公开(公告)号：US5234874A

公开(公告)日：1993-08-10

申请号：US681683

申请日：1991-04-08

Applicant: Mohammed Dekiouk ,  Gerard Hecquet ,  Stanislas Pietrzyk

Inventor： Mohammed Dekiouk ,  Gerard Hecquet ,  Stanislas Pietrzyk

IPC: B01J27/185 ,  B01J29/06 ,  B01J29/08 ,  B01J29/10 ,  B01J29/82 ,  B01J29/90 ,  B01J38/30 ,  C07B61/00 ,  C07C51/377 ,  C07C57/04 ,  C07C57/05

CPC classification number: B01J38/30 ,  B01J27/1853 ,  B01J29/084 ,  B01J29/90 ,  C07C51/377 ,  B01J29/82 ,  Y02P20/584

Abstract: For the oxidative dehydrogenation of saturated carboxylic acids to form .alpha.,.beta.-unsaturated carboxylic acids, saturated acids are contacted with a gas containing molecular oxygen and, where appropriate, an inert diluent gas, in the vapor phase, at a reaction temperature of 250.degree. to 600.degree. C., in the presence of a catalyst system comprising a non-supported catalyst of the formula FeP.sub.x Me.sub.y O.sub.z, wherein: Me is at least one of the following elements: Li, Na, K,, Rb, Cs, Mg, Ca, Sr and Ba; x has a value from 0.2 to 3.0; y has a value from 0.01 to 0.2; and z is the quantity of oxygen bonded to the other elements and corresponding to their oxidation state, in an entrained-bed reactor and, where appropriate, in the presence of steam in a molar ratio to the saturated acid not exceeding 0.5. The catalyst is beneficially associated with at least one zeolite, preferably in a concentration sufficient to improve the attrition resistance of the catalyst, e.g., in an amount by weight of about 1-10% of the catalyst.

Abstract translation: 对于饱和羧酸的氧化脱氢形成α，β-不饱和羧酸，饱和酸与含有分子氧的气体和适当的气态相反应的惰性稀释气体在250℃的反应温度下接触。 在含有式FeP x M y O z的非负载催化剂的催化剂体系的存在下，其中：Me是以下元素中的至少一种：Li，Na，K ,, Rb，Cs，Mg，Ca ，Sr和Ba; x的值为0.2〜3.0; y的值为0.01〜0.2; 并且z是在夹带床反应器中，并且在适当的情况下，在与饱和酸的摩尔比不超过0.5的蒸汽存在下，与其它元素结合并相应于其氧化态的氧的量。 该催化剂有利地与至少一种沸石有关，优选地具有足以提高催化剂耐磨性的浓度，例如以催化剂的约1-10％重量的量。

公开(公告)号：US4981830A

公开(公告)日：1991-01-01

申请号：US290326

申请日：1988-12-27

Applicant: Yutaka Sasaki ,  Hiroshi Utsumi ,  Masato Otani ,  Kazuo Morishita

Inventor： Yutaka Sasaki ,  Hiroshi Utsumi ,  Masato Otani ,  Kazuo Morishita

IPC: B01J27/185 ,  B01J27/186 ,  B01J27/188 ,  C01C3/02 ,  C07B31/00 ,  C07B33/00 ,  C07B61/00 ,  C07C67/00

CPC classification number: C01C3/0241 ,  B01J27/1853 ,  B01J27/188

Abstract: A process for preparing a metal oxide catalyst for a fluidized bed process, which comprises adjusting the pH of an aqueous slurry containing an iron compound, an antimony compound, a phosphorus compound, and a silica carrier material as essential elements, with the atomic ratio of phosphorus to antimony being at least 0.1:1, to a pH of 3 or less, spray drying the slurry, and calcining the resulting particles; which catalyst exhibits excellent activity and physical properties suitable for use in a fluidized bed process and can be obtained with good reproducibility.

