公开(公告)号：US3694555A

公开(公告)日：1972-09-26

申请号：US3694555D

申请日：1970-02-16

Applicant: KURT LEY ,  ULRICH EHOLZER ,  ROLAND NAST ,  KARL GEORG METZGER ,  DIETER FRITSCHE ,  BAYER AG

Inventor： LEY KURT ,  EHOLZER ULRICH ,  NAST ROLAND ,  METZGER KARL GEORG ,  FRITSCHE DIETER

IPC: C07D241/52 ,  A61K27/00

CPC classification number: C07D241/52

Abstract: Pharmaceutical compositions are provided for controlling bacterial infections caused by gram-positive and gram-negative bacteria containing a 3-carboxylic acid amido-quinoxaline-1,4-diN-oxide as active ingredient, as exemplified by 2-acetoxymethyl3-carboxylic acid ethylamidoquinoxaline-di-N-oxide and its congeners. The dosage ranges from 5 mg/kg to 150 mg/kg daily orally or parenterally.

公开(公告)号：US08394187B2

公开(公告)日：2013-03-12

申请号：US12600475

申请日：2008-05-10

Applicant: Klaus-Dieter Fritsche ,  Gerhard Tünker

Inventor： Klaus-Dieter Fritsche ,  Gerhard Tünker

IPC: C09D5/00 ,  C09D7/12 ,  C09D101/08 ,  C09D101/10 ,  C09D101/26 ,  C09D101/28

CPC classification number: C03C17/30 ,  C03C17/25 ,  C03C2217/213 ,  C03C2218/113 ,  C08K5/05 ,  C08K5/06 ,  C09D183/04 ,  C08L2666/34 ,  C08L2666/02

Abstract: A composition for the production of an antireflection coating, comprising a condensate obtainable by the condensation of silicon compounds of the general formula RnSiX4-n (I) in which the X groups are the same or different and represent hydrolyzable groups or hydroxyl groups, the R groups are the same or different and represent non-hydrolyzable groups, and n is 0, 1, 2, or 3, wherein the composition comprises at least one polymeric agent controlling the rheology and at least one solvent with a boiling point of at least 150° C. The present invention also describes methods for the preparation and use of the present composition. In particular, the composition can be applied by screen printing methods on substrates.

Abstract translation: 一种用于生产抗反射涂层的组合物，其包含通过使X基团相同或不同并且表示可水解基团或羟基的通式R n SiX 4-n（I）的硅化合物缩合而获得的缩合物，R 基团相同或不同并且表示非水解性基团，并且n为0,1,2或3，其中所述组合物包含至少一种控制流变性的聚合物和至少一种沸点至少为150的溶剂 本发明还描述了本发明组合物的制备和使用方法。 特别地，组合物可以通过丝网印刷方法施加在基材上。

公开(公告)号：US07544411B2

公开(公告)日：2009-06-09

申请号：US10467261

申请日：2001-12-21

Applicant: Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

Inventor： Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

IPC: B32B5/16 ,  B05D5/00

CPC classification number: B05D7/52 ,  B05D3/0254 ,  B05D5/083 ,  B05D2601/20 ,  B08B17/06 ,  B08B17/065 ,  C09D5/28 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/259 ,  Y10T428/31

Abstract: A self-cleaning paint coating that exhibits the LOTUS EFFECT and an agent and a method for producing the same. The paint coating comprises a paint base coat and a topcoat. The topcoat includes structure-forming particles and is at least partially hydrophobic. The structure-forming particles have an average particle diameter of less than 100 nanometers (nm) and form elevations in the topcoat surface that are interspaced at a distance of less than 50 nm. The topcoat of the paint coating is formed from the agent. The agent contains a liquid medium, a hydrophobating agent dissolved in the liquid medium, and structure-forming particles suspended in the medium. The method of forming the paint coating comprises coating a substrate with the base coat, applying the topcoat agent to the partially cured or uncured base coat, and curing of the top coat, and if required, the base coat.

Abstract translation: 展示LOTUS效应的自清洁涂料涂料及其制备方法。 油漆涂料包括漆底漆和面漆。 面漆包括结构形成颗粒并且至少部分疏水。 结构形成颗粒具有小于100纳米（nm）的平均粒径，并且形成在小于50nm的距离处间隔的顶涂层表面中的高度。 涂料的面漆由该剂形成。 该试剂含有液体介质，溶解在液体介质中的疏水化剂和悬浮在介质中的结构形成颗粒。 形成涂料的方法包括用底涂层涂覆基材，将面漆涂覆到部分固化或未固化的底涂层上，并固化顶涂层，如果需要的话，涂底漆。

