DIIOCYANATE-SCAVENGING PACKAGING LAMINATES
    71.
    发明申请

    公开(公告)号:US20190085159A1

    公开(公告)日:2019-03-21

    申请号:US16082432

    申请日:2016-03-07

    Abstract: The present invention is directed to packaging laminates for containing a food or pharmaceutical/medical product which includes an exterior film, a multilayer interior film comprising a diisocyanate-scavenging layer and an adhesive-contact layer, and a polyurethane adhesive layer bonding the exterior film to the multilayer interior film. The present invention reduces the amount of any unreacted diisocyanate precursor and primary amines which can migrate to a product in packaging assemblies formed with a polyurethane adhesive. This is achieved when an interior film (commonly known as a sealant film) includes a layer comprising a non-polymeric polyol which is not in direct contact with the polyurethane adhesive. With this approach, the nonpolymeric polyol reacts with any residual diisocyanate and/or primary amines which migrates from the polyurethane adhesive through the laminated assembly and thus, neutralizes any potential undesirable effects of these compounds.

    Method for preparing a composition comprising perfluoropolyether having a hydroxyl group at one terminal

    公开(公告)号:US09951222B2

    公开(公告)日:2018-04-24

    申请号:US14682290

    申请日:2015-04-09

    Abstract: An object of the present invention is to provide a method for efficiently and highly selectively preparing a composition comprising perfluoropolyether having a hydroxyl group at one terminal at a higher ratio. The present invention provides a method for increasing a ratio of perfluoropolyether having a hydroxyl group at one terminal, relative to a total amount of the perfluoropolyether having a hydroxyl group at one terminal and perfluoropolyether having hydroxyl groups at both terminals in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a hydroxyl group at one terminal at a higher ratio. Further, present invention provides for increasing a ratio of perfluoropolyether having a hydroxyl group at one terminal, relative to a total amount of the perfluoropolyether having a hydroxyl group at one terminal, perfluoropolyether having hydroxyl groups at both terminals and perfluoropolyether having no hydroxyl group at any terminal perfluoropolyether, in a composition comprising these perfluoropolyethers, wherein the method comprises a step of subjecting the composition to chromatography in which a moving phase is supercritical or subcritical state carbon dioxide of the specific temperature and the specific pressure, and a stationary phase is silica gel to thereby collect a fraction containing the perfluoropolyether having a hydroxyl group at one terminal at a higher ratio.

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