摘要:
The invention relates to a process for regenerating catalysts containing mixed oxides from the group of alkali metal and/or alkaline earth metal oxides, aluminium oxide and silicon oxide, characterized in that the regeneration comprises the following features: i) treatment of the catalyst in situ, ii) contacting of the catalyst with water, iii) treatment of the catalyst within a temperature range from 100 to 400° C., iv) treatment of the catalyst within a pressure range from 0.1 to 2 MPa, v) treatment of the catalyst over a period of 0.1 to 24 h, vi) treatment of the catalyst with a specific catalyst hourly space velocity of 0.1 to 100 h−1.
摘要:
The invention provides a catalyst system composed of: a) a support material selected from at least one of the following materials: silicon dioxide, aluminium oxide, magnesium oxide, zirconium oxide and mixed oxides thereof, carbon nanotubes; b) an ionic liquid; c) a catalytically active composition comprising nickel; d) an activator selected from the group of Lewis acids with alkylating properties. Additionally provided is the use of the catalyst systems of the invention in the oligomerization of unsaturated hydrocarbon mixtures.
摘要:
Silicon-aluminum mixed oxide powder having a weight ratio of (Al2O3/SiO2)ttl in the total primary particle of from 0.003 to 0.05, a weight ratio (Al2O3/SiO2)surface of the primary particles in a surface layer having a thickness of about 5 nm which is less than in the total primary particle and a BET surface area of from 50 to 250 m2/g. It is prepared by igniting one or more silicon compounds selected from the group consisting of CH3SiCl3, (CH3)2SiCl2, (CH3)3SiCl and (n-C3H7)SiCl3, a hydrolysable and oxidizable aluminum compound, at least one fuel gas and air and burning the flame into a reaction chamber, subsequently separating the solid from gaseous materials and subsequently treating the solid with water vapor. The silicon-aluminum mixed oxide powder can be used as catalyst.
摘要:
The present invention describes a process for the parallel selective hydrogenation of branched and unbranched multiply unsaturated C4-C6-hydrocarbons in olefin-containing hydrocarbon mixtures with minimization of hydrogenation and isomerization of the olefins present in the stream.
摘要:
The present invention relates to a process for efficient purification of MTBE-containing mixtures and for preparation of isobutene by cracking of MTBE-containing mixtures.
摘要:
The present invention describes a process for the parallel selective hydrogenation of branched and unbranched multiply unsaturated C4-C6-hydrocarbons in olefin-containing hydrocarbon mixtures with minimization of hydrogenation and isomerization of the olefins present in the stream.
摘要:
The invention relates to a process for regenerating catalysts containing mixed oxides from the group of alkali metal and/or alkaline earth metal oxides, aluminium oxide and silicon oxide, characterized in that the regeneration comprises the following features: i) treatment of the catalyst in situ, ii) contacting of the catalyst with water, iii) treatment of the catalyst within a temperature range from 100 to 400° C., iv) treatment of the catalyst within a pressure range from 0.1 to 2 MPa, v) treatment of the catalyst over a period of 0.1 to 24 h, vi) treatment of the catalyst with a specific catalyst hourly space velocity of 0.1 to 100 h−1.
摘要:
The invention provides a catalyst system composed of: a) a support material selected from at least one of the following materials: silicon dioxide, aluminum oxide, magnesium oxide, zirconium oxide and mixed oxides thereof, carbon nanotubes; b) an ionic liquid; c) a catalytically active composition comprising nickel; d) an activator selected from the group of Lewis acids with alkylating properties. Additionally provided is the use of the catalyst systems of the invention in the oligomerization of unsaturated hydrocarbon mixtures.