公开(公告)号：US4854963A

公开(公告)日：1989-08-08

申请号：US198030

申请日：1988-05-24

申请人： Werner Fory ,  Willy Meyer

发明人： Werner Fory ,  Willy Meyer

IPC分类号： A01N47/36 ,  C07D521/00

CPC分类号： C07D521/00 ,  A01N47/36

摘要： N-(3,4-Dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-pyrimidinylureas, N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-yl-sulfonyl)-N'-triazolylureas and N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-triazinylureas of the formula ##STR1## wherein R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.4 is hydrogen, methyl or ethyl,W is oxygen or sulfur, andA is a radical ##STR2## in which formulae the substituents E.sup.1, E.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.6, Y.sup.6 1, Y.sup.8, Y.sup.8 1, Z.sup.3 and Z.sup.5 are customary organic radicals,and the salts thereof with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good pre- and postemergence selective herbicidal and growth regulating properties.

摘要翻译： N-（3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基）-N'-嘧啶基脲，N-（3,4-二氢-2,2-二氧代-1,2 - 苯并恶嗪-8-基 - 磺酰基）-N'-三唑基和N-（3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基）-N'-三嗪基脲， （I）其中R1是氢，卤素，硝基，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷氧基羰基，C1-C4烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基或C2-C5烷氧基烷氧基 中，R 2和R 3各自独立地为氢或C 1 -C 4烷基，R 4为氢，甲基或乙基，W为氧或硫，并且A为基团 + TR 取代基E1，E2，X1，X2，X3，X4，X5，X6，X7，X8，Y1，Y2，Y3，Y4，Y6，Y6 1，Y8，Y8 1，Z3和Z5为式 常规有机基团及其与胺，碱金属碱或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质 ies。

公开(公告)号：US4759791A

公开(公告)日：1988-07-26

申请号：US872799

申请日：1986-06-11

申请人： Werner Fory ,  Willy Meyer

发明人： Werner Fory ,  Willy Meyer

IPC分类号： A01N47/36 ,  C07D521/00 ,  C07D411/12 ,  A01N43/54

CPC分类号： C07D521/00 ,  A01N47/36

摘要： N-(3,4-Dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-pyrimidinylureas, N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-yl-sulfonyl)-N'-triazolylureas and N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-triazinylureas of the formula ##STR1## wherein R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.4 is hydrogen, methyl or ethyl,W is oxygen or sulfur, andA is a radical ##STR2## in which formulae the substituents E.sup.1, E.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.6, Y.sup.61, Y.sup.8, Y.sup.81, Z.sup.3 and Z.sup.5 are customary organic radicals,and the salts thereof with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good pre- and postemergence selective herbicidal and growth regulating properties.

摘要翻译： N-（3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基）-N'-嘧啶基脲，N-（3,4-二氢-2,2-二氧代-1,2 - 苯并恶嗪-8-基 - 磺酰基）-N'-三唑基和N-（3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基）-N'-三嗪基脲， （I）其中R1是氢，卤素，硝基，C1-C4烷基，C1-C4卤代烷基，C1-C4-烷氧基，C1-C4卤代烷氧基，C1-C4烷氧基羰基，C1-C4烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基或C2- C5烷氧基烷氧基，R2和R3各自独立地为另一个氢或C 1 -C 4烷基，R 4是氢，甲基或乙基，W是氧或硫，A是基团。 + TR 其中取代基E1，E2，X1，X2，X3，X4，X5，X6，X7，X8，Y1，Y2，Y3，Y4，Y6，Y61，Y8，Y81，Z3和Z5分别为 常规有机基团及其与胺，碱金属碱或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节特性 s。

公开(公告)号：US4739068A

公开(公告)日：1988-04-19

申请号：US887762

申请日：1986-07-21

申请人： Karl Gass ,  Werner Fory ,  Willy Meyer ,  Werner Topfl

发明人： Karl Gass ,  Werner Fory ,  Willy Meyer ,  Werner Topfl

IPC分类号： C07D251/16 ,  A01N47/36 ,  C07D211/22 ,  C07D213/30 ,  C07D213/64 ,  C07D213/643 ,  C07D239/42 ,  C07D251/46 ,  C07D251/52 ,  C07D301/14 ,  C07D303/22 ,  C07D307/12 ,  C07D309/06 ,  C07D317/22 ,  C07D333/16 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D521/00 ,  C07D213/63 ,  C07D319/06

CPC分类号： C07D213/30 ,  C07D213/643 ,  C07D301/14 ,  C07D303/22 ,  C07D307/12 ,  C07D309/06 ,  C07D317/22 ,  C07D333/16 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and --N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.

