公开(公告)号：US07387834B2

公开(公告)日：2008-06-17

申请号：US10485352

申请日：2002-08-01

Applicant: Tetsuo Shimizu ,  Michio Asano ,  Makoto Ono ,  Yoshinori Nanba ,  Shunji Kasai ,  Shinichi Yano ,  Hiroyuki Yoshimoto

Inventor： Tetsuo Shimizu ,  Michio Asano ,  Makoto Ono ,  Yoshinori Nanba ,  Shunji Kasai ,  Shinichi Yano ,  Hiroyuki Yoshimoto

IPC: B32B5/16 ,  B05D7/00

CPC classification number: C08J3/12 ,  C08J2327/18 ,  Y10T428/2991 ,  Y10T428/3154

Abstract: The present invention provides a polytetrafluoroethylene molded article, particularly a PTFE molded article for high-frequency insulation, which is excellent in various electric properties and mechanical properties in a high frequency range of 3 to 30 GHz. The present invention also provides PTFE fine powder, which is excellent in extrusion moldability and capable of providing the molded article, and a process for preparing the same. More specifically, the present invention relates to a polytetrafluoroethylene fine powder having a standard specific gravity of 2.180 to 2.225, which is obtained by contacting polytetrafluoroethylene fine powder having a standard specific gravity of 2.180 to 2.225 with a fluorine radical source, wherein tanδ at 12 GHz of a film comprising the powder, which is obtained by cooling at 5 to 50° C./second after baking, is at most 2.0×10−4.

Abstract translation: 本发明提供一种聚四氟乙烯模塑制品，特别是用于高频绝缘的PTFE模塑制品，其在3至30GHz的高频范围内具有优异的各种电性能和机械性能。 本发明还提供挤出成型性优异且能够提供成形品的PTFE细粉及其制备方法。 更具体地说，本发明涉及通过使具有2.180至2.225标准比重的聚四氟乙烯细粉与氟根源接触而获得的标准比重为2.180至2.225的聚四氟乙烯细粉，其中12GHz处的tandelta 包含通过在烘烤后以5至50℃/秒冷却获得的粉末的薄膜的含量为至多2.0×10 -4。

公开(公告)号：US20080095936A1

公开(公告)日：2008-04-24

申请号：US11771908

申请日：2007-06-29

Applicant: Jiro Senda ,  Motohiro Oshima ,  Tetsuo Shimizu ,  Koji Tominaga ,  Koichiro Matsuda ,  Yutaka Yamagishi

Inventor： Jiro Senda ,  Motohiro Oshima ,  Tetsuo Shimizu ,  Koji Tominaga ,  Koichiro Matsuda ,  Yutaka Yamagishi

IPC: C23C16/455 ,  C23C16/52

CPC classification number: C23C16/4486 ,  C23C16/45523

Abstract: An obstruct of this invention is to downsize a chamber, consequently a film forming system, to improve a film thickness distribution and to improve throughput of film forming by increasing the amount of the vaporized liquid precursor. The film forming system 1 is to form a film by vaporizing a liquid precursor and then depositing the vaporized liquid precursor on a substrate W, and comprises a chamber 2 inside of which the substrate W is held and multiple injection valves 3 that are arranged at different positions in the chamber 2 and that directly inject the identical liquid precursor in the chamber 2, vaporize the identical liquid precursor by flash boiling and then supply the vaporized liquid precursor.

Abstract translation: 本发明的阻碍是通过增加蒸发的液体前体的量来减小室的尺寸，从而缩小成膜系统以改善膜厚度分布并提高成膜的生产量。 成膜系统1是通过蒸发液体前体而形成膜，然后将蒸发的液体前体沉积在基板W上，并且包括在其内保持基板W的腔室2和布置在不同的多个喷射阀3 在腔室2中的位置，并且将相同的液体前体直接注入到腔室2中，通过闪蒸来蒸发相同的液体前体，然后供应蒸发的液体前体。

