摘要:
A partly oxidized substrate, obtained by subjecting a substrate made of a porous metal or metal alloy comprising particles of at least one metal or metal alloy bound by sintering, said substrate comprising a first main surface and a second main surface, and said substrate having a porosity gradient from the first main surface to as far as the second main surface; to partial oxidation by an oxidizing gas such as oxygen and/or air.Method for preparing said substrate and high temperature electrolyzer cell ( >) comprising said substrate.
摘要:
Disclosed herein is a method of manufacturing an anode for in-situ sintering for a molten carbonate fuel cell, in which an anode green sheet is prepared using a slurry, and then a reinforcing layer is placed on the anode green sheet and then pressed, thereby improving the mechanical stability of a fuel cell stack and the long term stability of an anode, and an anode manufactured using the method.
摘要:
A flow field plate for a fuel cell that has one or more outer layers that makes the plate more conductive and hydrophilic. In one embodiment, the coating is co-deposited as combination of a conductive material and a metal oxide coating. A suitable conductive material is gold and suitable metal oxides include SiO2, HfO2, ZrO2, Al2O3, SnO2, Ta2O5, Nb2O5, MoO2, IrO2, RuO2 and mixtures thereof. The conductive material and metal oxide can also be deposited as two separate layers, where the metal oxide is the outer layer. According to another embodiment, a metal layer is deposited on the plate with nanopores that provide the hydrophilicity. Also, doping ions can be added to the metal oxide to provide low fluoride solubility of the coating to control the rate that hydrofluoric acid etches away the oxide layer.
摘要翻译:一种用于燃料电池的流场板,其具有使得该板更具导电性和亲水性的一个或多个外层。 在一个实施方案中,涂层作为导电材料和金属氧化物涂层的组合共沉积。 合适的导电材料是金,合适的金属氧化物包括SiO 2,HfO 2,ZrO 2,Al 2 O 3,SnO 2,Ta 2 O 5,Nb 2 O 5,MoO 2,IrO 2,RuO 2及其混合物。 导电材料和金属氧化物也可以沉积成两个分开的层,其中金属氧化物是外层。 根据另一实施例,金属层被沉积在与提供亲水性纳米孔的板。 此外,掺杂的离子可以被加入到所述金属氧化物以提供该涂层的低氟溶解度来控制速率氢氟酸蚀刻掉氧化层。
摘要:
The invention describes a bipolar unit consisting of a pair of metal plates at least one of which is corrugated, fixed by continuous and hydraulically impervious connections, and provided on the external surfaces thereof with porous electric current collectors also suitable for the distribution of the gaseous reactants. The collector facing the plate corrugations is interpenetrated therein, thereby achieving a continuous contact. Two bipolar units of the invention and one interposed MEA element are assembled to form an elementary fuel cell with an improved electric current distribution. Furthermore the channels formed between the mutually contacting surfaces of the plate pair by the corrugations of at least one of the plates of each bipolar unit, are crossed by a coolant allowing to optimally adjust the cell operative temperature.
摘要:
A fuel cell comprising: a membrane electrolyte assembly having a polymer electrolyte membrane and a pair of catalyst electrodes, namely an air electrode and a fuel electrode sandwiching the polymer electrolyte membrane; a pair of separators, namely an air electrode separator and a fuel electrode separator sandwiching the membrane electrolyte assembly; two or more oxidizing gas channels running in a certain direction for the purpose of supplying an oxidizing gas to the air electrode; and two or more linear fuel gas channels arranged parallel to the certain direction for the purpose of supplying a fuel gas to the fuel electrode. Large gaps and small gaps are provided alternately between adjacent two oxidizing gas channels along the certain direction, and the fuel gas channels do not overlap portions of the oxidizing gas channels, that are parallel to the fuel gas channels.
摘要:
A conductive and tabular separator is inserted into the gap between the fuel electrode layer of an i-th power generating cell and the oxidizer electrode layer of an (i+1)-th power generating cell adjacent to the fuel electrode layer. A fuel supply passage is so formed on one face of each of these separators that a fuel gas flows radially from almost the center of the fuel electrode layer to its edge. An oxidizer supply passage is so formed on the other face that an oxidizer gas outgoes almost uniformly in a shower toward the oxidizer polar layer. Thus, all of the surfaces of the power generating cells contribute to power generation to increase the frequency of collision between the fuel gas and the fuel electrode layer and that between the oxidizer gas and the oxidizer electrode layer, and to improve the generation efficiency.
摘要:
Fuel cells having cathode elements that are oriented such that dispersion of injected fuel through the fuel cell is caused at least in part by buoyancy force are disclosed. In one aspect of the present disclosure, the fuel cell includes a composite cathode element that is oriented such that dispersion of injected fuel through the fuel cell is caused at least in part by buoyancy force. For example, the composite cathode element and may be vertically oriented such that it is substantially parallel to the line of buoyancy. The composite cathode element further comprises, a porous matrix holding electrolyte, a cathode, and/or a cathode current collector. One embodiment of the fuel cell further includes, an anode chamber coupled to the composite cathode element. During operation, fuel injected into the fuel cell is oxidized in the anode chamber by oxidizer ions generated at the composite cathode element and transported to the anode chamber via the electrolyte in the porous matrix.
摘要:
A fuel cell in which carbon and water react to form hydrogen or water. The cells utilize electrolyte materials that hold or coordinate water to allow the useful reaction of carbon and water at moderate temperatures without the use of expensive pressure reactors. Activated carbon or carbon recovered from organic waste is used to fuel these cells to produce hydrogen gas or carbon dioxide and power at moderate temperatures and at very low cost.
摘要:
An object of the present invention is to provide a fuel cell stack which can prevent both cell voltages from decreasing and cracks from occurring in a solid electrolyte under the action of mechanical stress and a flat plate solid oxide fuel cell using the same. In order to achieve this object, the present invention provides a fuel cell stack having a sealless structure in which a plurality of power generation cells (16), each of which has a fuel electrode layer (12) formed on one (lower) surface of a plate-like solid electrolyte (11) and an oxidant electrode layer (13) formed on the other (upper) surface thereof, are laminated in a plate thickness direction by interposing a separator (2) between the power generation cells (16); and in which a fuel electrode current collector (14) is interposed between the fuel electrode layer and the separator and an oxidant electrode current collector (15) is interposed between the oxidant electrode layer and the separator, wherein an annular member (17) with a thickness thinner than a fuel electrode current collector interposed between the separator and the solid electrolyte or a raised portion with a height not to be in contact with a solid electrolyte formed on a fuel electrode current collector side of the separator is provided on an outer periphery of the fuel electrode current collector.
摘要:
Disclosed herein is a fuel cell including a multi-tubular support, including: a multi-tubular support consisting of a plurality of tubular supports which are concentrically arranged and have different diameters; a connection support extending from the innermost tubular support to the outermost tubular support of the plurality of tubular supports; and a membrane electrode assembly formed on the multi-tubular support or the connection support. The fuel cell is advantageous in that, since it includes the multi-tubular support, a reaction area is enlarged, so that the efficiency of a fuel cell is increased, thereby to decreasing power generation costs.