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公开(公告)号:US5208405A
公开(公告)日:1993-05-04
申请号:US845128
申请日:1992-03-03
CPC分类号: C07C5/05 , B01J23/892 , C07C2523/50 , C07C2523/755 , C07C2523/89 , C07C2527/25 , C07C2531/04
摘要: A process for selectively hydrogenating C.sub.4 -C.sub.10 diolefins to the corresponding monoolefins is carried out with a catalyst comprising (a) nickel metal and/or compound(s), (b) silver metal and/or compound(s), and (c) a solid inorganic support material (preferably alumina).
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公开(公告)号:US5096682A
公开(公告)日:1992-03-17
申请号:US686066
申请日:1991-04-16
摘要: Trialkyl arsines (in particular trimethyl arsine) are removed from a fluid (e.g., a hydrocarbon-containing gas) by contacting the fluid with a sorbent material comprising at least one copper hydrocarbon sulfonate, preferably a copper salt of an aliphatic or aromatic sulfonic acid, or with a copper-exchanged, sulfonated styrene polymer.
摘要翻译: 通过使流体与包含至少一种铜烃磺酸盐,优选脂族或芳族磺酸铜盐的吸附剂材料接触,从流体(例如含烃气体)中除去三烷基胂(特别是三甲基胂) 或用铜交换的磺化苯乙烯聚合物。
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公开(公告)号:US5095160A
公开(公告)日:1992-03-10
申请号:US719899
申请日:1991-06-24
申请人: Filippo Penella , Marvin M. Johnson
发明人: Filippo Penella , Marvin M. Johnson
IPC分类号: C07C2/00
CPC分类号: C07C2/00 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/04 , C07C2523/06 , C07C2523/755 , C07C2527/167
摘要: Benzene is converted to toluene in the presence of free hydrogen and a supported nickel metal catalyst.
摘要翻译: 在游离氢和负载的镍金属催化剂存在下,苯转化成甲苯。
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公开(公告)号:US5064626A
公开(公告)日:1991-11-12
申请号:US619355
申请日:1990-11-28
CPC分类号: B01D53/02 , B01D53/46 , B01J20/0229 , B01J20/0285 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/20 , B01J20/28004 , B01J20/3021 , B01J20/3204 , B01J20/3236
摘要: Trialkyl arsine (in particular trimethyl arsine) is removed from a fluid (e.g. a hydrocarbon-containing gas) by contacting the fluid with a sorbent material comprising (a) a transition metal polysulfide (preferably Fe.sub.2 (S.sub.3).sub.3, and (b) an inorganic support material (preferably alumina).
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公开(公告)号:US4927795A
公开(公告)日:1990-05-22
申请号:US264293
申请日:1988-10-28
CPC分类号: C10G11/04 , B01J38/48 , Y10S502/521
摘要: This invention comprises improvements to processes for the catalytic cracking of hydrocarbon feedstocks. One such improvement to catalytic cracking processes provides compositions comprising metals passivating agents having an increased degree of stability. These compositions comprise aqueous suspensions of antimony by vinyl copolymers, aqueous suspensions of antimony oxide by diesters of phosphoric acid, or aqueous suspensions of antimony oxide by cellulose derivatives. Another improvement to catalytic cracking processes provides a process for reducing the viscosity of liquid suspensions of metals passivating agents without substantially reducing the stability of the liquid suspension by the utilization of at least two different particle ranges of metals passivating agents. A further improvement to catalytic cracking processes provides an efficient utilization of metals passivating agents by introducing the selected agent into the catalyst regeneration cycle of a catalytic cracking unit.
摘要翻译: 本发明包括对烃原料的催化裂化方法的改进。 催化裂化方法的一个这样的改进提供了包含具有增加的稳定性的金属钝化剂的组合物。 这些组合物包含乙烯基共聚物的锑水悬浮液,磷酸二酯的氧化锑水悬浮液,或纤维素衍生物的氧化锑水悬浮液。 催化裂化方法的另一改进提供了降低金属钝化剂的液体悬浮液的粘度的方法,而不会通过利用至少两种不同的金属钝化剂的不同颗粒范围来显着降低液体悬浮液的稳定性。 催化裂化方法的进一步改进通过将所选择的试剂引入催化裂化装置的催化剂再生循环来提供金属钝化剂的有效利用。
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公开(公告)号:US4716256A
公开(公告)日:1987-12-29
申请号:US696971
申请日:1985-01-31
CPC分类号: C07C5/05 , C07C2101/16 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/12 , C07C2523/755 , C07C2527/167
摘要: Process for the selective hydrogenation of diolefinic compounds to monoolefinic compounds employing catalyst consisting essentially of elemental nickel on an inorganic support in the presence of hydrogen and at least one nitrogen-containing compound is disclosed. Selective hydrogenation of the less substituted of the two carbon-carbon double bonds of the diolefinic compound is achieved while isomerization of the more highly substituted, non-hydrogenated double bond, is minimized.
