公开(公告)号：US09517289B2

公开(公告)日：2016-12-13

申请号：US12680740

申请日：2008-11-26

申请人： Shigeru Sakamoto ,  Hiroyuki Ikeuchi ,  Sayaka Machida

发明人： Shigeru Sakamoto ,  Hiroyuki Ikeuchi ,  Sayaka Machida

IPC分类号： C08L57/10 ,  A61L15/60 ,  C08G65/332 ,  C08J3/12 ,  C08L71/02 ,  C08L101/14 ,  C08L33/02

CPC分类号： A61L15/60 ,  C08G65/3322 ,  C08J3/12 ,  C08J2300/14 ,  C08L33/02 ,  C08L71/02 ,  C08L101/14 ,  C08L2205/05 ,  C08L2666/04

摘要： The present invention provides a water-absorbing agent that includes water-absorbent resin particles as essential components and is suitable for a sanitary material. A water-absorbing agent of the present invention includes water-absorbent resin particles obtained by polymerizing an unsaturated monomer having an acid group. The water-absorbing agent has centrifuge retention capacity (CRC) of 5 to 20 g/g and includes: a compound with a structure unit derived from polyalkyleneglycol other than the unsaturated monomer; and a multivalent metal salt, and accordingly the water-absorbing agent has high saline flow conductivity (SFC) in a range of the above centrifuge retention capacity (CRC).

摘要翻译： 本发明提供一种吸水剂，其包含作为必要成分的吸水性树脂粒子，适用于卫生材料。 本发明的吸水剂包括通过聚合具有酸基的不饱和单体获得的吸水性树脂颗粒。 吸水剂具有5至20g / g的离心保留容量（CRC），并且包括：具有衍生自不饱和单体以外的聚亚烷基二醇的结构单元的化合物; 和多价金属盐，因此吸水剂在上述离心保留容量（CRC）的范围内具有高的盐水流动电导率（SFC）。

公开(公告)号：US09499466B2

公开(公告)日：2016-11-22

申请号：US13877751

申请日：2011-10-05

申请人： Tomomasa Kaneko

发明人： Tomomasa Kaneko

IPC分类号： C07C57/13 ,  C07C59/60 ,  C07F5/00 ,  C07F7/00 ,  C07F7/22 ,  C08F136/20 ,  C07C69/734 ,  C07F9/00 ,  C07F9/94 ,  C07F15/02 ,  C07F15/04

CPC分类号： C07C57/13 ,  C07C59/60 ,  C07C69/734 ,  C07F5/00 ,  C07F7/003 ,  C07F7/2224 ,  C07F9/005 ,  C07F9/94 ,  C07F15/025 ,  C07F15/045 ,  C08F136/20

摘要： The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

摘要翻译： 要求保护的发明提供了一种未经过研究的新化合物，即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂，反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐，特别是其金属盐，在常温下可根据结构处于液态， 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂，提供了各种性能，例如硬度，耐擦伤性，抗指纹性，阻气性，水蒸气阻隔性，氧吸收性，紫外线防护 红外线保护，显色和着色，高折射率，附着力，各种催化能力，荧光能力和发光能力，光学放大，分散性和抗静电性能。 此外，阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料，也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。

公开(公告)号：US20160311692A1

公开(公告)日：2016-10-27

申请号：US15105190

申请日：2014-12-19

申请人： NIPPON SHOKUBAI CO., LTD.

发明人： Morihiro KITAMURA ,  Shin-ya IMOTO ,  Tomonori SHINOKURA ,  Takashi ABE

IPC分类号： C01B33/107 ,  C07F9/50 ,  C09D1/00

CPC分类号： C01B33/10773 ,  C01B33/04 ,  C07F7/21 ,  C07F9/5022 ,  C09D1/00

摘要： A neutral complex of a cyclic silane characterized in being represented by the general formula [Y]1[SimZ2m-aHa]. (In the formula: Y is at least one kind of coordination compound selected from a group consisting of (1) compounds represented as X1R1n. (when X1 is P, P═O or N, n=3 and each R1 represents a substituted or unsubstituted alkyl group or aryl group and R1s are the same or different; when X1 is S, S═O or O, n=2 and each R1 represents the same group as described above and R1s are the same or different; and the number of amino groups in X1R1n is 0 or 1), and (2) at least one heterocyclic compound selected from the group consisting of substituted or unsubstituted N-, O-, S- or P-containing heterocyclic compounds that have an unshared electron pair in the ring (the number of amino groups in the heterocyclic compound is 0 or 1), each Z represents a halogen atom of any of Cl, Br, I and F and Zs are the same or different, l is 1 or 2, m is 3 to 8, and a is 0 to m.