公开(公告)号：US4859649A

公开(公告)日：1989-08-22

申请号：US162796

申请日：1988-02-26

Applicant: Kurt Bohnke ,  Helmut Brandis ,  Hans-Heinrich Domalski ,  Hans-Joachim Fleischer ,  Heinrich Frinken

Inventor： Kurt Bohnke ,  Helmut Brandis ,  Hans-Heinrich Domalski ,  Hans-Joachim Fleischer ,  Heinrich Frinken

IPC: B01J23/86 ,  B01J27/185 ,  B01J32/00 ,  C09K5/00 ,  C09K5/16 ,  C22C38/00 ,  C22C38/28 ,  H01C3/00 ,  H05B3/12

CPC classification number: B01J23/862 ,  C22C38/28 ,  H05B3/12

Abstract: A ferritic, heat-resistant steel whose behavior at high application temperatures is improved by the combined addition of oxygen affinitive elements. Apart from stabilizing the electric resistance of heating elements by addition of zirconium, titanium and rare earth metal, also the creep elongation of the steel is considerably reduced under load at temperatures above 900.degree. C., the thermal stress capacity thus being increased. The resulting complex oxide coating increases the protective function with regard to preserving the metallic cross-section in continuous and/or cyclic heat treatments.The steel is composed of:up to 0.10 % Cup to 0.80 % Si0.10 to 0.50 % Mnup to 0.035 % Pup to 0.020 % S12 to 30 % Cr0.10 to 1.0 % Moup to 1 % Ni3.5 to 8 % Al0.01 to 1 % Zr0.003 to 0.8 % rare earth metals0.003 to 0.30 % Ti0.003 to 0.050 % Nremainder Fe and incidental impurities.

Abstract translation: 一种铁素体耐热钢，其在高应用温度下的行为通过氧亲和元素的组合添加而得到改善。 除了通过添加锆，钛和稀土金属来稳定加热元件的电阻之外，在高于900℃的温度下，在负载下钢的蠕变伸长率也显着降低，因此热应力容量增加。 所得到的复合氧化物涂层增加了在连续和/或循环热处理中保留金属横截面的保护功能。 该钢由以下组成：高达0.10％C至0.80％Si 0.10至0.50％Mn至0.035％P至0.020％S 12至30％Cr 0.10至1.0％Mo至1％Ni 3.5至8％ Al 0.01〜1％Zr 0.003〜0.8％稀土金属0.003〜0.30％Ti 0.003〜0.050％N余量Fe及附带杂质。

公开(公告)号：US4834869A

公开(公告)日：1989-05-30

申请号：US161693

申请日：1988-02-29

Applicant: Philip J. Angevine ,  Pochen Chu ,  Thomas F. Degnan ,  Garry W. Kirker

Inventor： Philip J. Angevine ,  Pochen Chu ,  Thomas F. Degnan ,  Garry W. Kirker

IPC: B01J27/18 ,  B01J27/16 ,  B01J27/185 ,  B01J32/00 ,  B01J35/10 ,  B01J37/03 ,  C10G45/04 ,  C10G47/10

CPC classification number: B01J37/03 ,  B01J29/84 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/108

Abstract: This invention relates to a method of preparing a metal-containing amorphous magnesia-alumina-aluminum phosphate catalyst support involving the admixture of an organic cation having a size equal to or greater than 2 Angstroms, the organic cation preferably being a tertiary or a tetraalkylammonium or phosphonium cation. The method permits recovery of a catalyst support having a controlled pore size distribution. The invention also relates to an improved catalytic support as well as an improved petroleum residua upgrading process comprising hydrotreating residua in the presence of the improved catalyst support.

