公开(公告)号：US4774299A

公开(公告)日：1988-09-27

申请号：US36017

申请日：1987-04-08

申请人： Andre Dumain ,  Charles Raufast

发明人： Andre Dumain ,  Charles Raufast

IPC分类号： B01J4/00 ,  B01J3/02 ,  B01J8/00 ,  B01J8/24 ,  C08F2/34 ,  C08F4/24

CPC分类号： B01J3/02 ,  B01J8/0035 ,  C08F2/34 ,  B01J2208/00778 ,  Y10S526/901 ,  Y10S526/904 ,  Y10S526/919

摘要： Device and process for introducing a powder with catalytic activity into a fluidized bed polymerization reactor (1), the said device comprising:a storage enclosure (2) for powder with catalytic activity, provided with a feed line (3) for powder with catalytic activity and a shut-off valve (26), this enclosure being connected to a metering device (4) making it possible to deliver periodically a given volume of powder with catalytic activity,an intermediate chamber (5), placed below the metering device to receive direct the powder delivered by the latter, this intermediate chamber comprising in its upper part a tube (6) bringing in an inert carrier gas, provided with a shut-off valve,piping for conveying the powder (8) connecting the bottom part of the intermediate chamber to the fluidized-bed reactor, this piping having a portion which is more or less horizontal, the said powder conveying piping being provided with a full-bore rapid-opening valve (10).

公开(公告)号：US4687381A

公开(公告)日：1987-08-18

申请号：US716030

申请日：1985-03-26

申请人： Andre Dumain ,  Charles Raufast

发明人： Andre Dumain ,  Charles Raufast

IPC分类号： B01J4/00 ,  B01J3/02 ,  B01J8/00 ,  B01J8/24 ,  C08F2/34 ,  C08F4/24 ,  B65G53/40

CPC分类号： B01J3/02 ,  B01J8/0035 ,  C08F2/34 ,  B01J2208/00778 ,  Y10S526/901 ,  Y10S526/904 ,  Y10S526/919

摘要： Device and process for introducing a powder with catalytic activity into a fluidized bed polymerization reactor (1), the said device comprising:a storage enclosure (2) for powder with catalytic activity, provided with a feed line (3) for powder with catalytic activity and a shut-off valve (26), this enclosure being connected to a metering device (4) making it possible to deliver periodically a given volume of powder with catalytic activity,an intermediate chamber (5), placed below the metering device to receive direct the powder delivered by the latter, this intermediate chamber comprising in its upper part a tube (6) bringing in a inert carrier gas, provided with a shut-off valve,piping for conveying the powder (8) connecting the bottom part of the intermediate chamber to the fluidized-bed reactor, this piping having a portion which is more or less horizontal, the said powder conveying piping being provided with a full-bore rapid-opening valve (10).

摘要翻译： 用于将具有催化活性的粉末引入流化床聚合反应器（1）的装置和方法，所述装置包括：用于具有催化活性的粉末的储存壳体（2），其具有用于具有催化活性的粉末的进料管线（3） 和封闭阀（26），该外壳连接到计量装置（4），使得可以周期性地递送具有催化活性的给定体积的粉末，中间室（5），放置在计量装置下方以接收 引导由后者输送的粉末，该中间室在其上部包括带有惰性载体气体的管（6），设有截止阀，用于输送粉末（8）的管道，该粉末连接 中间室到流化床反应器，该管道具有或多或少水平的部分，所述粉末输送管道设置有全孔快速打开阀（10）。

公开(公告)号：US4158571A

公开(公告)日：1979-06-19

申请号：US907445

申请日：1978-05-19

申请人： Thomas J. Lynch ,  Robert J. Rowatt

发明人： Thomas J. Lynch ,  Robert J. Rowatt

IPC分类号： C08F10/00 ,  C08F4/02 ,  C08J3/20 ,  C08K9/00

CPC分类号： C08F10/00 ,  Y10S526/901 ,  Y10S526/903 ,  Y10S526/919

摘要： Bingham fluid compositions are provided which contain a functional material such as a polymerization initiator dispersed in a solid continuous phase, which is a mixture of a wax and a liquid hydrocarbon. Such compositions are prepared by heating the wax and the liquid hydrocarbon to form a melt and dispersing the functional material in the melt. Upon cooling, the composition solidifies with the functional material being uniformly dispersed throughout the continuous solid phase. The compositions, while solid at ambient temperature and pressure, assume the flow characteristics of a liquid under an applied pressure and can be pumped to feed the functional material to a polymerization reactor or molten polymer on a continuous basis.