摘要翻译： 其特征在于由通式[Y] 1 [SimZ2m-aHa]表示的环状硅烷的中性络合物。 （式中，Y为选自（1）X1R1n所示的化合物中的至少1种配位化合物（X1为P，P = O或N，n = 3，各R1表示取代或 未取代的烷基或芳基，R 1相同或不同;当X 1为S，S = O或O时，n = 2，并且每个R 1表示与上述相同的基团，并且R 1相同或不同; X1R1n中的氨基为0或1），和（2）至少一种选自具有取代或未取代的N-，O-，S-或P的杂环化合物中的杂环化合物，所述杂环化合物在 环（杂环化合物中的氨基数为0或1），Z表示Cl，Br，I和F中任一个的卤素原子，Zs相同或不同，l为1或2，m为3 至8，a为0至m。

公开(公告)号：US09466431B2

公开(公告)日：2016-10-11

申请号：US13980671

申请日：2012-01-20

申请人： Takayuki Kobatake ,  Masayuki Okajima ,  Taisuke Kasahara ,  Yasuyuki Miyoshi ,  Izuho Okada ,  Naohiko Itayama

发明人： Takayuki Kobatake ,  Masayuki Okajima ,  Taisuke Kasahara ,  Yasuyuki Miyoshi ,  Izuho Okada ,  Naohiko Itayama

IPC分类号： H01M6/04 ,  H01G9/035 ,  H01G11/62 ,  H01M10/0568 ,  H01M10/0569 ,  H01M10/0567 ,  H01G9/20

CPC分类号： H01G9/035 ,  H01G9/2018 ,  H01G11/62 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/13

摘要： The present invention provides an ionic compound containing a cyanoborate; a process for production thereof; and an electrolytic solution and a device. The electrolytic solution comprises an ionic compound represented by general formula (1) and a solvent, Mn+([B(CN)4-mYm]−)n  (1) wherein Mn+ represents an organic or inorganic cation having a valency of 1 to 3; Y represents a halogen, a hydrocarbon group which has a main chain having 1 to 10 carbon atoms and which may optionally contain a halogen, —C(O)R14, —S(O)lR14, —Z(R14)2, or —XR14; R14 represents H, a halogen, or an organic substituent group which has a main chain having 1 to 10 atoms; Z represents N or P; X represents O or S; R13 represents H, or an hydrocarbon group which has a main chain having 1 to 10 atoms; l represents an integer of 1 to 2; m and n represent an integer of 1 to 3 respectively.

公开(公告)号：US09290525B2

公开(公告)日：2016-03-22

申请号：US13934577

申请日：2013-07-03

申请人： Nippon Shokubai Co., Ltd.

发明人： Takashi Abe ,  Shin-ya Imoto ,  Morihiro Kitamura ,  Hikaru Takahashi

IPC分类号： C07F7/04 ,  C07F9/54 ,  C07C211/63 ,  C07C209/68

CPC分类号： C07F9/5442 ,  C07C209/68 ,  C07C211/63

摘要： An object of the present invention is to provide a production method that can efficiently produce a cyclic silane compound or a salt thereof with a high yield and to provide a novel salt having a cyclic silane dianion that is easy to handle and a cyclic silane dianion salt-containing composition. The method for producing a cyclic silane compound or a salt thereof of the present invention includes the step of allowing a halosilane compound to react in the presence of at least one of a phosphonium salt and an ammonium salt, and a compound represented by a specific formula.

摘要翻译： 本发明的目的是提供一种能够高效率地制备环状硅烷化合物或其盐的制造方法，提供具有易于处理的环状硅烷二价阴离子的新型盐和环状硅烷二阴离子盐 含有组成。 本发明的环状硅烷化合物或其盐的制造方法包括使卤代硅烷化合物在鏻盐和铵盐中的至少一种的存在下反应的工序，以及由具体式 。

公开(公告)号：US09243079B2

公开(公告)日：2016-01-26

申请号：US14301773

申请日：2014-06-11

申请人： Nippon Shokubai Co., Ltd.

发明人： Shigeru Sakamoto ,  Yoshio Irie ,  Kozo Nogi ,  Kunihiko Ishizaki

IPC分类号： C08F220/06 ,  C08F2/10 ,  C08F2/16 ,  C08C19/00 ,  C08F222/20 ,  C08F2/34 ,  C08F20/10 ,  C08F8/00

CPC分类号： C08C19/00 ,  C08F2/10 ,  C08F2/16 ,  C08F2/34 ,  C08F8/00 ,  C08F20/10 ,  C08F220/06 ,  C08F222/20

摘要： A method for producing a polyacrylic water-absorbent resin powder includes the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after polymerizing, fragmenting the resulting hydrated gel crosslinked polymer; and drying the fragmented hydrated gel crosslinked polymer. The gas is dissolved and/or dispersed in the monomer solution by (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; or (c) introducing the gas with the acrylic monomer solution via fine holes. The production method efficiently produces a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.