Abstract translation: 本发明涉及一种制备含金属的无定形氧化镁 - 氧化铝 - 磷酸铝催化剂载体的方法，该催化剂载体包括大小等于或大于2埃的有机阳离子的混合物，有机阳离子优选为叔烷基铵或四烷基铵或 鏻阳离子。 该方法允许回收具有可控孔径分布的催化剂载体。 本发明还涉及改进的催化剂载体以及改进的石油渣油改质方法，其包括在改进的催化剂载体存在下加氢处理残余物。

公开(公告)号：US4810686A

公开(公告)日：1989-03-07

申请号：US100663

申请日：1987-09-24

Applicant: Richard A. Kemp

Inventor： Richard A. Kemp

IPC: C10G45/38 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J27/188 ,  B01J35/10 ,  B01J37/00 ,  B01J37/03 ,  C10G45/08 ,  B01J27/19 ,  B01J27/185

CPC classification number: B01J27/188 ,  B01J35/10 ,  C10G45/08 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/03

Abstract: This invention relates to a process for preparing highly active hydrotreating catalysts prepared by incoporating an element selected from the group consisting of nickel, cobalt and mixtures thereof, a heavy metal selected from the group consisting of molybdenum, tungsten and mixtures thereof, and a stabilizing amount of phosphorus into an alumina hydrogel. The final calcined catalysts have surface areas at least about 300 m.sup.2 /g, at least about 20% of the pore volume in pores having diameters greater than about 350 .ANG. and at least about 20% of the pore volume in pores having diameters less than about 70 .ANG..

公开(公告)号：US4784981A

公开(公告)日：1988-11-15

申请号：US399633

申请日：1982-07-19

Applicant: Heinz-Jurgen Alpers ,  Karl-Heinz Heller ,  Gunther Lenz

Inventor： Heinz-Jurgen Alpers ,  Karl-Heinz Heller ,  Gunther Lenz

IPC: C07D307/60 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  B01J27/185

CPC classification number: B01J23/002 ,  B01J27/198 ,  C07C51/215 ,  C07C51/252 ,  B01J2523/00

Abstract: The invention relates to a vanadium/phosphorus mixed oxide catalyst, a process for its preparation and its use for the preparation of maleic anhydride.The catalyst according to the invention is prepared by reacting a vanadium(V) compound with phosphoric acid and/or a compound forming phosphoric acid with heating, optionally in the presence of water, and subsequently treating the product obtained after the reaction with organic solvents and/or diluents having reducing activity, optionally in the presence of a promoter, at an elevated temperature.

Abstract translation: 本发明涉及钒/磷混合氧化物催化剂，其制备方法及其用于制备马来酸酐的用途。 根据本发明的催化剂通过任选在水存在下使钒（V）化合物与磷酸和/或形成磷酸的化合物加热反应制备，随后将其与有机溶剂反应后得到的产物和 /或具有降低活性的稀释剂，任选地在助催化剂存在下，在升高的温度下。

公开(公告)号：US4717705A

公开(公告)日：1988-01-05

申请号：US924097

申请日：1986-10-28

Applicant: Richard A. Kemp

Inventor： Richard A. Kemp

IPC: B01J23/882 ,  B01J23/888 ,  B01J27/188 ,  B01J35/10 ,  C10G49/04 ,  B01J27/19 ,  B01J27/185 ,  C10G45/08

CPC classification number: C10G49/04 ,  B01J23/882 ,  B01J23/888 ,  B01J27/188 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/108

Abstract: This invention relates to a process for preparing highly active hydrotreating catalysts prepared by incorporating cobalt and an element selected from the group consisting of molybdenum, tungsten and mixtures thereof, into an alumina hydrogel support. The final calcined catalysts have surface areas greater than about 300 m.sup.2 /g, flat plate crush strengths greater than about 14 lbs and more than about 80% of their pore volume in pores having diameters less than about 70 .ANG..

