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公开(公告)号:US07736597B2
公开(公告)日:2010-06-15
申请号:US11384629
申请日:2006-03-20
申请人: John D. Hottovy , Dale A. Zellers , Penny A. Zellers, legal representative , Robert K. Franklin , Donald Paul Russell
CPC分类号: C08F2/01 , B01J8/0015 , B01J8/005 , B01J8/20 , B01J8/226 , B01J8/382 , B01J19/006 , B01J19/0066 , B01J19/1837 , B01J19/1875 , B01J2219/00094 , B01J2219/00114 , B01J2219/00189 , B01J2219/00777 , C08F6/003 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F210/16 , C08L23/10 , C08F2/14 , C08F210/14 , C08F210/08
摘要: An olefin polymerization process and apparatus wherein a fluid slurry comprising monomer, diluent and catalyst is circulated in a continuous loop reactor by two or more pumps. The process and apparatus allow operating the reaction at significantly higher solids content in the circulating fluid slurry. In a preferred embodiment, the fluid slurry is circulated by two impellers arranged so that the downstream impeller benefits from the rotational energy imparted by the upstream impeller. An olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation has improved efficiencies, particularly in larger-volume reactors.
摘要翻译: 一种烯烃聚合方法和装置,其中包含单体,稀释剂和催化剂的流体浆料在连续环流反应器中通过两个或多个泵循环。 该方法和装置允许在循环流体浆液中以显着更高的固体含量操作反应。 在优选实施例中,流体浆料通过布置成使得下游叶轮从由上游叶轮施加的旋转能量受益的两个叶轮循环。 通过更积极的循环在较高的反应器固体中操作的烯烃聚合方法具有改进的效率,特别是在较大体积的反应器中。
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公开(公告)号:US07615596B2
公开(公告)日:2009-11-10
申请号:US11241016
申请日:2005-09-30
申请人: David H. Burns , Donald W. Verser , Elizabeth A. Benham , Max P. McDaniel , John D. Hottovy , Dale A. Zellers , Penny A. Zellers, legal representative , Clay K Thurman , David A. Lockman , John O. Lawmaster , Matthew T. Haberly , Thomas H. Smith , Jerry T. Lanier , Matthew G. Thorn
发明人: David H. Burns , Donald W. Verser , Elizabeth A. Benham , Max P. McDaniel , John D. Hottovy , Dale A. Zellers , Clay K Thurman , David A. Lockman , John O. Lawmaster , Matthew T. Haberly , Thomas H. Smith , Jerry T. Lanier , Matthew G. Thorn
IPC分类号: C08F4/42 , C08F210/00
CPC分类号: G05B13/048 , B01J8/0015 , B01J19/0006 , B01J19/0033 , B01J19/1837 , B01J19/2435 , B01J2219/00038 , B01J2219/0004 , B01J2219/00164 , B01J2219/00184 , B01J2219/00186 , B01J2219/002 , B01J2219/00218 , B01J2219/00231 , C08F2/00 , C08F10/00 , G05B13/042 , Y10S526/943
摘要: Multiple components are selected, conveyed, and measured in a polymerization system. A control system adjusts the system variables to the desired values. Portions of the components can be fed to a pre-contactor before introduction into the polymerization reactor. The catalyst component concentrations and residence times are tightly controlled in the pre-contactor to affect product properties. The pre-contactor can be a single or multiple combinations of a CSTR or plug flow pre-contactors.
摘要翻译: 在聚合系统中选择,传送和测量多个组分。 控制系统将系统变量调整到所需的值。 在引入聚合反应器之前,可以将部分成分送入预接触器。 催化剂组分浓度和停留时间在预接触器中严格控制以影响产品性能。 预接触器可以是CSTR或塞流预接触器的单个或多个组合。
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公开(公告)号:US08128877B2
公开(公告)日:2012-03-06
申请号:US13207262
申请日:2011-08-10
申请人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers , Penny A. Zellers, legal representative
发明人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers
IPC分类号: B01J10/00 , C08F2/00 , C08F210/00
CPC分类号: B01J19/0013 , B01J8/0015 , B01J19/1837 , B01J19/2455 , B01J2208/00212 , B01J2208/00752 , B01J2219/00006 , B01J2219/0236 , C08F2/01 , C08F6/003 , C08F10/00 , C08F110/02 , C08L23/00 , C08F2/14
摘要: A manufacturing process for producing polyolefin, having a feed system, a reactor system including at least one polymerization reactor, a diluent/monomer recovery system, a fractionation system, and an extrusion/loadout system having an extruder. The manufacturing process is configured to consume less than 325 kilowatt-hours of electricity per metric ton of polyolefin produced.