摘要翻译： 具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物 应用芽前和芽后的生长调节性质。 式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素 原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自是未取代的或被C1-C4烷基取代，m是0或1，E是氮或次甲基， X是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基， 磺酸和羧酸，该基团可进一步被取代并具有官能结构。

公开(公告)号：US4726836A

公开(公告)日：1988-02-23

申请号：US887759

申请日：1986-07-21

申请人： Karl Gass ,  Werner Fory ,  Willy Meyer ,  Werner Topfl

发明人： Karl Gass ,  Werner Fory ,  Willy Meyer ,  Werner Topfl

IPC分类号： C07D251/16 ,  A01N47/36 ,  C07D211/22 ,  C07D213/30 ,  C07D213/64 ,  C07D213/643 ,  C07D239/42 ,  C07D251/46 ,  C07D251/52 ,  C07D301/14 ,  C07D303/22 ,  C07D307/12 ,  C07D309/06 ,  C07D317/22 ,  C07D333/16 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D521/00 ,  A01N43/54 ,  C07D239/69

CPC分类号： C07D213/30 ,  C07D213/643 ,  C07D301/14 ,  C07D303/22 ,  C07D307/12 ,  C07D309/06 ,  C07D317/22 ,  C07D333/16 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.2 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.

摘要翻译： 具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物 应用芽前和芽后的生长调节性质。 式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5链烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 2烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素 原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸的基团 酸和羧酸，该基团可以进一步被取代并具有官能结构。

公开(公告)号：US4690707A

公开(公告)日：1987-09-01

申请号：US784446

申请日：1985-10-04

申请人： Werner Fory ,  Karl Gass ,  Willy Meyer

发明人： Werner Fory ,  Karl Gass ,  Willy Meyer

IPC分类号： C07D401/12 ,  A01N47/36 ,  C07D213/71 ,  C07D213/72 ,  C07D213/73 ,  C07D213/74 ,  C07D521/00 ,  C07D251/18 ,  A01N43/66 ,  A01N43/70

CPC分类号： C07D213/73 ,  A01N47/36 ,  C07D213/71 ,  C07D213/72 ,  C07D213/74 ,  C07D521/00

摘要： The invention relates to N-pyridylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas of the formula I ##STR1## wherein A is a C.sub.3 -C.sub.6 alkynyl radical, a C.sub.1 -C.sub.6 alkyl radical which is substituted by halogen, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 haloalkylsulfinyl or C.sub.1 -C.sub.4 haloalkylsulfonyl, or is a C.sub.2 -C.sub.4 alkenyl radical which is unsubstituted or substituted as for C.sub.1 -C.sub.6 alkyl, or is a phenyl radical which is unsubstituted or substituted by halogen, cyano, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, an --X--C.sub.1 --C.sub.4 --alkyl, C.sub.1 -C.sub.4 alkoxycarbonyl, amino, mono- or di-(C.sub.1 -C.sub.4 alkyl)amino, carbamoyl, mono- or di-(C.sub.1 -C.sub.4 alkyl)carbamoyl, sulfamoyl, mono- or di-(C.sub.1 -C.sub.4 alkyl)sulfamoyl radical orA--X-- forms an amino radical --NR.sub.6 R.sub.7,E is the methine group or nitrogen,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.2 -C.sub.5 alkoxyalkoxy, C.sub.1 -C.sub.5 alkylthio, C.sub.1 -C.sub.5 alkylsulfinyl or C.sub.1 -C.sub.5 alkylsulfonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl which is unsubstituted or substituted by 1 to 3 halogen atoms, or is C.sub.1 -C.sub.2 alkoxy,R.sub.3 is hydrogen, halogen, an amino group --NR.sub.4 R.sub.5, or C.sub.1 -C.sub.3 alkyl which is unsubstituted or substituted by 1 to 3 halogen atoms, or is C.sub.1 -C.sub.4 alkoxy which is unsubstituted or substituted by methoxy, ethoxy or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,R.sub.6 and R.sub.7 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 alkoxyalkyl, C.sub.1 -C.sub.4 cyanoalkyl, or both together with the nitrogen atom to which they are attached also form a saturated 5- or 6-membered heterocyclic ring system which may also contain oxygen, sulfur or an --NR.sub.8 radical,R.sub.8 is hydrogen, C.sub.1 -C.sub.4 alkyl or benzyl, andX is oxygen, sulfur, or a sulfinyl or sulfonyl bridgeand to the salts thereof with amines, alkali metal bases or alkaline earth metal bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

