公开(公告)号：US20110073167A1

公开(公告)日：2011-03-31

申请号：US12993426

申请日：2009-05-21

申请人： Hidenori Ozaki ,  Kenji Kawasaki ,  Tatsuya Higuchi ,  Takayuki Araki

发明人： Hidenori Ozaki ,  Kenji Kawasaki ,  Tatsuya Higuchi ,  Takayuki Araki

IPC分类号： H01L31/048 ,  C08F114/18

CPC分类号： C08L27/20 ,  B29K2027/12 ,  B32B7/12 ,  B32B27/08 ,  B32B27/16 ,  B32B27/20 ,  B32B27/322 ,  B32B27/36 ,  B32B2250/02 ,  B32B2250/24 ,  B32B2264/102 ,  B32B2264/108 ,  B32B2270/00 ,  B32B2307/4026 ,  B32B2307/41 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2307/7246 ,  B32B2307/734 ,  B32B2310/14 ,  B32B2457/12 ,  C08J5/18 ,  C08J2327/02 ,  C08K3/22 ,  C08L27/04 ,  C08L27/12 ,  C08L27/18 ,  C09D5/32 ,  H01L31/049 ,  Y02E10/50

摘要： The present invention provides a polychlorotrifluoroethylene film having ultraviolet shielding ability, moisture resistance and small absolute values of thermal deformation rates. The present invention is a polychlorotrifluoroethylene film having an ultraviolet shield rate of not lower than 70%, a water vapor transmission rate of not higher than 1.00 g/m2·day and absolute values of thermal deformation rates after 30 minutes-heating at 150° C. of not higher than 5.0%.

摘要翻译： 本发明提供具有紫外线屏蔽能力，耐湿性和热变形率绝对值小的聚氯三氟乙烯膜。 本发明是紫外线屏蔽率不低于70％，水蒸气透过率不高于1.00g / m 2·天的聚氯三氟乙烯膜和在150℃加热30分钟后的热变形率的绝对值 不高于5.0％。

公开(公告)号：US07655742B2

公开(公告)日：2010-02-02

申请号：US11231992

申请日：2005-09-22

申请人： Takayuki Araki ,  Tetsuhiro Kodani

发明人： Takayuki Araki ,  Tetsuhiro Kodani

IPC分类号： C08F14/18

CPC分类号： C08F114/22 ,  C07C21/18 ,  Y10T428/3154 ,  Y10T428/31544

摘要： There is provided a method of forming a thin film of vinylidene fluoride homopolymer having crystal form I which is applicable to various substrates in relatively easy way (coating conditions, application method, etc.), a process for preparing a vinylidene fluoride homopolymer having crystal form I efficiently at high purity, and novel vinylidene fluoride homopolymers which can give a thin film being excellent in ferroelectricity. The method of forming a thin film of vinylidene fluoride homopolymer comprises (i) a step for preparing a green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component by subjecting vinylidene fluoride to radical polymerization in the presence of a bromine compound or iodine compound having 1 to 20 carbon atoms which contains at least one moiety represented by —CRf1Rf2X1, wherein X1 is iodine atom or bromine atom; Rf1 and Rf2 are the same or different and each is selected from fluorine atom or perfluoroalkyl groups having 1 to 5 carbon atoms and (ii) a step for forming a thin film on a substrate surface by using vinylidene fluoride homopolymer which comprises crystal form I alone or as main component and is obtained from the green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component.

摘要翻译： 提供一种以相对容易的方式（涂布条件，涂布方法等）形成可以适用于各种基材的结晶形式I的偏二氟乙烯均聚物的薄膜的方法，制备具有结晶形式的偏二氟乙烯均聚物 我高效率地得到高纯度的新型偏二氟乙烯均聚物，可以得到铁电性优异的薄膜。 形成偏氟乙烯均聚物薄膜的方法包括（i）通过在溴化合物的存在下使偏二氟乙烯进行自由基聚合，制备单晶或单体晶形的偏二氟乙烯均聚物的生粉产物的步骤 或含有至少一个由-CR f 1 R f 2 X 1表示的部分的碳原子数为1〜20的碘化合物，其中X1为碘原子或溴原子; Rf1和Rf2相同或不同，分别选自具有1〜5个碳原子的氟原子或全氟烷基，（ii）通过使用仅含有晶型I的偏二氟乙烯均聚物在基板表面上形成薄膜的步骤 或作为主要成分，并且由包含单晶晶体I或主要成分的偏二氟乙烯均聚物的绿色粉末产品获得。

