Substituted 2-phenylpyridines
    71.
    发明授权
    Substituted 2-phenylpyridines 失效
    取代的2-苯基吡啶

    公开(公告)号:US5783522A

    公开(公告)日:1998-07-21

    申请号:US592355

    申请日:1996-01-11

    摘要: Substituted 2-phenylpyridines I ##STR1## R.sup.1,R.sup.3 =H, halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO.sub.2 H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, CONH.sub.2, alkyl-aminocarbonyl, dialkylaminocarbonyl, pyrrolidinyl-carbonyl piperidylcarbonyl, morpholinylcarbonyl, NO.sub.2, NH.sub.2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R.sup.2 =halogen, CN, NO.sub.2, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio; or R.sup.1 +R.sup.2 or R.sup.2 +R.sup.3 =trimethylene or tetramethylene chain;R.sup.4 =halogen, alkyl, haloalkyl, alkoxyalkyl, alkoxy, alkoxyalkoxy, OH, haloalkoxy, alkylcarbonyloxy, haloalkylcarbonyloxy, SH, alkylthio, alkylsulfinyl, alkylsulfonyl, haloalkylthio, haloalkylsulfinyl, haloalkylsulfonyl, CHO, CN, CO.sub.2 H, alkoxycarbonyl, alkoxyalkoxycarbonyl, haloalkoxycarbonyl, alkylcarbonyl, haloalkylcarbonyl, alkoxyalkylcarbonyl, NO.sub.2, NH.sub.2, alkylamino, dialkylamino, pyrrolidinyl, piperidinyl, morpholinyl, alkylcarbonylamino, haloalkylcarbonylamino, alkylsulfonylamino; R.sup.5 =hydrogen or halogen; R.sup.6 =halogen, CN, NO.sub.2, OH, CF.sub.3, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkoxy; R.sup.7 =various radicals; and the N-oxides of I and the agriculturally utilizable salts of I where these exist, excepting those compounds I where R.sup.2 is C.sub.1 -C.sub.4 -alkoxy and R.sup.1 and/or R.sup.3 is carboxyl or the salt, ester or amide thereof.

    摘要翻译: PCT No.PCT / EP94 / 02263 371日期1996年1月11日 102(e)日期1996年1月11日PCT提交1994年7月11日PCT公布。 公开号WO95 / 02580 日期1995年1月26日取代的2-苯基吡啶I R1,R3 = H,卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,烷氧基烷氧基,OH,卤代烷氧基,烷基羰基氧基,卤代烷基羰氧基,SH,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷硫基, 卤代烷基亚磺酰基,卤代烷基磺酰基,CHO,CN,CO 2 H,烷氧基羰基,烷氧基烷氧基羰基,卤代烷氧基羰基,烷基羰基,卤代烷基羰基,烷氧基烷基羰基,CONH 2,烷基氨基羰基,二烷基氨基羰基,吡咯烷基 - 羰基哌啶基羰基,吗啉基羰基,NO 2,NH 2,烷基氨基,二烷基氨基,吡咯烷基,哌啶基,吗啉基 ,烷基羰基氨基,卤代烷基羰基氨基,烷基磺酰基氨基; R 2 =卤素,CN,NO 2,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,卤代烷硫基; 或R1 + R2或R2 + R3 =三亚甲基或四亚甲基链; R 4 =卤素,烷基,卤代烷基,烷氧基烷基,烷氧基,烷氧基烷氧基,OH,卤代烷氧基,烷基羰基氧基,卤代烷基羰氧基,烷硫基,烷基亚磺酰基,烷基磺酰基,卤代烷硫基,卤代烷基亚磺酰基,卤代烷基磺酰基,CHO,CN,CO 2 H,烷氧基羰基,烷氧基烷氧基羰基,卤代烷氧基羰基,烷基羰基, 卤代烷基羰基,烷氧基烷基羰基,NO 2,NH 2,烷基氨基,二烷基氨基,吡咯烷基,哌啶基,吗啉基,烷基羰基氨基,卤代烷基羰基氨基,烷基磺酰基氨基。 R5 =氢或卤素; R6 =卤素,CN,NO2,OH,CF3,C1-C6-烷基,C1-C4-烷氧基; R7 =各种基团; 和I的N-氧化物和其中存在的I的农业上可利用的盐,除了其中R 2是C 1 -C 4 - 烷氧基且R 1和/或R 3是羧基的化合物I或其盐,酯或酰胺。

    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect
    74.
    发明授权
    Substituted 2-benzoyl-cyclohexan-1,3-diones with herbicidal effect 失效
    取代的具有除草效果的2-苯甲酰基 - 环己烷-1,3-二酮

    公开(公告)号:US06576596B1

    公开(公告)日:2003-06-10

    申请号:US09331639

    申请日:1999-06-23

    IPC分类号: A01N3510

    摘要: The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereof; to processes and intermediates for preparing the compounds of the formula I; to compositions comprising them; and to the use of these derivatives or compositions comprising them for controlling undesirable plants.

    摘要翻译: 本发明涉及式I的2-苯甲酰基环己烷-1,3-二酮,其中R 1,R 2各自为氢,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基烷基,烯基,炔基,-OR 5,-OCOR 6,-OSO 2 R 6, -SH,-S(O)nR7,-SO2OR5,-SO2NR5R8,-NR8SO2R6或-NR8COR6; R3是氢,氰基,烷基,卤代烷基,-OR7,-SR7或-NR7R10; R4是氢,取代或未取代的烷基, 环烷基,烯基,环烯基,炔基,-COR 9,-CO 2 R 9,-COSR 9或-CONR 8 R 9; X是氧或NR 8; n是0,1或2; R 5是氢,烷基,卤代烷基,烷氧基烷基,烯基或炔基; 烷基或卤代烷基; R 7是烷基,卤代烷基,烷氧基烷基,烯基或炔基; R 8是氢或烷基; R 9是烷基,烯基,炔基,苯基或苄基; R 10是烷基,卤代烷基,烯基或炔基; Q是环己烷-1 具有或不具有取代基的2-二酮环;和其农业上有用的盐;制备式I化合物的方法和中间体; 包含它们的组合物; 以及使用这些衍生物或包含它们的组合物来控制不期望的植物。