摘要翻译： 聚丙烯酸吸水性树脂粉末的制造方法包括以下工序：制造溶解和/或分散有气体的丙烯酸类单体溶液; 在不存在表面活性剂的情况下或在不超过300ppm表面活性剂的存在下聚合单体溶液; 在聚合期间或之后，将所得水合凝胶交联聚合物破碎; 并干燥碎裂的水合凝胶交联聚合物。 通过（a）向丙烯酸单体溶液和气体施加压力，将气体溶解和/或分散在单体溶液中; （b）产生丙烯酸单体溶液和气体的旋流; 或（c）通过细孔将丙烯酸单体溶液引入气体。 制造方法有效地制造吸水率优异的吸水性树脂，而不会降低卫生用品等的吸液性。

公开(公告)号：US09234094B2

公开(公告)日：2016-01-12

申请号：US13704888

申请日：2011-06-17

申请人： Norihiro Wakao ,  Akihiko Kanzaki ,  Junichi Chosa

发明人： Norihiro Wakao ,  Akihiko Kanzaki ,  Junichi Chosa

IPC分类号： C08L33/00 ,  C08L33/02 ,  C08F2/10 ,  C08F20/06

CPC分类号： C08L33/02 ,  C08F2/10 ,  C08F20/06

摘要： An aqueous solution containing a poly(meth)acrylic acid-based polymer which shows excellent dispersibility for inorganic substances, satisfactory long-term dispersibility, and a favorable color is provided. The aqueous solution of the present invention is an aqueous solution comprising a poly(meth)acrylic acid-based polymer, the poly(meth)acrylic acid-based polymer including carboxyl groups, wherein in 100 mol % of the carboxyl groups, 30 to 85 mol % of the carboxyl groups are in an alkali metal salt form of the carboxyl groups, and 15 to 70 mol % of the carboxyl groups are in an acid form of the carboxyl groups, the poly(meth)acrylic acid-based polymer containing a phosphorus-containing group, the poly(meth)acrylic acid-based polymer having a weight average molecular weight of 2000 to 9000, the aqueous poly(meth)acrylic acid-based polymer solution having a concentration of inorganic anions, each including a sulfur or phosphorus atom, of 1000 to 10000 ppm relative to the aqueous poly(meth)acrylic acid-based polymer solution.

摘要翻译： 提供了含有对于无机物质具有优异的分散性，令人满意的长期分散性和良好的颜色的聚（甲基）丙烯酸类聚合物的水溶液。 本发明的水溶液是包含聚（甲基）丙烯酸类聚合物，包含羧基的聚（甲基）丙烯酸类聚合物）的水溶液，其中100摩尔％的羧基为30〜85 羧基的摩尔％为羧基的碱金属盐形式，羧基的15〜70摩尔％为羧基，聚（甲基）丙烯酸类聚合物含有 含磷基团，重均分子量为2000〜9000的聚（甲基）丙烯酸类聚合物，具有无机阴离子浓度的聚（甲基）丙烯酸系聚合物水溶液，各自含有硫或 磷原子相对于聚（甲基）丙烯酸系聚合物水溶液为1000〜10000ppm。

公开(公告)号：US20160005994A1

公开(公告)日：2016-01-07

申请号：US14768646

申请日：2014-02-28

申请人： NIPPON HOSO KYOKAI ,  NIPPON SHOKUBAI CO., LTD.

发明人： Hirohiko FUKAGAWA ,  Takahisa SHIMIZU ,  Katsuyuki MORII

IPC分类号： H01L51/52 ,  H01L51/00 ,  H01L51/50

CPC分类号： H01L51/5246 ,  H01L51/0034 ,  H01L51/0039 ,  H01L51/004 ,  H01L51/0072 ,  H01L51/008 ,  H01L51/0097 ,  H01L51/5088 ,  H01L51/5221 ,  H01L51/524 ,  H01L2251/301 ,  H01L2251/303 ,  H01L2251/5338

摘要： The present invention aims to provide an organic electroluminescence device that operates successfully without strict sealing. Provided is an organic electroluminescence device having a structure in which a plurality of layers is stacked between an anode and a cathode formed on a substrate, wherein the organic electroluminescence device is sealed to provide a water vapor transmission rate of 10−6 to 10−3 g/m2·day.

