公开(公告)号：US20110101275A1

公开(公告)日：2011-05-05

申请号：US13004554

申请日：2011-01-11

Applicant: Gundula ROTH ,  Walter TEWS ,  Chung Hoon LEE

Inventor： Gundula ROTH ,  Walter TEWS ,  Chung Hoon LEE

IPC: C09K11/79 ,  C09K11/78

CPC classification number: C09K11/7734 ,  C09K11/58 ,  C09K11/592 ,  C09K11/66 ,  C09K11/665 ,  C09K11/666 ,  C09K11/7457 ,  C09K11/753 ,  C09K11/756 ,  C09K11/757 ,  C09K11/758 ,  C09K11/7706 ,  C09K11/7707 ,  C09K11/7709 ,  C09K11/7714 ,  C09K11/7735 ,  C09K11/7737 ,  C09K11/7738 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7742 ,  C09K11/7783 ,  C09K11/7792

Abstract: This invention relates to luminescent materials for ultraviolet light or visible light excitation containing lead and/or copper doped chemical compounds. The luminescent material is composed of one or more than one compounds of aluminate type, silicate type, antimonate type, germanate/or germanate-silicate type, and/or phosphate type. Accordingly, the present invention is a good possibility to substitute earth alkaline ions by lead and copper for a shifting of the emission bands to longer or shorter wave length, respectively. Luminescent compounds containing copper and/or lead with improved luminescent properties and also with improved stability against water, humidity as well as other polar solvents are provided. The present invention is to provide lead and/or copper doped luminescent compounds, which has high color temperature range about 2,000K to 8,000K or 10,000K and CRI over 90.

Abstract translation: 本发明涉及含有铅和/或铜掺杂化合物的紫外光或可见光激发用发光材料。 发光材料由一种或多种铝酸盐型，硅酸盐型，锑酸盐型，锗酸盐或/或锗酸盐 - 硅酸盐型和/或磷酸盐型的化合物组成。 因此，本发明很有可能用铅和铜代替碱土离子，将发射带分别移动到更长或更短的波长。 提供含有铜和/或铅的发光化合物，其具有改善的发光性能，并且还具有改善的对水，湿度以及其它极性溶剂的稳定性。 本发明提供铅和/或铜掺杂的发光化合物，其具有大约2000K至8,000K或10,000K的高色温，以及90以上的CRI。

公开(公告)号：US20100176342A1

公开(公告)日：2010-07-15

申请号：US12731811

申请日：2010-03-25

Applicant: Gundula ROTH ,  Walter Tews ,  Chung Hoon Lee

Inventor： Gundula ROTH ,  Walter Tews ,  Chung Hoon Lee

IPC: C09K11/77 ,  C09K11/54 ,  C09K11/61 ,  C09K11/70

CPC classification number: C09K11/7734 ,  C09K11/58 ,  C09K11/592 ,  C09K11/66 ,  C09K11/665 ,  C09K11/666 ,  C09K11/7457 ,  C09K11/753 ,  C09K11/756 ,  C09K11/757 ,  C09K11/758 ,  C09K11/7706 ,  C09K11/7707 ,  C09K11/7709 ,  C09K11/7714 ,  C09K11/7735 ,  C09K11/7737 ,  C09K11/7738 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7742 ,  C09K11/7783 ,  C09K11/7792

Abstract: This invention relates to luminescent materials for ultraviolet light or visible light excitation containing lead and/or copper doped chemical compounds. The luminescent material is composed of one or more than one compounds of aluminate type, silicate type, antimonate type, germanate/or germanate-silicate type, and/or phosphate type. Accordingly, the present invention is a good possibility to substitute earth alkaline ions by lead and copper for a shifting of the emission bands to longer or shorter wave length, respectively. Luminescent compounds containing copper and/or lead with improved luminescent properties and also with improved stability against water, humidity as well as other polar solvents are provided. The present invention is to provide lead and/or copper doped luminescent compounds, which has high color temperature range about 2,000K to 8,000K or 10,000K and CRI over 90.