公开(公告)号：US20070135558A1

公开(公告)日：2007-06-14

申请号：US10577424

申请日：2004-10-29

Applicant: Nobuhiko Tsuda ,  Chie Sawauchi ,  Yasuhiko Sawada ,  Tetsuo Shimizu

Inventor： Nobuhiko Tsuda ,  Chie Sawauchi ,  Yasuhiko Sawada ,  Tetsuo Shimizu

IPC: D06M15/277

CPC classification number: C08F6/20 ,  C08F6/16 ,  C08F14/18 ,  C08F14/26 ,  C08F214/26 ,  C08L27/12 ,  C08F2/16

Abstract: The present invention provides a method of producing a fluoropolymer aqueous dispersion by which the fluorine-containing emulsifier contained in the fluoropolymer aqueous dispersion as obtained after polymerization can be efficiently removed as well as a fluoropolymer aqueous dispersion low in fluorine-containing emulsifier concentration. The present invention is a method of producing a fluoropolymer aqueous dispersion which comprises carrying out a concentration treatment comprising a concentration operation of a pretreatment fluoropolymer aqueous dispersion, wherein the pretreatment fluoropolymer aqueous dispersion is obtained by carrying out a polymerization in an aqueous medium in the presence of a fluorine-containing surfactant (A), the fluorine-containing surfactant (A) is a fluorine-containing surfactant having an octanol/water partition coefficient of 1.5 to 3.5.

Abstract translation: 本发明提供一种含氟聚合物水性分散体的制造方法，其中可以有效地除去聚合后得到的含氟聚合物水分散体中所含的含氟乳化剂以及含氟乳化剂浓度低的含氟聚合物水分散体。 本发明是一种含氟聚合物水性分散体的制造方法，其特征在于，进行包含预处理含氟聚合物水分散液的浓缩操作的浓缩处理，其中，所述预处理含氟聚合物水分散体是通过在水性介质中进行聚合而得到的 含氟表面活性剂（A）的含氟表面活性剂（A）为辛醇/水分配系数为1.5〜3.5的含氟表面活性剂。

公开(公告)号：US07129298B2

公开(公告)日：2006-10-31

申请号：US10333821

申请日：2001-08-02

Applicant: Makoto Ono ,  Michio Asano ,  Yoshinori Nanba ,  Shunji Kasai ,  Hiroyuki Yoshimoto ,  Shinichi Yano ,  Tetsuo Shimizu

Inventor： Makoto Ono ,  Michio Asano ,  Yoshinori Nanba ,  Shunji Kasai ,  Hiroyuki Yoshimoto ,  Shinichi Yano ,  Tetsuo Shimizu

IPC: C08F14/26

CPC classification number: C09D127/18 ,  C08F259/08 ,  C08L27/18 ,  Y10T428/3154 ,  C08F214/18 ,  C08F214/28

Abstract: The present invention provides a TFE resin molding material which has electric characteristics, particularly low dielectric dissipation factor, in a microwave area, can also lower extrusion pressure as the material is of low molecular weight and can provide a molded article excellent in surface smoothness. The material is especially useful as a coating material for a coaxial cable for equipment in which microwave is used, including satellite transmitting equipment and a cell phone base station. A tetrafluoroethylene resin molding material excellent in high frequency electric characteristics, which provides a molded article having a dielectric constant of at most 2.2 and a dielectric dissipation factor of at most 1.60×10−4 under 12 GHz, and a standard specific gravity of at least 2.192 and less than 2.3 is provided. As the tetrafluoroethylene resin, a tetrafluoroethylene homopolymer or a copolymer of 99.9 to 99.9999% by mole of tetrafluoroethylene and 0.0001 to 0.1% by mole of a specific fluoromonomer is used.

