公开(公告)号：US08434623B2

公开(公告)日：2013-05-07

申请号：US13054702

申请日：2009-07-17

申请人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

发明人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

IPC分类号： B03D3/00

CPC分类号： H01F1/44 ,  B03C1/015 ,  H01F1/0054

摘要： The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the following steps: (A) contacting of the mixture comprising the at least one first material and at least one second material with at least one selective hydrophobicizing agent in the presence of a suspension medium so that an adduct is formed from the at least one hydrophobicizing agent and the at least one first material but not with the at least one second material, (B) contacting of the adduct from step (A) with at least one magnetic particle which is functionalized on the surface with at least one polymeric compound having a transition temperature LCST (lower critical solution temperature) at a temperature at which the polymeric compound has hydrophobic character so that the adduct from step (A) and the at least one functionalized magnetic particle agglomerate, (C) if appropriate addition of further suspension medium to the mixture obtained in step (B), (D) separation of the agglomerate present in the suspension from step (B) or (C) from the suspension by application of a magnetic field, (E) dissociation of the agglomerate separated off in step (D) by setting of a temperature at which the polymeric compound has hydrophilic character in order to obtain the at least one first material.

摘要翻译： 本发明涉及从包含该至少一种第一材料和至少一种第二材料的混合物中分离出至少一种第一材料的方法，其包括以下步骤：（A）使包含至少一种第一材料和/ 材料和至少一种第二材料与至少一种选择性疏水剂在悬浮介质的存在下进行，使得加合物由至少一种疏水剂和至少一种第一材料形成，但不与至少一种第二材料形成 ，（B）将来自步骤（A）的加合物与至少一种在表面上官能化的磁性颗粒与至少一种具有转变温度LCST（较低临界溶解温度）的聚合化合物在聚合物 具有疏水性，使得步骤（A）和至少一种官能化磁性颗粒附聚物的加合物，（C）如果适当添加 的另外的悬浮介质加入到步骤（B）中获得的混合物中，（D）通过施加磁场从悬浮液中分离存在于步骤（B）或（C）的悬浮液中的附聚物，（E） 在步骤（D）中通过设定聚合物具有亲水特性的温度来分离聚集体，以获得至少一种第一材料。

公开(公告)号：US20120097901A1

公开(公告)日：2012-04-26

申请号：US13379048

申请日：2010-06-23

申请人： Simon Schroedle ,  Hartmut Hibst ,  Brian Roberts ,  Kirill Bramnik ,  Jordan Keith Lampert

发明人： Simon Schroedle ,  Hartmut Hibst ,  Brian Roberts ,  Kirill Bramnik ,  Jordan Keith Lampert

IPC分类号： H01B1/04 ,  C04B35/64 ,  C04B35/52

CPC分类号： H01M4/5825 ,  C01B25/45 ,  C01B25/455 ,  H01B1/24 ,  H01M4/131 ,  H01M4/1315 ,  H01M4/133 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/583 ,  H01M10/0525 ,  Y02E60/122

摘要： The present invention relates to a process for the preparation of particles comprising at least one compound according to general formula (I) M1aM2bM3cOoNnFf (I) wherein M1, M2, M3 O, N, F, a, b, c, o, n and f have the following meanings: M1 at least one alkaline metal, M2 at least one transition metal in oxidation state +2, M3 at least one non-metal chosen form S, Se, P, As, Si, Ge and/or B, O oxygen, N nitrogen, F fluorine, a 0.8-4.2, b 0.8-1.9, c 0.8-2.2, o 1.0-8.4, n 0-2.0 and f 0-2.0, wherein a, b, c, o, n and f are chosen to ensure electroneutrality of the compound according to general formula (I), and carbon, comprising at least the following steps: (A) providing an essentially aqueous mixture comprising at least one compound comprising M1, at least one compound comprising M2 having at least partially an oxidation state higher than +2, optionally at least one compound comprising M3, at least one compound comprising N, if present, and/or at least one compound comprising F, if present, at least one polysaccharide comprising glucose having a molecular weight M of at least 50000 g/mol as carbon precursor and at least one reducing agent, (B) drying the mixture provided in step (A), in order to obtain a solid particle and (C) calcining the solid particle obtained from step (B) at a temperature of 300 to 950° C.

