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    Thermoplastic elastomer blends of hydrogenated polybutadiene block copolymers with alpha-olefin polymers and copolymers
    71.
    发明授权
    Thermoplastic elastomer blends of hydrogenated polybutadiene block copolymers with alpha-olefin polymers and copolymers 失效
    氢化聚丁二烯嵌段共聚物与α-烯烃聚合物和共聚物的热塑性弹性体共混物

    公开(公告)号：US4252914A

    公开(公告)日：1981-02-24

    申请号：US68280

    申请日：1979-08-20

    申请人： Adel F. Halasa ,  Davis W. Carlson ,  James E. Hall

    发明人： Adel F. Halasa ,  Davis W. Carlson ,  James E. Hall

    IPC分类号： C08L23/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/02 ,  C08L53/00 ,  C08L101/00

    CPC分类号： C08L23/02 ,  C08L53/00 ,  C08L23/10

    摘要： Thermoplastic elastomer blends of alpha-olefin polymers and copolymers, such as polypropylene, having a melting point of at least 90.degree. C. with hydrogenated diblock copolymers of 1,4-polybutadiene and 1,2-polybutadiene have good physical properties such as low brittle point, good impact resistance at low temperatures, minimum creep at high temperatures, good elongation, good tensile and tear strengths and good impact strength. The blends can be repeatedly processed and still maintain good physical properties. The amount of alpha-olefin polymer or copolymer in the blend may range from about 10 percent to 60 percent, preferably 15 percent to about 48 percent with the amount of the hydrogenated butadiene block copolymer correspondingly ranging from about 90 percent to about 40 percent, preferably 85 percent to about 52 percent based on the combined weight of the two components. The blends are mixed at temperatures at least as high as the melting point of the alpha-olefin polymers or copolymer.

    摘要翻译： 具有至少90℃熔点至少为90℃的α-烯烃聚合物和共聚物的热塑性弹性体共混物与1,4-聚丁二烯和1,2-聚丁二烯的氢化二嵌段共聚物具有良好的物理性能，如低脆性 低温下耐冲击性好，高温蠕变最小，伸长率好，拉伸强度高，撕裂强度好，冲击强度好。 混合物可以重复处理，并且仍然保持良好的物理性能。 共混物中α-烯烃聚合物或共聚物的量可以为约10％至60％，优选15％至约48％，氢化丁二烯嵌段共聚物的量相应地为约90％至约40％，优选 基于两个组件的总重量，85％至约52％。 共混物在至少与α-烯烃聚合物或共聚物的熔点一样高的温度下混合。

    Process for the preparation of block copolymers
    72.
    发明授权
    Process for the preparation of block copolymers 失效
    制备嵌段共聚物的方法

    公开(公告)号：US4219627A

    公开(公告)日：1980-08-26

    申请号：US776047

    申请日：1977-03-09

    申请人： Adel F. Halasa ,  James E. Hall ,  Adolph Para

    发明人： Adel F. Halasa ,  James E. Hall ,  Adolph Para

    IPC分类号： C08F297/04 ,  C08G81/02

    CPC分类号： C08F297/044 ,  C08G81/022

    摘要： The process described herein involves the preparation of block copolymers of the S-B-S type wherein S represents a block of polystyrene and B represents a block of polybutadiene. In order to have the initial polystyrene block soluble in the polymerization medium, cyclohexane and aromatic hydrocarbons have been used as the diluent or solvent in these polymerizations. The present process permits the use of hexane as diluent by having dissolved therein prior to polymerization a small amount of the S-B-S type of block copolymer being produced in the polymerization. Advantageously this solution used as the polymerization medium is prepared merely by washing the reactor used in a previous polymerization for production of the same type of S-B-S block copolymer with hexane to dissolve solid residues of S-B-S block copolymer deposited on the wall or agitator of the reactor. This hexane solution is then retained in the reactor to serve as the medium for the next polymerization batch. The dissolved S-B-S copolymer serves as a suspension agent for dispersion of the initial polystyrene block.

