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1.发明授权公开(公告)号：US09090982B2
公开(公告)日：2015-07-28
申请号：US13427153
申请日：2012-03-22
CPC分类号： C25B11/0447 , C23C14/021 , C23C14/025 , C23C14/165 , C25B11/0473
摘要： The invention relates to a cathode for electrolytic processes provided with a catalytic coating based on ruthenium crystallites with highly controlled size falling in a range of 1-10 nm. The coating can be produced by physical vapor deposition of a ruthenium or ruthenium oxide layer.
摘要翻译： 本发明涉及一种电解方法的阴极，其具有基于铱微晶的催化涂层，其具有高度受控的尺寸，其范围为1-10nm。 涂层可以通过钌或氧化钌层的物理气相沉积来制备。
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公开(公告)号：US11634827B2
公开(公告)日：2023-04-25
申请号：US13877942
申请日：2011-11-25
IPC分类号： C25B11/093
摘要： An electrode suitable for chlorine evolution in electrolysis cells consists of a metal substrate coated with two distinct compositions applied in alternate layers, the former comprising oxides of iridium, ruthenium and valve metals, for instance tantalum, and the latter comprising oxides of iridium, ruthenium and tin.
The thus-obtained electrode couples excellent characteristics of anodic potential and selectivity towards the chlorine evolution reaction.-
公开(公告)号：US20110209992A1
公开(公告)日：2011-09-01
申请号：US13106133
申请日：2011-05-12
申请人： Christian Urgeghe , Alexander Morozov , Alice Calderara , Dino Floriano Di Franco , Antonio Lorenzo Antozzi
发明人： Christian Urgeghe , Alexander Morozov , Alice Calderara , Dino Floriano Di Franco , Antonio Lorenzo Antozzi
CPC分类号： C25B1/46 , C25B11/0426 , C25B11/0484
摘要： The invention relates to an electrode formulation comprising a catalytic layer containing tin, ruthenium, iridium, palladium and niobium oxides applied to a titanium or other valve metal substrate. A protective layer based on titanium oxide modified with oxides of other elements such as tantalum, niobium or bismuth may be interposed between the substrate and the catalytic layer. The thus obtained electrode is suitable for use as an anode in electrolysis cells for chlorine production.
摘要翻译： 本发明涉及包含施加到钛或其它阀金属基底上的含有锡，钌，铱，钯和铌氧化物的催化剂层的电极配料。 可以在基板和催化剂层之间插入基于用其他元素如钽，铌或铋的氧化物改性的氧化钛的保护层。 这样得到的电极适用于用于氯生产的电解槽中的阳极。
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公开(公告)号：US20070219085A1
公开(公告)日：2007-09-20
申请号：US11587332
申请日：2005-04-21
IPC分类号： B01J37/00
CPC分类号： B01J23/26 , A62D3/37 , A62D2101/43 , B01J37/16
摘要： Process for the reduction of a hexavalent chromium oxide based catalyst comprising contacting, under mixing conditions, a hexavalent chromium oxide based catalyst, with a molar excess, in respect of the chromium species, of a solid reducing agent and subjecting the mixture to a temperature in the range 30-1000 C.°. The process is simple, involves low costs and allows to obtain a permanently reduced chromium catalyst that can be disposed without toxicity risks.
摘要翻译： 还原六价铬氧化物基催化剂的方法，包括在混合条件下使六价铬氧化物基催化剂与铬物质摩尔过量相接触固体还原剂，并使混合物在 范围30-1000℃。 该方法简单，包括低成本，并且可以获得永久性还原的铬催化剂，其可以处置而没有毒性风险。
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公开(公告)号：US20130228450A1
公开(公告)日：2013-09-05
申请号：US13885118
申请日：2011-12-21
IPC分类号： C25B11/04
CPC分类号： C25B11/0442 , C25B11/0484 , C25B11/0494
摘要： The invention relates to an electrode for evolution of gaseous products in electrolysis cells comprising e metal substrate coated with at least two catalytic compositions, the outermost catalytic composition being deposited by means of chemical or physical phase vapour deposition technique and having a composition comprising noble metals selected from the group of platinum group metals or oxides thereof.
摘要翻译： 本发明涉及用于在电解槽中产生气体产物的电极，包括涂覆有至少两种催化组合物的e金属基底，最外层的催化剂组合物通过化学或物理相气相沉积技术沉积，并具有包含选自 由铂族金属或其氧化物组成。
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6.发明申请Activation of Electrode Surfaces by Means of Vacuum Deposition Techniques in a Continuous Process 审中-公开通过真空沉积技术在连续过程中激活电极表面公开(公告)号：US20120164344A1
公开(公告)日：2012-06-28
申请号：US13413121
申请日：2012-03-06
申请人： Antonio Lorenzo Antozzi , Andrea Francesco Gullá , Luciano Iacopetti , Gian Nicola Martelli , Enrico Ramunni , Christian Urgeghe
发明人： Antonio Lorenzo Antozzi , Andrea Francesco Gullá , Luciano Iacopetti , Gian Nicola Martelli , Enrico Ramunni , Christian Urgeghe
CPC分类号： C23C14/562 , C23C14/08 , C23C14/165 , C23C14/221 , C23C14/35 , C25B11/0405 , C25B11/0473 , H01M4/8871
摘要： The invention relates to a method of manufacturing of metal electrodes for electrolytic applications by means of a continuous deposition of a layer of noble metals upon metal substrates by a physical vapour deposition technique.