摘要翻译: 公开了在氢和至少一种含氮化合物的存在下,使用在无机载体上基本上由元素镍组成的催化剂将二烯化合物选择性氢化成单烯烃化合物的方法。 在更高取代的非氢化双键的异构化最小化的同时,实现了二烯烃化合物的两个碳 - 碳双键较少取代的选择性氢化。
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公开(公告)号:US4711868A
公开(公告)日:1987-12-08
申请号:US866551
申请日:1986-05-23
申请人: Yen-Shin Shyr , Marvin M. Johnson
发明人: Yen-Shin Shyr , Marvin M. Johnson
摘要: A process for preparing silica-alumina compositions comprises mixing a first aqueous solution containing an aluminum salt (preferably KAl(SO.sub.4).sub.2) and an ammonium salt (preferably (NH.sub.4).sub.2 SO.sub.4) with a second solution containing an alkali metal silicate (preferably Na.sub.2 SiO.sub.3), wherein the mol ratio of the alkali metal silicate to the aluminum salt is in the range of from about 2:1 to about 20:1, and the concentration of the ammonium salt is chosen so as to afford coprecipitation of silica-alumina hydrogel (preferably at a pH of about 3-6). The thus coprecipitated silica-alumina hydrogel can be separated from the mixture of the two solutions, optionally washed, and calcined so as to prepare acidic silica-alumina suitable as cracking catalyst material.
摘要翻译: 制备二氧化硅 - 氧化铝组合物的方法包括将含有铝盐(优选KAl(SO 4)2)和铵盐(优选(NH 4)2 SO 4)的第一水溶液与含有碱金属硅酸盐(优选Na 2 SiO 3)的第二溶液混合, 其中碱金属硅酸盐与铝盐的摩尔比在约2:1至约20:1的范围内,并且选择铵盐的浓度以提供二氧化硅 - 氧化铝水凝胶的共沉淀( 优选在约3-6的pH下)。 这样共沉淀的二氧化硅 - 氧化铝水凝胶可以从两种溶液的混合物中分离,任选地进行洗涤和煅烧,以制备适合作为裂化催化剂材料的酸性二氧化硅 - 氧化铝。
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公开(公告)号:US4629767A
公开(公告)日:1986-12-16
申请号:US754387
申请日:1985-07-12
申请人: Yen-Shin Shyr , Rex L. Bobsein , Marvin M. Johnson
发明人: Yen-Shin Shyr , Rex L. Bobsein , Marvin M. Johnson
摘要: The hydrogenation of olefin polymers and especially diene polymers can be carried out effectively in a fixed bed mode of operation, preferably with up-flow of polymer solution, using a heterogeneous catalyst containing an active hydrogenation metal in which the catalyst support has defined surface area and pore volume characteristics and the hydrogenation metal or metal compound is incorporated into the support by impregnation with a non-aqueous solution of the metal or metal compound.
摘要翻译: 烯烃聚合物,特别是二烯聚合物的氢化可以在固定床操作模式下进行,优选使用聚合物溶液的上流,使用含有活性氢化金属的多相催化剂,其中催化剂载体具有限定的表面积, 孔体积特性和氢化金属或金属化合物通过用金属或金属化合物的非水溶液浸渍而引入载体中。
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公开(公告)号:US4578179A
公开(公告)日:1986-03-25
申请号:US553445
申请日:1983-11-18
摘要: A treated decomposable compound of molybdenum, which has been prepared by the catalytic hydrogenation of a decomposable compound of molybdenum, wherein the molybdenum has a valence state greater than zero, or by the treating of the decomposable compound of molybdenum with a reducing agent, is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such treated decomposable compound of molybdenum is then contacted with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica alumina and a promoter comprising at least one metal selected from the group consisting of Group VIB, Group VIIB, and Group VIII of the Periodic Table to reduce the concentration of metals, sulfur, nitrogen, Ramsbottom carbon residue and/or heavies contained in the hydrocarbon-containing feed stream.
摘要翻译: 通过钼的可分解化合物的催化氢化制备的钼的经处理的可分解化合物,其中钼具有大于零的价态,或通过用还原剂处理钼的可分解化合物,被混合 与含烃的进料流。 然后将含有这种经处理的可分解钼的化合物的含烃进料流与包含选自氧化铝,二氧化硅和二氧化硅氧化铝的载体的催化剂组合物和包含至少一种选自组 VIB,VIIB族和VIII族,以减少含烃进料流中所含的金属,硫,氮,Ramsbottom碳残余物和/或重质物的浓度。
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公开(公告)号:US4404124A
公开(公告)日:1983-09-13
申请号:US260946
申请日:1981-05-06
CPC分类号: C07C5/08 , B01J23/50 , C07C7/167 , B01J23/44 , B01J35/008 , C07C2523/44 , C07C2523/50 , Y02P20/52
摘要: A catalyst and process for the selective hydrogenation of acetylene, said catalyst comprising palladium and silver with the palladium concentrated as a skin and the silver distributed throughout.
摘要翻译: 用于乙炔选择性氢化的催化剂和方法,所述催化剂包含钯和银,其中钯作为皮肤浓缩,银分布在整个过程中。
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