Abstract translation: 本发明涉及含有铅和/或铜掺杂化合物的紫外光或可见光激发用发光材料。 发光材料由一种或多种铝酸盐型，硅酸盐型，锑酸盐型，锗酸盐或/或锗酸盐 - 硅酸盐型和/或磷酸盐型的化合物组成。 因此，本发明很有可能用铅和铜代替碱土离子，将发射带分别移动到更长或更短的波长。 提供含有铜和/或铅的发光化合物，其具有改善的发光性能，并且还具有改善的对水，湿度以及其它极性溶剂的稳定性。 本发明提供铅和/或铜掺杂的发光化合物，其具有大约2000K至8,000K或10,000K的高色温，以及90以上的CRI。

公开(公告)号：US20100165645A1

公开(公告)日：2010-07-01

申请号：US12491780

申请日：2009-06-25

Applicant: Chung Hoon Lee ,  Gundula ROTH ,  Walter Tews

Inventor： Chung Hoon Lee ,  Gundula ROTH ,  Walter Tews

IPC: F21V29/00 ,  H01J1/62

CPC classification number: C09K11/665 ,  C09K11/666 ,  C09K11/753 ,  C09K11/756 ,  C09K11/7734 ,  C09K11/7735 ,  C09K11/7738 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7751 ,  C09K11/7756 ,  C09K11/7792 ,  C09K11/7796 ,  H01L33/502 ,  H01L2224/32257 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00012

Abstract: A light emitting device is disclosed. The light emitting device may include a light emitting diode (LED) for emitting light and phosphor adjacent to the LED. The phosphor may be excitable by light emitted by the LED and may include a first compound having a host lattice comprising first ions and oxygen. In one embodiment, the host lattice may include silicon, the copper ions may be divalent copper ions and first compound may have an Olivin crystal structure, a β-K2SO4 crystal structure, a trigonal Glaserite (K3Na(SO4)2) or monoclinic Merwinite crystal structure, a tetragonal Ackermanite crystal structure, a tetragonal crystal structure or an orthorhombic crystal structure. In another embodiment, the copper ions do not act as luminescent ions upon excitation with the light emitted by the LED.

Abstract translation: 公开了一种发光器件。 发光器件可以包括用于发射与LED邻近的光和磷光体的发光二极管（LED）。 磷光体可以由LED发出的光可激发，并且可以包括具有包含第一离子和氧的主晶格的第一化合物。 在一个实施方案中，主晶格可以包括硅，铜离子可以是二价铜离子，第一化合物可以具有橄榄石晶体结构，一个二氧化碳结晶结构，一个三角晶硅酸盐（K3Na（SO4）2））或单斜晶系 晶体结构，四方晶系晶体结构，四方晶体结构或正交晶体结构。 在另一个实施方案中，当由LED发射的光激发时，铜离子不起荧光离子的作用。

公开(公告)号：US07679101B2

公开(公告)日：2010-03-16

申请号：US11606170

申请日：2006-11-30

Applicant: Koichi Ota ,  Atsuo Hirano ,  Akihito Ota ,  Stefan Tasch ,  Peter Pachler ,  Gundula Roth ,  Walter Tews ,  Wolfgang Kempfert ,  Detlef Starick

Inventor： Koichi Ota ,  Atsuo Hirano ,  Akihito Ota ,  Stefan Tasch ,  Peter Pachler ,  Gundula Roth ,  Walter Tews ,  Wolfgang Kempfert ,  Detlef Starick

IPC: H01L33/00

CPC classification number: C09K11/7795 ,  B82Y20/00 ,  C09K11/7721 ,  C09K11/7734 ,  C09K11/774 ,  F21Y2105/10 ,  F21Y2115/10 ,  G02B6/0036 ,  G02B6/0073 ,  H01L25/0753 ,  H01L33/06 ,  H01L33/32 ,  H01L33/502 ,  H01L33/507 ,  H01L2224/16145 ,  H01L2224/32245 ,  H01L2224/32257 ,  H01L2224/45139 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/49107 ,  H01L2224/73265 ,  H01L2924/00011 ,  H01L2924/181 ,  H01L2933/0091 ,  Y02B20/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/01049 ,  H01L2924/00012

Abstract: The light emitting device has a light emitting diode which is made of a nitride semiconductor and a phosphor which absorbs a part of lights emitted from the light emitting diode and emits different lights with wavelengths other than those of the absorbed lights. The phosphor is made of alkaline earth metal silicate fluorescent material activated with europium.

