公开(公告)号：US06942715B2

公开(公告)日：2005-09-13

申请号：US10406385

申请日：2003-04-04

Applicant: Nobuaki Ito ,  Masanori Yamaguchi ,  Kenichi Kato ,  Shigeo Ampo

Inventor： Nobuaki Ito ,  Masanori Yamaguchi ,  Kenichi Kato ,  Shigeo Ampo

IPC: C22B5/04 ,  C22B34/12 ,  B22F9/24

CPC classification number: C22B34/1272

Abstract: A process for producing metallic titanium includes forming metallic titanium fine particles by supplying liquid or mist titanium tetrachloride from above the surface of a reaction bath liquid containing fused magnesium and fused magnesium chloride in a reaction vessel to effect a reaction, wherein a circulating flow perpendicular to the bath surface of the reaction bath liquid is generated or extended just under the bath surface by imparting a stirring force to the reaction bath liquid so as to generate or increase an upward flow rate of the reaction bath liquid in at least part of the region at a depth of more than 100 mm below the bath surface.

Abstract translation: 金属钛的制造方法包括通过在反应容器内从含有熔融镁和熔融氯化镁的反应浴液的表面的上方供给液体或者四氯化钛而形成金属钛微粒，进行反应，其中，与 通过向反应浴液体施加搅拌力而产生或延伸反应浴液体的浴表面，从而在该区域的至少一部分中产生或增加反应浴液体的向上流速 在浴面以下超过100毫米的深度。

公开(公告)号：US06863708B2

公开(公告)日：2005-03-08

申请号：US10343936

申请日：2002-06-11

Applicant: Wataru Kagohashi ,  Mitsugu Yoshida ,  Tsuyoshi Asai

Inventor： Wataru Kagohashi ,  Mitsugu Yoshida ,  Tsuyoshi Asai

IPC: B22F9/28 ,  C22B1/08 ,  C22B5/12 ,  C22B23/06 ,  H01G4/008 ,  B22F9/26

CPC classification number: C22B23/06 ,  B22F9/28 ,  C22B1/08 ,  C22B5/12 ,  H01G4/0085 ,  Y10T29/49165

Abstract: Metal chloride vapor and reducing gas are brought into contact to form metallic powder, the metallic powder is washed in carbonic acid aqueous solution, and the metallic powder is classified in a liquid phase. In this way, metallic powder, such as nickel powder, in which the content of chloride components is extremely small and the coarse particle content is small, can be efficiently produced.

Abstract translation: 使金属氯化物蒸气和还原气体接触形成金属粉末，金属粉末在碳酸水溶液中洗涤，金属粉末分级为液相。 以这种方式，可以有效地制备其中氯化物组分含量极小并且粗颗粒含量小的金属粉末，如镍粉。

公开(公告)号：US06858059B2

公开(公告)日：2005-02-22

申请号：US10279867

申请日：2002-10-25

Applicant: Norio Yamamoto ,  Katsuhiko Sakai

Inventor： Norio Yamamoto ,  Katsuhiko Sakai

IPC: C22B9/22 ,  C22B34/12

CPC classification number: C22B9/228

Abstract: An electron beam melting method for a metallic material which is melted by an electron beam in a melting furnace is disclosed. The method comprises: locating an actual melting material and a pre-melting material in the melting furnace; forming a melted surface on the pre-melting material by an electron beam under a reduced pressure; and melting the actual melting material by the electron beam while maintaining the reduced pressure in the melting furnace.

Abstract translation: 公开了一种在熔融炉中通过电子束熔化的金属材料的电子束熔化方法。 该方法包括：在熔炉中定位实际的熔化材料和预熔材料; 通过电子束在减压下在预熔材料上形成熔融表面; 并通过电子束熔化实际的熔融材料，同时保持熔化炉中的减压。

