公开(公告)号：US4837233A

公开(公告)日：1989-06-06

申请号：US50268

申请日：1987-05-15

Applicant: Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

Inventor： Linda C. Glaeser ,  James F. Brazdil, Jr. ,  Mark A. Toft

IPC: B01J27/199 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/847 ,  B01J23/88 ,  B01J27/057 ,  B01J27/192 ,  B01J27/198 ,  B01J37/04 ,  C07C67/00 ,  C07C253/00 ,  C07C253/24 ,  C07C255/08

CPC classification number: B01J23/002 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/28 ,  B01J23/8472 ,  B01J23/887 ,  B01J23/8871 ,  B01J23/8876 ,  B01J23/8877 ,  B01J27/057 ,  B01J27/192 ,  B01J27/198 ,  B01J37/04 ,  C07C253/24 ,  B01J2523/00 ,  Y02P20/52

Abstract: Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkano:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst composition, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.

Abstract translation: 使用（1）烷烃：NH 3的摩尔比为2至16，烷烃：O 2的摩尔比在1至10的范围内，使用NH 3和O 2将C3至C5无环烷烃氨氧化为（2） 颗粒催化剂组合物，第一种特别有效促进从石蜡形成不饱和腈和烯烃，第二催化剂组合物特别有效促进烯烃转化为不饱和腈。 公开了在该方法中有用的催化组合物。

公开(公告)号：US4647673A

公开(公告)日：1987-03-03

申请号：US733441

申请日：1985-05-13

Applicant: Noel J. Bremer ,  Dennis E. Dria ,  Ernest C. Milberger ,  Patricia R. Blum ,  Mark L. Nicholas

Inventor： Noel J. Bremer ,  Dennis E. Dria ,  Ernest C. Milberger ,  Patricia R. Blum ,  Mark L. Nicholas

IPC: B01J27/198 ,  C07C51/215 ,  C07C51/25 ,  C07D307/60

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J27/198 ,  C07C51/25 ,  C07C51/252 ,  B01J2523/00

Abstract: A process is provided for the preparation of attrition resistant, microspheroidal fluid bed catalysts comprising the mixed oxides of vanadium and phosphorus in which a vanadium phosphorus mixed oxided catalyst precursor is densified, comminuted, formed into fluidizable particles and calcined under fluidization-type conditions. The present invention further provides the attrition resistant fluidizable catalysts prepared by the inventive process, and further provides a process for utilizing such attrition resistant catalysts in the production of maleic anhydride in the vapor phase by the oxidation of 4 carbon atom hydrocarbons.

Abstract translation: 提供了一种制备耐磨耗的微球形流化床催化剂的方法，其包含钒和磷的混合氧化物，其中钒磷混合氧化催化剂前体致密化，粉碎，形成可流化颗粒并在流化型条件下煅烧。 本发明还提供了通过本发明方法制备的耐磨性可流化催化剂，并且还提供了通过氧化4个碳原子烃在气相中生产马来酸酐时利用这种耐磨催化剂的方法。

公开(公告)号：US4569925A

公开(公告)日：1986-02-11

申请号：US394415

申请日：1982-07-01

Applicant: Tai-Cheng Yang ,  Krishna K. Rao ,  I-Der Huang

Inventor： Tai-Cheng Yang ,  Krishna K. Rao ,  I-Der Huang

IPC: B01J27/198 ,  C07C51/215 ,  C07D307/34

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J27/198 ,  B01J2523/00

Abstract: A process for preparing a vanadium, phosphorus oxygen containing catalyst composition capable of partially oxidizing hydrocarbons (e.g., n-butane) to form a carboxylic anhydride (e.g., maleic anhydride), and a process for using this catalyst to form such anhydrides is disclosed. The catalyst composition is prepared by an organic solution technique followed by activation in an air-hydrocarbon atmosphere.

Abstract translation: 公开了一种制备能够部分氧化烃（例如正丁烷）以形成羧酸酐（例如马来酐）的含钒磷氧化催化剂组合物的方法，以及使用该催化剂形成这种酸酐的方法。 催化剂组合物通过有机溶液技术制备，然后在空气 - 烃气氛中活化。

公开(公告)号：US4560674A

公开(公告)日：1985-12-24

申请号：US566360

申请日：1983-12-28

Applicant: James T. Wrobleski ,  James W. Edwards ,  Charles R. Graham ,  Robert A. Keppel ,  Harold Raffelson

Inventor： James T. Wrobleski ,  James W. Edwards ,  Charles R. Graham ,  Robert A. Keppel ,  Harold Raffelson

