摘要:
A catalyst is described for reducing the quantity of nitrogen oxides in lean exhaust gas of motor vehicle engines. The catalyst contains, on a structure reinforcing body, a first catalytic coating of an aluminum oxide and/or cerium oxide of large surface area impregnated with a mixture of iridium and platinum as catalytically active noble metal components. A second catalytic coating including a zeolite of the mordenite type containing copper and/or iron is applied to the first coating layer.
摘要:
A process for operating an exhaust gas treatment device in a gasoline engine which is operated mainly with a stoichiometric air/fuel ratio and is operated with a rich-mix air/fuel ratio when accelerating or under full load. The exhaust gas treatment device contains a three-way converter catalyst and a first lambda probe upstream of the catalyst and a second lambda probe downstream of the catalyst. The air/fuel ratio is controlled by using the signal from the first lambda probe, whereas the signal from the second lambda probe is used to check the first lambda probe (trim control) and to diagnose the function of the catalyst. Trim control with the second lambda probe is enabled only when, in the event of rich exhaust gas, the voltage difference between the probe voltage for the second lambda probe and a set point voltage is not larger than a predetermined value.
摘要:
A method for the sealing of flow channels in an annular zone of a cylindrical honeycomb body. The sealing of the flow channels takes place by introduction of a ceramic compound into the flow channels by means of a nozzle, wherein nozzle and honeycomb body are moved relative to one another with simultaneous guiding of the nozzle past the lateral surface and/or past the end face contour of the honeycomb body.
摘要:
A process for applying a coating to honeycomb structures in an exhaust gas converter which contains two such honeycomb structures in a common housing or enveloping tube which are arranged one after the other and which are separated from each other by a gap. The coating dispersion is first supplied from one end of the exhaust gas converter up to the gap between the two honeycomb structures. Then excess coating dispersion is driven out using a blast of air from the direction of the uncoated honeycomb structure. To coat the second honeycomb structure, the exhaust gas converter is inverted and the coating dispersion is then applied in the same way but from the uncoated end. Following the dispersion coating procedure, production of the catalyst is completed by drying and optionally calcining.
摘要:
An oxidative diesel control catalyst is disclosed which has a high conversion rate for hydrocarbons and carbon monoxide and an inhibited oxidation effect on nitrogen oxides and sulfur dioxides and which contains a monolithic catalyst element with throughflow passages of ceramic or metal coated with an activity-promoting dispersion coating of the fine-particle metal oxides aluminum oxide, titanium oxide, silicon oxide, zeolite or mixtures thereof as support of the catalytically active components, the active components being present in the form of platinum, palladium, rhodium and/or iridium doped with vanadium or in contact with an oxidic vanadium compound. The reduced oxidation effect on sulfur dioxide is obtained by virtue of the fact that the fine-particle metal oxides are surface-modified aluminum oxide, titanium oxide, silicon oxide, zeolite or mixtures thereof. The surface modification is a coating of the specific surface of the metal oxides with a layer of titanium dioxide or silicon dioxide of 1 to 5 monolayers.
摘要:
An oxidizing and/or reducing exhaust gas purification catalyst with a reduced tendency to emit H.sub.2 S contains active Al.sub.2 O.sub.3 as carrier which is charged with CeO.sub.2 and optionally ZrO.sub.2 as well as Pt, Pd and/or Rh and, in addition, 0.1 to 40% by weight ZnO relative to Al.sub.2 O.sub.3.
摘要翻译:具有降低排放H 2 S的趋势的氧化和/或还原废气净化催化剂含有作为载体的活性Al 2 O 3作为载体,其被加入CeO 2和任选的ZrO 2以及Pt,Pd和/或Rh,另外还含有0.1至40% 重量ZnO相对于Al2O3。
摘要:
A process for simultaneously reducing the amounts of hydrocarbons, carbon monoxide and nitrogen oxides contained in the exhaust gas from an internal combustion engine in the exhaust gas from gasoline or diesel engines with high amounts of oxygen in the exhaust gas is disclosed. A high reductive effect towards nitrogen oxides is enabled by using a homogeneous aluminum silicate as a high surface area support material for the catalytically active components.
摘要:
Monolithic catalysts with a metal carrier that includes a catalytically coated matrix having at least one stack of several sheet-metal strips of corrugated or alternately corrugated and flat metal strips folded or intertwined with one another are described. The free ends of the metal strips are connected by a joining process with a surrounding jacket tube of any required cross-section. The monolithic catalyst is produced very economically and with a catalytic coating that has a uniform thickness. The at least one stack of sheet-metal strips required for the monolithic catalyst with a metal carrier is assembled from coated metal ribbons cut to length so as to form metal stacks. The stacks may be folded and/or intertwined with themselves or with one another so as to form the matrix. The matrix with intertwined and coated strips is inserted into the jacket tube and the free ends of the metal strips are secured by joining to the jacket tube. The coated metal strips may be formed by coating long metal ribbons with catalytic coating in a continuous operation prior to cutting the ribbons to the required length. The metal ribbon is also preferably corrugated prior to the coating step but can also be corrugated after the coating step. In another embodiment, the matrix is formed of a single, continuous and at least partially corrugated metal strip which is folded on to itself so as to form a stack arrangement.
摘要:
A monolithic or honeycomb-catalyst, in particular for purifying the exhaust gases of internal-combustion engines, composed of an inert ceramic or metallic support traversed by parallel flow channels, a layer disposed thereon and composed of catalysis-promoting metal oxide and a catalytically active component supported by the metal oxide, wherein the concentration of the catalysis-promoting metal oxide increases from the periphery to the central axis of the support. Alternatively, the catalysis-promoting metal oxide is essentially equally distributed between central axis and periphery of the support, but concentration of catalytically active component increases from the central axis to the periphery of the support.
摘要:
A catalyst support for detoxifying the exhaust gases of alcohol fueled internal combustion engines contains, besides rare earth metal oxides and palladium, molybdenum silicide on active aluminum oxide in order to improve the conversion of noxious substances and the start up behavior.