公开(公告)号：US20050170098A1

公开(公告)日：2005-08-04

申请号：US11059713

申请日：2005-02-16

Applicant: Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

Inventor： Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

IPC: B08B17/06 ,  C03C17/00 ,  C03C17/42 ,  C04B41/52 ,  C04B41/89 ,  C23C24/08 ,  C23C24/10 ,  C23C30/00 ,  B05D3/02

CPC classification number: C04B41/009 ,  B08B17/06 ,  B08B17/065 ,  C03C17/009 ,  C03C17/42 ,  C03C2217/452 ,  C03C2217/465 ,  C03C2217/475 ,  C03C2217/77 ,  C04B41/52 ,  C04B41/89 ,  C23C24/08 ,  C23C24/10 ,  C23C30/00 ,  Y10T428/24355 ,  Y10T428/24364 ,  Y10T428/24479 ,  Y10T428/31612 ,  Y10T428/31663 ,  C04B41/4539 ,  C04B41/5022 ,  C04B41/5024 ,  C04B41/4511 ,  C04B41/522 ,  C04B2103/54 ,  C04B41/4933 ,  C04B33/00

Abstract: The invention relates to glass, ceramic and metal substrates with at least one self-cleaning surface, comprising a layer with a micro-rough surface structure that is arranged on the substrate and made at least partly hydrophobic. The layer contains a glass flux and structure-forming particles with a mean particle diameter within the 0.1 to 50 μm range; the glass flux and structure-forming particles are present in a volume ratio within the 0.1 to 5 range, and the micro-rough surface structure has a ratio of mean profile height to mean distance between adjacent profile tips within the 0.3 to 10 range. To produce the subject of the invention the substrate is coated with a composition containing a glass flux and structure-forming particles, and the layer is burnt in and made hydrophobic.

Abstract translation: 本发明涉及具有至少一个自清洁表面的玻璃，陶瓷和金属基底，其包括布置在基底上并制成至少部分疏水的具有微粗糙表面结构的层。 该层含有平均粒径在0.1-50μm范围内的玻璃熔剂和结构形成颗粒; 玻璃熔剂和结构形成颗粒以体积比在0.1至5范围内存在，并且微粗糙表面结构具有在0.3至10范围内的相邻型头之间的平均轮廓高度与平均距离的比率。 为了制造本发明的主题，用包含玻璃熔剂和结构形成颗粒的组合物涂覆基材，并且该层被烧制并制成疏水性。

公开(公告)号：US06872441B2

公开(公告)日：2005-03-29

申请号：US10239066

申请日：2001-03-13

Applicant: Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

Inventor： Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

IPC: B08B17/06 ,  C03C17/00 ,  C03C17/42 ,  C04B41/52 ,  C04B41/89 ,  C23C24/08 ,  C23C24/10 ,  C23C30/00 ,  B32B3/00

CPC classification number: C04B41/009 ,  B08B17/06 ,  B08B17/065 ,  C03C17/009 ,  C03C17/42 ,  C03C2217/452 ,  C03C2217/465 ,  C03C2217/475 ,  C03C2217/77 ,  C04B41/52 ,  C04B41/89 ,  C23C24/08 ,  C23C24/10 ,  C23C30/00 ,  Y10T428/24355 ,  Y10T428/24364 ,  Y10T428/24479 ,  Y10T428/31612 ,  Y10T428/31663 ,  C04B41/4539 ,  C04B41/5022 ,  C04B41/5024 ,  C04B41/4511 ,  C04B41/522 ,  C04B2103/54 ,  C04B41/4933 ,  C04B33/00

Abstract: The invention relates to glass, ceramic and metal substrates with at least one self-cleaning surface, comprising a layer with a micro-rough surface structure which is arranged on the substrate and made at least partly hydrophobic. The layer contains a glass flux and structure-forming particles with a mean particle diameter within the 0.1 to 50 μm range; the glass flux and structure-forming particles are present in a volume ratio within the 0.1 to 5 range, and the micro-rough surface structure has a ratio of mean profile height to mean distance between adjacent profile tips within the 0.3 to 10 range.To produce the subject of the invention the substrate is coated with a composition containing a glass flux and structure-forming particles, and the layer is burnt in and made hydrophobic.