公开(公告)号：US20090291369A1

公开(公告)日：2009-11-26

申请号：US12471860

申请日：2009-05-26

申请人： Takayuki Araki ,  Meiten Koh

发明人： Takayuki Araki ,  Meiten Koh

IPC分类号： H01M6/18 ,  H01G9/028

CPC分类号： H01G9/028 ,  H01B1/122 ,  H01G9/038 ,  H01G11/56 ,  H01M8/0289 ,  H01M8/1023 ,  H01M8/1039 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0082 ,  Y02E60/13

摘要： There is provided a fluorine-containing polymer solid electrolyte which has an excellent ion-conducting property, is high in oxidation resistance, is stable electrochemically and thermally, has sufficient strength and is applicable to various electrochemical devices. The electrolyte comprises (I) a non-crystalline fluorine-containing polymer which has a polar nonionic functional group and has, in a side chain of the polymer molecule, a structural unit D having 1 to 4 units derived from a fluorine-containing ether in the form of continuous chain, (II) an electrolytic compound and as case demands, (III) a solvent. The electrolyte has an ionic conductivity of from 10−10 to 101 S/cm measured at 25° C. by an alternating current complex impedance method, and is useful for various electrochemical devices.

摘要翻译： 提供了具有优异的离子传导性，耐氧化性高，电化学和热稳定性好的含氟聚合物固体电解质，具有足够的强度并适用于各种电化学装置。 电解质包含（I）具有极性非离子官能团的非结晶性含氟聚合物，在聚合物分子的侧链中，具有1〜4个由含氟醚衍生的单元的结构单元D 连续链的形式，（II）电解化合物，如果需要，（III）溶剂。 电解质在25℃下通过交流复阻抗法测得的10-10至101S / cm的离子电导率，并且可用于各种电化学装置。

公开(公告)号：US07517548B2

公开(公告)日：2009-04-14

申请号：US11231976

申请日：2005-09-22

申请人： Takayuki Araki ,  Tetsuhiro Kodani

发明人： Takayuki Araki ,  Tetsuhiro Kodani

IPC分类号： B05D5/12 ,  B05D1/12

CPC分类号： C08F14/22 ,  H01L41/317 ,  H01L41/45

摘要： A method of forming a ferroelectric thin film containing vinylidene fluoride homopolymer, including the steps of (i) preparing a green powder of vinylidene fluoride homopolymer of crystal form I alone or as main component by subjecting vinylidene fluoride to radical polymerization in the presence of a radical polymerization initiator, (ii) forming a thin film on a substrate surface by using vinylidene fluoride homopolymer of crystal form I alone or as main component obtained from the green powder product of vinylidene fluoride homopolymer of I-form crystal structure alone or as main component, and (iii) subjecting the thin film of vinylidene fluoride homopolymer formed in step (ii) above to polarization.

摘要翻译： 一种形成含有偏二氟乙烯均聚物的铁电薄膜的方法，包括以下步骤：（i）通过在基团存在下使偏二氟乙烯进行自由基聚合，制备单晶晶形I偏二氟乙烯均聚物或主要成分的绿色粉末 聚合引发剂，（ii）通过单独使用晶型I的偏二氟乙烯均聚物或作为主要成分在I型晶体结构的偏二氟乙烯均聚物的主要成分中作为主要成分，在基板表面上形成薄膜， 和（iii）使上述步骤（ii）中形成的偏二氟乙烯均聚物的薄膜经极化。

