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公开(公告)号：US20100152504A1
公开(公告)日：2010-06-17
申请号：US12633420
申请日：2009-12-08
Applicant: Ryan Hulse , Rajiv R. Singh , Konstantin A. Pokrovski , Hsueh Sung Tung , Daniel Merkel , Haiyou Wang , Michael Van Der Puy
Inventor： Ryan Hulse , Rajiv R. Singh , Konstantin A. Pokrovski , Hsueh Sung Tung , Daniel Merkel , Haiyou Wang , Michael Van Der Puy
IPC: C07C21/18
CPC classification number: C07C17/358 , C07C17/383 , C07C21/18
Abstract: Disclosed are processes for an isomerization reaction between (E)1-chloro-3,3,3-trifluoropropene and (Z)1-chloro-3,3,3-trifluoropropene. Some of the disclosed processes include the step of contacting a feed stream with a heated surface, where the feed stream includes (E)1-chloro-3,3,3-trifluoropropene, (Z)1-chloro-3,3,3-trifluoropropene or mixtures thereof. The resulting product stream includes (E)1-chloro-3,3,3-trifluoropropene and (Z)1-chloro-3,3,3-trifluoropropene, where the ratio of (E) isomer to (Z) isomer in the product stream is different than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.
Abstract translation: 公开了（E）1-氯-3,3,3-三氟丙烯和（Z）1-氯-3,3,3-三氟丙烯之间异构化反应的方法。 一些所公开的方法包括使进料流与加热表面接触的步骤，其中进料流包含（E）1-氯-3,3,3-三氟丙烯，（Z）1-氯-3,3,3 - 三氟丙烯或其混合物。 所得产物流包含（E）1-氯-3,3,3-三氟丙烯和（Z）1-氯-3,3,3-三氟丙烯，其中（E）异构体与（Z）异构体的比例 产品流与进料流比不同。 产物流中的（E）和（Z）异构体可以彼此分离。
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公开(公告)号：US20070197841A1
公开(公告)日：2007-08-23
申请号：US11619589
申请日：2007-01-03
Applicant: Sudip Mukhopadhyay , Hsueh Tung , Michael Van Der Puy , Daniel Merkel , Jing Ji Ma , Cheryl Bortz , Barbara Light , Steven Phillips , Kim Fleming , Susan Ferguson
Inventor： Sudip Mukhopadhyay , Hsueh Tung , Michael Van Der Puy , Daniel Merkel , Jing Ji Ma , Cheryl Bortz , Barbara Light , Steven Phillips , Kim Fleming , Susan Ferguson
CPC classification number: C07C17/23 , C07C17/087 , C07C17/10 , C07C17/206 , C07C17/21 , C07C17/25 , C07C19/08 , C07C19/10 , C07C21/18
Abstract: Disclosed is a process for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of Formula (I): C(X)3CF2C(X)3 (I) to at least one compound of Formula (II) CF3CF═CHZ (II) where each X and Z is independently H, F, Cl, I or Br, said process preferably not including any substantial amount of oxygen-containing catalyst in certain embodiments. Preferably Z is H.
Abstract translation: 公开了一种生产含氟有机化合物的方法，包括氢氟丙烯，其优选包括转化至少一种式（I）的化合物：<？在线式描述=“在线式”末端=“铅”→> （X）3 C（X）3（I）<？in-line-formula description =“In-line Formulas” 结束=“尾”→至少一种式（II）的化合物<？在线公式描述=“在线公式”end =“lead”？> CF 3 CF- CHZ（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X和Z独立地为H，F，Cl，I或Br，所述方法优选不包括任何实质 在某些实施方案中含氧催化剂的量。 Z优选为
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公开(公告)号：US20060235248A1
公开(公告)日：2006-10-19
申请号：US11452856
申请日：2006-06-14
Applicant: Hsueh Tung , Daniel Merkel , Rajiv Singh
Inventor： Hsueh Tung , Daniel Merkel , Rajiv Singh
IPC: C07C19/08
Abstract: The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc can also be made from the dehydrofluorination of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa). HFC-1225zc) is a compound that has the potential to be used as a low Global Warming Potential refrigerant, blowing agent, aerosol propellant, or solvent.
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4.发明申请ENTERPRISE PERFORMANCE MANAGEMENT PLANNING OPERATIONS AT AN ENTERPRISE DATABASE 有权企业绩效管理企业数据库中的规划操作公开(公告)号：US20150149258A1
公开(公告)日：2015-05-28
申请号：US14151488
申请日：2014-01-09
Applicant: Jan Rittinger , Bernhard Jaecksch , Daniel Merkel , Gerrit Simon Kazmaier , Lars Volker , Stefan Uhrig , Yeonghee Choi
Inventor： Jan Rittinger , Bernhard Jaecksch , Daniel Merkel , Gerrit Simon Kazmaier , Lars Volker , Stefan Uhrig , Yeonghee Choi
IPC: G06Q10/06
CPC classification number: G06Q10/0637
Abstract: According to some embodiments, input data may be received from a data source in an enterprise database in accordance with an enterprise performance management planning model, stored by a processor at the enterprise database. An operation may then be performed on the input data to produce a result. The result may then be stored in a data target, wherein the data target points to a data holding entity in an instantiation of a plan data container at the enterprise database.