Abstract translation: 本发明提供一种在微波区域具有电特性，特别是低介电损耗因数的TFE树脂成型材料，还可以降低挤出压力，因为该材料具有低分子量，并且可提供表面平滑性优异的成型体。 该材料作为用于其中使用微波的设备的同轴电缆的涂层材料是特别有用的，包括卫星发射设备和蜂窝电话基站。 一种高频电特性优异的四氟乙烯树脂成型材料，其提供介电常数为2.2以下的介电损耗因数和12GHz以下的1.60×10 -4以下的介电损耗因数， 提供了至少2.192和小于2.3的标准比重。 作为四氟乙烯树脂，使用四氟乙烯均聚物或99.9〜99.9999摩尔％的四氟乙烯和0.0001〜0.1摩尔％的特定含氟单体的共聚物。

公开(公告)号：US07128861B2

公开(公告)日：2006-10-31

申请号：US10275440

申请日：2002-03-05

Applicant: Katsuhiko Hamanaka ,  Tetsuo Shimizu

Inventor： Katsuhiko Hamanaka ,  Tetsuo Shimizu

IPC: D01F1/08 ,  D01D5/16 ,  D01D5/247 ,  D01D5/08 ,  B01D63/02 ,  B01D69/08 ,  B29C55/22 ,  B29C55/06 ,  B29C55/00 ,  D01F6/12

CPC classification number: B01D67/0083 ,  B01D63/024 ,  B01D63/16 ,  B01D65/08 ,  B01D67/0027 ,  B01D67/003 ,  B01D67/0086 ,  B01D67/0088 ,  B01D69/00 ,  B01D69/02 ,  B01D69/08 ,  B01D69/084 ,  B01D71/34 ,  B01D2321/04 ,  B01D2321/185 ,  B01D2323/46 ,  B01D2325/02 ,  B01D2325/28 ,  C02F1/444 ,  D01D5/24 ,  D01F6/48 ,  Y10T428/1328

Abstract: In a method for producing hollow fiber membranes which comprises melt kneading a mixture comprising polyvinylidene fluoride and an organic liquid or a mixture comprising polyvinylidene fluoride, an organic liquid and an inorganic fine powder, extruding the kneaded mixture to form hollow fibers, and extracting the organic liquid or the organic liquid and the inorganic fine powder from the hollow fibers, which includes the steps of drawing the hollow fibers before or after termination of the extraction and then shrinking the fibers. According to this method, it is possible to stably produce hollow fiber membranes having dense pores and having a high water permeation performance, excellent endurance and stain resistance, and which are suitable for filtration uses such as removal of turbidity of water.

公开(公告)号：US06998454B2

公开(公告)日：2006-02-14

申请号：US10465643

申请日：2003-06-20

Applicant: Takahiro Taira ,  Takahisa Aoyama ,  Katsuhide Otani ,  Tetsuo Shimizu

Inventor： Takahiro Taira ,  Takahisa Aoyama ,  Katsuhide Otani ,  Tetsuo Shimizu

IPC: C08F16/24

CPC classification number: C08F214/262 ,  C08L27/18 ,  Y10T428/3154

Abstract: To provide a suitable material having improved impermeability to liquid chemicals and cracking resistance while retaining excellent heat resistance and processability inherent in FEP-based fluororesins, a molded article of which is useful in the field of semiconductor production apparatus and the like. The present invention provides a fluorine-containing resin material comprising a fluorine-containing copolymer comprising 85 to 95.5% by mole of a repeating unit derived from tetrafluoroethylene, 5 to 10% by mole of a repeating unit derived from hexafluoropropylene and 0.1 to 5% by mole of a repeating unit derived from at least one higher perfluoro(vinyl ether) represented by the formula (1): CF2═CF—O—Rf1  (1) wherein Rf1 is a perfluoroalkyl group having 5 to 10 carbon atoms or a perfluoro(alkoxyalkyl) group having 4 to 17 carbon atoms, and molded article thereof.

Abstract translation: 为了提供对液体化学品具有改进的不渗透性和耐开裂性的合适的材料，同时保持了基于FEP的氟树脂固有的优异的耐热性和加工性，其成型制品可用于半导体制造装置等领域。 本发明提供一种含氟树脂材料，其含有含有85〜95.5摩尔％的来自四氟乙烯的重复单元，5〜10摩尔％的来自六氟丙烯的重复单元和0.1〜5重量％ 摩尔衍生自由式表示的至少一种较高全氟（乙烯基醚）的重复单元

公开(公告)号：US20050287471A1

公开(公告)日：2005-12-29

申请号：US11033954

申请日：2005-01-13

Applicant: Takayuki Araki ,  Meiten Koh ,  Yoshito Tanaka ,  Takuji Ishikawa ,  Hirokazu Aoyama ,  Tetsuo Shimizu