摘要翻译： 提供了含有分散在固相连续相中的聚合引发剂（它是蜡和液态烃的混合物）的功能材料的宾汉液体组合物。 通过加热蜡和液体烃以形成熔体并将功能材料分散在熔体中来制备这些组合物。 冷却后，组合物固化，功能材料均匀分散在整个连续固相中。 组合物在环境温度和压力下为固体，在施加的压力下呈现液体的流动特性并且可以被泵送以将功能材料连续供给到聚合反应器或熔融聚合物。

公开(公告)号：US3726845A

公开(公告)日：1973-04-10

申请号：US3726845D

申请日：1971-03-22

申请人： EXXON RESEARCH ENGINEERING CO

发明人： NICKERSON J

IPC分类号： B01J4/00 ,  B01J8/02 ,  C08F2/00 ,  C08F10/00 ,  C08F1/42 ,  C08F3/06 ,  C08F3/08

CPC分类号： C08F10/00 ,  C08F110/06 ,  Y10S526/919 ,  C08F4/642 ,  C08F10/06 ,  C08F2/00

摘要： IN THE POLYMERIZATION OF ALPHA MONO-OLEFINS WITH A CATALYST WHICH TENDS TO CLOG LINES AND PUMPS AND WHEREIN A DILUENT FOR THE REACTION IS EMPLOYED, THE CATALYST LINE AND PUMP AREMAINTAINED CLEAN AND FREE OF CATALYST DEPOSITS BY ALTERNATELY FLOWING OR SUPPLYING CATALYST AND DILUENT AS SEPARATE STREAMS THROUGH SAID CATALYST LINE AND PUMP WHICH ALSO ALLOWS CATALYST SUPPLY TO BE CONTROLLED.

公开(公告)号：US3694423A

公开(公告)日：1972-09-26

申请号：US3694423D

申请日：1971-01-18

申请人： GULF RESEARCH DEVELOPMENT CO

发明人： SMITH WAYNE E ,  BATCHELOR ROBERT L ,  FULK KENNETH J

IPC分类号： B01J3/02 ,  B01J4/00 ,  B01J8/00 ,  B01J19/18 ,  C08F2/00 ,  C08F10/00 ,  C08F1/98 ,  C08F3/02

CPC分类号： B01J4/007 ,  B01J3/02 ,  B01J4/002 ,  B01J8/0015 ,  B01J8/002 ,  B01J19/1837 ,  C08F10/00 ,  Y10S526/919 ,  C08F4/642 ,  C08F4/6495

摘要： In mono 1-olefin and diolefin polymerization processes, an improved method and apparatus for introducing a catalyst slurry into the polymerization zone which comprises pressurizing a catalyst slurry through a first transport zone to a second transport zone and thereafter sweeping the catalyst slurry through the second transport zone to the polymerization zone.

公开(公告)号：US20150175720A1

公开(公告)日：2015-06-25

申请号：US14573095

申请日：2014-12-17

申请人： Total Research & Technology Feluy

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  Andre Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： C08F2/01 ,  C08F2/00

CPC分类号： C08F110/02 ,  B01J8/0015 ,  B01J2208/00548 ,  C08F2/005 ,  C08F2/01 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/919 ,  Y10T137/85978 ,  Y10T137/86035 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08 ,  C08F2/001

摘要： The present invention relates to an apparatus and process for polymerizing olefins. One embodiment comprises polymerizing at least one monomer in a first loop reactor in the presence of a catalyst to produce a first polyolefin fraction. A portion of the first polyolefin fraction is transferred to a second loop reactor, connected in series with the first loop reactor. The process further comprises polymerizing in the second loop reactor at least one monomer in the presence of a catalyst to produce a second polyolefin fraction in addition to the first polyolefin fraction. The combination of the first and second polyolefin fractions can produce a polymer resin fluff having bimodal molecular weight distribution.