Abstract translation: 根据一些实施例，可以根据由企业数据库处理器存储的企业性能管理规划模型从企业数据库中的数据源接收输入数据。 然后可以对输入数据执行操作以产生结果。 然后将结果存储在数据目标中，其中数据目标指向企业数据库中的计划数据容器的实例化中的数据保存实体。
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公开(公告)号：US20070197842A1
公开(公告)日：2007-08-23
申请号：US11619592
申请日：2007-01-03
Applicant: Sudip Mukhopadhyay , Hsueh Tung , Barbara Light , Steven Phillips , Jing Ma , Cheryl Bortz , Michael Van Der Puy , Daniel Merkel , Rajesh Dubey
Inventor： Sudip Mukhopadhyay , Hsueh Tung , Barbara Light , Steven Phillips , Jing Ma , Cheryl Bortz , Michael Van Der Puy , Daniel Merkel , Rajesh Dubey
CPC classification number: C07C17/25 , C07C17/00 , C07C17/04 , C07C17/087 , C07C17/10 , C07C17/20 , C07C17/204 , C07C17/206 , C07C17/21 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18 , C07C19/01 , C07C19/10 , C07C19/08 , C07C21/073 , C07C21/04
Abstract: Disclosed are processes for the production of fluorinated olefins, preferably adapted to commercialization of CF3CF═CH2 (1234yf). Three steps may be used in preferred embodiments in which a feedstock such as CCl2═CClCH2Cl (which may be purchased or synthesized from 1,2,3-trichloropropane) is fluorinated (preferably with HF in gas-phase in the presence of a catalyst) to synthesize a compound such as CF3CCl═CH2, preferably in a 80-96% selectivity. The CF3CCl═CH2 is preferably converted to CF3CFClCH3 (244-isomer) using a SbCl5 as the catalyst which is then transformed selectively to 1234yf, preferably in a gas-phase catalytic reaction using activated carbon as the catalyst. For the first step, a mixture of Cr2O3 and FeCl3/C is preferably used as the catalyst to achieve high selectivity to CF3CCl═CH2 (96%). In the second step, SbCl5/C is preferably used as the selective catalyst for transforming 1233xf to 244-isomer, CF3CFClCH3. The intermediates are preferably isolated and purified by distillation and used in the next step without further purification, preferably to a purity level of greater than about 95%.
Abstract translation: 公开了用于生产氟化烯烃的方法，优选适于CF 3 CH 2 CH 2（1234yf）的商业化。 在优选实施方案中可以使用三个步骤，其中原料如CCl 2 -CClCH 2 Cl（其可以从1,2,3-三氯丙烷购买或合成） 被氟化（优选在催化剂存在下在气相中用HF）合成化合物如CF 3 CCl-CH 2，优选在80-96 ％选择性。 CF 3 CCl-CH 2 2优选使用以下化合物转化为CF 3 CFClCH 3（244-异构体） SbCl 5作为催化剂，然后将其选择性地转化为1234yf，优选在使用活性炭作为催化剂的气相催化反应中进行。 对于第一步，优选使用Cr 2 O 3 O 3和FeCl 3 / C的混合物作为催化剂以实现对CF的高选择性 3 CCl-CH 2（96％）。 在第二步中，优选使用SbCl 5 / C作为将1233xf转化为244-异构体CF 3 CFClCH 3的选择性催化剂。 中间体优选通过蒸馏分离和纯化，并用于下一步骤而不进一步纯化，优选纯度高于约95％。
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Patent Agency Ranking
公开(公告)号：US20070238908A1
公开(公告)日：2007-10-11
申请号：US11757782
申请日：2007-06-04
Applicant: Daniel Merkel , Rajiv Singh , Hsueh Tung
Inventor： Daniel Merkel , Rajiv Singh , Hsueh Tung
IPC: C07C21/18
CPC classification number: C07C21/18 , C07C17/206 , C07C17/25 , C07C19/10 , C07C19/08
Abstract: Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fluorine, chlorine, bromine and iodine; and N and P are independently integers equal to 0, 1 or 2, provided that (N+P)=2.