摘要翻译: 具有进料系统的聚烯烃的制造方法,包括至少一个聚合反应器的反应器系统,稀释剂/单体回收系统,分馏系统和具有挤出机的挤出/压出系统。 制造过程被配置为每公吨生产的聚烯烃消耗少于325千瓦小时的电力。
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公开(公告)号:US08303899B2
公开(公告)日:2012-11-06
申请号:US13372979
申请日:2012-02-14
申请人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers , Penny A. Zellers, legal representative
发明人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers
CPC分类号: B01J19/0013 , B01J8/0015 , B01J19/1837 , B01J19/2455 , B01J2208/00212 , B01J2208/00752 , B01J2219/00006 , B01J2219/0236 , C08F2/01 , C08F6/003 , C08F10/00 , C08F110/02 , C08L23/00 , C08F2/14
摘要: A manufacturing system for producing polyolefin includes a polymerization reactor, a flash chamber, and a purge column. In certain embodiments, the purge column may receive a solids stream directly from the flash chamber. Further, the purge column may function as a feed tank for an extruder within an extrusion/loadout system. According to certain embodiments, the manufacturing system may be configured to consume less than 445 kilowatt-hours of energy per metric ton of polyolefin produced based on consumption of electricity, steam, and fuel gas.
摘要翻译: 用于生产聚烯烃的制造系统包括聚合反应器,闪蒸室和吹扫塔。 在某些实施方案中,净化塔可以直接从闪蒸室接收固体物流。 此外,吹扫塔可用作挤出/挤出系统中的挤出机的进料罐。 根据某些实施例,制造系统可以被配置为消耗基于消耗电力,蒸汽和燃料气体的每公吨聚烯烃消耗少于445千瓦小时的能量。
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公开(公告)号:US08017701B2
公开(公告)日:2011-09-13
申请号:US11213374
申请日:2005-08-26
申请人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers , Penny A. Zellers, legal representative
发明人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers
IPC分类号: C08F2/00 , C08F210/00
CPC分类号: B01J19/0013 , B01J8/0015 , B01J19/1837 , B01J19/2455 , B01J2208/00212 , B01J2208/00752 , B01J2219/00006 , B01J2219/0236 , C08F2/01 , C08F6/003 , C08F10/00 , C08F110/02 , C08L23/00 , C08F2/14
摘要: A manufacturing process for producing polyolefin, having a feed system, a reactor system including at least one polymerization reactor, a diluent/monomer recovery system, a fractionation system, and an extrusion/loadout system having an extruder. The manufacturing process is configured to consume less than 325 kilowatt-hours of electricity per metric ton of polyolefin produced.
摘要翻译: 具有进料系统的聚烯烃的制造方法,包括至少一个聚合反应器的反应器系统,稀释剂/单体回收系统,分馏系统和具有挤出机的挤出/压出系统。 制造过程被配置为每公吨生产的聚烯烃消耗少于325千瓦小时的电力。
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公开(公告)号:US20100215550A1
公开(公告)日:2010-08-26
申请号:US12771383
申请日:2010-04-30
申请人: John D. Hottovy , Dale A. Zellers , Penny A. Zellers , Robert K. Franklin, III , Donald Paul Russell
发明人: John D. Hottovy , Dale A. Zellers , Penny A. Zellers , Robert K. Franklin, III , Donald Paul Russell
IPC分类号: B01J19/18
CPC分类号: C08F2/01 , B01J8/0015 , B01J8/005 , B01J8/20 , B01J8/226 , B01J8/382 , B01J19/006 , B01J19/0066 , B01J19/1837 , B01J19/1875 , B01J2219/00094 , B01J2219/00114 , B01J2219/00189 , B01J2219/00777 , C08F6/003 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F210/16 , C08L23/10 , C08F2/14 , C08F210/14 , C08F210/08
摘要: An olefin polymerization process and apparatus wherein a fluid slurry comprising monomer, diluent and catalyst is circulated in a continuous loop reactor by two or more pumps. The process and apparatus allow operating the reaction at significantly higher solids content in the circulating fluid slurry. In a preferred embodiment, the fluid slurry is circulated by two impellers arranged so that the downstream impeller benefits from the rotational energy imparted by the upstream impeller. An olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation has improved efficiencies, particularly in larger-volume reactors.