公开(公告)号：US4685961A

公开(公告)日：1987-08-11

申请号：US699388

申请日：1985-02-07

申请人： Werner Topfl ,  Willy Meyer ,  Hans-Dieter Schneider

发明人： Werner Topfl ,  Willy Meyer ,  Hans-Dieter Schneider

IPC分类号： A01N47/36 ,  C07D239/42 ,  C07D239/46 ,  C07D239/48 ,  C07D239/52 ,  C07D249/08 ,  C07D251/52 ,  C07D403/12 ,  C07D521/00 ,  C07D239/69 ,  A01N43/54 ,  A01N43/707

CPC分类号： C07D239/42 ,  A01N47/36 ,  C07D231/12 ,  C07D233/56 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D249/08 ,  C07D251/52 ,  C07D403/12 ,  C07D521/00

摘要： Novel substituted N-sulfonyl-N'-pyrimidinylureas or N-sulfonyl-N'-triazinylureas of the formula I ##STR1## have good pre- and postemergence selective herbicidal and growth regulating properties.In this formula E is nitrogen or --CH.dbd., the group ##STR2## is a phenyl, naphthyl, furyl, thiophenyl, pyrrole or pyridinyl radical which is substituted in accordance with the definitions ofR.sup.1 and R.sup.2,R.sup.3 and R.sup.4 are hydrogen, lower alkyl or lower alkoxy, or one of R.sup.3 and R.sup.4 may also be halogen, lower alkenyl, lower haloalkenyl, lower haloalkoxy, amino, lower alkylamino, --CH(OCH.sub.3).sub.2, a cyclised ketal group or a saturated 5- to 7-membered heterocycle which is bound through the nitrogen atom,R.sup.5 is hydrogen, lower alkyl, lower haloalkyl, or an unsubstituted or substituted phenyl, benzyl or naphthyl radical, andR.sup.6 is an alkyl, acyl or acylamido radical which is bound through sulfur or a sulfinyl or sulfonyl group and is as defined in the description, or is a 5- to 7-membered heterocyclic amino radical which is bound through the nitrogen atom.These compounds are particularly suitable for selectively controlling weeds in crops of cereals.

摘要翻译： 式I（I）的新型取代的N-磺酰基-N'-嘧啶基或N-磺酰基-N'-三嗪基脲具有良好的芽前和芽后选择性除草和生长调节性质。 在该式中，E是氮或-CH =，根据R1和R2的定义被取代的苯基，萘基，呋喃基，噻吩基，吡咯基或吡啶基，R3和R4是氢，低级 烷基或低级烷氧基，或者R 3和R 4中的一个也可以是卤素，低级链烯基，低级卤代烯基，低级卤代烷氧基，氨基，低级烷基氨基，-CH（OCH 3）2，环化的缩酮基或饱和的5-至7-元 通过氮原子结合的杂环，R5是氢，低级烷基，低级卤代烷基或未取代或取代的苯基，苄基或萘基，R6是通过硫或亚磺酰基结合的烷基，酰基或酰基酰氨基， 磺酰基，如描述中所定义，或是通过氮原子结合的5-至7-元杂环氨基。 这些化合物特别适用于选择性地控制谷物作物中的杂草。

公开(公告)号：US4668800A

公开(公告)日：1987-05-26

申请号：US708204

申请日：1985-03-04

申请人： Willy Meyer ,  Werner F/o/ ry ,  Werner T/o/ pfl

发明人： Willy Meyer ,  Werner F/o/ ry ,  Werner T/o/ pfl

IPC分类号： C07D251/16 ,  A01N47/36 ,  C07C67/00 ,  C07C301/00 ,  C07C303/36 ,  C07C311/53 ,  C07C325/00 ,  C07C333/12 ,  C07D239/42 ,  C07D239/47 ,  C07D333/38 ,  C07D521/00 ,  C07D333/32 ,  C07C147/13 ,  C07C155/02 ,  C07D333/34

