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61.发明授权
公开(公告)号：US5036130A
公开(公告)日：1991-07-30
申请号：US347438
申请日：1989-05-02
摘要： A transparent thermoplastic molding material contains, based on A+B,A: from 5 to 95% by weight of polystyrene andB; from 95 to 5% by weight of a nonelastomeric star block copolymer which is composed of, based on B, b.sub.1 from 60 to 95% by weight of styrene and b.sub.2 from 5 to 40% by weight of one or more conjugated dienes of 4 or 5 carbon atoms and is prepared in a conventional manner by sequential anionic polymerization using one or more organolithium compounds as an initiator and in the presence of a solvent with subsequent coupling.In this process, component A is produced by conventional anionic polymerization using one or more organolithium compounds in the presence of an organic solvent.The molding material is prepared by mixing the components A and B, with or without C, in a conventional manner and is used for the production of moldings.
摘要翻译： 透明热塑性成型材料以A + B为基准，A：5〜95重量％的聚苯乙烯和B; 95至5重量％的非弹性星形嵌段共聚物，其基于B，由60至95重量％的苯乙烯b1和b1为5至40重量％的一种或多种共轭二烯的4或4 5个碳原子，并且以常规方式通过使用一种或多种有机锂化合物作为引发剂并且在溶剂存在下随后偶联的顺序阴离子聚合制备。 在该方法中，通过在有机溶剂存在下使用一种或多种有机锂化合物的常规阴离子聚合制备组分A. 成型材料通过以常规方式混合具有或不具有C的组分A和B而制备，并用于制备模制品。
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62.发明授权
公开(公告)号：US4866114A
公开(公告)日：1989-09-12
申请号：US250170
申请日：1988-09-28
CPC分类号： C08L51/08 , C08G65/485 , C08L71/126 , C08L77/00
摘要： Self-extinguishing, thermoplastic polyphenylene ether/polyamide molding materials contain, as essential components,(A) from 10 to 90% by weight of component (A), which consists of(A.sub.1) from 70 to 99% by weight of a modified polyphenylene ether,(A.sub.2) from 1 to 30% by weight of a compound containing bound phosphorus, the percentages by weight being based on the total weight of component (A), and(B) from 90 to 10% by weight of component (B), which consists of(B.sub.1) from 80 to 99% by weight of one or more polyamides and(B.sub.2) from 1 to 20% by weight of one or more compounds containing a bound triazine radical and from the group consisting of cyanuric acid and its derivatives.
摘要翻译： 自熄性热塑性聚苯醚/聚酰胺成型材料含有作为必要成分的（A）10〜90重量％的成分（A），（A1）70〜99重量％的改性聚亚苯基 乙醚，（A2）1〜30重量％的含有结合磷的化合物，其重量百分比以组分（A）的总重量计，和（B）90至10重量％的组分（B ），其由（B1）80至99重量％的一种或多种聚酰胺和（B2）1至20重量％的一种或多种含有结合的三嗪基的化合物和由以下组成的组：（a）氰尿酸和 其衍生物。
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公开(公告)号：US4797453A
公开(公告)日：1989-01-10
申请号：US63687
申请日：1987-06-19
IPC分类号： C08F283/06 , C08F283/08 , C09D151/08 , C08L71/02
CPC分类号： C09D151/08 , C08F283/08
摘要： Graft polymers of(A) a polyphenylene ether as a base polymer and(B) a half ester of an unsaturated dicarboxylic acid of the general formula ##STR1## as a graft monomer, where R.sup.1 is C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkylene or aryl, R.sup.2 and R.sup.3 are each H, Br, Cl or one of the radicals R.sup.1, and Q is H or an alkali metal, an alkaline earth metal or an ammonium cation,with or without(C) further olefinically unsaturated monomers,and their preparation.
摘要翻译： （A）聚苯醚作为基础聚合物的接枝聚合物和（B）作为接枝单体的通式为不饱和二羧酸的半酯，其中R 1是C 1 -C 25烷基，C 2 -C 25 - 亚烷基或芳基，R 2和R 3各自为H，Br，Cl或基团R 1中的一个，Q为H或碱金属，碱土金属或铵阳离子，具有或不具有（C）另外的烯属不饱和单体 ，及其准备。
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公开(公告)号：US4493922A
公开(公告)日：1985-01-15
申请号：US573853
申请日：1984-01-25
申请人： Adolf Echte , Hermann Gausepohl
发明人： Adolf Echte , Hermann Gausepohl
CPC分类号： C08L51/04 , Y10S525/901
摘要： An impact-resistant thermoplastic molding material, containing polystyrene as the matrix, and, dispersed therein, two elastomeric polymers or copolymers I and II composed entirely or predominantly of 1,3-dienes and containing particles of different mean size, namely, in I, particles from 0.2 to 0.6 .mu.m in size and having capsule particle morphology, and, in II, particles from 2 to 8 .mu.m in size, having cell particle or coil particle morphology.
