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    Process for regenerating a catalyst
    3.
    发明授权
    Process for regenerating a catalyst 有权
    再生催化剂的方法

    公开(公告)号：US08877667B2

    公开(公告)日：2014-11-04

    申请号：US13381676

    申请日：2010-06-16

    申请人： Christian Boeing ,  Dirk Roettger ,  Reiner Bukohl ,  Markus Winterberg ,  Dietrich Maschmeyer

    发明人： Christian Boeing ,  Dirk Roettger ,  Reiner Bukohl ,  Markus Winterberg ,  Dietrich Maschmeyer

    IPC分类号： B01J38/04 ,  B01J38/06 ,  B01J38/02 ,  B01J23/92 ,  B01J23/02 ,  B01J21/12

    CPC分类号： B01J38/06 ,  B01J21/12 ,  B01J23/02 ,  B01J23/92

    摘要： The invention relates to a process for regenerating catalysts containing mixed oxides from the group of alkali metal and/or alkaline earth metal oxides, aluminium oxide and silicon oxide, characterized in that the regeneration comprises the following features: i) treatment of the catalyst in situ, ii) contacting of the catalyst with water, iii) treatment of the catalyst within a temperature range from 100 to 400° C., iv) treatment of the catalyst within a pressure range from 0.1 to 2 MPa, v) treatment of the catalyst over a period of 0.1 to 24 h, vi) treatment of the catalyst with a specific catalyst hourly space velocity of 0.1 to 100 h−1.

    摘要翻译： 本发明涉及一种从碱金属和/或碱土金属氧化物，氧化铝和氧化硅组中再生含有混合氧化物的催化剂的方法，其特征在于再生包括以下特征：i）原位处理催化剂 ，ii）催化剂与水的接触，iii）在100-400℃的温度范围内处理催化剂，iv）在0.1-2MPa的压力范围内处理催化剂，v）处理催化剂 在0.1至24小时的时间内，vi）用特定催化剂处理催化剂，小时空速为0.1至100h-1。

    PROCESS FOR REGENERATING A CATALYST
    9.
    发明申请
    PROCESS FOR REGENERATING A CATALYST 有权
    再生催化剂的方法

    公开(公告)号：US20120149549A1

    公开(公告)日：2012-06-14

    申请号：US13381676

    申请日：2010-06-16

    申请人： Christian Boeing ,  Dirk Roettger ,  Reiner Bukohl ,  Markus Winterberg ,  Dietrich Maschmeyer

    发明人： Christian Boeing ,  Dirk Roettger ,  Reiner Bukohl ,  Markus Winterberg ,  Dietrich Maschmeyer

    IPC分类号： B01J38/06

    CPC分类号： B01J38/06 ,  B01J21/12 ,  B01J23/02 ,  B01J23/92

    摘要： The invention relates to a process for regenerating catalysts containing mixed oxides from the group of alkali metal and/or alkaline earth metal oxides, aluminium oxide and silicon oxide, characterized in that the regeneration comprises the following features: i) treatment of the catalyst in situ, ii) contacting of the catalyst with water, iii) treatment of the catalyst within a temperature range from 100 to 400° C., iv) treatment of the catalyst within a pressure range from 0.1 to 2 MPa, v) treatment of the catalyst over a period of 0.1 to 24 h, vi) treatment of the catalyst with a specific catalyst hourly space velocity of 0.1 to 100 h−1.

    摘要翻译： 本发明涉及一种从碱金属和/或碱土金属氧化物，氧化铝和氧化硅组中再生含有混合氧化物的催化剂的方法，其特征在于再生包括以下特征：i）原位处理催化剂 ，ii）催化剂与水的接触，iii）在100-400℃的温度范围内处理催化剂，iv）在0.1-2MPa的压力范围内处理催化剂，v）处理催化剂 在0.1至24小时的时间内，vi）用特定催化剂处理催化剂，小时空速为0.1至100h-1。

    Preparation of isobutene by dissociation of MTBE
    10.
    发明授权
    Preparation of isobutene by dissociation of MTBE 有权
    通过MTBE离解制备异丁烯

    公开(公告)号：US08940951B2

    公开(公告)日：2015-01-27

    申请号：US13381680

    申请日：2010-06-16

    申请人： Markus Winterberg ,  Dirk Roettger ,  Armin Rix ,  Reiner Bukohl ,  Walter Luh ,  Holger Wiederhold ,  Gunnar Schilling ,  Christian Boeing

    发明人： Markus Winterberg ,  Dirk Roettger ,  Armin Rix ,  Reiner Bukohl ,  Walter Luh ,  Holger Wiederhold ,  Gunnar Schilling ,  Christian Boeing

    IPC分类号： C07C1/20 ,  C07C11/09

    CPC分类号： C07C11/09 ,  C07C1/20

    摘要： A process for preparing isobutene by dissociation of MTBE, including: a) reaction of isobutene-containing hydrocarbon mixtures, with methanol, present in one or more methanol-containing streams, over acidic ion exchangers to give a stream, containing MTBE and TBA; b) separation of a stream containing MTBE and TBA, from a stream by distillation; c) dissociation of a stream in the gas phase over a heterogeneous catalyst to give a stream containing at least isobutene, methanol, MTBE and water and possibly TBA, d) separation of a stream by distillation to give a stream containing in each case more than 50% by mass of the amounts of methanol, TBA and water present in another stream and a stream containing isobutene, e) separation of water from stream to below 1% by mass by distillation to give a stream, f) total or partial recirculation of the methanol-containing stream.

    摘要翻译： 一种通过MTBE离解制备异丁烯的方法，包括：a）通过酸性离子交换剂使存在于一个或多个含甲醇的物流中的含异丁烯的烃混合物与甲醇反应，得到含有MTBE和TBA的物流; b）通过蒸馏从流中分离含有MTBE和TBA的物流; c）气相中的物流在非均相催化剂上的解离，得到至少含有异丁烯，甲醇，MTBE和水以及可能的TBA的物流，d）通过蒸馏分离物流，得到含有多于 50重量％的甲醇，TBA和存在于另一个流中的水和含有异丁烯的物流，e）通过蒸馏将水从流分离成低于1质量％，得到流，f）全部或部分再循环 含甲醇的流。