Abstract translation: 发光装置具有由氮化物半导体构成的发光二极管和吸收从发光二极管发出的一部分光并发出不同于吸收光的波长的不同光的荧光体。 磷光体由铕活化的碱土金属硅酸盐荧光材料制成。

公开(公告)号：US20090050849A1

公开(公告)日：2009-02-26

申请号：US12196923

申请日：2008-08-22

Applicant: Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

Inventor： Chung Hoon Lee ,  Walter Tews ,  Gundula Roth ,  Stefan Tews

IPC: C09K11/79

CPC classification number: C09K11/7734 ,  Y02B20/181

Abstract: Disclosed are non stoichiometric Copper Alkaline Earth Silicate phosphors activated by divalent europium for using them as high temperature stable luminescent materials for ultraviolet or daylight excitation. The phosphors are represented as the formula (BauSrvCawCux)3-y(Zn,Mg,Mn)zSi1+bO5+2b:Eua. The nonstoichiometric tetragonal silicate is prepared in a high temperature solid state reaction with a surplus of silica in the starting mixture. Furthermore, luminescent tetragonal Copper Alkaline Earth Silicates are provided for LED applications, which have a high color temperature range from about 2,000K to 8,000K or 10,000K showing a CRI with Ra=80˜95, when mixed with other luminescent materials.

Abstract translation: 公开了由二价铕活化的非化学计量的铜碱土硅酸盐荧光体，用于将其用作用于紫外线或日光激发的高温稳定发光材料。 磷光体用式（BauSrvCawCux）3-y（Zn，Mg，Mn）zSi1 + bO5 + 2b：Eua表示。 非化学计量的四方硅酸盐在起始混合物中与多余二氧化硅的高温固相反应制备。 此外，发光四方铜碱土硅酸盐提供用于LED应用，其具有约2,000K至8,000K或10,000K的高色温，当与其它发光材料混合时，其具有Ra = 80〜95的CRI。

公开(公告)号：US20080224163A1

公开(公告)日：2008-09-18

申请号：US12098263

申请日：2008-04-04

Applicant: Gundula ROTH ,  Walter TEWS ,  Chung-Hoon LEE

Inventor： Gundula ROTH ,  Walter TEWS ,  Chung-Hoon LEE

IPC: H01L27/15

CPC classification number: C09K11/7734 ,  C09K11/665 ,  C09K11/666 ,  C09K11/753 ,  C09K11/756 ,  C09K11/7735 ,  C09K11/7738 ,  C09K11/7739 ,  C09K11/774 ,  C09K11/7751 ,  C09K11/7756 ,  C09K11/7792 ,  C09K11/7796 ,  H01L33/502 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/73265 ,  H01L2924/00014

Abstract: A light emitting device can be characterized as including a light emitting diode configured to emit light and a phosphor configured to change a wavelength of the light. The phosphor substantially covers at least a portion of the light emitting diode. The phosphor includes a compound having a host material. Divalent copper ions and oxygen are components of the host material.

Abstract translation: 发光器件可以被表征为包括被配置为发光的发光二极管和被配置为改变光的波长的磷光体。 磷光体基本上覆盖发光二极管的至少一部分。 荧光体包括具有主体材料的化合物。 二价铜离子和氧是主体材料的成分。

公开(公告)号：US20080179621A1

公开(公告)日：2008-07-31

申请号：US12009634

申请日：2008-01-18

Applicant: Hermann Oppermann ,  Julius Muschaweck ,  Jochen Kunze ,  Thomas Luce ,  Eike Krochmann ,  Walter Tews ,  Gundula Roth

Inventor： Hermann Oppermann ,  Julius Muschaweck ,  Jochen Kunze ,  Thomas Luce ,  Eike Krochmann ,  Walter Tews ,  Gundula Roth

