MESOPOROUS CARBON MOLECULAR SIEVE AND SUPPORTED CATALYST EMPLOYING THE SAME
    71.
    发明申请
    MESOPOROUS CARBON MOLECULAR SIEVE AND SUPPORTED CATALYST EMPLOYING THE SAME 有权
    多孔碳分子筛和支持相同的催化剂

    公开(公告)号:US20070172721A1

    公开(公告)日:2007-07-26

    申请号:US11688537

    申请日:2007-03-20

    IPC分类号: H01M4/96 B01J21/18

    摘要: The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.

    摘要翻译: 本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。 另外,本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。 介孔碳分子筛的平均一次粒径小于约500nm,平均中孔尺寸在约3nm至约6nm的范围内,表面积在约500μm2范围内, /约至约2000m 2 / g。

    Fuel composition for fuel cell and fuel cell using the same
    72.
    发明申请
    Fuel composition for fuel cell and fuel cell using the same 有权
    用于燃料电池和使用其的燃料电池的燃料组成

    公开(公告)号:US20070148515A1

    公开(公告)日:2007-06-28

    申请号:US11635031

    申请日:2006-12-07

    IPC分类号: H01M8/10 C10L1/16

    摘要: Provided is a fuel composition for a fuel cell including a first fuel which generates protons and electrons, and hydrogen gas. Also, provided is a fuel cell using the fuel composition. Using the fuel composition for a fuel cell, catalyst activation can be increased. Also, a fuel cell having high efficiency and excellent performance can be prepared using the fuel composition.

    摘要翻译: 本发明提供一种燃料电池用燃料组合物,其包括产生质子和电子的第一燃料和氢气。 此外,提供了使用燃料组合物的燃料电池。 使用燃料电池用燃料组合物可以提高催化剂活化。 此外,可以使用燃料组合物来制备具有高效率和优异性能的燃料电池。

    Water recovery system and direct liquid feed fuel cell having the same
    73.
    发明申请
    Water recovery system and direct liquid feed fuel cell having the same 有权
    水回收系统和具有该回收系统的直接液体进料燃料电池

    公开(公告)号:US20070087251A1

    公开(公告)日:2007-04-19

    申请号:US11515900

    申请日:2006-09-06

    IPC分类号: H01M8/04 H01M8/10

    摘要: A water recovery system of a direct liquid feed fuel cell and a direct liquid feed fuel cell having the water recovery system. The water recovery system in which water produced at a cathode electrode of a membrane electrode assembly (MEA) is recovered to supply to an anode electrode, the water recovery system includes: a first member located on the cathode electrode and a first supporting plate that supports the first member; and a second member located on the anode electrode and a second supporting plate that supports the second member, wherein the first member and the second member are connected to each other through a slit formed in an electrolyte membrane of the MEA. The direct liquid feed fuel cell having the water recovery system can be used, for example, in a direct methanol fuel cell (DMFC).

    摘要翻译: 直接液体进料燃料电池的水回收系统和具有水回收系统的直接液体进料燃料电池。 水回收系统,其中回收在膜电极组件(MEA)的阴极处产生的水以供应到阳极电极,所述水回收系统包括:第一构件,位于所述阴极电极上,第一支撑板支撑 第一名成员; 以及位于阳极电极上的第二构件和支撑第二构件的第二支撑板,其中第一构件和第二构件通过形成在MEA的电解质膜中的狭缝相互连接。 具有水回收系统的直接液体进料燃料电池可以用于例如直接甲醇燃料电池(DMFC)中。

    Supported catalyst and method of preparing the same
    74.
    发明申请
    Supported catalyst and method of preparing the same 有权
    负载催化剂及其制备方法

    公开(公告)号:US20060159980A1

    公开(公告)日:2006-07-20

    申请号:US11334472

    申请日:2006-01-19

    摘要: A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

    摘要翻译: 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂,其含有平均尺寸较小的催化金属颗粒,而不管催化剂载体的类型如何,这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

    Method of preparing carbon nanocages

    公开(公告)号:US20060062712A1

    公开(公告)日:2006-03-23

    申请号:US11140979

    申请日:2005-06-01

    IPC分类号: C01B31/02

    摘要: The present invention provides a simple method of mass producing high purity carbon nanocages. The method of preparing carbon nanocages comprises introducing an inert gas into a reactor equipped with a spray nozzle and raising the temperature of the reactor to a pyrolysis temperature of a catalyst compound. The method further comprises spraying a reactant including the catalyst compound and a carbon-containing compound into the reactor through the spray nozzle, wherein the ratio of a space velocity of the inert gas to a space velocity of the reactant is 100 or more.

    Method of forming catalyst layer for fuel cell
    77.
    发明授权
    Method of forming catalyst layer for fuel cell 有权
    形成燃料电池催化剂层的方法

    公开(公告)号:US06344428B1

    公开(公告)日:2002-02-05

    申请号:US09258802

    申请日:1999-02-26

    申请人: Chan Lim Hyuk Chang

    发明人: Chan Lim Hyuk Chang

    IPC分类号: H01M488

    摘要: A method for preparing a slurry for forming a catalyst layer of a PEM fuel cell electrode and a method for fabricating the PEM fuel cell produced thereby are provided. The method for preparing a slurry for forming a catalyst layer of a proton exchange membrane (PEM) fuel cell according to the present invention comprises the steps of (a) adding an MOH solution to a perfluorosulfonate ionomer (PFSI) solution to convert PFSI in the PFSI solution into an M+ form-PFSI solution, wherein M is an alkaline metal selected from the group consisting of Li, Na and K; (b) adding an organic polar solvent having a higher boiling point than that of alcohol remaining in the PFSI solution to a mixed solution obtained in step (a) and heating the mixture at a temperature range of the boiling point of the alcohol to 20° C. higher than the boiling point to remove the remaining alcohol to obtain a pretreated PFSI solution; and (c) mixing the pretreated PFSI solution with Pt/C to form a slurry for forming a catalyst layer of a PEM fuel cell. Since processing stability is improved and the slurry can be easily prepared, Pt loading greater than a conventional level can be achieved by a single coating step by preventing a Pt catalyst from penetrating into a backing layer, the electrode characteristics are improved. Also, mass production of the PEM fuel cells is possible.