    摘要翻译： 本文所述的方法涉及制备S-B-S型嵌段共聚物，其中S代表聚苯乙烯嵌段，B代表聚丁二烯嵌段。 为了使初始聚苯乙烯嵌段可溶于聚合介质，环己烷和芳烃已经用作这些聚合中的稀释剂或溶剂。 本方法允许在聚合之前将少量的S-B-S型嵌段共聚物在聚合反应中溶解，使己烷作为稀释剂。 有利地，用作聚合介质的溶液仅通过洗涤先前聚合中使用的反应器来制备相同类型的S-B-S嵌段共聚物与己烷以溶解沉积在反应器的壁或搅拌器上的S-B-S嵌段共聚物的固体残余物来制备。 然后将该己烷溶液保留在反应器中以用作下一个聚合批料的介质。 溶解的S-B-S共聚物用作初始聚苯乙烯嵌段分散体的悬浮剂。

    Process for polymerizing butadiene
    73.
    发明授权
    Process for polymerizing butadiene 失效
    丁二烯聚合方法

    公开(公告)号：US4198496A

    公开(公告)日：1980-04-15

    申请号：US869334

    申请日：1978-01-13

    申请人： Adel F. Halasa ,  James E. Hall

    发明人： Adel F. Halasa ,  James E. Hall

    IPC分类号： C08F4/70 ,  C08F36/06

    CPC分类号： C08F36/06

    摘要： 1,3-Butadiene is polymerized in hexane solution in the presence of a catalyst composition comprising:(a) A hexane-soluble cobalt component;(b) A reducing agent comprising RAlX.sub.2 wherein R is a hydrocarbyl radical of 1-8 carbon atoms, and X is halogen; and(c) MgCl.sub.2, MgBr.sub.2, MnCl.sub.2, MnBr.sub.2 or a Mg or Mn salt of a carboxylic acid having 12-25 carbon atoms.The cobalt component may be a cobalt salt of a carboxylic acid or thiocarboxylic acid having at least six carbon atoms or a hexane-soluble complex of a cobalt salt with an oxygen-containing or nitrogen-containing group either in the same salt molecule or in a separate compound. Typical aluminum hydride or hydrocarbyl dihalides that may be used are aluminum hydride dichloride, ethyl aluminum dichloride, butyl aluminum dibromide, etc. Butadiene polymers having a high cis-1,4 and low 1,2 contents are obtained in high yield, and it is possible to produce high molecular weight polymers without the gel formation often accompanying such high molecular weight polymers.

    摘要翻译： 1,3-丁二烯在催化剂组合物存在下在己烷溶液中聚合，所述催化剂组合物包含：（a）可溶于己烷的钴组分; （b）包含RA1X2的还原剂，其中R是1-8个碳原子的烃基，X是卤素; 和（c）具有12-25个碳原子的羧酸的MgCl 2，MgBr 2，MnCl 2，MnBr 2或Mg或Mn盐。 钴组分可以是具有至少六个碳原子的羧酸或硫代羧酸的钴盐或钴盐与含氧或含氮基团的己烷可溶性络合物在相同的盐分子中或在 单独的化合物。 可以使用的典型的氢化铝或二卤化烃是二氢化铝，二氯化乙基铝，二溴化丁基铝等。以高产率获得具有高顺-1,4和低1,2含量的丁二烯聚合物， 可能生产高分子量聚合物，而没有凝胶形成，通常伴随着这种高分子量聚合物。

    Catalyst system and process for polymerization of conjugatged dienes therewith
    74.
    发明授权
    Catalyst system and process for polymerization of conjugatged dienes therewith 失效
    用于与其共轭二烯的聚合的催化剂体系和方法