Abstract translation: 本发明涉及一种制备高活性加氢处理催化剂的方法，该催化剂通过将钴和选自钼，钨及其混合物的元素掺入到氧化铝水凝胶载体中而制备。 最终煅烧的催化剂具有大于约300m 2 / g的表面积，平板压碎强度大于约14lbs，并且具有直径小于约70的孔的孔体积的大于约80％。

公开(公告)号：US4717704A

公开(公告)日：1988-01-05

申请号：US924221

申请日：1986-10-28

Applicant: Richard A. Kemp

Inventor： Richard A. Kemp

IPC: B01J27/188 ,  B01J27/19 ,  B01J35/10 ,  C10G45/08 ,  B01J27/185

CPC classification number: C10G45/08 ,  B01J27/188 ,  B01J27/19 ,  B01J35/0026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1047 ,  B01J35/108

Abstract: This invention relates to a process for preparing highly active hydrotreating catalysts prepared by incorporating cobalt and an element selected from the group consisting of molybdenum, tungsten and mixtures thereof, into a phosphated alumina hydrogel support. The final calcined catalysts have surface areas greater than about 300 m.sup.2 /g, flat plate crush strengths greater than about 18 lbs and more than about 80% of their pore volume in pores having diameters less than about 70 .ANG..

Abstract translation: 本发明涉及一种制备高活性加氢处理催化剂的方法，该催化剂通过将钴和选自钼，钨及其混合物的元素掺入磷酸化氧化铝水凝胶载体而制备。 最终煅烧的催化剂具有大于约300m 2 / g的表面积，平板挤压强度大于约18lbs，并且其直径小于约70的孔的孔体积的大于约80％。

公开(公告)号：US4670415A

公开(公告)日：1987-06-02

申请号：US791977

申请日：1985-10-28

Applicant: Robert A. Keppel ,  Victoria M. Franchetti

Inventor： Robert A. Keppel ,  Victoria M. Franchetti

IPC: B01J27/198 ,  C07C51/215 ,  C07C51/25 ,  B01J27/185 ,  C07D307/34

CPC classification number: C07C51/252 ,  B01J23/002 ,  B01J27/198 ,  C07C51/215 ,  C07C51/25 ,  B01J2523/00

Abstract: Iron/lithium promoted phosphorus-vanadium-oxygen catalysts for the production of maleic anhydride are prepared by contacting a substantially tetravalent vanadium-containing compound and a phosphorus-containing compound and a promoter component containing each of iron and lithium in a substantially anhydrous alcohol medium in the presence of anhydrous hydrogen chloride to form an iron/lithium promoted phosphorus-vanadium-oxygen catalyst precursor. The catalyst precursor is recovered, dried, roasted, formed into structures if structures are desired, and calcined.

Abstract translation: 通过使基本上四价的含钒化合物和含磷化合物和含有铁和锂的助催化剂组分在基本上无水的醇介质中接触来制备用于生产马来酐的铁/锂促进的磷 - 钒 - 氧催化剂 存在无水氯化氢以形成铁/锂促进的磷 - 钒 - 氧催化剂前体。 将催化剂前体回收，干燥，焙烧，如果需要结构，则形成结构并煅烧。

公开(公告)号：US4629717A

公开(公告)日：1986-12-16

申请号：US743349

申请日：1985-06-11

Applicant: Tai-Hsiang Chao

Inventor： Tai-Hsiang Chao

IPC: B01J27/16 ,  B01J27/188 ,  C10G49/02 ,  B01J27/14 ,  B01J27/185 ,  B01J27/19

CPC classification number: B01J27/16 ,  B01J27/188 ,  C10G49/02

Abstract: A novel phosphorus-modified alumina composite comprising a hydrogel having a molar ratio on an elemental basis of phosphorus to aluminum of from 1:1 to 1:100 together with a surface area of about 140 to 450 m.sup.2 /gm is defined. The composite is prepared by admixing an alumina hydrosol with a phosphorus-containing compound to form a phosphorus-modified sol and gelling said admixture. The phosphorus-modified alumina composite is useful as a catalyst support for various catalytic reactions.

Abstract translation: 定义了一种新型的磷改性氧化铝复合材料，其包含具有1至1：100的基于磷与铝的元素摩尔比的水凝胶以及约140至450m 2 / gm的表面积。 通过将氧化铝水溶胶与含磷化合物混合以形成磷改性溶胶和胶凝所述混合物来制备复合材料。 磷改性氧化铝复合物可用作各种催化反应的催化剂载体。