公开(公告)号：US20160280903A1

公开(公告)日：2016-09-29

申请号：US15075241

申请日：2016-03-21

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Wei Gao ,  Yogesh Tiwary

IPC: C08L33/12 ,  C08L33/08

CPC classification number: C08L33/12 ,  C08F2/22 ,  C08F220/18 ,  C08F265/06 ,  C08L33/08 ,  C08L43/02 ,  C08L2207/53 ,  C09D4/06 ,  C09D151/003 ,  C08F2220/1825 ,  C08F220/14 ,  C08F2220/343 ,  C08F220/06 ,  C08F220/40 ,  C08F230/02

Abstract: The present invention relates to an in situ method for preparing a bimorphological aqueous dispersion of first polymer particles with protuberating phosphorus acid cores and second polymer particles without protuberating cores. The method provides a more efficient way of making compositions for pigmented coating formulations.

Abstract translation: 本发明涉及一种用于制备具有突出的磷酸芯的第一聚合物颗粒和没有凸起芯的第二聚合物颗粒的双曲线性水性分散体的原位方法。 该方法提供了制备用于着色涂层制剂的组合物的更有效的方法。

公开(公告)号：US09303160B2

公开(公告)日：2016-04-05

申请号：US14365673

申请日：2012-12-17

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Catherine A. Finegan

IPC: C08F230/02 ,  C08L33/08 ,  C08F220/18 ,  C08F265/04 ,  C08K3/22 ,  C08F228/00 ,  C08K5/42 ,  C08K5/521 ,  C08F275/00

CPC classification number: C08L43/02 ,  C08F220/18 ,  C08F228/00 ,  C08F230/02 ,  C08F265/04 ,  C08F275/00 ,  C08K3/22 ,  C08K5/42 ,  C08K5/521 ,  C08K2003/2241 ,  C08L33/08 ,  C08L2201/54 ,  C09D143/02 ,  C08F212/14 ,  C08F220/34

Abstract: The present invention is a process for preparing a multistage polymer by contacting under emulsion polymerization conditions an acrylic monomer, a sulfur acid monomer, and a phosphorous acid monomer as described herein. The present invention is also a composition comprising a nonionic surfactant and a stable aqueous dispersion of polymer particles comprising structural units of butyl acrylate, methyl methacrylate, a sodium vinylbenzenesulfonate, and phosphoethyl methacrylate; wherein the polymer particles have a Tg of less than 10° C. The composition of the present invention is useful as a binder for coatings compositions.

Abstract translation: 本发明是一种通过在乳液聚合条件下与本文所述的丙烯酸类单体，硫酸单体和亚磷酸单体接触来制备多级聚合物的方法。 本发明还是一种包含非离子表面活性剂和稳定的聚合物颗粒的水性分散体的组合物，其包含丙烯酸丁酯，甲基丙烯酸甲酯，乙烯基苯磺酸钠和甲基丙烯酸磷酸乙酯的结构单元; 其中聚合物颗粒具有小于10℃的Tg。本发明的组合物可用作涂料组合物的粘合剂。

公开(公告)号：US20150361294A1

公开(公告)日：2015-12-17

申请号：US14761222

申请日：2014-01-15

Applicant: ROHM AND HAAS COMPANY

Inventor： James C. Bohling ,  Catherine A. Finegan ,  Ericka Lynn Killian ,  Edwin Hugh Nungesser ,  Morris C. Wills

IPC: C09D133/14 ,  C09D101/28 ,  C09D175/04

CPC classification number: C09D133/14 ,  C08K2003/2241 ,  C08L2201/54 ,  C09D101/28 ,  C09D131/04 ,  C09D143/02 ,  C09D175/04 ,  C08F218/08 ,  C08F2220/1825 ,  C08F230/02 ,  C08F2220/585

Abstract: The present invention relates to a coatings composition comprising an aqueous dispersion of polymer particles, pigment particles, and extender particles. The polymer particles comprise from 35 to 99.8 weight percent structural units of vinyl acetate and from 0.1 to 6 weight percent structural units of a phosphorus acid monomer or a salt thereof, and the coating composition has a pigment volume concentration in the range of from 25 up to the critical pigment volume concentration of the composition.

Abstract translation: 本发明涉及包含聚合物颗粒，颜料颗粒和增量剂颗粒的水性分散体的涂料组合物。 聚合物颗粒包含35至99.8重量％的乙酸乙烯酯的结构单元和0.1至6重量％的磷酸单体或其盐的结构单元，并且涂料组合物的颜料体积浓度范围为25升 至组合物的临界颜料体积浓度。

公开(公告)号：US20230374332A1

公开(公告)日：2023-11-23

申请号：US18029928

申请日：2021-06-21

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Ibrahim Eryazici ,  Philip R. Harsh ,  Partha S. Majumdar ,  Mario G. L. Mirabelli ,  Edwin A. Nungesser ,  Teresa A. Phillips ,  Daniel A. Saucy

IPC: C09D17/00 ,  C09D133/04 ,  C09D7/65 ,  C09D7/40 ,  C09D7/80

CPC classification number: C09D17/001 ,  C09D133/04 ,  C09D7/65 ,  C09D7/70 ,  C09D7/67 ,  C09D7/68 ,  C09D7/69 ,  C09D7/80 ,  C09D17/003

Abstract: The present invention relates to a method for preparing a multiplicity of containers of paint from a plurality of vessels separately containing an aqueous solution of a rheology modifier, an aqueous dispersion of a colorant, an aqueous dispersion of polymer particles, and an aqueous dispersion of organic polymeric microspheres. In another embodiment, the present invention relates to a method of dispensing a colorant or an opacifying agent or an inorganic extender into separate containers partially filled with a waterborne pre-paint mixture of rheology modifier, polymer particles, and organic polymeric microspheres. The process of the present invention provides a simple and cost-effective way of preparing a wide variety of a large quantity of contained and finished paints at point-of-sale.