公开(公告)号：US20070218289A1

公开(公告)日：2007-09-20

申请号：US11578054

申请日：2005-03-11

申请人： Yoshito Ando ,  Takayuki Araki

发明人： Yoshito Ando ,  Takayuki Araki

IPC分类号： B32B27/30 ,  B32B7/02

CPC分类号： H05B33/20 ,  C09K11/06 ,  C09K2211/182 ,  H01L51/0089 ,  Y10T428/31504 ,  Y10T428/3154

摘要： There is provided a photofunctional laminated article being excellent in various photofunctionalities, particularly an intensity of light emission, light emitting efficiency and further fluorescence life and light amplifying property. The photofunctional laminated article comprises the transparent substrate (L0), the photofunctional layer (L1) comprising the fluorine-containing polymer (A) and the rare earth metal compound (B) and being formed on the substrate (L0) and the low refractive index layer (L2) formed on the photofunctional layer (L1), and when refractive indices of each layer are assumed to be n(L0), n(L1) and n(L2), the following equation: n(L0)≧n(L1)>n(L2) is satisfied.

摘要翻译： 提供了各种光功能特别优异的发光强度，发光效率和荧光寿命以及光放大性能的光功能性层压制品。 光功能性层压制品包括透明基材（L0），包含含氟聚合物（A）和稀土金属化合物（B）的光官能层（L1）并形成在基材（L0）上，低折射率 形成在光功能层（L1）上的层（L2），并且当各层的折射率被假设为n（L0），n（L1）和n（L2）时，下列等式：n（L0）> = n （L1）> n（L2）。

公开(公告)号：US07262252B2

公开(公告)日：2007-08-28

申请号：US10704829

申请日：2003-11-12

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

IPC分类号： F21V9/04 ,  C07D211/78 ,  C07D211/90 ,  C08F20/02 ,  C08F4/34 ,  C08F226/06 ,  C09K19/52

CPC分类号： G02F1/3615 ,  G02F1/3616 ,  G02F1/3617

摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.

摘要翻译： 提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键 并且还提供了由含氟树脂组合物制造的非线性光波导器件。 产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

公开(公告)号：US20070172763A1

公开(公告)日：2007-07-26

申请号：US11727908

申请日：2007-03-29

申请人： Takayuki Araki ,  Yuzo Komatsu ,  Meiten Koh

发明人： Takayuki Araki ,  Yuzo Komatsu ,  Meiten Koh

IPC分类号： G03C1/00 ,  C08F12/20 ,  C07C43/17

CPC分类号： G03F7/091 ,  C07C33/423 ,  C07C43/178 ,  C07C45/45 ,  C07C49/227 ,  C07C49/255 ,  C08F16/04 ,  C08F16/34 ,  C08F216/04 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392

摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.

公开(公告)号：US20070135667A1

公开(公告)日：2007-06-14

申请号：US10576854

申请日：2004-10-20

申请人： Takayuki Araki ,  Koichi Fukuda ,  Kenji Kato

发明人： Takayuki Araki ,  Koichi Fukuda ,  Kenji Kato

IPC分类号： C10G1/10 ,  C07C4/00

CPC分类号： B29B17/02 ,  B29B2017/0496 ,  B29K2027/06 ,  C08J11/12 ,  C10B53/07 ,  C10B57/04 ,  Y02P20/143 ,  Y02W30/622 ,  Y02W30/625 ,  Y02W30/703 ,  Y10S264/911

摘要： The present invention provides a method of reutilization and method of shaping of waste plastic which reduces the amount of volatile ingredients and oil cake* to extents preferable as materials for coke ovens, enables the formation of plastic granular materials able to maintain suitable shapes even after charging into a coke oven, and does not require expensive facilities for treating any produced hydrogen chloride gas, that is, a method of reutilization of waste plastic characterized by melting waste plastic at over 160° C. to 250° C. in temperature in part or whole, compression shaping it to thereby obtain a plastic granular material having an apparent density of 0.7 to 1.2 kg/liter, and mixing this plastic granular material with coal for dry distillation in a coke oven. By bringing the gas produced at the time of compression shaping the waste plastic into contact with water or an ammonia solution and combining the water or ammonia solution with an ammonia solution of an ammonia solution treatment facility attached to the coke furnace, it is possible to remove the hydrogen chloride contained in the produced gas.