CPC分类号： C07D521/00 ,  C07D333/38

摘要： There is described a process for producing sulfonylureas of the formula ##STR1## wherein G is an unsubstituted or substituted furanyl, thienyl, pyrrolyl, pyridinyl or phenyl radical,X is alkyl, haloalkyl, alkoxy, alkylthio, halogen, haloalkoxy, alkylamino or dialkylamino,Y is alkyl, alkoxy or haloalkoxy,Z is a nitrogen atom or the methyne group --CH.dbd..This novel process comprises reacting a sulfonamide of the formulaG--SO.sub.2 --NH.sub.2,in the presence of a base, with a chloroformic acid ester of the formulaCl--CO--Q--T,or a sulfonyl chloride of the formulaG--SO.sub.2 Cl,in the presence of a base, with a urethane of the formulaH.sub.2 N--CO--Q--T;and converting the formed carbamate of the formulaG--SO.sub.2 --NH--CO--Q--Tby reaction with an amine of the formula ##STR2## into the sulfonylurea of the above formula. There are also described novel sulfonylcarbamates of the above formula as intermediates.

摘要翻译： 描述了一种制备式IMA的磺酰脲的方法，其中G是未取代或取代的呋喃基，噻吩基，吡咯基，吡啶基或苯基，X是烷基，卤代烷基，烷氧基，烷硫基，卤素，卤代烷氧基，烷基氨基或二烷基氨基， Y是烷基，烷氧基或卤代烷氧基，Z是氮原子或甲炔基-CH =。 该新方法包括使式G-SO 2 -NH 2的磺酰胺在碱的存在下与式Cl-CO-QT的氯甲酸酯或式G-SO 2 Cl的磺酰氯反应， 碱的存在与式H2N-CO-QT的氨基甲酸酯反应; 并且通过与下式的磺酰脲反应将式G-SO 2 -NH-CO-Q-T的所形成的氨基甲酸酯转化为式（I）所示的磺酰脲。 还描述了上述式的新型磺酰基氨基甲酸酯作为中间体。

公开(公告)号：US4643760A

公开(公告)日：1987-02-17

申请号：US676905

申请日：1984-11-30

申请人： Willy Meyer ,  Werner Fory

发明人： Willy Meyer ,  Werner Fory

IPC分类号： C07D251/16 ,  A01N47/36 ,  C07D213/70 ,  C07D213/71 ,  C07D239/47 ,  C07D239/52 ,  C07D251/46 ,  C07D401/12 ,  C07D521/00 ,  C07D239/46

CPC分类号： C07D213/70 ,  A01N47/36 ,  C07D521/00

摘要： Substituted N-arylsulfonyl-N'-pyrimidinylureas and N-arylsulfonyl-N'-triazinylureas of the general formula ##STR1## wherein R.sup.1 is a ##STR2## R.sup.2 is hydrogen, halogen, nitro, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or --COOR.sup.9,R.sup.3 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,R.sup.4 and R.sup.5 are each independently of the other hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkylthio, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.3 -C.sub.6 -cycloalkyl or --NR.sup.10 R.sup.11,R.sup.6 is hydrogen or C.sub.1 -C.sub.3 alkyl,R.sup.7 is hydrogen or methyl,R.sup.8 is C.sub.4 -C.sub.6 cycloalkanonyl which is unsubstituted or substituted by C.sub.1 -C.sub.3 alkyl or halogen; C.sub.3 -C.sub.6 cycloalkyl which is unsubstituted or substituted by one or more identical or different members selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy, halogen or cyano; or is C.sub.5 -C.sub.6 cycloalkenyl which is unsubstituted or substituted by C.sub.1 -C.sub.3 alkyl, halogen or cyano,R.sup.9 is C.sub.1 -C.sub.3 alkyl or allyl,R.sup.10 and R.sup.11 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl,n is 0 or 1,X is sulfur or oxygen, andE and Z are each independently of the other nitrogen or the methine bridge, with the proviso that R.sup.8 is only unsubstituted or substituted C.sub.3 -C.sub.6 cycloalkyl if at the same time Z is nitrogen,and the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases, have good pre- and postemergence selective herbicidal and growth regulating properties.

