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公开(公告)号：US09371345B2
公开(公告)日：2016-06-21
申请号：US14730623
申请日：2015-06-04
发明人： Krzysztof Skowerski , Lukasz Gulajski , Michal Bieniek , Stefan Czarnocki , Grzegorz Szczpaniak , Celina Wierzbicka
IPC分类号： C07F15/00 , B01J31/22 , C07C209/68 , C07D307/28 , C07C29/32 , C07C29/56 , C07C67/333 , C08G61/08
CPC分类号： C07F15/0046 , B01J31/2204 , B01J31/2273 , B01J31/2278 , B01J31/2295 , B01J2231/543 , B01J2531/821 , B01J2531/825 , B01J2531/96 , B01J2540/42 , B01J2540/64 , C07B2200/09 , C07C29/32 , C07C29/56 , C07C67/333 , C07C209/68 , C07C2601/10 , C07D307/28 , C08G61/08 , C08G2261/3324 , C08G2261/418 , C07C211/63 , C07C69/74 , C07C33/035
摘要： Disclosed herein is a general method for the preparation of complexes containing a quaternary onium group in an inert ligand. Some of these complexes may be represented by formula 1: Methods for the preparation of complexes of formula 1, the preparation of intermediates and the use of complexes of formula 1 in metathesis reactions and a method for conducting an olefin metathesis reaction are also described.
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2.发明申请NOVEL METAL COMPLEXES, ESPECIALLY THE RUTHENIUM COMPLEXES, AND USE THEREOF 有权新型金属复合材料，特别是金属复合材料及其应用公开(公告)号：US20150217283A1
公开(公告)日：2015-08-06
申请号：US14421752
申请日：2013-08-14
IPC分类号： B01J31/22 , C07C67/333 , C07D207/48 , C08F132/08 , C07F7/18 , C07D211/96 , C07D307/28 , C07C6/04 , C07F15/00 , C07D209/30
CPC分类号： B01J31/2295 , B01J31/2273 , B01J31/2278 , B01J2231/54 , B01J2531/821 , B01J2531/825 , C07B2200/09 , C07C6/04 , C07C67/333 , C07C2531/22 , C07C2531/24 , C07C2601/10 , C07D207/48 , C07D209/30 , C07D211/96 , C07D307/28 , C07F7/1804 , C07F7/1892 , C07F15/0046 , C08F132/08 , C07C11/02 , C07C69/74 , C07C69/16
摘要： The object of the invention is a novel metal complex of the formula (1), the parameters of which are as defined in the description of the invention, as well as use of the metal complex of the formula (1) in the olefin metathesis reactions.
摘要翻译： 本发明的目的是一种新颖的式（1）金属络合物，其参数如本发明描述中所定义，以及式（1）的金属络合物在烯烃复分解反应中的应用 。
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3.发明申请NOVEL RUTHENIUM COMPLEXES, THEIR USE IN THE METATHESIS REACTIONS, AND A PROCESS FOR CARRYING OUT THE METATHESIS REACTION 有权新颖的金属复合物，它们在金属反应中的使用以及进行金属反应的方法公开(公告)号：US20150158896A1
公开(公告)日：2015-06-11
申请号：US14406741
申请日：2013-07-26
IPC分类号： C07F15/00 , C08F132/06 , C07D307/28 , C07C67/333 , C07C67/293
CPC分类号： C07F15/0046 , C07C67/293 , C07C67/333 , C07C67/475 , C07C2601/10 , C07D307/28 , C08F132/06 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C07C69/74 , C07C69/157
摘要： The invention is related to the metal complexes of the general formula (1). The invention is related also to the use of metal complexes of the formula 1 as (pre)catalysts for the olefin metathesis reactions, as well as to the process for carrying out the olefin metathesis reaction.