摘要翻译： 本发明涉及一种制备颗粒的方法，所述颗粒包含至少一种根据通式（I）的M1aM2bM3cOoNnFf（I）的化合物，其中M1，M2，M3O，N，F，a，b，c，o，n和 f具有以下含义：M1至少一种碱金属，M2至少一种氧化态过渡金属+2，M3至少一种非金属选择形式S，Se，P，As，Si，Ge和/或B， O氧，N氮，F氟，0.8-4.2，b 0.8-1.9，c 0.8-2.2，o 1.0-8.4，n 0-2.0和f 0-2.0，其中a，b，c，o，n和 选择f以确保根据通式（I）的化合物和至少包括以下步骤的碳的电中性：（A）提供基本上含水的混合物，其包含至少一种包含M1的化合物，至少一种包含M2的化合物，其包含具有 至少部分地高于+2的氧化态，任选地至少一种包含M3的化合物，至少一种包含N的化合物（如果存在）和/或至少一种包含F的化合物 送出至少一种包含分子量M至少为50000g / mol的葡萄糖作为碳前体和至少一种还原剂的至少一种多糖，（B）干燥步骤（A）中提供的混合物，以获得固体颗粒 和（C）在300-950℃的温度下煅烧由步骤（B）得到的固体颗粒。

公开(公告)号：US20110245391A1

公开(公告)日：2011-10-06

申请号：US13139437

申请日：2009-12-09

申请人： Andrey Karpov ,  Hartmut Hibst ,  Berend Eling ,  Joern Duwenhorst ,  Richard Riggs ,  Alexander Traut ,  Christof Kujat ,  Cornelia Roeger ,  Christian Krausche

发明人： Andrey Karpov ,  Hartmut Hibst ,  Berend Eling ,  Joern Duwenhorst ,  Richard Riggs ,  Alexander Traut ,  Christof Kujat ,  Cornelia Roeger ,  Christian Krausche

IPC分类号： C08K9/06 ,  C08L63/02 ,  G02B5/22 ,  C08L79/02 ,  C08L67/02 ,  C08L75/12 ,  C08L75/06

CPC分类号： C08K9/10 ,  C08K3/22

摘要： Dispersion comprising functionalized metal oxide particles, polymerizable compounds and if appropriate a solvent and their use for stabilizing polymers.

摘要翻译： 包含官能化金属氧化物颗粒，可聚合化合物和适当的溶剂的分散体及其用于稳定聚合物的用途。

公开(公告)号：US20110147671A1

公开(公告)日：2011-06-23

申请号：US13060976

申请日：2009-08-25

申请人： Kirill Bramnik ,  Hartmut Hibst ,  Jordan Keith Lampert

发明人： Kirill Bramnik ,  Hartmut Hibst ,  Jordan Keith Lampert

IPC分类号： H01B1/02 ,  H01M4/88 ,  H01B1/04 ,  B82Y30/00

CPC分类号： H01M4/131 ,  C01B25/45 ,  H01M4/1391 ,  H01M4/5825

摘要： The present invention relates to a process for the preparation of compounds of general Formula (I) La−bM1bFe1−cM2cPd−eM3eOx (I), wherein Fe has the oxidation state +2 and M1, M2, M3, a, b, c, d, e and x are: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Al Ca, Ti Co, Ni, Cr, V, M3: Si, S, F a: 0.8-1.9, b: 0-0.3, c: 0-0.9, 15 d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of Li, M1, M2, P, M3, wherein compounds of general Formula (I) are neutrally charged, comprising the following steps (A) providing a mixture comprising at least one lithium-comprising compound, at least one iron-comprising compound, in which iron has the oxidation state +3, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, and (B) heating the mixture obtained in step (A) at a temperature of 100 to 500° C. and at an autogeneous pressure to reduce Fe to oxidation state +2 and to obtain a compound of general Formula (I).

