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    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
    61.
    发明授权
    Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
    含有菱沸石的分子筛的合成及其在含氧化合物转化为烯烃的用途

    公开(公告)号：US08399578B2

    公开(公告)日：2013-03-19

    申请号：US13589289

    申请日：2012-08-20

    申请人： Machteld M. Mertens ,  Stephen N. Vaughn

    发明人： Machteld M. Mertens ,  Stephen N. Vaughn

    IPC分类号： C01B39/54 ,  C01B37/08 ,  C07C1/20 ,  C07C2/10

    CPC分类号： C07C1/20 ,  B01J29/85 ,  B01J29/90 ,  B01J2229/42 ,  C01B39/54 ,  C07C2529/85 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    摘要： In a method of synthesizing a silicoaluminophosphate molecular sieve having 90+% CHA framework-type character, a reaction mixture is prepared comprising sources of water, silicon, aluminum, and phosphorus, as well as an organic template. In one aspect, the reaction mixture is heated at more than 10° C./hour to a crystallization temperature and is retained at the crystallization temperature or within the crystallization temperature range for a crystallization time from 16 hours to 350 hours to produce the silicoaluminophosphate molecular sieve. In another aspect, the reaction mixture is heated at less than 10° C./hour to a crystallization temperature from about 150° C. to about 225° C. and is then retained there for less than 10 hours to produce the silicoaluminophosphate molecular sieve. The molecular sieve can then be recovered from the reaction mixture and, preferably, used in a hydrocarbon conversion process, such as oxygenates to olefins.

    摘要翻译： 在合成具有90 + CHA框架型特征的硅铝磷酸盐分子筛的方法中，制备包含水，硅，铝和磷源以及有机模板的反应混合物。 在一个方面，将反应混合物在大于10℃/小时加热至结晶温度，并保持在结晶温度或结晶温度范围内，结晶时间为16小时至350小时，以产生硅铝磷酸盐分子 筛。 在另一方面，将反应混合物在小于10℃/小时加热至约150℃至约225℃的结晶温度，然后将其保留在少于10小时以产生硅铝磷酸盐分子筛 。 然后可以从反应混合物中回收分子筛，并且优选用于烃转化方法，例如含氧化合物至烯烃。

    Method and apparatus for regenerating catalyst during oxygenates to olefins reaction
    62.
    发明授权
    Method and apparatus for regenerating catalyst during oxygenates to olefins reaction 有权
    在含氧化合物到烯烃反应过程中再生催化剂的方法和装置

    公开(公告)号：US08178741B2

    公开(公告)日：2012-05-15

    申请号：US12793340

    申请日：2010-06-03

    申请人： Chunshe J. Cao ,  James H. Beech, Jr. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    发明人： Chunshe J. Cao ,  James H. Beech, Jr. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    IPC分类号： C07C1/00 ,  B01J20/34 ,  B01J19/00

    CPC分类号： B01J38/02 ,  B01J29/90 ,  B01J38/32 ,  C07C1/20 ,  C07C2529/85 ,  Y02P20/584 ,  C07C11/02

    摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.

    摘要翻译： 本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。 这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。 在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。

    Method And Apparatus For Regenerating Catalyst During Oxygenates To Olefins Reaction
    63.
    发明申请
    Method And Apparatus For Regenerating Catalyst During Oxygenates To Olefins Reaction 有权
    氧化催化剂再生催化剂对烯烃反应的方法与装置

    公开(公告)号：US20110021857A1

    公开(公告)日：2011-01-27

    申请号：US12793340

    申请日：2010-06-03

    申请人： Chunshe J. Cao ,  James H. Beech, JR. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    发明人： Chunshe J. Cao ,  James H. Beech, JR. ,  Michael P. Nicoletti ,  Thomas H. Colle ,  Teng Xu ,  Stephen N. Vaughn

    IPC分类号： C07C1/00 ,  B01J20/34 ,  B01J19/00

    CPC分类号： B01J38/02 ,  B01J29/90 ,  B01J38/32 ,  C07C1/20 ,  C07C2529/85 ,  Y02P20/584 ,  C07C11/02

    摘要： Disclosed herein is a method of recovery of the activity of a molecular sieve catalyst following use of the catalyst in an OTO conversion process. This is achieved by a regeneration apparatus and a method of regenerating a molecular sieve catalyst, comprising two stages. In a pretreatment stage, the catalyst is pretreated under pretreatment conditions by heating the catalyst to a temperature of between 320° C. to 700° C. in an oxygen depleted medium for a residence time of between 1 minute to two hours; and, in a regeneration stage, the catalyst is regenerated under regeneration conditions by heating the catalyst at a temperature of between 200° C. to 700° C. in an oxidizing medium for a residence time of between 1 to 60 minutes.