Inventor： Takayuki Araki ,  Meiten Koh ,  Yoshito Tanaka ,  Takuji Ishikawa ,  Hirokazu Aoyama ,  Tetsuo Shimizu

IPC: G03F7/004 ,  G03F7/038 ,  G03F7/039 ,  G03F7/075 ,  G03C1/76

CPC classification number: G03F7/039 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392 ,  G03F7/0395 ,  G03F7/0397 ,  G03F7/0758 ,  Y10S430/106 ,  Y10S430/108

Abstract: There is provided a novel fluorine-containing polymer having an acid-reactive group which has a high transparency against energy rays (radioactive rays) in a vacuum ultraviolet region (157 nm), and further there are provided a material for fluorine-containing base polymer prepared from the polymer and suitable for a photoresist and a chemically amplifying type resist composition obtained therefrom. The polymer has a number average molecular weight of from 1,000 to 1,000,000 and represented by the formula: -(M1)-(M2)-(A)-, wherein M1 is a structural unit having an acid-labile or acid-degradable functional group, M2 is a structural unit of fluorine-containing acryl ester, A is a structural unit derived from other copolymerizable monomer, the percent by mole ratio M1/M2 is 1 to 99/99 to 1 and the polymer comprises from 1 to 99% by mole of the structural unit M1, from 1 to 99% by mole of the structural unit M2 and from 0 to 98% by mole of the structural unit A1. The material for fluorine-containing base polymer comprises a fluorine-containing polymer having an acid-reactive group such as the above-mentioned polymer and is suitable for a photoresist, and the chemically amplifying type resist composition is obtained from those polymer and material.

Abstract translation: 提供了一种具有酸反应性基团的新型含氟聚合物，其具有对真空紫外区域（157nm）中的能量射线（放射线）的高透明性，并且还提供了含氟基础聚合物 由聚合物制备并适用于由其获得的光致抗蚀剂和化学放大型抗蚀剂组合物。 聚合物的数均分子量为1,000〜1,000,000，由下式表示： - （M1） - （M2） - （A） - ，其中M1是具有酸不稳定性或酸可降解官能团的结构单元 M2是含氟丙烯酸酯的结构单元，A是来自其它可共聚单体的结构单元，M1 / M2的摩尔比为1〜99/99〜1，聚合物的含量为1〜99％ 结构单元M1的摩尔数，结构单元M2的1〜99摩尔％和结构单元A1的0〜98摩尔％。 含氟基础聚合物的材料包括具有酸反应性基团的含氟聚合物如上述聚合物，并且适用于光致抗蚀剂，化学放大型抗蚀剂组合物由那些聚合物和材料获得。

公开(公告)号：US06893729B2

公开(公告)日：2005-05-17

申请号：US10203967

申请日：2001-02-19

Applicant: Takeshi Inaba ,  Taketo Kato ,  Shigehito Sagisaka ,  Takuya Arase ,  Tetsuo Shimizu

Inventor： Takeshi Inaba ,  Taketo Kato ,  Shigehito Sagisaka ,  Takuya Arase ,  Tetsuo Shimizu

IPC: B32B27/08 ,  B32B27/30 ,  C08L77/00

CPC classification number: B32B27/08 ,  B32B1/08 ,  B32B27/34 ,  B32B2377/00 ,  B32B2597/00 ,  B32B2605/08 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T428/1393 ,  Y10T428/31504 ,  Y10T428/3154 ,  Y10T428/31725 ,  Y10T428/31732 ,  Y10T428/31743

Abstract: The present invention is to provide a laminated resin molding comprising a polyamide-based resin composition as an outer layer and being excellent in interlayer adhesion strength, in particular a laminated resin molding comprising a fluorine-containing resin as an inner layer.The present invention is a laminated resin molding which comprises a layer (A) comprising a polyamide-based resin composition and a layer (B) laminated to said layer (A), said layer (B) comprising a fluorine-containing ethylenic polymer having a carbonyl group, and said polyamide-based resin composition having a functional group, in addition to an amide group, selected from the group consisting of hydroxyl group, carboxyl group, ester group and sulfonamide group in a total amount of 0.05 to 80 equivalent percent relative to the amide group.