Abstract translation: 本发明涉及具有至少一个自清洁表面的玻璃，陶瓷和金属基底，其包括布置在基底上并制成至少部分疏水的具有微粗糙表面结构的层。 该层含有平均粒径在0.1-50μm范围内的玻璃熔剂和结构形成颗粒; 玻璃熔剂和结构形成颗粒以体积比在0.1至5范围内存在，并且微粗糙表面结构具有在0.3至10范围内的相邻轮廓尖端之间的平均轮廓高度与平均距离的比率。 产生本发明的主题，所述基材用含有玻璃熔剂和结构形成颗粒的组合物涂覆，并且该层被烧制并制成疏水性。

公开(公告)号：US06800354B2

公开(公告)日：2004-10-05

申请号：US10021558

申请日：2001-12-12

Applicant: Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

Inventor： Martin Baumann ,  Klaus-Dieter Fritsche ,  Dagmar Korbelarz ,  Stephan Ludwig ,  Lutz Poth

IPC: B32B516

CPC classification number: C04B41/009 ,  B08B17/06 ,  B08B17/065 ,  C03C8/14 ,  C03C8/20 ,  C03C17/007 ,  C03C17/34 ,  C03C17/42 ,  C03C2205/04 ,  C03C2217/452 ,  C03C2217/475 ,  C03C2217/76 ,  C03C2217/77 ,  C04B41/52 ,  C04B41/89 ,  C04B2111/2069 ,  C23C24/08 ,  C23C24/10 ,  Y10T428/24355 ,  Y10T428/24364 ,  Y10T428/24372 ,  Y10T428/2438 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/258 ,  Y10T428/259 ,  Y10T428/2982 ,  Y10T428/31504 ,  Y10T428/31612 ,  Y10T428/31663 ,  Y10T428/31667 ,  C04B41/0072 ,  C04B41/4539 ,  C04B41/5006 ,  C04B41/5035 ,  C04B41/5015 ,  C04B41/522 ,  C04B41/4933 ,  C04B33/00

Abstract: A substrate of glass, ceramic, plastic and metal, or a glazed or enamelled substrate, with a self-cleaning and/or hydrophobic surface. The substrate having disposed thereon a coating that includes a plurality of particles affixed to the surface of the substrate by a binder. The particles are preferably of nanoscale size and extend outwardly from a surface of the coating to form a nano-rough surface. The nano-rough surface causes a hydrophobic or water repellent effect. The binder can be formed from an organic or an inorganic material and operates to fix the plurality of particles to substrate surface.

Abstract translation: 玻璃，陶瓷，塑料和金属的基材，或具有自清洁和/或疏水表面的玻璃或搪瓷基材。 衬底上设置有通过粘合剂固定到衬底的表面上的多个颗粒的涂层。 颗粒优选具有纳米尺寸并且从涂层的表面向外延伸以形成纳米粗糙表面。 纳米粗糙表面引起疏水或疏水作用。 粘结剂可以由有机或无机材料形成，并将多个颗粒固定在基材表面上。

公开(公告)号：US20110052815A1

公开(公告)日：2011-03-03

申请号：US12600475

申请日：2008-05-10

Applicant: Klaus-Dieter Fritsche ,  Gerhard Tünker

Inventor： Klaus-Dieter Fritsche ,  Gerhard Tünker

IPC: B05D5/06 ,  C09D5/00

CPC classification number: C03C17/30 ,  C03C17/25 ,  C03C2217/213 ,  C03C2218/113 ,  C08K5/05 ,  C08K5/06 ,  C09D183/04 ,  C08L2666/34 ,  C08L2666/02

Abstract: A composition for the production of an antireflection coating, comprising a condensate obtainable by the condensation of silicon compounds of the general formula RnSiX4-n (I) in which the X groups are the same or different and represent hydrolyzable groups or hydroxyl groups, the R groups are the same or different and represent non-hydrolyzable groups, and n is 0, 1, 2, or 3, wherein the composition comprises at least one polymeric agent controlling the rheology and at least one solvent with a boiling point of at least 150° C. The present invention also describes methods for the preparation and use of the present composition. In particular, the composition can be applied by screen printing methods on substrates.

Abstract translation: 一种用于生产抗反射涂层的组合物，其包含通过使X基团相同或不同并且表示可水解基团或羟基的通式R n SiX 4-n（I）的硅化合物缩合而获得的缩合物，R 基团相同或不同并且表示非水解性基团，并且n为0,1,2或3，其中所述组合物包含至少一种控制流变性的聚合物和至少一种沸点至少为150的溶剂 本发明还描述了本发明组合物的制备和使用方法。 特别地，组合物可以通过丝网印刷方法施加在基材上。

公开(公告)号：US3651229A

公开(公告)日：1972-03-21

申请号：US3651229D

申请日：1969-11-12

Applicant: BAYER AG ,  DIETER FRITSCHE

Inventor： LEY KURT ,  EHOLZER ULRICH ,  METZGER KARL GEORG

IPC: C07D241/52 ,  A61K27/00

CPC classification number: C07D241/52

Abstract: PHARMACEUTICAL COMPOSITIONS COMPRISING 2-METHYL-3AMIDINO-QUINOXALINE-1,4-DI-N-OXIDES OF THE FORMULA:

1,4-DI(O=),2-(R2-NH-C(=NH)-),3-(CH3-),R1-QUINOXALINE

WHEREIN:

R1 IS HYDROGEN, LOWER ALKYL, LOWER ALKOXY OR CHLORINE, AND R2 IS HYDROXY OR AMINO,

IN COMBINATION WITH A PHARMACEUTICALLY ACCEPTABLE INSERT CARRIER ARE USEFUL AS ANTIBACTERIAL AGENTS.

