公开(公告)号：US20190233551A1

公开(公告)日：2019-08-01

申请号：US16377358

申请日：2019-04-08

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Randall S. Muninger ,  Qing Yang ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F4/6192 ,  C08L23/08 ,  C08F210/16 ,  C08J5/18 ,  C08F10/02 ,  C08F4/659 ,  C08F4/64

CPC classification number: C08F4/6192 ,  C08F4/64 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/02 ,  C08F210/16 ,  C08F2410/01 ,  C08F2420/04 ,  C08F2500/01 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0815 ,  C08L2207/068 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2500/10 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/26

Abstract: Disclosed herein are ethylene-based polymers generally characterized by a density from 0.89 to 0.93 g/cm3, a ratio of Mw/Mn from 3 to 6.5, a Mz from 200,000 to 650,000 g/mol, a CY-a parameter at 190° C. from 0.2 to 0.4, and a reverse short chain branching distribution. The ATREF profile of these polymers can have a high temperature peak from 92 to 102° C., and a low temperature peak from 18 to 36° C. less than that of the high temperature peak. These polymers can have comparable physical properties to that of a metallocene-catalyzed LLDPE, but with improved processability, shear thinning, and melt strength, and can be used in blown film and other end-use applications.

公开(公告)号：US10214603B2

公开(公告)日：2019-02-26

申请号：US15981489

申请日：2018-05-16

Applicant: Chevron Phillips Chemical Company LP

Inventor： Chung Tso ,  Carlos A. Cruz ,  Qing Yang ,  Max P. McDaniel ,  Jared L. Barr ,  Youlu Yu ,  Yongwoo Inn ,  Ashish M. Sukhadia ,  Brandy Rutledge-Ryal ,  Daniel G. Hert ,  Kelly Frey ,  Bill Bridendolph ,  William Fisher

IPC: C08F10/02 ,  C08J5/18 ,  B29D7/01 ,  B32B27/32 ,  C08F210/16 ,  C09D123/08 ,  C08J7/04 ,  B32B7/00 ,  B32B37/15 ,  B29C47/02 ,  B29C47/00 ,  B29C47/92 ,  C08F210/14

Abstract: A polyolefin having a density of greater than about 0.930 g/ml which when extruded at a temperature in the range of from about 590° F. to about 645° F. and then coated onto a substrate at a rate of from about 300 ft/min to about 1000 ft/min has an edge weave of from about 0 in/side to about 2.5 in/side and a neck-in of less than about 3.0 in/side.

公开(公告)号：US09975976B1

公开(公告)日：2018-05-22

申请号：US15489663

申请日：2017-04-17

Applicant: Chevron Phillips Chemical Company LP

Inventor： Chung Tso ,  Jared L. Barr ,  Kelly Frey ,  Carlos A. Cruz ,  Youlu Yu ,  Bill Bridendolph ,  Qing Yang ,  Yongwoo Inn ,  William Fisher ,  Max P. McDaniel ,  Ashish M. Sukhadia ,  Brandy Rutledge-Ryal ,  Daniel G. Hert

IPC: C08F210/16 ,  C09D123/08 ,  C08J7/04 ,  B32B7/00 ,  B32B27/32 ,  B32B37/15 ,  C08F210/14

CPC classification number: C08F210/16 ,  B29C47/025 ,  B32B7/005 ,  B32B27/327 ,  B32B37/153 ,  B32B2250/02 ,  B32B2307/72 ,  B32B2323/046 ,  C08F210/14 ,  C08F2500/26 ,  C08J7/047 ,  C08J2323/20 ,  C09D123/0815

Abstract: A polyolefin having a density of greater than about 0.930 g/ml which when extruded at a temperature in the range of from about 590° F. to about 645° F. and then coated onto a substrate at a rate of from about 300 ft/min to about 1000 ft/min has an edge weave of from about 0 in/side to about 2.5 in/side and a neck-in of less than about 3.0 in/side.

公开(公告)号：US09926393B2

公开(公告)日：2018-03-27

申请号：US15622114

申请日：2017-06-14

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Chung C. Tso ,  Youlu Yu ,  Qing Yang ,  Richard M. Buck

IPC: C08F4/00 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16 ,  C08F4/659

CPC classification number: C08F210/02 ,  C08F4/65912 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17 ,  C08F110/02

Abstract: Catalyst systems having both a metallocene catalyst component and a Ziegler-Natta component are disclosed. Such catalyst systems can contain a metallocene compound, an activator-support, an organoaluminum compound, and a Ziegler-Natta component comprising titanium supported on magnesium chloride.