    摘要翻译: 提供了一种制备用于形成PEM燃料电池电极的催化剂层的浆料的方法和由此制备的PEM燃料电池的制造方法。 制备根据本发明的用于形成质子交换膜(PEM)燃料电池的催化剂层的浆料的方法包括以下步骤:(a)将MOH溶液加入到全氟磺酸根离子交联聚合物(PFSI)溶液中,以将PFSI在 PFSI溶液转化成M +形式-PFSI溶液,其中M是选自Li,Na和K的碱金属; (b)将具有比在PFSI溶液中残留的醇的沸点高的沸点的有机极性溶剂加入到步骤(a)中获得的混合溶液中,并将该混合物在醇的沸点范围内加热至20℃ C.高于沸点以除去剩余的醇以获得预处理的PFSI溶液; 和(c)将预处理的PFSI溶液与Pt / C混合以形成用于形成PEM燃料电池的催化剂层的浆料。 由于加工稳定性得到改善并且可以容易地制备浆料,所以可以通过单一的涂覆步骤通过防止Pt催化剂渗透到背衬层中来实现大于常规水平的Pt负载,从而提高电极特性。 此外,PEM燃料电池的批量生产是可能的。

    Catalyst coated electrolyte membrane, fuel cell including the same, method of preparing the catalyst coated electrolyte membrane
    78.
    发明授权
    Catalyst coated electrolyte membrane, fuel cell including the same, method of preparing the catalyst coated electrolyte membrane 有权
    催化剂涂覆的电解质膜,包括其的燃料电池,制备催化剂涂覆的电解质膜的方法

    公开(公告)号:US08343672B2

    公开(公告)日:2013-01-01

    申请号:US11444473

    申请日:2006-06-01

    IPC分类号: H01M8/06 H01M8/24 H01M8/10

    摘要: A catalyst coated electrolyte membrane including an anode catalyst layer and a cathode catalyst layer at opposite sides thereof, respectively, wherein micro cracks of the anode catalyst layer or cathode catalyst layer occupy 0.01-1 area % of the total area of the respective anode catalyst layer or cathode catalyst layer, a fuel cell including the same, and a method of preparing the catalyst coated electrolyte membrane. In the catalyst coated electrolyte membrane, micro cracks of the cathode catalyst layer or the anode catalyst layer can be minimized and thus the resistance between the electrode catalyst layer and an electrolyte membrane can be minimized, and crossover of a fuel, such as methanol, ethanol, other alcohols, methane, etc., to a cathode electrode can be minimized, and thus the catalyst coated electrolyte membrane has improved performance and durability.

    摘要翻译: 一种催化剂涂覆的电解质膜,其分别在其相对侧包括阳极催化剂层和阴极催化剂层,其中阳极催化剂层或阴极催化剂层的微裂纹占相应阳极催化剂层的总面积的0.01-1面积% 或阴极催化剂层,包含该催化剂层的燃料电池和制备催化剂涂覆的电解质膜的方法。 在催化剂涂覆的电解质膜中,可以使阴极催化剂层或阳极催化剂层的微裂纹最小化,从而电极催化剂层和电解质膜之间的电阻可以最小化,并且燃料如甲醇,乙醇 ,其他醇,甲烷等可以最小化,因此催化剂涂覆的电解质膜具有改进的性能和耐久性。

    METHOD OF MANUFACTURING HIERARCHICAL MESOPOROUS CARBON AND CARBON OBTAINED THEREBY
    80.
    发明申请
    METHOD OF MANUFACTURING HIERARCHICAL MESOPOROUS CARBON AND CARBON OBTAINED THEREBY 审中-公开
    制造分层碳酸钙和碳的方法

    公开(公告)号:US20120196745A1

    公开(公告)日:2012-08-02

    申请号:US13360892

    申请日:2012-01-30

    摘要: A hierarchical mesoporous carbon is provided in which a total volume of mesopores of the hierarchical mesoporous carbon is 80% or greater of a total volume of pores of the hierarchical mesoporous carbon; a volume of mesopores with a average diameter greater than 20 nm and no greater than 50 nm is 3% or greater of the total volume of the pores; and a volume of mesopores with a average diameter greater than 2 nm and no greater than 10 nm is 65% or greater of the total volume of the pores. The hierarchical mesoporous carbon, which also contains macropores, has an optimized mesoporous distribution characteristic, and has an increased total volume of pores, thereby having a significantly improved catalytic activity when used as a catalyst support. When such a supported catalyst is used in a fuel cell, supply of fuel and transporting of byproducts are facilitated.

    摘要翻译: 提供了分级介孔碳,其中分层介孔碳的介孔的总体积为分级介孔碳的总体积的80%或更大; 平均直径大于20nm且不大于50nm的介孔的体积为孔的总体积的3%或更大; 并且平均直径大于2nm且不大于10nm的体积的介孔为孔的总体积的65%或更大。 还含有大孔的层状中孔碳具有优化的介孔分布特征,并且具有增加的孔体积,从而当用作催化剂载体时具有显着改善的催化活性。 当这种负载型催化剂用于燃料电池中时,燃料的供应和副产物的运输便利。