摘要翻译: 一种烯烃聚合方法和装置,其中包含单体,稀释剂和催化剂的流体浆料在连续环流反应器中通过两个或多个泵循环。 该方法和装置允许在循环流体浆液中以显着更高的固体含量操作反应。 在优选实施例中,流体浆料通过布置成使得下游叶轮从由上游叶轮施加的旋转能量受益的两个叶轮循环。 通过更积极的循环在较高的反应器固体中操作的烯烃聚合方法具有改进的效率,特别是在较大体积的反应器中。
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公开(公告)号:US07014821B2
公开(公告)日:2006-03-21
申请号:US10663322
申请日:2002-09-16
CPC分类号: C08F2/01 , B01J8/0015 , B01J8/005 , B01J8/20 , B01J8/226 , B01J8/382 , B01J19/006 , B01J19/0066 , B01J19/1837 , B01J19/1875 , B01J2219/00094 , B01J2219/00114 , B01J2219/00189 , B01J2219/00777 , C08F6/003 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F210/16 , C08L23/10 , C08F2/14 , C08F210/14 , C08F210/08
摘要: An olefin polymerization process and apparatus wherein a fluid slurry comprising monomer, diluent and catalyst is circulated in a continuous loop reactor by two or more pumps. The process and apparatus allow operating the reaction at significantly higher solids content in the circulating fluid slurry. In a preferred embodiment, the fluid slurry is circulated by two impellers arranged so that the downstream impeller benefits from the rotational energy imparted by the upstream impeller. An olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation has improved efficiencies, particularly in larger-volume reactors.
摘要翻译: 一种烯烃聚合方法和装置,其中包含单体,稀释剂和催化剂的流体浆料在连续环流反应器中通过两个或多个泵循环。 该方法和装置允许在循环流体浆液中以显着更高的固体含量操作反应。 在优选实施例中,流体浆料通过布置成使得下游叶轮从由上游叶轮施加的旋转能量受益的两个叶轮循环。 通过更积极的循环在较高的反应器固体中操作的烯烃聚合方法具有改进的效率,特别是在较大体积的反应器中。
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公开(公告)号:US08354063B2
公开(公告)日:2013-01-15
申请号:US12771383
申请日:2010-04-30
CPC分类号: C08F2/01 , B01J8/0015 , B01J8/005 , B01J8/20 , B01J8/226 , B01J8/382 , B01J19/006 , B01J19/0066 , B01J19/1837 , B01J19/1875 , B01J2219/00094 , B01J2219/00114 , B01J2219/00189 , B01J2219/00777 , C08F6/003 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F210/16 , C08L23/10 , C08F2/14 , C08F210/14 , C08F210/08
摘要: An olefin polymerization process and apparatus wherein a fluid slurry comprising monomer, diluent and catalyst is circulated in a continuous loop reactor by two or more pumps. The process and apparatus allow operating the reaction at significantly higher solids content in the circulating fluid slurry. In a preferred embodiment, the fluid slurry is circulated by two impellers arranged so that the downstream impeller benefits from the rotational energy imparted by the upstream impeller. An olefin polymerization process operating at higher reactor solids by virtue of more aggressive circulation has improved efficiencies, particularly in larger-volume reactors.