摘要翻译： 本发明涉及制备通式（I）化合物La-bM1bFe1-cM2cPd-eM3eOx（Ⅰ）的方法，其中Fe具有氧化态+2和M1，M2，M3，a，b，c， d，e和x是：M1：Na，K，Rb和/或Cs，M2：Mn，Mg，Al Ca，Ti Co，Ni，Cr，V，M3：Si，S，F a：0.8-1.9， b：0-0.3，c：0-0.9,15d：0.8-1.9，e：0-0.5，x：1.0-8，这取决于Li，M1，M2，P，M3的量和氧化态，其中 通式（I）的化合物是中性带电的，包括以下步骤（A），提供包含至少一种含锂化合物，至少一种含铁化合物的混合物，其中铁具有+3的氧化态， 至少一种含M1化合物（如果存在）和/或至少一种含M2化合物（如果存在）和/或至少一种含M3化合物（如果存在）和至少一种被氧化成至少一种 包含至少一个氧化态+5的磷原子的化合物，和（B）加热混合物 在步骤（A）中，在100-500℃的温度和自发压力下将Fe还原成氧化态+2，得到通式（I）的化合物。

公开(公告)号：US07959882B2

公开(公告)日：2011-06-14

申请号：US12595794

申请日：2008-04-14

申请人： Kirill Bramnik ,  Hartmut Hibst ,  Julian Prölβ

发明人： Kirill Bramnik ,  Hartmut Hibst ,  Julian Prölβ

IPC分类号： C01D15/00

CPC分类号： C01G31/00 ,  C01P2002/72 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/485 ,  H01M10/052 ,  H01M2300/0082 ,  H01M2300/0091

摘要： A process for preparing lithium-rich metal oxides. The process comprises subjecting a mixture of a metal oxide or a metal oxide with low lithium content and a lithium sulfide in a solid state to a thermal treatment to form a lithium-rich metal oxide and elemental sulfur and subliming off the elemental sulfur. The lithium-rich metal oxides produced from the process may be used as cathode material in lithium ion batteries or electrochemical cells. Suitable metal oxides may be selected from metal oxides of the elements of group Va to VIIa of the Periodic Table and may include vanadium oxides, manganese dioxide, manganese oxide, chromium trioxide, niobium pentoxide, tantalum pentoxide, molybdenum oxides or tungsten trioxide. Metal oxides with low lithium content are metal oxides as defined above which comprise a small amount of lithium, in which the molar ratio of lithium atoms to metal atoms is not more than 1:2.30.

摘要翻译： 一种制备富锂金属氧化物的方法。 该方法包括使具有低锂含量的金属氧化物或金属氧化物与固体状态的硫化锂的混合物进行热处理，以形成富锂金属氧化物和元素硫，并使元素硫升华。 从该工艺生产的富锂金属氧化物可用作锂离子电池或电化学电池中的阴极材料。 合适的金属氧化物可以选自周期表第Va至VIIa族元素的金属氧化物，并且可以包括氧化钒，二氧化锰，氧化锰，三氧化铬，五氧化二铌，五氧化二钽，氧化钼或三氧化钨。 低锂含量的金属氧化物是如上定义的金属氧化物，其含有少量的锂，其中锂原子与金属原子的摩尔比不大于1:2.30。

公开(公告)号：US07956200B2

公开(公告)日：2011-06-07

申请号：US12701600

申请日：2010-02-07

申请人： Thomas Heidemann ,  Hartmut Hibst ,  Stefan Bauer ,  Ulf Dietrich

发明人： Thomas Heidemann ,  Hartmut Hibst ,  Stefan Bauer ,  Ulf Dietrich

IPC分类号： C07D307/89 ,  C07C51/255

CPC分类号： B01J23/682 ,  B01J23/683 ,  C01G31/00 ,  C01G31/006 ,  C01G39/006 ,  C01P2002/50 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  C01P2004/10 ,  C01P2004/54 ,  C01P2004/61 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/82 ,  C07C51/265 ,  C07C51/313 ,  C07C63/16

摘要： A multimetal oxide of the formula I Aga-bMbV2Ox*cH2O,  I where M is a metal selected from the group consisting of Li, Na, K, Rb, Cs, Tl, Mg, Ca, Sr, Ba, Cu, Zn, Cd, Pb, Cr, Au, Al, Fe, Co, Ni and/or Mo, a is from 0.3 to 1.9 and b is from 0 to 0.5, with the proviso that the difference (a−b)≧0.1 and c is from 0 to 20 and x is a number determined by the valence and amount of elements different from oxygen in the formula I, which has a crystal structure giving an X-ray powder diffraction pattern which displays reflections at the lattice spacings d of 15.23±0.6, 12.16±0.4, 10.68±0.3, 3.41±0.04, 3.09±0.04, 3.02±0.04, 2.36±0.04 and 1.80±0.04 Å. Precatalysts and catalysts produced therefrom for the partial oxidation of aromatic hydrocarbons are also provided.

