Thermostable and thermoplastic linear polythioethers
    81.
    发明授权
    Thermostable and thermoplastic linear polythioethers 失效
    热稳定和热塑性线性聚合物

    公开(公告)号:US3730949A

    公开(公告)日:1973-05-01

    申请号:US3730949D

    申请日:1971-10-01

    Applicant: JUNGBLUT C

    Inventor: JUNGBLUT C

    CPC classification number: C08G75/12 C08G75/02 C08G75/0227 C08G75/024 C08G75/04

    Abstract: LINEAR THERMOPLASTICS, HAVING EXCEPTIONAL THERMAL STABLILITY AND WEATHER RESISTANCE, OF THE GENERAL FORMULA

    $S-R-S-R
    $

    IN WHICH R IS A BIFUNCTIONAL AROMATIC RADICAL AND R'' IS AN AROMATIC-LIKE 6-MEMBERED RING COMPOUND CONTAINING 2 NITROGEN HETEROATOMS AND 3 CONJUGATED DOUBLE BONDS IN THE RING, SELECTED FROM THE GROUP CONSISTING OF PYRIDAZIINE, PHTHALAZINE, PYRAZINE, AND PYRIMIDINE, AND THE PROCESS FOR PRODUCING THESE POLYMERS BY THE POLYCONDENSATION OF A SALT OF AN AROMATIC DIITHIOL WITH THE DIHALOGENATED DERIVATIVE OF PYRIDAZINE, PHTHALAZINE, PYRAZINE OR PYRAMIDINE UNDER SPECIFIED CONDITIONS ARE DISCLOSED.

    Treatment of keratinous fibres and fabrics with polythiols
    82.
    发明授权
    Treatment of keratinous fibres and fabrics with polythiols 失效
    用聚硅氧烷处理卡氏纤维和织物

    公开(公告)号:US3706527A

    公开(公告)日:1972-12-19

    申请号:US3706527D

    申请日:1970-08-25

    Applicant: CIBA GEIGY AG

    Abstract: A PROCESS FOR MODIFYING KERATINOUS MATERIALS BY USING A POLYTHIOL ESTER OF THE FORMULA

    (HO-(R''-O)A)QY-R(-((CO)X-(O-R1)AY-O-(CO)Y-R2-SH)P)-

    (CO2H)QX

    WHEREIN R REPRESENTS A HYDROCARBON RADICAL, CONTAINING A CHAIN OR AT LEAST 3 AND AT MOST 60 CARBON ATOMS, R1 REPRESENTS AN ALKYLENE GROUP CONTAINING AT LEAST 2 AND AT MOST 6 CARBON ATOMS, R2 REPRESENTS A HYDROCARBON RADICAL, A, X, AND Y IN EACH OF THE P CHAINS ARE INDIVIDUALLY CHOSEN FROM THE GROUP COMPRISING ZERO AND 1, WITH THE PROVISO THAT X AND Y ARE UNEQUAL, P IS AN INTEGER OF AT LEAST 3 AND AT MOST 6, Q IS CHOSEN FROM THE GROUP COMPRISING ZERO AND POSITIVE INTEGERS OF AT LEAST 1 AND AT MOST 3, (P+Q) IS AT MOST 6, OPTIONALLY IN COMBINATION WITH OTHER POLYMERIC POLYMEROPTIONALLY IN COMBINATION WITH OTHER POLYMERIC POLYMERCAPTANES, AMINOPLASTS, EPOXY RESINS, ACRYLIC RESINS, ACRYLAMIDE OR POLYISOCYANATES. THE POLYMERS CURE ON THE FIBRE. THE KERATINOUS MATERIALS ARE RENDERED RESISTANT TO SHRINKAGE AND DURABLE PRESS CHARACTERISTICS ARE IMPARTED TO THEM. THE TREATED MATERIAL RETAIN THEIR DIMENSION AND SHAPE WHEN WASHED IN MACHINES AND HAVE GOOD RECOVERY FROM WRINKLING.

    Dual image formation on separate supports of photocurable composition
    84.
    发明授权
    Dual image formation on separate supports of photocurable composition 失效
    双色图像形成对可光合成分的独立支持

    公开(公告)号:US3650746A

    公开(公告)日:1972-03-21

    申请号:US3650746D

    申请日:1969-06-16

    Applicant: GRACE W R & CO

    Inventor: BAILEY ROBERT J

    Abstract: This invention is directed to forming two silverless continuous tone photographic images from a sandwich comprising two UV transparent outer support layers and a pigment or dye filled photosensitive composition as the inner layer by exposing said composition to actinic radiation e.g., UV light through imagebearing transparencies adjacent each outer support layer to selectively insolublize the UV exposed areas of said composition, peeling said outer support layer apart and removing soluble portions of the composition in the unexposed areas thereby forming a silverless, continuous tone, photographic image on each outer support layer.

    Abstract translation: 本发明涉及通过将所述组合物暴露于光化辐射(例如通过图像承载透明胶片的UV光)形成来自包含两个UV透明外支撑层和颜料或染料填充的感光组合物作为内层的两个无银连续色调照相图像 邻近每个外部支撑层以选择性地不透明所述组合物的UV暴露区域,剥离所述外部支撑层并且去除未曝光区域中的组合物的可溶部分,从而在每个外部支撑层上形成无银色,连续色调的摄影图像。

    Method for producing heat-resistant linear thermoplastic aromatic polythioethers
    85.
    发明授权
    Method for producing heat-resistant linear thermoplastic aromatic polythioethers 失效
    生产耐热线性热塑性芳族聚氧乙烯醚的方法

    公开(公告)号:US3547887A

    公开(公告)日:1970-12-15

    申请号:US3547887D

    申请日:1968-06-05

    Applicant: INVENTA AG

    CPC classification number: C08G75/025 C08G75/04

    Abstract: 1,160,666. Polythioethers. INVENTA A.G. FUR FORSCHUNG UND PATENTVERWERTUNG, ZURICH. 4 June, 1968 [9 June, 1967], No. 26484/68. Heading C3R. Polythioethers containing units of formula where R and R 1 are aromatic radicals, are obtained by reacting an alkali metal or alkaline earth metal salt of an aromatic dithiol with an aromatic dihalogen compound having at least three carbon atoms between the halogen atoms, the aromatic radical being free from electronattracting groups in o- or p-positions with respect to the halogen atoms, in a polar solvent at elevated temperature. In examples, polymers are obtained by heating potassium, lithium and sodium salts of diphenyl ether 4,41- dithiol with p-dibromo-benzene, p-dichlorobenzene and 4,4 1 -dibromodiphenyl ether, in N-methylpyrrolidone. Other salts mentioned are those of diphenyl sulphide dithiol, diphenylmethane dithiol and 4,4 1 -dimercaptodiphenyl, and other dihalogen compounds are 1,3- dibromo - benzene, 1,4 - dichloronaphthalene, 4 - chloro - 4 1 - bromodiphenyl, 4,41 - diiododiphenyl - methane and 4,41 - dichlorodiphenyl sulphide. A catalyst, e.g. copper, copper oxides, copper salts, N-bromosuccinimide or N-bromo-phthalimide, may be present in the reaction.

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