WHEREIN Z IS BROMINE, M AND M'' AR INTEGERS HAVING A VALUE OF 1-4, I AND I'' ARE INTEGERS HAVING A VALUE OF 1 OR 2, ALKYLENE IS A STRAIGHT OR BRANCHED CHAIN ALKYLENE GROUP HAVING FROM 1 TO 6 CARBON ATOMS AND A IS CYANO, NITRO, LOWER ALKOXY, LOWER ALKYL, FLUORINE, DIALKYL AMINE, PHENYL, HALO-PHENYL, BENZYL OR HALO-BENZYL.
Abstract:
This invention provides for a self-sustaining fluidized bed reactor after the wave rotor reactor in which the reactor may be a fluidized bed reactor, a self-catalytic system, and may include an arrangement for the continuous removal and/or replenishment of particles in the fluidized bed, as well as possibly including a heater for heating the walls and/or a way for managing buildup of solids on the walls of the reactor.
Abstract:
A reactor comprises a reactor vessel defining a confined reactor volume, a support assembly extending about a periphery of the confined reactor volume, a basket positioned within the reactor vessel and supported by the support assembly, the basket having an interior surface and an exterior surface, a downflow zone being defined between the exterior surface of the basket and an interior surface of the confined reactor volume, an inlet screen positioned adjacent to one end of the interior surface and an outlet screen positioned adjacent to an opposite end of the interior surface, an upflow zone defined between the inlet screen and outlet screen, the inlet screen and the outlet screen containing a quantity of particulate catalyst, and a circulating device positioned above said upflow zone and configured to continuously circulate fluid upwardly though said upflow zone and downwardly through said downflow zone, the support assembly and the basket configured to promote the formation of a fluid vortex within a portion of the downflow zone.
Abstract:
The invention relates to a rotary disc device (1) in a rotary fluidized bed, the outer edge of said disc rotating inside, and faster than, the fluidized bed, thereby allowing: the rotation speed of the fluidized bed to be accelerated, solid particles and/or micro-droplets to be supplied to the fluidized bed or to the free central area, and different annular areas of the fluidized bed to be separated. The invention also relates to methods for transforming solid particles or micro-droplets on contact with the fluids flowing through the rotary fluidized bed or for transforming fluids on contact with solids in suspension in the rotary fluidized bed, using said device.
Abstract:
Integrated primary and secondary cyclone assembly includes a secondary cyclone having an outlet tube extending therefrom and a primary cyclone operatively coupled with the secondary cyclone. The outlet tube has a cross dimension and length and is configured to be secured to a pressure vessel closure head to support the secondary cyclone therefrom. The primary cyclone has a tubular support member extending therefrom. The tubular support member is aligned substantially parallel with and has a length similar to the outlet tube of the secondary cyclone and is configured to be joined to the pressure vessel closure head to support the primary cyclone therefrom.
Abstract:
A method of making acetic anhydride or a mixture of acetic anhydride and acetic acid comprising: (a) catalytically reacting a feedstock containing methyl acetate and/or dimethyl ether with carbon monoxide in the presence of a homogeneous rhodium catalyst and methyl iodide in a reactor vessel which contains a substantially anhydrous liquid reaction mixture including acetic acid, acetic anhydride, methyl acetate and/or dimethyl ether, methyl iodide and the homogeneous catalyst, the reactor vessel being operated at a reactor pressure; (b) withdrawing reaction mixture from the reaction vessel and feeding the withdrawn reaction mixture along with additional carbon monoxide to a pre-flasher/post reactor vessel operated at a reduced pressure below the reactor vessel pressure; (c) venting light ends in the pre-flasher vessel and concurrently consuming methyl acetate and/or dimethyl ether in the pre-flasher/post reactor vessel to produce a pre-flash mixture which is enriched in acetic anhydride and diminished in methyl iodide and methyl acetate and/or dimethyl ether as compared with the reaction mixture; (d) withdrawing the pre-flash reaction mixture from the pre-flasher/post reactor vessel and feeding the pre-flash mixture to a flash vessel; and (e) flashing a crude product stream from the mixture in a flash vessel operated at a pressure substantially below the pressure of the pre-flasher/post reactor vessel.
Abstract:
The present application provides multistage and multilayer reactors useful for the efficient and continuous production of carbon nanotubes and methods of using the apparatus in the preparation of carbon nanotubes. In one aspect, the multistage reactors include an array of interconnected fluidized-bed reactors. The multilayer reactors include a plurality of reaction zones.
Abstract:
An olefin polymerization process and apparatus wherein a fluid slurry comprising monomer, diluent and catalyst is circulated in a continuous loop reactor by two or more pumps. The process and apparatus allow operating the reaction at significantly higher solids content in the circulating fluid slurry. In a preferred embodiment, the fluid slurry is circulated by two impellers arranged so that the downstream impeller benefits from the rotational energy imparted by the upstream impeller. An olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation has improved efficiencies, particularly in larger-volume reactors.
Abstract:
An olefin polymerization process and apparatus wherein a fluid slurry comprising monomer, diluent and catalyst is circulated in a continuous loop reactor by two or more pumps. The process and apparatus allow operating the reaction at significantly higher solids content in the circulating fluid slurry. In a preferred embodiment, the fluid slurry is circulated by two impellers arranged so that the downstream impeller benefits from the rotational energy imparted by the upstream impeller. An olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation has improved efficiencies, particularly in larger-volume reactors.
Abstract:
A process for high temperature hydrolysis of halosilanes and halides with the steps of: providing a bed of fluidized particulate material heated to at least 300° C., injecting steam and an excess of reactants into the reactor, removing solid waste from a bottom outlet, removing the effluent gases through a solids removal device such as a cyclone, condensing and separating some of the unreacted waste from the effluent gas in a distillation column and sending the effluent gases containing hydrogen and hydrogen chloride to a compressor. In a preferred embodiment the reactants contain at least one water reactive halide, selected from the group halosilane, organohalosilane, aluminum halide, titanium halide, boron halide, manganese halide, copper halide, iron halide, chromium halide, nickel halide, indium halide, gallium halide and phosphorus halide and where the halide content is selected from chlorine, bromine and iodine.