IPC: C07D307/60 ,  B01J27/198 ,  C01B25/37 ,  C01B25/45 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C51/31 ,  B01J27/14

CPC classification number: B01J23/002 ,  B01J27/198 ,  C07C51/215 ,  C07C51/25 ,  C07C51/252 ,  C07C51/313 ,  B01J2523/00

Abstract: Catalysts useful for the partial oxidation of non-aromatic hydrocarbons, particularly n-butane, with molecular oxygen or a molecular oxygen-containing gas in the vapor phase to produce maleic anhydride are provided which comprise mixed oxides of phosphorus and vanadium. The catalysts are highly effective in that they exhibit a weight/weight productivity of at least 70 grams of maleic anhydride per kilogram of catalyst per hour.

Abstract translation: 提供了可用于在气相中分子氧或分子氧气体部分氧化非芳族烃，特别是正丁烷以产生马来酸酐的催化剂，其包含磷和钒的混合氧化物。 催化剂是非常有效的，因为它们表现出每千克催化剂每小时至少70克马来酸酐的重量/重量产率。

公开(公告)号：US4515904A

公开(公告)日：1985-05-07

申请号：US537983

申请日：1983-09-30

Applicant: Robert C. Edwards

Inventor： Robert C. Edwards

IPC: B01J27/198 ,  B01J27/199 ,  B01J35/00 ,  C07C51/215 ,  B01J27/14 ,  C07D307/60

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J27/198 ,  B01J27/199 ,  B01J35/002 ,  B01J35/1014 ,  B01J35/1038 ,  B01J2523/00

Abstract: A process for the manufacture of a phosphorus-vanadium and phosphorus-vanadium-co-metal catalysts suitable for use in the manufacture of maleic anhydride from butane which process comprises reacting at a temperature of about 0.degree. C. to about 200.degree. C. a vanadium compound in an organic ether solvent having about 2 to about 10 carbon atoms with a phosphoryl halide in the presence of water or an aliphatic alcohol having from about 1 to about 8 carbon atoms, eliminating the solvent and activating the catalyst by the addition of butane or other hydrocarbon feedstock and a phosphorus compound at a temperature of about 300.degree. C. to about 500.degree. C. The catalysts are useful for the manufacture of maleic anhydride from butane feedstock.

Abstract translation: 一种制备适用于从丁烷制备马来酸酐的磷钒和磷 - 钒 - 共 - 金属催化剂的方法，该方法包括在约0℃至约200℃的温度下反应a 钒化合物在具有约2至约10个碳原子的有机醚溶剂中与磷酰卤在水或具有约1至约8个碳原子的脂族醇的存在下反应，除去溶剂并通过加入丁烷来活化催化剂 或其他烃原料和磷化合物在约300℃至约500℃的温度下进行。催化剂可用于从丁烷原料制造马来酸酐。

公开(公告)号：US4435521A

公开(公告)日：1984-03-06

申请号：US381206

申请日：1982-05-24

Applicant: Tai-Cheng Yang ,  Krishna K. Rao ,  I-der Huang

Inventor： Tai-Cheng Yang ,  Krishna K. Rao ,  I-der Huang

IPC: B01J27/198 ,  B01J37/08 ,  C07C51/215 ,  C07C51/25 ,  C07C51/265 ,  B01J27/14

CPC classification number: C07C51/265 ,  B01J23/002 ,  B01J27/198 ,  B01J37/08 ,  C07C51/215 ,  C07C51/252 ,  B01J2523/00

Abstract: A heterogeneous process for preparing a vanadium-phosphorus-oxygen containing catalyst for use in the preparation of carboxylic anhydrides is disclosed. This process employs an activation procedure in an air-hydrocarbon atmosphere.

Abstract translation: 公开了一种制备用于制备羧酸酐的含钒 - 含氧 - 氧的催化剂的非均相方法。 该方法在空气 - 烃气氛中采用活化程序。

公开(公告)号：US4416802A

公开(公告)日：1983-11-22

申请号：US382180

申请日：1982-05-26

Applicant: Carl A. Udovich ,  Robert C. Edwards

Inventor： Carl A. Udovich ,  Robert C. Edwards

IPC: B01J27/198 ,  C07C51/215 ,  B01J27/14

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J27/198 ,  B01J2523/00

Abstract: A process for the manufacture of a phosphorus/vanadium/metal oxide catalyst suitable for the oxidation of butane to maleic anhydride can be prepared by reacting in an aqueous medium a vanadium compound, inorganic acid and metal oxide, then adding orthophosphoric acid to form a soluble vanadium phosphorus metal oxide catalyst, removing the acidified water and adding an aliphatic alcohol, removing the alcohol and recovering under vacuum the solid phosphorus vanadium metal oxide catalyst.

