5个碳原子的烷氧基羰基，具有2-5个碳原子的酰基，芳基，被1-4个碳原子的烷基取代的芳基或羟基，含有4-6个 成员，取代或未被具有1-4个碳原子的烷基，卤素或羟基，或R 1和R 2一起形成含有4-12个链的饱和环，任选地被具有1-4个碳原子的烷基，卤素或羟基或桥接的 并含有选自N，O或S的杂原子; 并且R 3表示氢，含有1-6个碳原子的低级脂族基团，含有1-4个碳原子的低级烷氧基或卤素，条件是R1，R2和R3不同时为氢; 及其酸加成盐。

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