METHOD FOR PROCESSING HYDROCARBON FUELS USING MICROWAVE ENERGY
    65.
    发明申请
    METHOD FOR PROCESSING HYDROCARBON FUELS USING MICROWAVE ENERGY 有权
    使用微波能量处理碳氢燃料的方法

    公开(公告)号:US20150053592A1

    公开(公告)日:2015-02-26

    申请号:US14464345

    申请日:2014-08-20

    Abstract: A method of operating a hydrocarbon material processing system includes feeding a hydrocarbon feedstock from a hydrocarbon feedstock source into a reaction tube positioned within an opening of a waveguide, feeding a process gas from a process gas source into the reaction tube, receiving microwaves in the waveguide from a microwave generator, energy from the waveguide in the reaction tube to cause the feedstock and process gas to react and form into a product stream comprising a fuel product. The method also includes periodically delivering a cleaning gas into the reaction tube, without stopping the propagation of the energy and without pausing the feeding of the hydrocarbon feedstock and the process gas into the reaction tube.

    Abstract translation: 一种操作烃材料处理系统的方法包括将来自烃原料源的烃原料进料到位于波导开口内的反应管中,将处理气体从工艺气体源供给到反应管中,在波导中接收微波 来自微波发生器的能量来自反应管中的波导,以使原料和处理气体反应并形成包含燃料产物的产物流。 该方法还包括将清洁气体周期性地输送到反应管中,而不停止能量的传播,而不会暂停将烃原料和工艺气体进料到反应管中。

    Catalytic pyrolysis using UZM-39 aluminosilicate zeolite
    68.
    发明授权
    Catalytic pyrolysis using UZM-39 aluminosilicate zeolite 有权
    使用UZM-39铝硅酸盐沸石催化裂解

    公开(公告)号:US08853477B2

    公开(公告)日:2014-10-07

    申请号:US14074742

    申请日:2013-11-08

    Applicant: UOP LLC

    Abstract: A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. NanMmn+RrQqAl1-xExSiyOz where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,Ω-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

    Abstract translation: 已经合成了一系列TUN和IMF染色体型相干生长复合材料,并被证明是生物质催化热解的有效催化剂。 这些沸石由经验公式表示。 NanMmn + RrQqAl1-xExSiyOz其中M表示锌或金属或来自第1族,第2族,第3族的金属或元素周期表的镧系元素的金属,R是A,&OH,二卤代烷烃,例如1,4-二溴丁烷, Q是含有5个或更少碳原子的中性胺如1-甲基吡咯烷,E是骨架元素如镓。 该方法包括在热解条件下使碳质生物质原料与UZM-39接触以产生包含烃的热解气体。 催化剂催化将氧化烃转化成烃并将氧作为碳氧化物和水去除​​的脱氧反应。 一部分热解气体被冷凝以产生低氧生物质衍生的热解油。

    HIGH SURFACE AREA GRAPHENE-SUPPORTED METAL CHALCOGENIDE ASSEMBLY
    69.
    发明申请
    HIGH SURFACE AREA GRAPHENE-SUPPORTED METAL CHALCOGENIDE ASSEMBLY 有权
    高表面积石墨支撑的金属氯化铝组件

    公开(公告)号:US20140121425A1

    公开(公告)日:2014-05-01

    申请号:US13844225

    申请日:2013-03-15

    Abstract: A composition comprising at least one graphene-supported assembly, which comprises a three-dimensional network of graphene sheets crosslinked by covalent carbon bonds, and at least one metal chalcogenide compound disposed on said graphene sheets, wherein the chalcogen of said metal chalcogenide compound is selected from S, Se and Te. Also disclosed are methods for making and using the graphene-supported assembly, including graphene-supported MoS2. Monoliths with high surface area and conductivity can be achieved. Lower operating temperatures in some applications can be achieved. Pore size and volume can be tuned. Electrochemical methods can be used to make the materials.

    Abstract translation: 包含至少一个石墨烯支撑的组件的组合物,其包含通过共价碳键交联的石墨烯片的三维网络,以及设置在所述石墨烯片材上的至少一种金属硫族化物化合物,其中选择所述金属硫属化物化合物的硫族元素 从S,Se和Te。 还公开了制备和使用石墨烯支撑的组件的方法,包括石墨烯支持的MoS 2。 可以实现具有高表面积和导电性的单晶。 在一些应用中可以降低工作温度。 可以调节孔径和体积。 电化学方法可用于制造材料。

    Catalytic pyrolysis using UZM-39 aluminosilicate zeolite
    70.
    发明授权
    Catalytic pyrolysis using UZM-39 aluminosilicate zeolite 有权
    使用UZM-39铝硅酸盐沸石催化裂解

    公开(公告)号:US08609910B1

    公开(公告)日:2013-12-17

    申请号:US13743715

    申请日:2013-01-17

    Applicant: UOP LLC

    Abstract: A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. NanMmn+RrQqAl1-xExSiyOz where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,Ω-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

    Abstract translation: 已经合成了一系列TUN和IMF染色体型相干生长复合材料,并被证明是生物质催化热解的有效催化剂。 这些沸石由经验公式表示。 NanMmn + RrQqAl1-xExSiyOz其中M表示锌或金属或来自组1,组2,组3或周期表的镧系元素的金属,R是A,ω-二卤代烷烃,例如1,4-二溴丁烷,Q 是含有5个或更少碳原子的中性胺如1-甲基吡咯烷,E是骨架元素如镓。 该方法包括在热解条件下使碳质生物质原料与UZM-39接触以产生包含烃的热解气体。 催化剂催化将氧化烃转化成烃并将氧作为碳氧化物和水去除​​的脱氧反应。 一部分热解气体被冷凝以产生低氧生物质衍生的热解油。

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