摘要翻译： 取代的N-芳基磺酰基-N'-嘧啶基脲和通式为其中R 1是R 2的N-芳基磺酰基-N'-三嗪基脲是其中R 1是氢，卤素，硝基，C 1 -C 3烷基，C 1 -C 3烷氧基 或-COOR 9，R 3为氢，C 1 -C 3烷基或C 1 -C 3烷氧基，R 4和R 5各自独立地为氢，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷硫基， C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 3 -C 6环烷基或-NR 10 R 11，R 6是氢或C 1 -C 3烷基，R 7是氢或甲基，R 8是未被取代或被C 1 -C 3烷基或卤素取代的C 4 -C 6环烷酰基; 未被取代或被一个或多个选自C 1 -C 3烷基，C 1 -C 3烷氧基，卤素或氰基的相同或不同的成员取代的C 3 -C 6环烷基; 或未被取代或被C 1 -C 3烷基，卤素或氰基取代的C 5 -C 6环烯基，R 9为C 1 -C 3烷基或烯丙基，R 10和R 11各自独立地为氢或C 1 -C 4烷基，n为0或1，X为 硫或氧，并且E和Z各自独立地为另一个氮或次甲基桥，条件是如果同时Z是氮，则R8仅为未取代的或取代的C 3 -C 6环烷基，并且这些化合物与胺的盐 碱金属碱或碱土金属碱，具有良好的芽前和芽后选择性除草和生长调节性质。

公开(公告)号：US4565887A

公开(公告)日：1986-01-21

申请号：US571986

申请日：1984-01-19

申请人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

发明人： Werner Fory ,  Karl Gass ,  Willy Meyer ,  Rolf Schurter

IPC分类号： A01N47/24 ,  A01N47/08 ,  A01N47/22 ,  A01N47/36 ,  C07C303/36 ,  C07C311/16 ,  C07C311/53 ,  C07C323/67 ,  C07D239/42 ,  C07D239/46 ,  C07D239/47 ,  C07D239/48 ,  C07D239/52 ,  C07D239/56 ,  C07D251/16 ,  C07D251/22 ,  C07D251/40 ,  C07D251/46 ,  C07D251/52 ,  C07D521/00 ,  C07C143/78 ,  C07C149/447

CPC分类号： C07C311/65 ,  A01N47/36 ,  C07D239/47 ,  C07D239/48 ,  C07D521/00

摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.

摘要翻译： 具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后 芽后选择性，除草和生长调节性质。 该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个 或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8 各自独立地为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

公开(公告)号：US4537619A

公开(公告)日：1985-08-27

申请号：US458694

申请日：1983-01-17

申请人： Willy Meyer ,  Werner Fory

发明人： Willy Meyer ,  Werner Fory

IPC分类号： C07D239/42 ,  A01N41/06 ,  A01N43/66 ,  A01N47/36 ,  A01P13/00 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C311/00 ,  C07C311/29 ,  C07C313/00 ,  C07C317/14 ,  C07C317/18 ,  C07C317/22 ,  C07C317/44 ,  C07C323/12 ,  C07C323/67 ,  C07D239/46 ,  C07D239/47 ,  C07D239/52 ,  C07D239/56 ,  C07D251/14 ,  C07D251/16 ,  C07D251/22 ,  C07D251/42 ,  C07D251/44 ,  C07D251/46 ,  C07D521/00

CPC分类号： C07D521/00 ,  A01N47/36

摘要： N-Phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaQ is chlorine, bromine, trifluoromethyl, chlorodifluoromethyl, bromodifluoromethyl or methyl,X is oxygen, sulfur, a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 -haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl of at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.

摘要翻译： 具有通式“IMAGE”的N-苯基磺酰基-N'-三嗪基脲及其与胺，碱金属或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质。 在上式中，Q是氯，溴，三氟甲基，氯二氟甲基，溴二氟甲基或甲基，X是氧，硫，亚磺酰基或磺酰基桥，Z是氧或硫，R2是氢，卤素，C1-C5烷基，C2-C5链烯基， C1-C4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4分别独立地为氢，C1-C4烷基，C1-C4烷氧基，C1- C 4烷硫基，C 1 -C 4卤代烷基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自独立地为C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 7和R 8各自独立地为 氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，Y是氧，硫，亚磺酰基或磺酰基桥。