公开(公告)号：US09879101B2

公开(公告)日：2018-01-30

申请号：US15425646

申请日：2017-02-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Youlu Yu ,  Eric D. Schwerdtfeger ,  Max P. McDaniel ,  Alan L. Solenberger ,  Kathy S. Clear

IPC: B01J23/26 ,  B01J35/10 ,  C08F110/02 ,  C08F10/02 ,  C08F210/02

CPC classification number: C08F110/02 ,  B01J23/26 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  C08F10/02 ,  C08F210/02 ,  C08F2500/04 ,  C08F2500/09 ,  C08F4/69 ,  C08F4/025

Abstract: A polymer having a long chain branching content peaking at greater than about 20 long chain branches per million carbon atoms, and a polydispersity index of greater than about 10 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution. A polymer having a long chain branching content peaking at greater than about 8 long chain branches per million carbon atoms, a polydispersity index of greater than about 20 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution. A polymer having a long chain branching content peaking at greater than about 1 long chain branches per chain, and a polydispersity index of greater than about 10 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution.

公开(公告)号：US09845367B2

公开(公告)日：2017-12-19

申请号：US14863698

申请日：2015-09-24

Applicant: Chevron Phillips Chemical Company LP

Inventor： Errun Ding ,  Jeffrey F. Greco ,  Qing Yang ,  Youlu Yu

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/10 ,  C08F4/6543 ,  C08F4/025

Abstract: Catalyst systems containing a Ziegler-Natta catalyst component are disclosed. Such catalyst systems can contain a co-catalyst and a supported catalyst containing a fluorided silica-coated alumina, a magnesium compound, and vanadium and/or tetravalent titanium.

公开(公告)号：US20170145124A1

公开(公告)日：2017-05-25

申请号：US15425646

申请日：2017-02-06

Applicant: Chevron Phillips Chemical Company LP

Inventor： Youlu Yu ,  Eric D. Schwerdtfeger ,  Max P. McDaniel ,  Alan L. Solenberger ,  Kathy S. Clear

IPC: C08F110/02

CPC classification number: C08F110/02 ,  B01J23/26 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  C08F10/02 ,  C08F210/02 ,  C08F2500/04 ,  C08F2500/09 ,  C08F4/69 ,  C08F4/025

Abstract: A polymer having a long chain branching content peaking at greater than about 20 long chain branches per million carbon atoms, and a polydispersity index of greater than about 10 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution. A polymer having a long chain branching content peaking at greater than about 8 long chain branches per million carbon atoms, a polydispersity index of greater than about 20 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution. A polymer having a long chain branching content peaking at greater than about 1 long chain branches per chain, and a polydispersity index of greater than about 10 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution.

公开(公告)号：US20170114169A1

公开(公告)日：2017-04-27

申请号：US15397805

申请日：2017-01-04

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Jeff F. Greco ,  Max P. McDaniel ,  Youlu Yu ,  Gary L. Glass ,  Tony R. Crain

IPC: C08F210/16

CPC classification number: C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/02 ,  C08F110/02 ,  C08F210/08 ,  C08F210/14 ,  C08L23/0815 ,  C08F4/025 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/04

Abstract: Disclosed herein are ethylene-based polymers having a melt index less than 50 g/10 min, a ratio of Mw/Mn from 4 to 20, a density from 0.90 to 0.945 g/cm3, and a substantially constant short chain branch distribution. These polymers can be produced using a dual catalyst system containing a boron bridged metallocene compound with a cyclopentadienyl group and an indenyl group, and a single atom bridged metallocene compound with a fluorenyl group.

公开(公告)号：US09598513B2

公开(公告)日：2017-03-21

申请号：US14676581

申请日：2015-04-01

Applicant: Chevron Phillips Chemical Company LP

Inventor： Youlu Yu ,  Eric D. Schwerdtfeger ,  Max P. McDaniel ,  Alan L. Solenberger ,  Kathy S. Clear

IPC: C08F110/02 ,  C08F10/02 ,  C08F210/02

CPC classification number: C08F110/02 ,  B01J23/26 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  C08F10/02 ,  C08F210/02 ,  C08F2500/04 ,  C08F2500/09 ,  C08F4/69 ,  C08F4/025

Abstract: A polymer having a long chain branching content peaking at greater than about 20 long chain branches per million carbon atoms, and a polydispersity index of greater than about 10 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution. A polymer having a long chain branching content peaking at greater than about 8 long chain branches per million carbon atoms, a polydispersity index of greater than about 20 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution. A polymer having a long chain branching content peaking at greater than about 1 long chain branches per chain, and a polydispersity index of greater than about 10 wherein the long chain branching decreases to approximately zero at the higher molecular weight portion of the molecular weight distribution.

公开(公告)号：US20160017069A1

公开(公告)日：2016-01-21

申请号：US14870361

申请日：2015-09-30

Applicant: Chevron Phillips Chemical Company LP

Inventor： Qing Yang ,  Max P. McDaniel ,  Tony R. Crain ,  Youlu Yu ,  Yongwoo Inn

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/00 ,  C08F210/16 ,  C08L23/00 ,  C08L23/0815 ,  C08L2314/06 ,  Y10S526/943 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/05 ,  C08F210/14 ,  C08L23/06

Abstract: Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.

Abstract translation: 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法使用含有三种茂金属组分的催化剂体系，其常常导致聚合物具有反向共聚单体分布和广泛的和非双峰分子量分布。