摘要翻译： 本发明提供一种再利用方法和废塑料成型方法，其将挥发成分和油饼*的量优选为焦化炉的材料，使得能够形成即使在充电之后能够保持合适形状的塑料颗粒材料 并且不需要昂贵的设备来处理任何产生的氯化氢气体，也就是废旧塑料的再利用方法，其特征在于废塑料在160℃至250℃的温度下部分熔化，部分或部分温度 全部进行压缩成型，得到表观密度为0.7〜1.2kg / l的塑料颗粒状材料，并将该塑料颗粒材料与焦炉中的干馏混合。 通过将废塑料压缩成型时产生的气体与水或氨溶液接触并将水或氨溶液与附着在焦炉上的氨溶液处理设备的氨溶液结合，可以除去 生成气体中所含的氯化氢。

公开(公告)号：US07211635B2

公开(公告)日：2007-05-01

申请号：US10654971

申请日：2003-09-05

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi

IPC分类号： C08F16/24

CPC分类号： C08K5/0091 ,  C08K5/098 ,  G02B6/1221 ,  H01S3/17 ,  H01S3/178 ,  C08L27/12

摘要： There can be obtained a suitable optical material which has a stable structure with a rare earth metal ion while maintaining transparency in a region of from visible light to near infrared light. The optical material is obtained by curing a fluorine-containing resin composition comprising (I) a fluorine-containing prepolymer and (II) a compound containing a rare earth metal ion and/or a rare earth metal element, wherein the fluorine-containing prepolymer (I) is a curable fluorine-containing polymer which: (1) is a non-crystalline polymer having a fluorine content of not less than 25% by weight and (2) has a cure site in a side chain of the polymer and/or at an end of a trunk chain of the polymer.

摘要翻译： 可以获得具有稀土金属离子稳定结构的合适的光学材料，同时保持从可见光到近红外光的区域的透明度。 光学材料通过固化含有（I）含氟预聚物和（II）含有稀土金属离子和/或稀土金属元素的化合物的含氟树脂组合物而获得，其中含氟预聚物（ I）是可固化的含氟聚合物，其中：（1）是氟含量不小于25重量％的非结晶聚合物，和（2）在聚合物的侧链中具有固化位点和/或 在聚合物的主链的末端。

公开(公告)号：US07106940B2

公开(公告)日：2006-09-12

申请号：US11043204

申请日：2005-01-27

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi

IPC分类号： G02B6/138 ,  G03C1/73

CPC分类号： C08F299/00 ,  C08F290/00 ,  G02B6/1221

摘要： There is provided a material which can give a high elasticity and heat resistance to an optical waveguide member by photo-curing while maintaining transparency in a near infrared region and further makes it possible to use a film forming process by a spin coating method and a process for producing a waveguide by photolithograph, to obtain a waveguide having a large area and to produce an optical waveguide having reduced water absorption, and further there can be provided an optical waveguide member and an optical waveguide device. Namely, there are provided a fluorine-containing optical waveguide material comprising a curable fluorine-containing prepolymer (I) which is a non-crystalline polymer having a fluorine content of not less than 25% by weight and has a carbon-carbon double bond in a polymer side chain and/or at an end of a polymer trunk chain, an optical waveguide member which is a cured article of the optical waveguide material and an optical waveguide device comprising the optical waveguide member.

摘要翻译： 提供了一种能够通过光固化赋予光波导构件高弹性和耐热性的材料，同时保持近红外区域的透明性，并且还可以通过旋涂法和方法使用成膜方法 通过光刻制造波导，得到面积大的波导管，制造吸水率降低的光波导，并且还可以提供光波导部件和光波导器件。 即，提供了含氟系预聚物（I）的含氟光波导材料，其为氟含量为25重量％以上且具有碳 - 碳双键的非结晶性聚合物 聚合物侧链和/或在聚合物主链的末端，作为光波导材料的固化物的光波导部件和包括光波导部件的光波导装置。