摘要翻译： 本发明涉及一种聚合烯烃的装置和方法。 一个实施方案包括在催化剂存在下在第一环管反应器中聚合至少一种单体以产生第一聚烯烃级分。 将第一聚烯烃部分的一部分转移到与第一回路反应器串联连接的第二回路反应器。 该方法还包括在催化剂存在下在第二环管反应器中聚合至少一种单体，以产生除第一聚烯烃级分之外的第二聚烯烃级分。 第一和第二聚烯烃级分的组合可产生具有双峰分子量分布的聚合物树脂绒毛。

公开(公告)号：US09023958B2

公开(公告)日：2015-05-05

申请号：US14357704

申请日：2012-10-25

申请人： Univation Technologies, LLC

发明人： Dale A. Wright ,  John R. Parrish ,  James L. Swecker, II ,  Mark G. Goode

IPC分类号： C08F2/00 ,  C08F2/34 ,  B01J4/00 ,  B01J7/00 ,  B65G51/02 ,  B01J8/24 ,  B01J8/00 ,  C08F110/02

CPC分类号： B01J4/001 ,  B01J7/00 ,  B01J8/00 ,  B01J8/24 ,  B01J2204/002 ,  B01J2204/007 ,  B01J2219/00042 ,  B65G51/02 ,  C08F110/02 ,  Y10S526/919 ,  C08F2500/12 ,  C08F10/00 ,  C08F2/34 ,  C08F2/01

摘要： A method for the delivery of a catalyst to a polymerization reactor is disclosed, comprising: contacting a catalyst with a carrier fluid comprising an inert hydrocarbon in gaseous form, the inert hydrocarbon having a normal boiling point of about −1° C. to about 81° C.; and flowing the carrier fluid to the polymerization reactor such that the carrier fluid transports the catalyst to the polymerization reactor. A catalyst delivery system is disclosed, comprising: a catalyst vessel for containing a catalyst; a catalyst injection line for delivering the catalyst to a polymerization reactor, the catalyst injection line being in fluid communication with the catalyst vessel and the polymerization reactor; and a carrier fluid line in fluid communication with the catalyst injection line for delivering a carrier fluid comprising an inert hydrocarbon to the catalyst injection line, the inert hydrocarbon having a normal boiling point of about −1° C. to about 81° C.

摘要翻译： 公开了一种将催化剂递送到聚合反应器的方法，包括：使催化剂与包含气态惰性烃的载体流体接触，所述惰性烃的标准沸点为约-1℃至约81℃ C。; 并将载体流体流动到聚合反应器，使得载体流体将催化剂输送到聚合反应器。 公开了一种催化剂输送系统，包括：用于容纳催化剂的催化剂容器; 用于将催化剂输送到聚合反应器的催化剂注入管线，催化剂注入管线与催化剂容器和聚合反应器流体连通; 以及与所述催化剂注入管线流体连通以将包含惰性烃的载体流体输送到所述催化剂注入管线的载体流体管线，所述惰性烃的正常沸点为约-1℃至约81℃。

公开(公告)号：US08492489B2

公开(公告)日：2013-07-23

申请号：US12862655

申请日：2010-08-24

申请人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  André Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

发明人： Louis Fouarge ,  Eric Damme ,  Olivier Miserque ,  Daniel Siraux ,  Philippe Bodart ,  André Lewalle ,  Marc Van der Auwera ,  Frans Van den Brande ,  Giacomo Conti ,  Hugo Vandaele ,  Mark Verleysen ,  Carl Van Camp ,  Etienne Laurent ,  Philippe Marechal ,  Marc Moers ,  Leopold D'Hooghe ,  Marjan Sillis ,  Kai Hortman ,  Pascal Folie ,  Renaud Oreins

IPC分类号： C08F2/12 ,  B01J19/18

CPC分类号： C08F110/02 ,  B01J8/0015 ,  B01J2208/00548 ,  C08F2/005 ,  C08F2/01 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/919 ,  Y10T137/85978 ,  Y10T137/86035 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/18 ,  C08F210/08 ,  C08F2/001

摘要： A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein. The method generally includes introducing an ethylene monomer, a C3+ alpha olefin comonomer and a diluent carrier liquid into a reactor system comprising at least one loop reactor; supplying at least one polymerization catalyst system to said reactor system; circulating said diluent liquid, ethylene monomer, and alpha olefin copolymer through said loop reactor while copolymerizing said ethylene and said alpha olefin monomer in the presence of said catalyst system to produce a slurry of polymer fluff particles in said diluent carrier liquid; diverting the flow of said slurry through said loop reactor into at least one settling leg connected to the loop reactor and sequentially discharging the settled polymer slurry from said at least one settling leg to withdraw said polymer slurry from said reactor system; and introducing an ethylene monomer co-feed into said loop reactor at least two spaced locations downstream of the point of introduction of ethylene comonomer and diluent in subparagraph a), said ethylene co-feed being introduced in an amount effective to reduce the variation in the ratio of ethylene monomer and comonomer within said loop reactor.