Abstract translation: 本发明提供一种层叠树脂成型体，其包含聚酰胺类树脂组合物作为外层，层间粘合强度优异，特别是包含含氟树脂作为内层的层叠树脂成型体。 本发明是一种层叠树脂成型体，其包含层叠在所述层（A）上的层叠体（B）的聚酰胺系树脂组合物层（A）和所述层（B）的层（B），所述层（B）含有含氟乙烯系聚合物， 羰基，所述具有官能团的所述聚酰胺类树脂组合物除了选自羟基，羧基，酯基和磺酰胺基的酰胺基外，其总量相对于0.05〜80当量的总量 到酰胺基。

公开(公告)号：US06774196B1

公开(公告)日：2004-08-10

申请号：US10148230

申请日：2002-05-28

Applicant: Takahiro Taira ,  Takahisa Aoyama ,  Katsuhide Otani ,  Tetsuo Shimizu

Inventor： Takahiro Taira ,  Takahisa Aoyama ,  Katsuhide Otani ,  Tetsuo Shimizu

IPC: C08F11612

CPC classification number: C08L27/18 ,  C08F214/262

Abstract: To provide a novel PFA-based fluorine-containing copolymer having improved impermeability to liquid chemicals while retaining the excellent heat resistance, stress cracking resistance and processability inherent in PFA-based fluororesins, a material and a molded article useful in the field of semiconductor production apparatus and the like, using the copolymer. The present invention provides a fluorine-containing copolymer comprising 90 to 99.4% by mole of a repeating unit derived from tetrafluoroethylene, 0.5 to 5% by mole of a repeating unit derived from at least one lower perfluoro(alkyl vinyl ether) represented by the formula (1): CF2═CF—O—Rf1  (1) in which Rf1 is a perfluoroalkyl group having 2 to 4 carbon atoms, and 0.1 to 5% by mole of a repeating unit derived from at least one higher perfluoro(vinyl ether) represented by the formula (2): CF2═CF—O—Rf2  (2) in which Rf2 is a perfluoroalkyl group having 5 to 10 carbon atoms or a perfluoro(alkoxy alkyl) group having 4 to 17 carbon atoms, wherein the fluorine-containing copolymer has a melt flow rate of 0.1 g/10 minutes to 100 g/10 minutes and melting point of 290° to 325° C., and a resin composition using the same.

Abstract translation: 提供一种具有改善的对液体化学品的不渗透性的新型PFA基含氟共聚物，同时保持了PFA类氟树脂中固有的优异的耐热性，抗应力开裂性和加工性，可用于半导体制造装置领域的材料和模塑制品 等等，使用该共聚物。 本发明提供一种含有90〜99.4摩尔％的来自四氟乙烯的重复单元的含氟共聚物，0.5〜5摩尔％的由式（1）表示的至少一种以下的低级全氟（烷基乙烯基醚）的重复单元， （1）表示的化合物：其中Rf 1为碳原子数2〜4的全氟烷基，0.1〜5摩尔％的由式（2）表示的至少一种以上的全氟（乙烯基醚）的重复单元， ：其中Rf 2为碳原子数5〜10的全氟烷基或碳原子数4〜17的全氟（烷氧基烷基），其中，所述含氟共聚物的熔体流动速率为0.1g / 10分钟〜 100g / 10分钟，熔点为290〜325℃，使用该树脂组合物。

公开(公告)号：US06677044B2

公开(公告)日：2004-01-13

申请号：US09423895

申请日：1999-11-16

Applicant: Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

Inventor： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

IPC: B32B1508

CPC classification number: C08F214/184 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31547 ,  Y10T428/31678

Abstract: A composite material having sliding property is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above. The composite material having sliding property which is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.

Abstract translation: 通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料，制造具有滑动性的复合材料，该材料通过（a）将0.05〜30摩尔％的含氟乙烯性聚合物 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。 具有滑动性的复合材料，其通过向基材施加包含具有优异的粘附性的含氟聚合物的材料而不需要复杂的步骤而制备。