公开(公告)号：US4970186A

公开(公告)日：1990-11-13

申请号：US289551

申请日：1988-12-23

Applicant: Minoru Terano ,  Hirokazu Soga ,  Masuo Inoue

Inventor： Minoru Terano ,  Hirokazu Soga ,  Masuo Inoue

IPC: C08F4/64 ,  C08F4/649 ,  C08F10/00

CPC classification number: C08F10/00 ,  Y10S526/903

Abstract: A solid catalyst component prepared by admixing and reacting, with a reaction product which has been obtained by suspending diethoxymagnesium in an alkylbenzene and bringing the suspension into contact with titanium tetrachloride in an amount less than 1 in terms of volume ratio to the alkylbenzene, a phthaloyl dichloride at a temperature within the range between 80.degree. C. and 125.degree. C., washing the resultant solid substance with an alkylbenzene, and reacting the solid substance in the presence of an alkylbenzene with titanium tetrachloride in an amount less than 1 in terms of volume ratio to the alkylbenzene as well as an olefin polymerization catalyst which comprises (A) the above specified solid catalyst component, (B) a silicon compound of the general formula: SiR.sub.m (OR').sub.4-m wherein R is a group selected from an alkyl group, a cycloalkyl group, an aryl group and vinyl group, R' is an alkyl group and m is zero or an integer of 1-3, with the proviso that when m is 2 or 3, plural R groups may be identical or different, that when m is zero or 1, plural R' groups may be identical or different and/or that when R is an alkyl group, R may be identical with or different from R', and (C) an organoaluminum compound of the general formula: R".sub.n AlX.sub.3-n wherein R" is an alkyl group, X is a halogen atom and n is an integer of 1-3, with the proviso that when n is 2 or 3, plural R" groups may be identical or different. This catalyst exhibits an extremely high polymerization activity combined with a high stereospecific performance and enables the production of stereoregular olefin polymers with a negligible residual chlorine content in a high yield.

公开(公告)号：US4612040A

公开(公告)日：1986-09-16

申请号：US735136

申请日：1985-05-17

Applicant: Masaaki Koizumi ,  Nobuo Fukada ,  Hiroyuki Okano

Inventor： Masaaki Koizumi ,  Nobuo Fukada ,  Hiroyuki Okano

IPC: C22C1/00 ,  B23K35/04 ,  B23K35/06 ,  C22B9/20 ,  C22C1/02 ,  H05B7/07 ,  C22B4/00

CPC classification number: C22C1/02 ,  Y10S505/825

Abstract: A consumable electrode for the production of Nb-Ti alloy is disclosed which is capable of obtaining homogeneous titanium alloy without segregation which contains substantially equal amounts of niobium and titanium. The consumable electrode consists essentially of a compact formed by compressing a uniform mixture of niobium chips and sponge titanium.

Abstract translation: 公开了用于生产Nb-Ti合金的可消耗电极，其能够获得不含偏析的均匀的钛合金，其含有基本上相等量的铌和钛。 消耗电极基本上由通过压缩铌碎片和海绵钛的均匀混合物形成的压块组成。

公开(公告)号：US4460701A

公开(公告)日：1984-07-17

申请号：US482059

申请日：1983-04-05

Applicant: Minoru Terano ,  Kouhei Kimura ,  Atsushi Murai ,  Masuo Inoue ,  Katsuyoshi Miyoshi

Inventor： Minoru Terano ,  Kouhei Kimura ,  Atsushi Murai ,  Masuo Inoue ,  Katsuyoshi Miyoshi

IPC: C08F4/00 ,  C08F4/10 ,  C08F4/16 ,  C08F4/60 ,  C08F4/64 ,  C08F4/65 ,  C08F10/00 ,  C08F4/02

CPC classification number: C08F10/00

Abstract: A process for the preparation of the former catalyst component of a catalyst for the polymerization of olefins composed of a titanium-based catalyst component and an organo aluminium compound is disclosed, which process comprises suspending (a) a fatty acid salt of magnesium and (b) dialkoxymagnesium into (c) a liquid halogenated hydrocarbon to form a first suspension, and adding said first suspension to (d) a titanium halide of the general formula: TiX.sub.4, wherein X represents a halogen atom, to be contacted for reaction to form a first reaction mixture, (e) an electron donor compound being present in at least one of the first suspension, the titanium halide and the first reaction mixture; or suspending the dialkoxymagnesium into the liquid halogenated hydrocarbon to form a second suspension, and adding said second suspension to a mixture of the titanium halide and the fatty acid salt of magnesium to be contacted for reaction to form a second reaction mixture, the electron donor compound being present in at least one of the second suspension, the mixture of the titanium halide and the fatty acid salt of magnesium, and the second reaction mixture.In the polymerization of olefins by use of the former catalyst component, both the amount of catalyst residues in the produced polymer and halogen content therein are greatly reduced with high polymerization activity per unit weight of the former catalyst component and with high yield of stereoregular polymer.

Abstract translation: 公开了制备由钛基催化剂组分和有机铝化合物组成的烯烃聚合催化剂的前催化剂组分的方法，该方法包括将（a）镁的脂肪酸盐和（b ）二烷氧基镁转化为（c）液体卤代烃以形成第一悬浮液，并将所述第一悬浮液加入到（d）通式TiX 4的卤化钛，其中X表示卤素原子，以进行反应以形成 第一反应混合物，（e）电子给体化合物存在于第一悬浮液，卤化钛和第一反应混合物中的至少一种中; 或将二烷氧基镁悬浮到液体卤代烃中以形成第二悬浮液，并将所述第二悬浮液加入到待接触的卤化钛和镁的脂肪酸盐的混合物中以形成第二反应混合物，电子给体化合物 存在于第二悬浮液，卤化钛和镁的脂肪酸盐的混合物中的至少一种和第二反应混合物中。 在通过使用前述催化剂组分的烯烃聚合中，所制备的聚合物中的催化剂残余物的量和其中的卤素含量都大大降低，而单一重量的前一种催化剂组分具有高的聚合活性，并且立体有规聚合物的产率高。