摘要翻译： 式I Aga-bMbV2Ox * cH2O，I的多金属氧化物，其中M是选自Li，Na，K，Rb，Cs，Tl，Mg，Ca，Sr，Ba，Cu，Zn，Cd ，Pb，Cr，Au，Al，Fe，Co，Ni和/或Mo，a为0.3〜1.9，b为0〜0.5，条件是（a-b）≥0.1，c为 0〜20，x为通式I中与氧不同的元素的化合价和数量决定的数字，该结晶结构具有表示晶格间距d为15.23±0.6的反射的X射线粉末衍射图， 12.16±0.4，10.68±0.3，3.41±0.04，3.09±0.04，3.02±0.04,2.36±0.04和1.80±0.04。 还提供了预催化剂和由其制备的用于芳族烃的部分氧化的催化剂。

公开(公告)号：US20110120954A1

公开(公告)日：2011-05-26

申请号：US13054713

申请日：2009-07-15

申请人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

发明人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

IPC分类号： B03C1/01 ,  B01D39/00

CPC分类号： H01F1/44 ,  B03C1/015 ,  B82Y25/00 ,  H01F1/0045

摘要： The present invention relates to a process of the invention for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) Contacting of at least one magnetic particle and at least one bifunctional molecule or an adduct of the two with the mixture comprising the at least one first material and at least one second material so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first material, (B) suspension of the adduct obtained in step (A) in a suitable suspension medium, (C) separation of the adduct present in the suspension from step (B) from the suspension by application of a magnetic field, (D) if appropriate, dissociation of the adduct separated off in step (C) in order to obtain the at least one first material. a corresponding adduct and the use of such an adduct for the separation of mixtures of materials.

摘要翻译： 本发明涉及一种本发明的方法，用于从包含该至少一种第一材料和至少一种第二材料的混合物中分离至少一种第一材料，其包括以下步骤：（A）接触至少一种磁性颗粒和 至少一种双功能分子或两者的加合物与混合物包含至少一种第一材料和至少一种第二材料，使得加合物由至少一个磁性颗粒形成，通式（I）的双官能化合物 ）和所述至少一种第一材料，（B）步骤（A）中获得的加合物的悬浮液在合适的悬浮介质中，（C）通过施用将来自步骤（B）的悬浮液中存在的加合物与悬浮液 （D）如果合适，在步骤（C）中分离的加合物的解离以获得至少一种第一材料。 相应的加合物和这种加合物用于分离材料混合物的用途。

公开(公告)号：US20100307982A1

公开(公告)日：2010-12-09

申请号：US12743655

申请日：2008-11-17

申请人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst

发明人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst

IPC分类号： B03C1/023

CPC分类号： B03C1/015 ,  B03C1/32 ,  B03C2201/18

摘要： The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) production of a suspension of the mixture comprising at least one first material and at least one second material and at least one magnetic particle in a suitable suspension medium, (B) setting of the pH of the suspension obtained in step (A) to a value at which the at least one first material and the at least one magnetic particle bear opposite surface charges so that these agglomerate, (C) separation of the agglomerate obtained in step (B) from the suspension by application of a magnetic field and (D) dissociation of the agglomerate separated off in step (C) by setting of the pH to a value at which the at least one first material and the at least one magnetic particle bear the same surface charges in order to obtain the at least one first material.

摘要翻译： 本发明涉及从包含这种至少一种第一材料和至少一种第二材料的混合物中分离出至少一种第一材料的方法，其包括以下步骤：（A）制备混合物的悬浮液，其包含至少一种 第一材料和至少一种第二材料和至少一种在适合的悬浮介质中的磁性颗粒，（B）将步骤（A）中获得的悬浮液的pH设定为至少一种第一材料和第 至少一个磁性颗粒承受相反的表面电荷，使得这些附聚物，（C）通过施加磁场将步骤（B）中获得的附聚物与悬浮液分离，并且（D）在步骤（C）中分离的附聚物的解离， 通过将pH设定为至少一个第一材料和至少一个磁性颗粒承载相同表面电荷的值，以获得至少一种第一材料。