摘要翻译： 一种抗冲击热塑性成型材料，其包含聚苯乙烯作为基体，并分散在其中，两个完全或主要由1,3-二烯构成并含有不同平均尺寸的颗粒的弹性聚合物或共聚物I和II，即I， 颗粒尺寸为0.2至0.6微米，具有胶囊颗粒形态，II型颗粒尺寸为2至8微米，具有细胞颗粒或线粒体形态。
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65.发明授权Process for the continuous preparation of rubber-modified polymers of vinylaromatics 失效连续制备乙烯基芳烃橡胶改性聚合物的方法
公开(公告)号：US4427826A
公开(公告)日：1984-01-24
申请号：US273689
申请日：1981-06-15
IPC分类号： C08F2/38 , C08F4/00 , C08F279/02
CPC分类号： C08F279/02
摘要： A process, carried out without a diluent or in solution, in more than 2 reaction zones, for the continuous preparation of rubber-modified polymers of vinylaromatics, wherein a monomeric aromatic vinyl compound and an elastomeric polymer, in an amount of from 3 to 16% by weight based on the monomer, are polymerized, in the absence of a free radical initiator, but in the presence of a mercaptan as a chain transfer agent, at from 80.degree. to 180.degree. C. in a first reaction zone, with stirring, up to a maximum monomer conversion, U.sub.max, given by the equationU.sub.max =K-1where K is the amount of rubber in % by weight based on monomer, and, in a second reaction zone, polymerization is continued, with stirring, to a conversion of up to about 50% by weight, after which a chain transfer agent is introduced in an amount of from 0.01 to 0.2% by weight, based on vinyl-aromatic monomer, and polymerization is continued, if appropriate in more than one reaction zone, up to a monomer conversion of less than 85% by weight. The polymer is treated in a devolatilization zone to remove vinyl-aromatic monomer and solvent, if any, and these constituents are recycled to the process. The process produces products which exhibit good gloss coupled with good mechanical properties, and which can be employed for conventional applications.
摘要翻译： 用于连续制备乙烯基芳族化合物的橡胶改性聚合物的方法，其中没有稀释剂或在溶液中，在多于2个反应区中进行，其中单体芳族乙烯基化合物和弹性体聚合物的量为3-16 基于单体的重量％在不存在自由基引发剂的情况下，在作为链转移剂的硫醇存在下，在第一反应区中在80-180℃下进行聚合，同时搅拌 ，达到最大单体转化率，Umax，由方程式Umax = K-1给出，其中K是基于单体的以重量％计的橡胶量，并且在第二反应区中，在搅拌下继续聚合至 高达约50重量％的转化率，之后以基于乙烯基芳族单体的0.01至0.2重量％的量引入链转移剂，并且如果适当的话在多于一个反应中继续聚合 区域，单体转化率小于 85重量％。 将聚合物在脱挥发区进行处理以除去乙烯基芳族单体和溶剂（如果有的话），并将这些组分再循环到该方法中。 该方法产生具有良好光泽性和良好机械性能的产品，并且其可用于常规应用。
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公开(公告)号：US4107231A
公开(公告)日：1978-08-15
申请号：US669740
申请日：1976-03-23
CPC分类号： C08K5/03 , C08L67/02 , Y10S260/24
摘要： Flame-proofed linear polyesters containing, as flame-proofing agents, halogenated oligomeric styrenes and synergistic compounds.
摘要翻译： 作为阻燃剂，含有卤化低聚苯乙烯和协同化合物的防火线性聚酯。
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公开(公告)号：US4061858A
公开(公告)日：1977-12-06
申请号：US703955
申请日：1976-07-09
申请人： Hans Wild , Rudolf Jung , Adolf Echte , Johann Zizlsperger , Hermann Gausepohl
发明人： Hans Wild , Rudolf Jung , Adolf Echte , Johann Zizlsperger , Hermann Gausepohl
IPC分类号： C08F6/00 , C08F6/02 , C08F20/44 , C07C121/30
CPC分类号： C07C253/34
摘要： Acrylonitrile or monomer mixtures containing acrylonitrile are purified by treating them with alkaline reacting compounds followed by distillation. The products are particularly suitable for the manufacture of acrylonitrile polymers showing improved color stability.
摘要翻译： 通过用碱性反应化合物处理丙烯腈或丙烯腈的单体混合物，然后蒸馏纯化。 该产品特别适用于制备显示改进的颜色稳定性的丙烯腈聚合物。
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