摘要翻译： 本发明的目的在于提供一种在没有严格密封的情况下成功运行的有机电致发光器件。 本发明提供一种有机电致发光元件，其具有多个层叠在形成于基板上的阳极和阴极之间的结构，其中，将有机电致发光元件密封，提供10-6〜10-3的水蒸气透过率 g / m2·天。

公开(公告)号：US20150364790A1

公开(公告)日：2015-12-17

申请号：US14764386

申请日：2014-01-30

申请人： NIPPON SHOKUBAI CO., LTD.

发明人： Koji YONEHARA ,  Hironobu ONO ,  Satoshi OGAWA ,  Yasuyuki TAKAZAWA ,  Hiroko HARADA

IPC分类号： H01M10/0565

CPC分类号： H01M10/0565 ,  H01B1/122 ,  H01G11/30 ,  H01G11/38 ,  H01G11/48 ,  H01G11/52 ,  H01G11/62 ,  H01M2/16 ,  H01M2/166 ,  H01M4/244 ,  H01M4/48 ,  H01M4/622 ,  H01M4/623 ,  H01M4/92 ,  H01M4/925 ,  H01M6/181 ,  H01M8/1039 ,  H01M8/1048 ,  H01M10/24 ,  H01M10/26 ,  H01M10/30 ,  H01M12/08 ,  H01M2008/1095 ,  H01M2300/0082 ,  Y02E60/128 ,  Y02E60/13

摘要： The present invention aims to provide an anion conducting material having excellent anion conductivity and durability, which can be suitably used as a separator, an electrolyte, or an electrode protecting agent of an alkaline cell, for example. The present invention also aims to provide a cell including a cell component containing the anion conducting material. The present invention provides an anion conducting material containing a polymer and a compound containing at least one element selected from Groups 1 to 17 of the periodic table.

摘要翻译： 本发明的目的在于提供具有优异的阴离子导电性和耐久性的阴离子导电材料，其可以适当地用作碱性电池的隔膜，电解质或电极保护剂。 本发明还旨在提供一种包含含有阴离子导电材料的电池组件的电池。 本发明提供含有聚合物和含有选自周期表第1至17族中的至少一种元素的化合物的阴离子导电材料。

公开(公告)号：US09187579B2

公开(公告)日：2015-11-17

申请号：US12524989

申请日：2008-02-04

申请人： Hiroyuki Ikeuchi ,  Hirotama Fujimaru ,  Makoto Nagasawa ,  Kazuhiko Sakamoto ,  Shigeru Sakamoto ,  Kazushi Torii ,  Ryoko Tahara

发明人： Hiroyuki Ikeuchi ,  Hirotama Fujimaru ,  Makoto Nagasawa ,  Kazuhiko Sakamoto ,  Shigeru Sakamoto ,  Kazushi Torii ,  Ryoko Tahara

IPC分类号： B01J20/22 ,  B01J20/26 ,  C08F20/06 ,  C08F2/44 ,  C08F220/06 ,  C08L33/02 ,  A61F13/53 ,  C08F222/10 ,  C08K5/00 ,  C08L71/02

CPC分类号： C08F2/44 ,  A61F2013/530583 ,  C08F220/06 ,  C08F222/1006 ,  C08K5/0008 ,  C08L33/02 ,  C08L71/02 ,  Y10T428/2982 ,  C08L2666/22

摘要： An object of the present invention is to provide a particle-shaped water absorbing agent having a remarkably improved surface color and excellent water-absorbing properties (better water absorption capacity, and lower water soluble content and residual monomer content) at the same time. In order to attain the object, a particle-shaped water absorbing agent according to the present invention is a particle-shaped water absorbing agent whose main component is a polyacrylic acid and/or a salt thereof, the particle-shaped water absorbing agent having a surface color of Hunter b value in a range of −5 to 10, and having a cross-linking absorption property index (CPI) in a range of 1 to 100, the CPI defined by the following two equations: GEX=(GVs+17)/Ln (water soluble content);  Equation 1: CPI=(GEX/residual monomer content)×100  Equation 3: where GVs is gel volume in saline, Ln (water soluble content) is a logarithm natural of water soluble content.

摘要翻译： 本发明的目的是提供一种具有显着改善的表面颜色和优异的吸水性（更好的吸水能力，更低的水溶性含量和残留的单体含量）的颗粒状吸水剂。 为了达到上述目的，本发明的颗粒状吸水剂是主要成分为聚丙烯酸和/或其盐的颗粒状吸水剂，该颗粒状吸水剂具有 Hunter b值的表面颜色在-5至10的范围内，并且交联吸收特性指数（CPI）在1至100的范围内，由以下两个等式定义的CPI：GEX =（GVs + 17 ）/ Ln（水溶性成分）; 方程1：CPI =（GEX /残留单体含量）×100等式3：其中GV是盐水中的凝胶体积，Ln（水溶性含量）是水溶性含量的对数自然。