Abstract translation: 用于从相应的卤代丙烷制备氟丙烯的脱卤化氢方法，其中氟丙烯具有式CF 3 C 1 -C 6 N N H P H，其中X Y独立地为氢或选自氟，氯，溴和碘的卤素; 并且N和P独立地为等于0,1或2的整数，条件是（N + P）= 2。
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公开(公告)号：US20070112228A1
公开(公告)日：2007-05-17
申请号：US11592415
申请日：2006-11-03
Applicant: Sudip Mukhopadhyay , Haridasan Nair , Hsueh Tung , Michael Van Der Puy , Daniel Merkel , Rajesh Dubey , Jing Ji Ma , Barbara Light , Kim Fleming , Cheryl Bortz , Richard Udy
Inventor： Sudip Mukhopadhyay , Haridasan Nair , Hsueh Tung , Michael Van Der Puy , Daniel Merkel , Rajesh Dubey , Jing Ji Ma , Barbara Light , Kim Fleming , Cheryl Bortz , Richard Udy
IPC: C07C17/093
CPC classification number: C07C17/00 , C07C17/02 , C07C17/04 , C07C17/10 , C07C21/18 , C07C19/08 , C07C19/10
Abstract: A method for preparing fluorinated organic compounds comprising contacting hydrogen fluoride with at least one compound of formula I: CX3CXYCH3 Iwhere each X is independently Cl, I or Br, and each Y is independently H or F, said contacting step being carried out under conditions effective to produce a compound of formula II CF3CZCH2 IIwhere Z is Cl, I, Br, or F.
Abstract translation: 一种制备氟化有机化合物的方法，包括使氟化氢与至少一种式I化合物接触：<？in-line-formula description =“In-Line Formulas”end =“lead”→> 3 其中每个X独立地为Cl，I或Br，并且每个Y独立地为H，其中每个X独立地为H， 或F，所述接触步骤在有效产生式II化合物的条件下进行。＆lt;线内公式描述=“在线配方”末端=“铅”→CF 3 CZCH II II <？in-line-formula description =“In-line Formulas”end =“tail”？>其中Z是Cl，I，Br或F.
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公开(公告)号：US20050070746A1
公开(公告)日：2005-03-31
申请号：US10671810
申请日：2003-09-26
Applicant: Hsueh Tung , Daniel Merkel , Rajiv Singh
Inventor： Hsueh Tung , Daniel Merkel , Rajiv Singh
Abstract: The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc can also be made from the dehydrofluorination of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa). HFC-1225zc) is a compound that has the potential to be used as a low Global Warming Potential refrigerant, blowing agent, aerosol propellant, or solvent.
Abstract translation: 本发明提供了制造氢氟烃1,1,3,3,3-五氟丙烯（HFC-1225zc）的经济方法。 HFC-1225zc可以由1-氯-1,1,3,3,3-五氟丙烷（HCFC-235fa）的脱氯化氢制成。 或者，HFC-1225zc也可以由1,1,1,3,3,3-六氟丙烷（HFC-236fa）的脱氟化氢制成。 HFC-1225zc）是具有潜在用作低全球变暖潜能的制冷剂，发泡剂，气溶胶推进剂或溶剂的化合物。
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公开(公告)号：US20050020862A1
公开(公告)日：2005-01-27
申请号：US10626997
申请日：2003-07-25
Applicant: Hsueh Tung , Robert Johnson , Daniel Merkel
Inventor： Hsueh Tung , Robert Johnson , Daniel Merkel
CPC classification number: B01J27/10 , B01J21/18 , C07C17/04 , C07C17/206 , C07C17/25 , C07C19/08 , C07C21/18 , C07C19/10
Abstract: The invention provides an economic process for the manufacture of 1,3,3,3-tetrafluoropropene (HFC-1234ze) by a two stage process. A hydrofluorination of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) into 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) and 1,1,1,3,3-pentafluoropropane (HFC-245fa) is conducted, followed by the dehydrochlorination of HCFC-244fa and dehydrofluorination of HFC-245fa into HFC-1234ze.
Abstract translation: 本发明提供了通过两阶段方法制备1,3,3,3-四氟丙烯（HFC-1234ze）的经济方法。 将1-氯-3,3,3-三氟丙烯（HCFC-1233zd）氢氟化为1-氯-1,3,3,3-四氟丙烷（HCFC-244fa）和1,1,1,3,3-五氟丙烷 （HFC-245fa），然后将HCFC-244fa的脱氯化氢和HFC-245fa的脱氟化氢分解成HFC-1234ze。
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公开(公告)号：US09922300B2
公开(公告)日：2018-03-20
申请号：US14151488
申请日：2014-01-09
Applicant: Jan Rittinger , Bernhard Jaecksch , Daniel Merkel , Gerrit Simon Kazmaier , Lars Volker , Stefan Uhrig , Yeonghee Choi
Inventor： Jan Rittinger , Bernhard Jaecksch , Daniel Merkel , Gerrit Simon Kazmaier , Lars Volker , Stefan Uhrig , Yeonghee Choi
CPC classification number: G06Q10/0637
Abstract: According to some embodiments, input data may be received from a data source in an enterprise database in accordance with an enterprise performance management planning model, stored by a processor at the enterprise database. An operation may then be performed on the input data to produce a result. The result may then be stored in a data target, wherein the data target points to a data holding entity in an instantiation of a plan data container at the enterprise database.
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