Method for oligomerization of ethylene

    公开(公告)号:US10329211B2

    公开(公告)日:2019-06-25

    申请号:US15594115

    申请日:2017-05-12

    Abstract: Methods for the oligomerization of ethylene, and more specifically, methods for the preparation of mainly ethylene oligomers of C10 or higher are described. A method can include performing a first oligomerization of an ethylene gas using a Ni-containing mesoporous catalyst, followed by a second oligomerization using an ion exchange resin, etc. to produce ethylene oligomers of C10 or higher. The method for the preparation of ethylene oligomers can produce C8-16 ethylene oligomers in high yield without inducing deactivation of the catalyst, compared to the conventional technology of ethylene oligomerization by a one-step process.

    Method for Preparing Non-Acid-Treated Eco-Friendly Cellulose Nanocrystal, and Cellulose Nanocrystal Prepared Thereby

    公开(公告)号:US20190023857A1

    公开(公告)日:2019-01-24

    申请号:US16138752

    申请日:2018-09-21

    Abstract: The present invention relates to a method for preparing a non-acid-treated eco friendly cellulose nanocrystal and the cellulose nanocrystals prepared by the same. The methods for preparing the non-acid-treated cellulose nanocrystal and extracting the cellulose nanocrystal from cellulosic materials of the present invention are eco-friendly methods, compared with the conventional preparation method for cellulose nanocrystal based on acid-hydrolysis; are efficient due to the total energy saving process; are easy to utilize side products; and are characterized by high yield to produce the target cellulose nanocrystal. The nanocrystal prepared according to the present invention exhibits equivalent or higher aspect ratio, yield and crystallinity than the cellulose nanocrystal prepared through acid hydrolysis, and has remarkably excellent thermal stability, so that it can be effectively used for the production of membranes, electrical and electronic parts, substrates, heat insulating materials, and reinforcing materials required for durability against heat.

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