    摘要翻译： 本文公开了在OTO转化方法中使用催化剂后回收分子筛催化剂的活性的方法。 这是通过再生装置和再生分子筛催化剂的方法实现的，包括两个阶段。 在预处理阶段，催化剂在预处理条件下通过将催化剂在耗氧贫乏的介质中在320℃至700℃之间的温度下进行预处理，停留时间为1分钟至2小时; 并且在再生阶段，催化剂在再生条件下通过在氧化介质中在200℃至700℃的温度下加热催化剂，停留时间为1至60分钟而再生。

    Molecular sieve catalyst composition, its making and use in conversion processes
    64.
    发明授权
    Molecular sieve catalyst composition, its making and use in conversion processes 有权
    分子筛催化剂组成，其制备和用途在转化过程中

    公开(公告)号：US07557256B2

    公开(公告)日：2009-07-07

    申请号：US11818495

    申请日：2007-06-14

    申请人： Yun-Feng Chang ,  Stephen N. Vaughn ,  Kenneth R. Clem ,  Luc R. Martens ,  Weiguo Hu

    发明人： Yun-Feng Chang ,  Stephen N. Vaughn ,  Kenneth R. Clem ,  Luc R. Martens ,  Weiguo Hu

    IPC分类号： C07C1/00

    CPC分类号： B01J37/0045 ,  B01J29/06 ,  B01J29/84 ,  B01J29/85 ,  B01J35/002 ,  B01J37/0009 ,  C07C1/20 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/16 ,  C07C2529/85 ,  Y02P30/20 ,  Y02P30/42 ,  Y10S502/504 ,  C07C11/02

    摘要： This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27 Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.

    摘要翻译： 本发明提供制备分子筛催化剂颗粒，可用于这些方法的分子筛浆料，分子筛催化剂组合物及其在催化烃转化方法中的应用的方法。 在其一个方面，本发明提供了制备分子筛催化剂颗粒的方法，该方法包括以下步骤：a）提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b）将含铝的无机氧化物前体的溶液或悬浮液与分子筛和任选的其它配制剂组合以形成催化剂配方浆料; c）使催化剂配方浆料老化，以在所述浆料中产生一种百分比，或者在所述浆料中增加所述含铝前体的铝原子的现有百分比，其具有在62-63ppm具有尖锐的27Al NMR峰的低聚物的形式 ; 和d）从催化剂配方浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性，并且在烃转化方法中特别有用。

    Method of high pressure and high capacity oxygenate conversion with catalyst exposure cycle
    67.
    发明申请
    Method of high pressure and high capacity oxygenate conversion with catalyst exposure cycle 有权
    用催化剂曝光循环的高压和高容量含氧化合物转化方法

    公开(公告)号：US20070232844A1

    公开(公告)日：2007-10-04

    申请号：US11698511

    申请日：2007-01-26

    申请人： Keith H. Kuechler ,  James H. Beech ,  Doron Levin ,  Stephen N. Vaughn ,  Stephen H. Brown

    发明人： Keith H. Kuechler ,  James H. Beech ,  Doron Levin ,  Stephen N. Vaughn ,  Stephen H. Brown

    IPC分类号： C07C1/00

    CPC分类号： C07C1/20 ,  B01J29/90 ,  B01J38/06 ,  C07C2529/85 ,  C08F10/00 ,  C10G3/49 ,  C10G3/57 ,  C10G3/62 ,  C10G2300/308 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/802 ,  C10G2300/805 ,  C10G2400/20 ,  Y02P20/584 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02 ,  C08F2/00

    摘要： A gas-solids reaction system is provided for improving product recovery in a multiple reactor reaction system. An oxygenate feedstock, desirably of high concentration in oxygenate, is reacted with a catalyst having a low to modest acidity and a Si/Al2 ratio of from 0.10 to 0.32. The reaction occurs in a reaction zone of a fluidized bed reactor at an oxygenate partial pressure of at least 45 psia and a reactor gas superficial velocity of at least 10 ft/s, conveying catalyst through the reaction zone to a circulation zone. The catalyst undergoes displacement with an inert gas in the circulation zone at a displacement gas superficial velocity of at least 0.03 m/s, after which at least a portion, preferably a large portion is returned to the reaction zone. The catalyst has a residence time in the circulation zone of at least twice that of the residence time of catalyst in the reaction zone. Extraordinary catalyst activity at high olefin selectivity results despite insignificant changes in coke on catalyst and coke yield when compared to lower pressure operations.

    摘要翻译： 提供了一种气体 - 固体反应系统，用于改善多反应器反应体系中的产物回收。 含氧化合物的含氧化合物原料，优选在含氧化合物中的高浓度与具有低至适度酸度和0.10 / 0.32的Si / Al 2 O比的催化剂反应。 反应在流化床反应器的反应区中发生，氧化分压至少为45psia，反应器气体表观速度为至少10ft / s，将催化剂通过反应区输送到循环区。 催化剂在循环区中以惰性气体置换，位移气体空速为至少0.03m / s，此后至少一部分，优选大部分返回到反应区。 催化剂在循环区中的停留时间至少是催化剂在反应区中的停留时间的两倍。 尽管与较低压力操作相比，尽管催化剂上的焦炭和焦炭产率都没有显着变化，但是在高烯烃选择性方面具有特殊的催化剂活性。