公开(公告)号：US20100087663A1

公开(公告)日：2010-04-08

申请号：US12531537

申请日：2008-03-12

申请人： Hartmut Hibst ,  Robert Glaum ,  Ernst Benser

发明人： Hartmut Hibst ,  Robert Glaum ,  Ernst Benser

IPC分类号： C07D307/33 ,  B01J27/198

CPC分类号： C01B25/45 ,  B01J23/002 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/1009 ,  B01J37/0045 ,  B01J2523/00 ,  C07C51/215 ,  C07C51/252 ,  C07D307/60 ,  B01J2523/51 ,  B01J2523/55 ,  B01J2523/847 ,  B01J2523/17 ,  B01J2523/845

摘要： A novel polynary metal oxide phosphate of the general formula I MaV2Ob(PO4)c is described, in which M is one or more metals selected from V, Cr, Fe, Co, Ni, Ru, Rh, Pd, Cu, Zn, Cd, Hg, Be, Mg, Ca, Sr and Ba, a is from 0.5 to 1.5, b is from 1.5 to 2.5, c is from 1.5 to 2.5, having a crystal structure whose powder X-ray diffractogram is characterized by defined reflections. Preferred representatives are CoV2O2(PO4)2, NiV2O2(PO4)2 or CuV2O2(PO4)2. The metal oxide phosphates are suitable as gas phase oxidation catalysts, for example for preparing maleic anhydride from a hydrocarbon having at least four carbon atoms.

摘要翻译： 描述了通式I MaV2Ob（PO​​4）c的新型多金属氧化物磷酸盐，其中M是选自V，Cr，Fe，Co，Ni，Ru，Rh，Pd，Cu，Zn，Cd中的一种或多种金属 ，Hg，Be，Mg，Ca，Sr和Ba中的一种，a为0.5至1.5，b为1.5至2.5，c为1.5至2.5，具有其粉末X射线衍射图的特征在于定义反射的晶体结构。 优选的代表是CoV2O2（PO4）2，NiV2O2（PO4）2或CuV2O2（PO4）2。 金属氧化物磷酸盐适合用作气相氧化催化剂，例如从具有至少四个碳原子的烃制备马来酸酐。

公开(公告)号：US20090291845A1

公开(公告)日：2009-11-26

申请号：US12158858

申请日：2006-12-20

申请人： Samuel Neto ,  Hartmut Hibst ,  Frank Rosowski ,  Sebastian Storck ,  Jürgen Zühlke

发明人： Samuel Neto ,  Hartmut Hibst ,  Frank Rosowski ,  Sebastian Storck ,  Jürgen Zühlke

IPC分类号： B01J21/18

CPC分类号： B01J23/682 ,  B01J23/002 ,  B01J23/96 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/0018 ,  B01J37/0219 ,  B01J37/0223 ,  B01J37/08 ,  B01J2523/00 ,  C01G31/006 ,  C01P2002/72 ,  C01P2006/12 ,  C07C51/265 ,  C07C51/313 ,  Y02P20/584 ,  C07C63/16 ,  B01J2523/18 ,  B01J2523/3712 ,  B01J2523/55

摘要： A process is described for converting a precatalyst which comprises an inert support, an organic carbon source and a multimetal oxide comprising silver and vanadium to a gas phase oxidation catalyst which comprises the inert support and a catalytically active silver vanadium oxide bronze, by treating the precatalyst thermally at a temperature of at least 350° C. in a gas atmosphere which comprises less than 10% by volume of oxygen, wherein, before the thermal treatment, the amount of the carbon source in the precatalyst is adjusted to a value below a critical amount The carbon content is reduced by burning-off at a temperature of from 80 to 200° C. in an oxygenous atmosphere with decomposition of a portion of the carbon source. The catalysts obtained serve for the gas phase partial oxidation of aromatic hydrocarbons to aldehydes, carboxylic acids and/or carboxylic anhydrides.

摘要翻译： 描述了一种将包含惰性载体，有机碳源和包含银和钒的多金属氧化物的预催化剂转化成气相氧化催化剂的方法，该催化剂包含惰性载体和催化活性银钒氧化物青铜，通过处理预催化剂 在包含小于10体积％氧气的气体气氛中，在至少350℃的温度下进行热处理，其中在热处理之前，将预催化剂中的碳源的量调节至低于临界值 量在碳源的一部分分解的氧气氛中，在80〜200℃的温度下，通过烧成而降低碳含量。 获得的催化剂用于将芳烃气相部分氧化成醛，羧酸和/或羧酸酐。