公开(公告)号：US3764591A

公开(公告)日：1973-10-09

申请号：US3764591D

申请日：1971-12-28

Applicant: TOHO TITANIUM CO LTD

Inventor： HOTTA Y ,  FUJII M ,  MIYOSHI K ,  IWASAKI Y

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00 ,  C08F1/56 ,  C08F3/10

CPC classification number: C08F10/00 ,  Y10S526/906 ,  C08F4/631

Abstract: Alpha -OLEFIN POLYMERIZATION IS EFFECTED IN THE PRESENCE OF A CATALYST COMPRISING: (1) AN ORGANO ALUMINUM COMPOUND, AND (2) A COMPOUND PREPARED BY MILLING A HALOGEN COMPOUND OF TITANIUM, WHEREIN SAID TITANIUM ION HAS A VALANCE OF LESS THAN THE MAXIMUM VALENCE, WITH AN Alpha , Beta -UNSATURATED CARBOXYLIC ESTER AND THEREAFTER TREATING WITH 0.1 - 5 MOLE PERCENT OF OXYGEN, BASED ON SAID TITANIUM COMPOUND.

Abstract translation: α-烯烃聚合在催化剂存在下受到影响：（1）有机铝化合物，和（2）通过研磨钛酸盐的化合物制备的化合物，其中所述的钛离子具有小于最大值的值 ，具有α，β-受体羧酸酯和具有0.1〜5％的氧含量的氧化亚铁，基于固体钛化合物。

公开(公告)号：US20250073778A1

公开(公告)日：2025-03-06

申请号：US18718084

申请日：2022-11-24

Applicant: Toho Titanium Co., Ltd.

Inventor： Yosuke Inoue

IPC: B22F3/11 ,  B22F1/052 ,  B22F3/00

Abstract: The titanium porous body according to the present invention is in a form of a sheet, and has a thickness of 0.3 mm or less and a compressive strain amount of 0.20 or less upon pressurization at 80 MPa, wherein a half width of a first peak that is the highest peak height in a pore size distribution showing a relationship between a diameter and a volume of pores is less than or equal to 3.5 μm, and a peak height of a second peak that is the second highest peak height after the first peak is less than or equal to 10% of the peak height of the first peak.

公开(公告)号：US12090549B2

公开(公告)日：2024-09-17

申请号：US17794300

申请日：2020-12-15

Applicant: Toho Titanium Co., Ltd.

Inventor： Yosuke Inoue ,  Syogo Tsumagari ,  Yasuhiko Goto

IPC: B22F1/16 ,  B22F1/142 ,  B22F1/145 ,  B22F3/10 ,  B22F3/11 ,  B22F5/00 ,  C22C14/00

CPC classification number: B22F1/16 ,  B22F1/142 ,  B22F1/145 ,  B22F3/1007 ,  B22F3/11 ,  B22F5/006 ,  C22C14/00 ,  B22F2201/03 ,  B22F2201/10 ,  B22F2201/20 ,  B22F2301/205 ,  B22F2302/25 ,  B22F2304/10 ,  B22F2999/00 ,  B22F1/145 ,  B22F2201/03 ,  B22F1/16

Abstract: A method for manufacturing a porous metal body according to the present invention includes: a surface oxidizing step of heating a titanium-containing powder in an atmosphere containing oxygen at a temperature of 250° C. or more for 30 minutes or more to provide a surface-oxidized powder; and a sintering step of depositing the surface-oxidized powder in a dry process, and sintering the surface-oxidized powder by heating it in a reduced pressure atmosphere or an inert atmosphere at a temperature of 950° C. or more.

公开(公告)号：US20230311205A1

公开(公告)日：2023-10-05

申请号：US18019709

申请日：2021-08-17

Applicant: Toho Titanium Co., Ltd.

Inventor： Yosuke Inoue ,  Shougo Tsumagari

IPC: B22F3/11 ,  B22F1/052 ,  C22C1/08

CPC classification number: B22F3/11 ,  B22F1/052 ,  C22C1/08 ,  B22F2301/205 ,  B22F2304/10

Abstract: The titanium-based porous body according to the present invention is in a form of a sheet and contains titanium, and the titanium-based porous body has a thickness of 0.8 mm or less, a porosity of 30% to 65%, a maximum height Rz1 of one sheet surface of 30 µm or less, a ratio of a maximum height Rz2 of other sheet surface to the maximum height Rz1 of the one sheet surface (Rz2/Rz1) of 1.2 or more, and a compression deformation rate of 19% or less.