    公开(公告)号：US4148984A

    公开(公告)日：1979-04-10

    申请号：US900362

    申请日：1978-04-26

    申请人： Adel F. Halasa ,  James E. Hall

    发明人： Adel F. Halasa ,  James E. Hall

    IPC分类号： C08F36/04 ,  C08F4/08 ,  C08F4/52 ,  C08F36/06

    CPC分类号： C08F36/04

    摘要： The catalyst system disclosed herein comprises one suitable for the polymerization of a conjugated diene, which system comprises a trihydrocarbyl aluminum compound, in which the hydrocarbyl group is an alkyl, aryl or cycloalkyl radical of 1-10 carbon atoms, and an alkali metal compound of the formula M--Y--R wherein M represents Li, Na or K; Y represents O, S or NR.sup.1 ; R represents H or a hydrocarbyl group of 1-10 carbon atoms; R.sup.1 represents a hydrocarbyl group of 1-10 carbon atoms, an acyl group of 1-10 carbon atoms; and when Y is NR.sup.1 the R and R.sup.1 can represent divalent groups so that together they form, with the N, a cyclic radical such as piperdyl, morpholino or diethylene diamino. Lithium alkoxides are preferred forms of the MYR formula and Al(CH.sub.3).sub.3 and Al(C.sub.2 H.sub.5).sub.3 are preferred aluminum components.

    摘要翻译： 本文公开的催化剂体系包括适于共轭二烯聚合的体系，该共轭二烯的体系包含三烃基铝化合物，其中烃基是具有1-10个碳原子的烷基，芳基或环烷基，以及碱金属化合物 式MYR其中M表示Li，Na或K; Y表示O，S或NR1; R代表H或1-10个碳原子的烃基; R1表示1-10个碳原子的烃基，1-10个碳原子的酰基; 并且当Y是NR 1时，R和R 1可以表示二价基团，使得它们一起与N形成环状基团，例如哌啶基，吗啉代或二亚乙基二氨基。 醇锂是MYR配方的优选形式，Al（CH 3）3和Al（C 2 H 5）3是优选的铝组分。

    Wetter for fine dry powder
    75.
    发明授权
    Wetter for fine dry powder 失效
    润湿干细粉

    公开(公告)号：US4021021A

    公开(公告)日：1977-05-03

    申请号：US678566

    申请日：1976-04-20

    申请人： James E. Hall ,  Everett H. Williams

    发明人： James E. Hall ,  Everett H. Williams

    IPC分类号： B01F7/00 ,  B01F7/22 ,  C02F1/00 ,  B01F5/12

    CPC分类号： C02F1/00 ,  B01F7/22 ,  B01F7/00591

    摘要： A system for wetting fine dry powders such as bentonite clay with water or other liquids is described. The system includes a wetting tank for receiving water and a continuous flow of fine powder feed. The wetting tank has a generally square horizontal cross section with a bottom end closure in the shape of an inverted pyramid. Positioned centrally within the wetting tank is a flow control cylinder which is supported from the walls of the wetting tank by means of radially extending inclined baffles. A variable speed motor drives a first larger propeller positioned immediately below the flow control cylinder in a direction which forces liquid filling the tank to flow downward through the flow control cylinder and a second smaller propeller positioned below the larger propeller having a reverse pitch to oppose the flow of liquid being driven downward by the larger propeller.

    摘要翻译： 描述了用于润湿细干燥粉末如膨润土与水或其它液体的系统。 该系统包括用于接收水和连续流动的细粉末进料的润湿罐。 润湿槽具有大致正方形的水平横截面，底端封闭件呈倒金字塔形。 位于润湿槽中央的是一个流量控制缸，其通过径向延伸的倾斜挡板从润湿箱的壁被支撑。 变速马达驱动位于流量控制缸正下方的第一个较大的螺旋桨，其方向是迫使液体向罐内流动，使其向下流过流量控制缸，第二较小的螺旋桨位于较大的螺旋桨下方，具有相反的间距， 液体的流动由较大的螺旋桨向下驱动。