Abstract translation: 制备适于将丁烷氧化成马来酸酐的磷/钒/金属氧化物催化剂的方法可以通过在水性介质中使钒化合物，无机酸和金属氧化物反应，然后加入正磷酸形成可溶的 钒磷金属氧化物催化剂，除去酸化水并加入脂肪醇，除去醇并在真空下回收固体磷钒金属氧化物催化剂。

公开(公告)号：US4400306A

公开(公告)日：1983-08-23

申请号：US392961

申请日：1982-06-28

Applicant: Dennis E. Dria ,  Noel J. Bremer

Inventor： Dennis E. Dria ,  Noel J. Bremer

IPC: B01J27/198 ,  B01J37/02 ,  C07C51/215 ,  C07C51/25 ,  B01J31/12 ,  B01J21/02 ,  B01J27/14

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J27/198 ,  B01J37/0209 ,  C07C51/215 ,  C07C51/25 ,  B01J2523/00

Abstract: A process is provided for preparing supported catalysts by impregnating a pre-formed support with a solution of a metal alkoxide and contacting the impregnated support with a solution of at least one additional catalyst component. This process is particularly suitable for forming attrition resistant fluidizable catalysts. Catalysts prepared by this method are useful in various reaction processes, and may be utilized in oxidation processes such as the production of maleic anhydride from 4 carbon atom hydrocarbons.

Abstract translation: 提供了一种通过用金属醇盐溶液浸渍预形成的载体并将浸渍的载体与至少一种另外的催化剂组分的溶液接触来制备负载型催化剂的方法。 该方法特别适用于形成耐磨性可流化催化剂。 通过该方法制备的催化剂可用于各种反应过程中，可用于氧化方法如从4个碳原子烃生产马来酸酐。

公开(公告)号：US4351773A

公开(公告)日：1982-09-28

申请号：US221670

申请日：1980-12-31

Applicant: Ernest C. Milberger ,  Michael F. Lemanski ,  Gregory G. Spitnale

Inventor： Ernest C. Milberger ,  Michael F. Lemanski ,  Gregory G. Spitnale

IPC: C07D307/60 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C01B25/45 ,  C07B61/00 ,  C07C51/215

CPC classification number: B01J23/002 ,  B01J27/198 ,  C07C51/215 ,  B01J2523/00

Abstract: A process is provided for the preparation of fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus, comprising the steps of preparing the catalyst precursor, comminuting the precursor, introducing the precursor into water to form an aqueous slurry and spray drying the slurry. The resulting microspheroidal particles are excellent fluid bed catalysts for the preparation of maleic anhydride from 4-carbon atom hydrocarbons.

Abstract translation: 提供了一种制备含有钒和磷的混合氧化物的流化床氧化催化剂的方法，包括制备催化剂前体，粉碎前体，将前体引入水中以形成含水浆料并喷雾干燥浆料的步骤。 所得微球颗粒是用于从4-碳原子烃制备马来酸酐的优异流化床催化剂。

公开(公告)号：US4337173A

公开(公告)日：1982-06-29

申请号：US189346

申请日：1980-09-22

Applicant: Masayuki Otake

Inventor： Masayuki Otake

IPC: B01J27/198 ,  C01B25/45 ,  C07C51/215 ,  B01J27/14 ,  C01B15/16

CPC classification number: B01J23/002 ,  B01J27/198 ,  C01B25/45 ,  C07C51/215 ,  B01J2523/00

Abstract: A substitutional solid-solution type crystalline oxide represented by the general formula:[(V.sub.1-x-y-z Fe.sub.x Cr.sub.y Al.sub.z)O].sub.2 P.sub.2 O.sub.7wherein 0.ltoreq.x.ltoreq.0.40, 0.ltoreq.y.ltoreq.0.40, 0.ltoreq.z.ltoreq.0.40, and 0

Abstract translation: 由以下通式表示的取代固溶体型结晶氧化物：[（V1-xy-zFexCryAlz）O] 2 P2O7，其中0≤x≤0.40，0≤y≤0.40，0 < 并且具有与（VO）2 P 2 O 7相同的晶体结构和具有特定结晶结构的前体取代的固溶体型结晶氧化物。 前述氧化物作为气相氧化催化剂具有高活性和选择性，特别是从含有四个碳原子的烃生产马来酸酐。