1,4-DI(O=),2-(NC-),3-(CH3-),R1-BENZENE

THESE COMPOSITIONS OR THE ACTIVE COMPOUND CAN BE ADMINISTERED SUBCUTANEOUSLY OR ORALLY TO HUMANS AND ANIMALS.

公开(公告)号：US5707436A

公开(公告)日：1998-01-13

申请号：US412972

申请日：1995-03-29

Applicant: Klaus-Dieter Fritsche ,  Bernd Dorbath ,  Norbert Giesecke ,  Kerstin Ruhnau

Inventor： Klaus-Dieter Fritsche ,  Bernd Dorbath ,  Norbert Giesecke ,  Kerstin Ruhnau

IPC: C04B41/86 ,  C03C1/04 ,  C03C8/14 ,  C09C1/00 ,  C09C1/28 ,  C09C3/06 ,  C09C1/62

CPC classification number: C03C8/14 ,  C03C1/04 ,  C09C1/0078 ,  C09C1/28 ,  C09C3/066 ,  C01P2002/02 ,  C01P2004/84 ,  Y10T428/2993

Abstract: Prior art production of purple pigments based on colloidal gold on stovable/sinterable/fireable support material involves the reduction of a gold compound in the presence of a chemical reducing agent. Purple pigments may be produced more simply according to the invention by intimately mixing and/or grinding the support material and the gold compound in dry form or by bringing an aqueous solution or suspension of a gold compound and a support material into contact and then thermally treating the mixture at a temperature above the decomposition temperature of the gold compound and below the sintering temperature of the support material, wherein the gold compound is converted into colloidal gold.

Abstract translation: 现有技术生产基于可挥发/烧结/可燃/支持材料上胶体金的紫色颜料包括在化学还原剂存在下还原金化合物。 根据本发明可以更简单地制备紫色颜料，通过将干燥形式的载体材料和金化合物紧密混合和/或研磨，或通过使金化合物和载体材料的水溶液或悬浮液接触，然后热处理 所述混合物在高于金化合物的分解温度并低于载体材料的烧结温度的温度下，其中金化合物转化为胶体金。

公开(公告)号：US5589273A

公开(公告)日：1996-12-31

申请号：US412888

申请日：1995-03-29

Applicant: Bernd Dorbath ,  Norbert Giesecke ,  Klaus-Dieter Fritsche

Inventor： Bernd Dorbath ,  Norbert Giesecke ,  Klaus-Dieter Fritsche

IPC: B44C1/02 ,  C03C8/14 ,  C03C17/00 ,  C04B41/86 ,  B32B9/00

CPC classification number: C03C17/008 ,  C03C8/14 ,  Y10T428/24802 ,  Y10T428/24851 ,  Y10T428/24868 ,  Y10T428/2993

Abstract: Purple colors based on colloidal gold on stovable substrates and the use thereof for the production of purple decoration on glass, ceramics and porcelain are known. The production of such purple colors is elaborate.Agents according to the invention should be viewed as pigment precursors, wherein the pigment is formed during firing of the decoration. The agents contain a gold compound, with the exception of gold oxide, which may be decomposed to colloidal gold on firing of the decoration and a finely divided glass flux in a weight ratio of gold to glass flux of between 1:10 and 1:2,000. Preferred agents contain HAuCl.sub.4, Au.sub.2 S.sub.3, AuCN or KAu(CN).sub.2 as the gold compound and a lead-free glass frit as the glass flux.The agents may be obtained by grinding the glass flux with a gold compound.Purple decoration is obtained by applying the agent to the substrate to be decorated and storing at 400.degree. to 1,050.degree. C.

Abstract translation: 可溶性基材上的基于胶体金的紫色和用于在玻璃，陶瓷和瓷器上生产紫色装饰的用途是已知的。 这种紫色的制作是精心制作的。 应将本发明的试剂视为颜料前体，其中颜料在装饰的烧制过程中形成。 除了金氧化物之外，这些试剂含有金化合物，其可以在装饰物烧制时分解成胶态金，并且以金分子量与玻璃流量的重量比为1:10至1:2,000的细碎玻璃熔剂 。 优选的试剂含有作为金化合物的HAuCl4，Au2S3，AuCN或KAu（CN）2以及作为玻璃助熔剂的无铅玻璃料。 可以通过用金化合物研磨玻璃熔剂来获得试剂。 通过将该试剂涂布在待装饰的基材上并在400〜1050℃下保存而获得紫色装饰。