    Method of preparing rubber comprising polymeric compositions and isoprene comprising interpolymers
    77.
    发明授权
    Method of preparing rubber comprising polymeric compositions and isoprene comprising interpolymers 失效
    制备包含聚合物组合物和包含互聚物的异戊二烯的橡胶的方法

    公开(公告)号：US08754169B2

    公开(公告)日：2014-06-17

    申请号：US13616809

    申请日：2012-09-14

    申请人： Mark N. Dedecker ,  James E. Hall ,  Daniel F. Graves

    发明人： Mark N. Dedecker ,  James E. Hall ,  Daniel F. Graves

    IPC分类号： C08F287/00 ,  C08L55/02 ,  C08L9/06

    CPC分类号： C08F287/00

    摘要： A method for forming a rubber-modified polymeric composition includes polymerizing vinyl aromatic monomer within a mixture including the vinyl aromatic monomer and an interpolymer having at least one block of polyisoprene, at lest one block of polystyrene, and at lest one block of polybutadiene to thereby form the rubber-modified polymeric composition, where the interpolymer includes an internal block of polyisoprene.

    摘要翻译： 形成橡胶改性聚合物组合物的方法包括在包含乙烯基芳族单体和互聚物的混合物中聚合乙烯基芳族单体，所述互聚物具有至少一个聚异戊二烯嵌段，至少一个聚苯乙烯嵌段，至少一个聚丁二烯嵌段 形成橡胶改性的聚合物组合物，其中互聚物包括聚异戊二烯的内部嵌段。

    Vulcanizable nanoparticles having a core with a high glass transition temperature
    78.
    发明授权
    Vulcanizable nanoparticles having a core with a high glass transition temperature 有权
    具有高玻璃化转变温度的芯的可硫化纳米粒子

    公开(公告)号：US08697775B2

    公开(公告)日：2014-04-15

    申请号：US11642802

    申请日：2006-12-20

    申请人： James E. Hall ,  Sandra Warren ,  Alberto Scurati ,  Xiaorong Wang

    发明人： James E. Hall ,  Sandra Warren ,  Alberto Scurati ,  Xiaorong Wang

    IPC分类号： C08L83/00

    CPC分类号： C08F297/04 ,  C08F257/00 ,  C08F257/02 ,  C08L21/00 ,  C08L51/003 ,  C08L53/02 ,  Y10T428/2982 ,  C08L2666/24 ,  C08L2666/02

    摘要： Provided is a polymer nanoparticle comprising a core and a vulcanizable shell, wherein the core has a glass transition temperature (Tg) of at least about 150° C. Also provided is a method of preparing polymer nanoparticles with a core and a vulcanizable shell, comprising (a) in a liquid hydrocarbon medium, polymerizing conjugated diene monomers to produce a poly(conjugated diene) block and (b) copolymerizing the poly(conjugated diene) block with a mixture of mono-vinyl aromatic monomers and multiple-vinyl aromatic monomers to produce an aromatic block, wherein the core has a Tg of at least about 150° C. Also provided is a composition comprising (a) a rubber matrix; and (b) a polymer nanoparticle including a core and a vulcanizable shell; wherein the Tg of the core is at least about 150° C.

    摘要翻译： 本发明提供一种聚合物纳米颗粒，其包含芯和可硫化的壳，其中芯具有至少约150℃的玻璃化转变温度（Tg）。还提供了制备具有芯和可硫化壳的聚合物纳米颗粒的方法，包括 （a）在液体烃介质中，聚合共轭二烯单体以产生聚（共轭二烯）嵌段和（b）使聚（共轭二烯）嵌段与单乙烯基芳族单体和多乙烯基芳族单体的混合物共聚 产生芳族嵌段，其中芯的Tg至少为约150℃。还提供了一种组合物，其包含（a）橡胶基质; 和（b）包含核和可硫化壳的聚合物纳米颗粒; 其中芯的Tg至少约为150℃