摘要翻译： 本文描述了环管反应器系统中乙烯与C 3+烯烃共聚物共聚合的方法及由其形成的聚合物。 该方法通常包括将乙烯单体，C 3+α-烯烃共聚单体和稀释剂载体液体引入到包含至少一个环管反应器的反应器系统中; 向所述反应器系统供应至少一种聚合催化剂体系; 在所述催化剂体系的存在下使所述乙烯和所述α-烯烃单体共聚合，从而通过所述环管反应器循环所述稀释液体，乙烯单体和α-烯烃共聚物，以在所述稀释剂载体液体中产生聚合物绒毛颗粒的浆料; 将所述浆料的流动通过所述环管反应器转移到连接到环管反应器的至少一个沉降腿中，并且从所述至少一个沉降腿顺序排出沉降的聚合物浆料以从所述反应器系统中抽出所述聚合物浆料; 并且在乙烯共聚单体和稀释剂在a）部分引入点下游的至少两个间隔位置处将乙烯单体共进料引入所述环管反应器中，所述乙烯共进料以有效减少 乙烯单体和共聚单体在所述环管反应器内的比例。

公开(公告)号：US20130125996A1

公开(公告)日：2013-05-23

申请号：US13812713

申请日：2011-07-29

申请人： Daan Dewachter ,  Alain Brusselle

发明人： Daan Dewachter ,  Alain Brusselle

IPC分类号： F03B17/00

CPC分类号： F03B17/00 ,  B01J8/002 ,  B01J2208/00752 ,  C08F4/65916 ,  C08F10/00 ,  C08F210/16 ,  Y10S417/90 ,  Y10S526/919 ,  Y10T137/0318 ,  C08F2/14 ,  C08F2/01 ,  C08F210/14

摘要： The present invention relates to a method for feeding metallocene catalyst slurry to an olefin polymerization loop reactor (1) using a positive displacement device (5) positive displacement device comprising a first chamber and a second chamber, each chamber having an inlet and an outlet and each chamber comprising an ball arranged between the walls of said chamber, wherein said chambers are connected to each other by a pump chamber operably connected to a pump, wherein, the difference between the diameter of said ball and the diameter of said chamber is comprised between 5 to 200 times the average particle size (d50) of said catalyst.

摘要翻译： 本发明涉及使用包括第一室和第二室的正位移装置（5）的正位移装置将茂金属催化剂浆料供给到烯烃聚合反应器（1）的方法，每个室具有入口和出口， 每个室包括布置在所述室的壁之间的球，其中所述室通过可操作地连接到泵的泵室彼此连接，其中，所述球的直径和所述室的直径之间的差包括在 所述催化剂的平均粒度（d50）为5〜200倍。

公开(公告)号：US07781547B2

公开(公告)日：2010-08-24

申请号：US11628608

申请日：2004-06-25

申请人： Yuan-Ju (Ray) Chen ,  Michael Francis McDonald ,  Timothy Daniel Shaffer ,  David Yen-Lung Chung ,  Robert Norman Webb

发明人： Yuan-Ju (Ray) Chen ,  Michael Francis McDonald ,  Timothy Daniel Shaffer ,  David Yen-Lung Chung ,  Robert Norman Webb

IPC分类号： C08F2/14 ,  C08F110/10

CPC分类号： C08F10/10 ,  C08F110/10 ,  Y10S526/919 ,  C08F2/14 ,  C08F2500/03

摘要： The invention relates to new polymerization processes using hydrofluorocarbons to produce polymers. In particular, the invention relates to new polymerization processes using turbulent flow reactor systems using diluents including one or more hydrofluorocarbon(s) to produce polymers.

摘要翻译： 本发明涉及使用氢氟烃生产聚合物的新聚合方法。 特别地，本发明涉及使用包含一种或多种氢氟烃的稀释剂来制造聚合物的湍流反应器系统的新的聚合方法。