公开(公告)号：US10099933B2

公开(公告)日：2018-10-16

申请号：US14435588

申请日：2013-10-09

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Jeff Yang ,  Stefan Maurer ,  Manuela Gaab ,  Karsten Seidel ,  Olga Gerlach ,  Ulrich Mueller

IPC: C01B39/48 ,  B01J35/00 ,  C01B39/02 ,  B01J29/70

Abstract: A process for the post-treatment of a zeolitic material having an MWW framework structure, the process comprising (i) providing a zeolitic material having an MWW framework structure, wherein the framework structure of the zeolitic material comprises X2O3 and YO2, wherein Y is a tetravalent element and X is a trivalent element and wherein the molar ratio X2O3:YO2 is greater than 0.02:1; (ii) treating the zeolitic material provided in (i) with a liquid solvent system thereby obtaining a zeolitic material having a molar ratio X2O3:YO2 of at most 0.02:1, and at least partially separating the zeolitic material from the liquid solvent system; (iii) treating the zeolitic material obtained from (ii) with a liquid aqueous system having a pH in the range of 5.5 to 8 and a temperature of at least 75° C.

公开(公告)号：US09943838B2

公开(公告)日：2018-04-17

申请号：US14907714

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Joaquim Henrique Teles ,  Bianca Seelig ,  Philip Kampe ,  Markus Weber ,  Peter Resch ,  Christian Bartosch ,  Dominic Riedel ,  Daniel Urbanczyk ,  Alexander Schroeder ,  Ulrike Wegerle

IPC: C07D301/12 ,  B01J29/90 ,  B01J37/06 ,  B01J37/10 ,  B01J38/48 ,  B01J29/70 ,  B01J29/89 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02 ,  C07D303/04 ,  B01J37/08 ,  B01J37/30 ,  B01J38/02 ,  B01J38/06

CPC classification number: B01J29/90 ,  B01J29/7088 ,  B01J29/89 ,  B01J35/00 ,  B01J37/0009 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/06 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  B01J38/02 ,  B01J38/06 ,  B01J38/48 ,  B01J2229/183 ,  B01J2229/186 ,  B01J2229/42 ,  C07D301/12 ,  C07D303/04 ,  Y02P20/584

Abstract: The present invention relates to a process for the regeneration of a catalyst comprising a titanium-containing zeolite, said catalyst having been used in a process for the preparation of an olefin oxide and having phosphate deposited thereon, said process for the regeneration comprising the steps: (a) separating the reaction mixture from the catalyst, (b) washing the catalyst obtained from (a) with liquid aqueous system; (c) optionally drying the catalyst obtained from (b) in a gas stream comprising an inert gas at a temperature of less than 300° C.; (d) calcining the catalyst obtained from (c) in a gas stream comprising oxygen at a temperature of at least 300° C.

公开(公告)号：US09732054B2

公开(公告)日：2017-08-15

申请号：US15246028

申请日：2016-08-24

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： Joaquim Henrique Teles ,  Dominic Riedel ,  Bianca Seelig ,  Philip Kampe ,  Daniel Urbanczyk ,  Markus Weber ,  Alexander Schroeder ,  Andrei-Nicolae Parvulescu ,  Ulrich Mueller ,  Meinolf Weidenbach ,  Werner J. Witzl ,  Holger Baer

IPC: C07D301/12 ,  B01D3/14 ,  C07D301/32

CPC classification number: C07D301/12 ,  B01D3/143 ,  C07D301/32

Abstract: A continuous process for the preparation of propylene oxide, comprising (a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log Kow) of the at least one component B is greater than zero; (b) separating propylene oxide from S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3; (d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).

公开(公告)号：US20150274540A1

公开(公告)日：2015-10-01

申请号：US14433566

申请日：2013-10-01

Applicant: BASF SE

Inventor： Stefan Maurer ,  Roger Ruetz ,  Julia Petry ,  Ulrich Mueller

IPC: C01B39/04 ,  B01J29/86 ,  B01J29/89 ,  B01J20/18 ,  B01J29/40

CPC classification number: C01B39/04 ,  B01J20/18 ,  B01J29/035 ,  B01J29/40 ,  B01J29/86 ,  B01J29/89 ,  B01J35/002 ,  B01J35/023 ,  B01J2229/186 ,  B01J2229/42 ,  C01B37/02 ,  C01B39/06 ,  C01B39/12 ,  C01B39/40 ,  C07D301/12

Abstract: The present invention relates to a process for the production of a zeolitic material having a framework structure comprising YO2, wherein said process comprises: (1) preparing a mixture comprising one or more tetravalent elements Y in elemental form, one or more organic hydroxide salts, and one or more protic solvents; (2) reacting the mixture obtained in step (1) for converting at least part of the one or more tetravalent elements Y into an oxidic form thereof containing one or more Y—O single bonds and/or one or more Y═O double bonds; and (3) crystallizing a zeolitic material from the mixture obtained in step (2).

Abstract translation: 本发明涉及一种制备具有包含YO 2的骨架结构的沸石材料的方法，其中所述方法包括：（1）制备包含一种或多种元素形式的四价元素Y，一种或多种有机氢氧化物盐， 和一种或多种质子溶剂; （2）使步骤（1）中获得的混合物使至少部分一种或多种四价元素Y转化为含有一个或多个Y-O单键和/或一个或多个Y = O双键的氧化形式 ; 和（3）从步骤（2）中获得的混合物中结晶沸石材料。

公开(公告)号：US20130296159A1

公开(公告)日：2013-11-07

申请号：US13869418

申请日：2013-04-24

Applicant: BASF SE

Inventor： Mathias FEYEN ,  Ulrich Mueller ,  Andrei-Nicolae Parvulescu ,  Bernd Bastian Schaack ,  Sebastian Ahrens ,  Dirk Gerhard ,  Sunghee Son ,  Gabriele Iffland ,  Bianca Seelig

IPC: B01J29/89 ,  B01J29/00 ,  B01J29/40

CPC classification number: C01B39/48 ,  B01J20/18 ,  B01J20/186 ,  B01J20/28057 ,  B01J20/3085 ,  B01J29/00 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/89 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/009 ,  B01J37/04 ,  B01J37/06 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B37/005 ,  C01B37/02 ,  C01B39/04 ,  C01B39/085 ,  C01B39/40 ,  C01P2002/72 ,  C01P2006/12

Abstract: The present invention relates to a process for the preparation of a zeolitic material comprising the steps of: (1) providing a mixture comprising one or more sources for YO2 and one or more alkenyltrialkylammonium cation R1R2R3R4N+-containing compounds as structure directing agent; and (2) crystallizing the mixture obtained in step (1) to obtain a zeolitic material; wherein Y is a tetravalent element, and wherein R1, R2, and R3 independently from one another stand for alkyl; and R4 stands for alkenyl, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备沸石材料的方法，包括以下步骤：（1）提供包含一种或多种YO 2源和一种或多种烯基三烷基铵阳离子R 1 R 2 R 3 R 4 N +化合物作为结构导向剂的混合物; 和（2）使步骤（1）中获得的混合物结晶以获得沸石材料; 其中Y是四价元素，并且其中R 1，R 2和R 3彼此独立地代表烷基; 并且R4代表烯基，以及可以根据本发明方法获得的沸石材料及其用途。