摘要翻译: 一种烯烃聚合方法和装置,其中包含单体,稀释剂和催化剂的流体浆料在连续环流反应器中通过两个或多个泵循环。 该方法和装置允许在循环流体浆液中以显着更高的固体含量操作反应。 在优选实施例中,流体浆料通过布置成使得下游叶轮从由上游叶轮施加的旋转能量受益的两个叶轮循环。 通过更积极的循环在较高的反应器固体中操作的烯烃聚合方法具有改进的效率,特别是在较大体积的反应器中。
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公开(公告)号:US07645841B2
公开(公告)日:2010-01-12
申请号:US10928047
申请日:2004-08-27
IPC分类号: C08F2/00 , C08F4/00 , C08F210/00 , C08F110/02 , B01J8/18
CPC分类号: C08F10/02 , B01J19/0006 , B01J19/002 , B01J19/1837 , B01J2208/00734 , B01J2219/00063 , B01J2219/00094 , B01J2219/00191 , B01J2219/00247 , B01J2219/00254 , C08F110/02 , C08F2400/02 , Y02P20/582 , Y10S526/901 , C08F2/002 , C08F2/14 , C08F2/00 , C08F2500/24
摘要: Techniques are provided for the prevention of reactor fouls in polymerization reactors. A technique is provided for limiting polymer particle size to prevent or limit the occurrence of reactor fouls associated with large polymer particles. A technique is also provided for measuring reactor temperature at one or more local hot spots of the reactor and for controlling the polymerization reaction based upon these temperature measurements. In particular, control of the reaction may be based on the hottest temperature, such that the hottest temperature in the reactor is maintained within the reactor fouling curve. A technique is also discussed for predicting reactor fouls by using statistical analyses, such as periodogram analysis, to identify leading indicators of impending fouls. Preventative measures may be performed upon identification of such a leading indicator. In addition, the statistical analyses may be used to identify catalysts having less propensity to foul.
摘要翻译: 提供了防止聚合反应堆中反应堆犯规的技术。 提供了一种限制聚合物粒度以防止或限制与大聚合物颗粒相关的反应堆犯规的发生的技术。 还提供了用于测量反应器的一个或多个局部热点处的反应器温度并基于这些温度测量来控制聚合反应的技术。 特别地,反应的控制可以基于最热的温度,使得反应器中最热的温度保持在反应器结垢曲线内。 还讨论了一种通过使用统计分析(如周期图分析)来确定即将发生的犯规的领先指标来预测反应堆犯规的技术。 在确定此类领先指标时,可采取预防措施。 此外,统计学分析可用于鉴定具有较小的污染倾向的催化剂。
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公开(公告)号:US20120139149A1
公开(公告)日:2012-06-07
申请号:US13372979
申请日:2012-02-14
申请人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers , Penny A. Zellers
发明人: Robert R. McElvain , John D. Hottovy , Ralph W. Romig , Donald W. Verser , David H. Burns , John H. Tait , Richard Peacock , James E. Hein , Scott E. Kufeld , Carl W. Fenderson , Anurag Gupta , Dale A. Zellers , Penny A. Zellers
IPC分类号: B29B9/06
CPC分类号: B01J19/0013 , B01J8/0015 , B01J19/1837 , B01J19/2455 , B01J2208/00212 , B01J2208/00752 , B01J2219/00006 , B01J2219/0236 , C08F2/01 , C08F6/003 , C08F10/00 , C08F110/02 , C08L23/00 , C08F2/14
摘要: A manufacturing system for producing polyolefin includes a polymerization reactor, a flash chamber, and a purge column. In certain embodiments, the purge column may receive a solids stream directly from the flash chamber. Further, the purge column may function as a feed tank for an extruder within an extrusion/loadout system. According to certain embodiments, the manufacturing system may be configured to consume less than 445 kilowatt-hours of energy per metric ton of polyolefin produced based on consumption of electricity, steam, and fuel gas.
摘要翻译: 用于生产聚烯烃的制造系统包括聚合反应器,闪蒸室和吹扫塔。 在某些实施方案中,净化塔可以直接从闪蒸室接收固体物流。 此外,吹扫塔可用作挤出/挤出系统中的挤出机的进料罐。 根据某些实施例,制造系统可以被配置为消耗基于消耗电力,蒸汽和燃料气体的每公吨聚烯烃消耗少于445千瓦小时的能量。
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