摘要:
The present invention relates to a process for determining the state of an exhaust-gas purification device. The exhaust-gas purification device is one which can store gas and/or particles. By means of the proposed process, it is for example possible for the loading state of the exhaust-gas aftertreatment system, for example the oxygen storage state of a catalytic converter which is provided with an oxygen-storing material, such as for example a three-way catalytic converter, to be analyzed. The present process operates contactlessly through the analysis of resonances which arise upon the excitation of the catalytic converter using the purification device as microwave cavity resonator.
摘要:
The present invention relates to an exhaust-gas aftertreatment system which comprises a preferably catalytically active particle filter (wall-flow filter) which is followed in turn by a throughflow monolith (flow-through monolith) which is preferably provided with a catalytically active function. Both components have the same storage functions for gaseous substances present in the exhaust gas of internal combustion engines. The system is suitable in particular for the simultaneous removal of particles and pollutants from the exhaust gas of both predominantly lean-operated internal combustion engines and also of internal combustion engines operated predominantly with a stoichiometric air/fuel mixture. Likewise described is a process for the production and the use of such a system for exhaust-gas aftertreatment.
摘要:
An oxygen storage material comprising cerium oxide and at least one second oxide of a metal M1 is disclosed as well as a process for manufacturing the material and the use of this material in an exhaust gas cleaning catalyst. In a preferred embodiment the oxygen storage material comprises particles from a Ce/M1 mixed oxide solid solution coated with an oxide of another metal M2. Metal M1 e.g. can be calcium or zirconium while metal M2 most preferably is aluminum.
摘要翻译:公开了一种包含氧化铈和至少一种金属M 1 O 2的第二氧化物的储氧材料,以及用于制造材料的方法以及在废气清洁催化剂中使用该材料。 在优选的实施方案中,储氧材料包含涂覆有另一种金属M 2 O 2的氧化物的Ce / M 1混合氧化物固溶体的颗粒。 金属M 1,例如 可以是钙或锆,而金属M 2最优选是铝。
摘要:
Described is a method for cleaning the exhaust gases of internal combustion engines, which method is suitable for reducing harmful gases and particle emissions. Here, the exhaust gas to be cleaned is conducted, under operating conditions, with a discontinuous profile of the air ratio λ across a wall-flow filter substrate which comprises a catalytically active coating containing one storage material. The storage material is suitable for temporarily storing one or more exhaust-gas components under certain operating conditions and releasing said exhaust-gas components again in a targeted fashion in the event of a suitable change in the operating conditions. The coating is configured such that the component has a gradient of the storage material concentration and/or of the total coating amount, with the highest concentration of the storage material in the longitudinal direction of the component being present on the inflow side. At least 60% by weight of the storage material in relation to its total amount is present in the walls between inflow and outflow ducts, and at least 50% by weight of the storage material in relation to its total amount is present in a first, inflow-side zone in the wall-flow filter substrate.
摘要:
When a nitrogen oxide storage catalyst is being regenerated, the regeneration may be terminated for example as a result of a premature load change in the engine, which can lead to incomplete emptying of the storage catalyst. The residual filling level which remains in the catalyst following an incomplete regeneration of this nature is used as the starting value for calculation of the filling level during the next storage phase. After incomplete regeneration, the nitrogen oxide conversion rate is initially greater than would be expected, on account of the residual filling level. By taking this increased conversion rate into account when calculating the filling level during the storage phase, it is possible to further improve the accuracy of the calculation.
摘要:
An oxygen storage material comprising cerium oxide and at least one second oxide of a metal M1 is disclosed as well as a process for manufacturing the material and the use of this material in an exhaust gas cleaning catalyst. In a preferred embodiment the oxygen storage material comprises particles from a Ce/M1 mixed oxide solid solution coated with an oxide of another metal M2. Metal M1 e.g. can be calcium or zirconium while metal M2 most preferably is aluminum.
摘要:
A starter catalyst for the purification of the exhaust gases from internal combustion engines, which include palladium on aluminum oxide and of barium oxide, as well as a process for its production. The barium oxide and palladium are together deposited in a finely divided state on the supporting material aluminum oxide and the average particle size of the palladium crystallites is between 3 and 7 nm. The small crystallite size of palladium and the barium oxide likewise deposited in finely divided state on the supporting material impart to the catalyst a high activity and long-term stability to high temperature stresses.
摘要:
A single layer high performance catalyst containing on an inert carrier body a catalytic coating comprising platinum, rhodium and various oxide materials. The catalyst contains a catalytic coating having at least one first support material selected from the group having a first active alumina, a ceria rich ceria/zirconia mixed oxide and a zirconia component, said at least one first support material being catalyzed with a first part of the total platinum amount of the catalyst, and a second support material catalyzed with the second part of the total platinum amount and with rhodium said second support material being a second active alumina.
摘要:
The present invention relates to a process for determining the state of an exhaust-gas purification device. The exhaust-gas purification device is one which can store gas and/or particles. By means of the proposed process, it is for example possible for the loading state of the exhaust-gas aftertreatment system, for example the oxygen storage state of a catalytic converter which is provided with an oxygen-storing material, such as for example a three-way catalytic converter, to be analysed. The present process operates contactlessly through the analysis of resonances which arise upon the excitation of the catalytic converter using the purification device as microwave cavity resonator
摘要:
The invention describes a method for determining the light-off temperature of a catalytic converter on board a vehicle. The aging condition of the catalytic converter is determined by means of the method. To test the catalytic converter, the latter is loaded for example with a CO/HC test pulse. During the combustion of the additional CO and HC on the catalytic converter, an axial temperature profile is generated. The position of the maximum of said temperature profile along the catalytic converter is dependent on the current light-off temperature. The temperature profile travels through the catalytic converter and can be measured at the outlet of the catalytic converter as a time-dependent profile. The original axial temperature profile can be inferred from the time-dependent profile. Using a calculation program, the current light-off temperature of the catalytic converter on the vehicle can be determined. The method has the advantage that the test can take place at exhaust-gas temperatures considerably higher than the light-off temperature. In this way, it is ensured that the test pulse does not lead to increased pollutant emissions.