摘要翻译： 本发明涉及通过物理气相沉积技术在金属基底上连续沉积贵金属层而制造用于电解应用的金属电极的方法。
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公开(公告)号：US07972484B2
公开(公告)日：2011-07-05
申请号：US12249301
申请日：2008-10-10
申请人： Christian Urgeghe , Fulvio Federico
发明人： Christian Urgeghe , Fulvio Federico
CPC分类号： C25B1/46 , C25B11/035 , H01M4/8605 , H01M4/8807 , H01M4/8814 , H01M4/8828 , H01M4/8882 , H01M4/90 , H01M8/083 , Y02P70/56 , Y10T29/49112 , Y10T29/49115
摘要： The invention relates to a gas-diffusion electrode for chlor-alkali electrolysis cells integrated in a percolator of plastic porous material suitable for being vertically crossed by a downward flow of electrolyte. The electrode comprises a catalytic composition based on silver and/or nickel mixed to a polymeric binder, directly supported on the percolator without any interposed reticulated metal current collector.
摘要翻译： 本发明涉及一种用于聚合在塑料多孔材料的渗滤器中的氯碱电解池的气体扩散电极，其适用于通过向下的电解液垂直交叉。 电极包括基于银和/或镍混合到聚合物粘合剂的催化组合物，其直接负载在渗滤器上，而没有任何插入的网状金属集流体。
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公开(公告)号：US20130087450A1
公开(公告)日：2013-04-11
申请号：US13704718
申请日：2011-06-17
申请人： Antonio Lorenzo Antozzi , Mariachiara Benedetto , Alice Calderara , Chiara Pezzoni , Christian Urgeghe
发明人： Antonio Lorenzo Antozzi , Mariachiara Benedetto , Alice Calderara , Chiara Pezzoni , Christian Urgeghe
IPC分类号： C25B11/04
CPC分类号： C25B11/0405 , C02F1/46109 , C02F1/4674 , C02F2001/46119 , C02F2001/46142 , C02F2201/4613 , C02F2303/14 , C25B1/26 , C25B11/0484
摘要： The invention relates to an electrode for electrochemical generation of hypochlorite. The electrode comprises a valve metal substrate coated with a catalytic system consisting of two super-imposed layers of distinct composition and having a different activity towards hypochlorite anodic generation from chloride solutions. The electrode has a high duration in cathodic operation conditions, imparting self-cleaning characteristics thereto when used in combination with an equivalent one with periodic polarity reversal. Moreover, the deactivation of the electrode at the end of its life cycle occurs in two subsequent steps, allowing to schedule the substitution thereof with a significant notice period.
摘要翻译： 本发明涉及一种用于电化学生成次氯酸盐的电极。 电极包括涂覆有催化体系的阀金属基底，该催化体系由两个不同组成的超级施加层组成，并且对氯化物溶液中的次氯酸盐阳极生成具有不同的活性。 电极在阴极操作条件下具有高持续时间，当与等同的具有周期极性反转的组合使用时，赋予其自清洁特性。 此外，在其生命周期结束时电极的失活发生在两个后续步骤中，允许以显着的通知期限安排其替代。
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9.发明申请公开(公告)号：US20120175270A1
公开(公告)日：2012-07-12
申请号：US13427153
申请日：2012-03-22
IPC分类号： C25B11/08 , C25B11/04 , C23C14/14 , C23C16/06 , C23C16/40 , C25B1/02 , C23C14/08 , B82Y30/00
CPC分类号： C25B11/0447 , C23C14/021 , C23C14/025 , C23C14/165 , C25B11/0473
摘要： The invention relates to a cathode for electrolytic processes provided with a catalytic coating based on ruthenium crystallites with highly controlled size falling in a range of 1-10 nm. The coating can be produced by physical vapour deposition of a ruthenium or ruthenium oxide layer.
摘要翻译： 本发明涉及一种电解方法的阴极，其具有基于铱微晶的催化涂层，其具有高度可控的尺寸，其范围为1-10nm。 涂层可以通过钌或氧化钌层的物理气相沉积来制备。
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公开(公告)号：US07943020B2
公开(公告)日：2011-05-17
申请号：US12422514
申请日：2009-04-13
申请人： Antonio Lorenzo Antozzi , Claudia Jennifer Bargioni , Alice Calderara , Luciano Iacopetti , Gian Nicola Martelli , Christian Urgeghe
发明人： Antonio Lorenzo Antozzi , Claudia Jennifer Bargioni , Alice Calderara , Luciano Iacopetti , Gian Nicola Martelli , Christian Urgeghe
IPC分类号： C25B11/08
CPC分类号： C25B1/34 , C23C18/08 , C25B11/0478 , C25B11/0494
摘要： The invention relates to a cathode for electrolytic processes, particularly suitable for hydrogen evolution in chlor-alkali electrolysis, consisting of a nickel substrate provided with a coating comprising a protective zone containing palladium and a physically distinct catalytic activation containing platinum or ruthenium optionally mixed with a highly oxidizing metal oxide, preferably chromium or praseodymium oxide.
摘要翻译： 本发明涉及一种用于电解方法的阴极，特别适用于氯碱电解中的析氢，其由具有包含含钯保护区和物理上不同的催化活性的涂层的镍基底组成，该催化活性含有铂或钌，任选与 高度氧化的金属氧化物，优选为铬或氧化镨。
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