摘要:
Provided is a polymerization liquid for electropolymerization, which uses a solvent that is mainly composed of water, which is greatly increased in the amount of a monomer contained therein, and which is capable of quickly forming a conductive polymer layer having high conductivity and heat resistance, A polymerization liquid for electropolymerization of the present invention contains: a solvent that is composed of 100-80% by mass of water and 0-20% by mass of an organic solvent; at least one monomer having a pi-conjugated double bond; at least one supporting electrolyte; and at least two nonionic surfactants. The at least two nonionic surfactants are composed of at least one acetylenol surfactant and at least one water-soluble nonionic surfactant other than the acetylenol surfactant. Due to the combination of the two nonionic surfactants, the amount of the monomer emulsified with the solvent can be greatly increased.
摘要:
Provided is a method whereby metal oxide nanoparticles having evenness of size are efficiently and highly dispersedly adhered to conductive carbon powder. This method comprises: a preparation step in which a reaction solution containing water, a compound with a transition metal selected from the group consisting of Mn, Fe, Co, and Ni, and conductive carbon powder and having a pH in the range of 9 to 11 is introduced into a rotatable reactor; a supporting step in which the reactor is rotated to apply shear stress and centrifugal force to the reaction solution, thereby yielding a core of a hydroxide of the transition metal and dispersing the thus-yielded core of a hydroxide of the transition metal and the conductive carbon powder and simultaneously supporting the hydroxide of the transition metal by the conductive carbon powder; and a heat treatment step in which the conductive carbon powder loaded with the hydroxide of the transition metal is heated to thereby convert the hydroxide supported by the conductive carbon powder into an oxide nanoparticle.
摘要:
Highly dispersed lithium titanate crystal structures having a thickness of few atomic layers level and the two-dimensional surface in a plate form are supported on carbon nanofiber (CNF). The lithium titanate crystal structure precursors and CNF that supports these are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The mass ratio between the lithium titanate crystal structure and carbon nanofiber is preferably between 75:25 and 85:15. The carbon nanofiber preferably has an external diameter of 10-30 nm and an external specific surface area of 150-350 cm2/g. This composite is mixed with a binder and then molded to obtain an electrode, and this electrode is employed for an electrochemical element.
摘要:
Disclosed are an aluminum electrolytic capacitor having low impedance properties and a long service life, and an electrolytic solution which enables to give such capacitor. The electrolytic solution contains a solvent containing water, a phosphorus oxoacid ion-generating compound which can generate a phosphorus oxoacid ion in an aqueous solution, and a chelating agent which can coordinate with aluminum to form an aqueous aluminum chelate complex. The electrolytic solution further contains a compound selected from the group consisting of azelaic acid and an azelaic acid salt, and a compound selected from the group consisting of formic acid, a formic acid salt, adipic acid, an adipic acid salt, glutaric acid and a glutaric acid salt. The content of azelaic acid and/or the azelaic acid salt is at least 0.03 moles per kg of the solvent. When the electrolytic solution is used in an electrolytic capacitor which utilizes an anode having an aluminum oxide film containing phosphorus in an amount of 30 to 150 mg per unit CV product in terms of phosphoric acid, the service life of the capacitor is remarkably prolonged.
摘要:
A positive electrode 21 and negative electrode 22 formed of a thin metal plate are disposed on the same plane with a space provided therebetween. An insulative resin is disposed in the space between the both electrodes. The insulative resin electrically insulates the positive and the negative electrodes, and making both electrodes integrated as a sheet to form a terminal board. Positive- and negative-electrode drawing portions are formed on the same surface of the main body of a capacitor element, and that surface serves as a joined face with the terminal board. With the terminal board being superimposed on the joined face of the capacitor element, the metal plate forming the positive and negative electrodes of the terminal board are electrically coupled to the positive- and negative-electrode drawing portions of the element, respectively.
摘要:
A capacitor includes a capacitor element that is a wound element or an element other than the wound element, and that includes electrode bodies each of which is in an anode side and a cathode side, and separators that intervenes between the electrode bodies; a sealing member that seals an opening of a case member accommodating the capacitor element; at least one electrode protrusion that protrudes from one of the electrode bodies on an element end-face of the capacitor element, at least one of current collector plate that is connected to the electric protrusion; and at least one terminal member that is disposed in the sealing member, and is superposed on the current collector plate, a side face part of the terminal member being welded to a side face part of the current collector plate.
摘要:
An object of the invention is to provide a capacitor device that can be made slimmer and lighter and that enables the strength and heat dissipation properties to be improved. A capacitor device (1) has a plurality of capacitor units (2) integrally housed within a housing case (3), the housing case (3) having cylindrical housing sections (5) for housing the capacitor bodies. The housing sections (5) are longitudinally aligned in the same direction and are joined together as an integrated whole. A capacitor unit (2) is inserted via an opening (9) at one end of each of the housing sections (5) so that the entire circumference of the capacitor unit (2) is covered by the corresponding housing section (5). The housing sections (5) have a uniform thickness at least on the outer side along the outer periphery of the capacitor units.
摘要:
An electrolytic capacitor in which a capacitor element can be fixed firmly into a metal case without having adverse effects on the electrical characteristics of the electrolytic capacitor. An anode foil provided with an anode internal terminal and a cathode foil provided with a cathode internal terminal are wound or laminated through a separator to produce a capacitor element. The capacitor element is then contained in a metal case together with a driving electrolyte, and then the side surface of the metal case is caulked to press and fix the capacitor element, thus producing an electrolytic capacitor. The electrolytic capacitor is characterized in that a tape material is wound by a plurality of turns around the outer circumference of the capacitor element between the capacitor element and the caulking of the metal case such that a total thickness of the tape material is so large as to relax deformation of the capacitor element when the side surface of the metal case is caulked.
摘要:
The present invention aims at: providing an accelerated reaction in a liquid-phase reaction; forming, by way of the reaction, a metal oxide nanoparticle and carbon that carries the metal oxide nanoparticle in a highly dispersed state; and providing an electrode containing the carbon and an electrochemical device using the electrode. In order to solve the above-mentioned problem, shear stress and centrifugal force are applied to the reactant in the rotating reactor so that an accelerated chemical reaction is attained in the course of the reaction. Further, the carbon carrying a metal oxide nanoparticle in a highly dispersed state comprises: a metal oxide nanoparticle produced by the accelerated chemical reaction, wherein shear stress and centrifugal force are applied to a reactant in a rotating reactor in the course of the reaction; and carbon dispersed in the rotating reactor by applying shear stress and centrifugal force. An electrochemical device produced by using the carbon carrying the metal oxide nanoparticle as an electrode has high output and high capacity characteristics.
摘要:
An electrolytic capacitor employs a capacitor element wherein an anode foil having an anode internal terminal and a cathode foil having a cathode internal terminal are wound or laminated through a separator. The end of the anode foil faces the cathode foil through the separator and the surface area of the cathode internal terminal is provided with an enlargement treatment, whereby the small area portion of the cathode foil that faces with the anode foil is eliminated, improving the charge/discharge characteristics. Furthermore, in the electrolytic capacitor provided with the capacitor element wherein the anode foil having the anode internal terminal and the cathode foil having the cathode internal terminal are wound or laminated through the separator, the capacitor element being impregnated with an electrolyte, the cathode internal terminal includes an aluminum material, the surface of the cathode internal terminal is etched and iron concentration in the etching layer