公开(公告)号：US20230250205A1

公开(公告)日：2023-08-10

申请号：US18015552

申请日：2021-07-16

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Philip R. Harsh ,  Christopher Kozak ,  Partha S. Majumdar

IPC: C08F212/08 ,  C08F220/18 ,  C08F230/02

CPC classification number: C08F212/08 ,  C08F220/1804 ,  C08F230/02 ,  C08F2400/02

Abstract: The present invention is a composition comprising an aqueous dispersion of first and second polymer particles; and polymeric organic crosslinked microspheres; wherein, the weight-to-weight ratio of second polymer particles to first polymer particles is in the range of from 50:50 to 80:20; and wherein the weight-to-weight ratio of the microspheres to the first and second polymer particles is in the range of from 3:97 to 20:80. The composition of the present invention is useful semi-gloss or satin paint formulations with excellent mar resistance.

公开(公告)号：US20230144769A1

公开(公告)日：2023-05-11

申请号：US17906694

申请日：2021-02-09

Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA ,  Rohm and Haas Company

Inventor： James C. Bohling ,  Juan F. Callejas ,  Alexander Katz ,  Manish K. Mishra ,  Antony K. Van Dyk

IPC: C01F17/247

CPC classification number: C01F17/247 ,  C01P2004/64 ,  C01P2004/62

Abstract: The present invention relates to a method of preparing an aqueous dispersion of nanosized cerium (III) carbonate particles comprising the step of admixing in water a) a water-soluble ammonium cerium (III) salt, b) a water-soluble carbonate, and c) a capping ligand to form an aqueous dispersion of cerium (III) carbonate particles having a resultant z-average particle size is in the range of from 5 nm to 500 nm. The method is useful for the preparation of an additive that is useful in formulations that contain polymer, pigments, dyes, or tints, or a combination thereof, to promote color retention and attenuate unwanted color formation in coatings formed from these formulations.

公开(公告)号：US20220325124A1

公开(公告)日：2022-10-13

申请号：US17764677

申请日：2020-10-07

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Philip R. Harsh ,  Patrick E. Hartnett ,  Partha S. Majumdar ,  Qing Zhang

IPC: C09D133/08 ,  C09D7/42 ,  C09D5/16 ,  C09D7/40 ,  C09D5/02

Abstract: The present invention relates to a composition comprising an aqueous dispersion of a) polymer particles having a z-average particle size in the range of from 50 nm to 500 nm; b) anion exchange resin particles having a D50 median particle size in the range of from 0.1 μm to 50 μm; and c) polymeric organic microspheres having a D50 median particle size in the range of from 1 μm to 20 μm, wherein the weight-to-weight ratio of polymer particles to microspheres is in the range of from 0.5:1 to 20:1. The composition of the present invention is useful for paint compositions that form matte finishes with an excellent balance of stain blocking and stain removal properties.

公开(公告)号：US10913867B2

公开(公告)日：2021-02-09

申请号：US16214916

申请日：2018-12-10

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Ibrahim Eryazici ,  Philip R. Harsh ,  Christopher Kozak ,  Partha S. Majumdar ,  Edwin Aloysius Nungesser, Jr. ,  Andrew Swartz

IPC: C09D7/42 ,  C09D7/40 ,  C09D133/04 ,  C09D5/02 ,  C09D7/43

Abstract: The present invention relates to a matte coating composition comprising an aqueous dispersion of a) polymer particles having an average particle size in the range of from 80 nm to 500 nm; b) polymeric organic crosslinked microspheres having a particle size in the range of from 1 μm to 20 μm; c) polyethylene wax particles having a particle size in the range of from 0.3 μm to 30 μm; and d) a rheology modifier. The composition of the present invention gives matte finish coatings with excellent burnish resistance.

公开(公告)号：US20190071540A1

公开(公告)日：2019-03-07

申请号：US16115738

申请日：2018-08-29

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Ibrahim Eryazici ,  Philip R. Harsh ,  Partha S. Majumdar ,  Edwin Nungesser

IPC: C08G65/22 ,  C08L71/02 ,  C09D7/40 ,  C09D7/65 ,  C09D7/42

Abstract: The present invention relates to composition comprising an aqueous dispersion of microspheres and a class of a nonionic polyalkylene oxide of a distyryl or tristyryl phenol or an anionic polyalkylene oxide salt of a distyryl or tristyryl phenol and a process for preparing the composition. The microspheres have an average particle size in the range of from 1 μm to 25 μm, as well as a low coefficient of variation and low gel concentration; the composition is useful in coatings applications, especially where a matte finish is desired.

公开(公告)号：US20180346660A1

公开(公告)日：2018-12-06

申请号：US15830676

申请日：2017-12-04

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Andrew Swartz

IPC: C08J3/05 ,  C08L33/14 ,  C08F30/02

Abstract: The present invention provides a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell; wherein the core comprises from 5 to 90 weight percent structural units of a fluoroalkylated monomer, and 2) less than 0.09 weight percent structural units of a phosphorus acid monomer; and wherein the shell comprises from 0.1 to 5 weight percent of itaconic acid or a phosphorus acid monomer, based on the weight of the shell. The present invention addresses a need in the art by providing a way of selectively concentrating fluoroalkyl functionality into polymer particles with acorn morphology, thereby providing an improvement in dirt pick-up resistance of the subsequent coating.