IPC: H01L33/00 ,  H01L21/02

CPC classification number: H01L33/58 ,  H01L33/20 ,  H01L33/507 ,  H01L33/641 ,  H01L2224/48091 ,  H01L2224/48227 ,  H01L2224/48471 ,  H01L2224/73265 ,  H01L2924/181 ,  H01L2924/00014 ,  H01L2924/00012

Abstract: A light-emitting semi-conductor diode comprising a light emitting chip at least partially surrounded by a transparent electronics protecting body on which a composite layer foil is disposed, the composite layer foil includes at its side facing away from the electronics protection body a carrier layer, which has a refraction index that is greater than the refraction index of the electronics protection body and, at the opposite side, an active layer of the same material of which the electronics protecting body consists.

Abstract translation: 一种发光半导体二极管，包括至少部分地被透明电子保护体围绕的发光芯片，所述透明电子保护体设置有复合层箔，所述复合层箔在其背离电子保护体的一侧包括载体层 其具有大于电子保护体的折射率的折射率，并且在相对侧具有电子保护体所构成的相同材料的有源层。

公开(公告)号：US07259396B2

公开(公告)日：2007-08-21

申请号：US11499589

申请日：2006-08-04

Applicant: Stefan Tasch ,  Peter Pachler ,  Gundula Roth ,  Walter Tews ,  Wolfgang Kempfert ,  Detlef Starick

Inventor： Stefan Tasch ,  Peter Pachler ,  Gundula Roth ,  Walter Tews ,  Wolfgang Kempfert ,  Detlef Starick

IPC: H01L27/15

CPC classification number: C09K11/7795 ,  B82Y20/00 ,  C09K11/7721 ,  C09K11/7734 ,  C09K11/774 ,  F21Y2105/10 ,  F21Y2115/10 ,  G02B6/0036 ,  G02B6/0073 ,  H01L25/0753 ,  H01L33/06 ,  H01L33/32 ,  H01L33/502 ,  H01L33/507 ,  H01L2224/16145 ,  H01L2224/32245 ,  H01L2224/32257 ,  H01L2224/45139 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/49107 ,  H01L2224/73265 ,  H01L2924/00011 ,  H01L2924/181 ,  H01L2933/0091 ,  Y02B20/181 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/01049 ,  H01L2924/00012

Abstract: The invention relates to a light source comprising a light-emitting element, which emits light in a first spectral region, and comprising a luminophore, which comes from the group of alkaline-earth orthosilicates and which absorbs a portion of the light emitted by the light source and emits light in another spectral region. According to the invention, the luminophore is an alkaline-earth orthosilicate, which is activated with bivalent europium and whose composition consists of: (2-x-y)SrOx(Ba, Ca)O (1-a-b-c-d)SiO2aP2O5bAl2O3cB2O3dGeO2: y Eu2+ and/or (2-x-y)BaOx((Sr, Ca)O (1-a-b-c-d)SiO2aP2O5bAl2O3cB2O3dGeO2: y Eu2+. The desired color (color temperature) can be easily adjusted by using a luminophore of the aforementioned type. The light source can contain an additional luminophore selected from the group of alkaline-earth aluminates, activated with bivalent europium and/or manganese, and/or can contain an additional red-emitting luminophore selected from the group Y(V, P, Si)O4:Eu or can contain alkaline-earth magnesium disilicate.

Abstract translation: 本发明涉及一种光源，其包括发光元件，该发光元件在第一光谱区域中发光，并且包括来自所述碱土原硅酸盐并且吸收由所述光发射的光的一部分的发光体 来源并在另一个光谱区域发光。 根据本发明，发光体是碱土原硅酸盐，其用二价铕活化，其组成由以下组成：（2-xy）SrO x（Ba，Ca）O（1-abcd）SiO 2 2> a2 2 和/或（2-xy）BaO x（（Sr，Ca）O（1-abcd）SiO 2） 2> 2 a2 通过使用发光体，可以容易地调节所需的颜色（色温），可以容易地调节所需的颜色（色温） 光源可以含有选自由二价铕和/或锰活化的碱土铝酸盐的另外的发光体，和/或可以含有选自Y（V，P）的另外的发红光 ，Si）O 4：Eu或可以含有二硅酸碱土镁。