摘要翻译： 本发明涉及通式（1）的金属络合物。 本发明还涉及将式1的金属络合物用作烯烃复分解反应的（预）催化剂以及进行烯烃复分解反应的方法。
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公开(公告)号：US11999754B2
公开(公告)日：2024-06-04
申请号：US17048092
申请日：2019-04-16
发明人： Rafal Gawin , Patryk Krajczy , Anna Gawin , Krzysztof Skowerski
CPC分类号： C07F15/0046 , B01J31/1825 , C07C6/04 , C07C2531/22
摘要： The invention relates to a ruthenium complex of formula (1), (1) wherein all variables have a meaning as defined in the specification to be used as a (pre)catalyst in the olefin metathesis reaction, ring metathesis reaction (RCM), homometathesis (self-CM), cross-metathesis including ethanolysis (CM).
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公开(公告)号：US20220073549A1
公开(公告)日：2022-03-10
申请号：US17513752
申请日：2021-10-28
发明人： Krzystof Skowerski , Rafal Gawin
摘要： The invention provides a new process for producing ruthenium complexes represented by the Formula 1. Invention provides also the use of ruthenium complexes represented by the Formula 1 as precatalysts and/or catalysts in olefin metathesis reactions.
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公开(公告)号：US09533937B2
公开(公告)日：2017-01-03
申请号：US14443048
申请日：2014-06-24
IPC分类号： C07C67/56 , C22B11/00 , C07C67/48 , B01J31/22 , C07C291/00 , C22B3/00 , C07C291/10
CPC分类号： C07C67/56 , B01J31/2278 , B01J2231/324 , B01J2531/821 , C07C67/48 , C07C291/10 , C07C2601/10 , C07D295/13 , C22B11/048 , Y02P10/214
摘要： The invention concerns use of metal scavengers of the formula (1), wherein the variables are as defined in the description of the invention, for removal of ruthenium residues, compounds, or complexes thereof, from the post-reaction mixtures, from the products of reactions catalyzed with ruthenium complexes, as well as from organic compounds contaminated with ruthenium.
摘要翻译： 本发明涉及式（1）的金属清除剂的用途，其中变量如本发明的描述中所定义，用于从反应后混合物中除去钌残基，化合物或其络合物，从 用钌络合物催化的反应，以及被钌污染的有机化合物。
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公开(公告)号：US20160297742A1
公开(公告)日：2016-10-13
申请号：US14443048
申请日：2014-06-24
CPC分类号： C07C67/56 , B01J31/2278 , B01J2231/324 , B01J2531/821 , C07C67/48 , C07C291/10 , C07C2601/10 , C07D295/13 , C22B11/048 , Y02P10/214
摘要： The invention concerns use of metal scavengers of the formula (1), wherein the variables are as defined in the description of the invention, for removal of ruthenium residues, compounds, or complexes thereof, from the post-reaction mixtures, from the products of reactions catalysed with ruthenium complexes, as well as from organic compounds contaminated with ruthenium.
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公开(公告)号：US11976085B2
公开(公告)日：2024-05-07
申请号：US17513752
申请日：2021-10-28
发明人： Krzysztof Skowerski , Rafal Gawin
CPC分类号： C07F15/0046 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2295 , C07C6/02 , B01J2231/54 , B01J2231/543 , B01J2531/821 , B01J2540/44 , C07C2531/22
摘要： The invention provides a new process for producing ruthenium complexes represented by the Formula 1. Invention provides also the use of ruthenium complexes represented by the Formula 1 as precatalysts and/or catalysts in olefin metathesis reactions.
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公开(公告)号：US11192911B2
公开(公告)日：2021-12-07
申请号：US15764123
申请日：2016-07-27
发明人： Krzysztof Skowerski , Rafał Gawin
摘要： The invention provides a new process for producing ruthenium complexes represented by the Formula 1. Invention provides also the use of ruthenium complexes represented by the Formula 1 as precatalysts and/or catalysts in olefin metathesis reactions.
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10.发明申请公开(公告)号：US20180298046A1
公开(公告)日：2018-10-18
申请号：US15764123
申请日：2016-07-27
发明人： Krzysztof SKOWERSKI , Rafal Gawin
摘要： The invention provides a new process for producing ruthenium complexes represented by the Formula 1. Invention provides also the use of ruthenium complexes represented by the Formula 1 as precatalysts and/or catalysts in olefin metathesis reactions.
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