公开(公告)号：US06849340B1

公开(公告)日：2005-02-01

申请号：US10130939

申请日：2000-11-24

申请人： Didier Dhaler ,  André Lievre ,  Christian Mirou ,  Christophe Guyot

发明人： Didier Dhaler ,  André Lievre ,  Christian Mirou ,  Christophe Guyot

IPC分类号： C09D183/06 ,  C09J7/02 ,  B32B25/20

CPC分类号： C09D183/06 ,  C09J7/401 ,  C09J2203/334 ,  C09J2205/31 ,  C09J2433/005 ,  C09J2483/005 ,  Y10T428/31663 ,  C08L83/00 ,  C08L2666/04

摘要： The invention concerns a silicone/adhesive complex including at least one silicone coating applied on a first support and an adhesive coating applied on a second support, wherein the release force of a silicone/adhesive interface is capable of being modulated. The invention is characterized in that its silicone coating results from polymerization and/or curing by cationic process of polyorganosiloxane monomers, oligomers and/or polymers bearing as reactive groups at least epoxy, oxetane, dioxolane and/or alkenylether functions and the silicone coating further includes at least an additive regulating the release force of a silicone/adhesive interface and whereof the activity is photochemically initiated and adjustable.

摘要翻译： 本发明涉及一种硅氧烷/粘合剂复合物，其包括施加在第一载体上的至少一种硅氧烷涂层和施加在第二载体上的粘合剂涂层，其中硅氧烷/粘合剂界面的释放力能够被调制。 本发明的特征在于，其硅氧烷涂层是由至少环氧，氧杂环丁烷，二氧戊环和/或烯烃醚官能团作为反应性基团的聚有机硅氧烷单体，低聚物和/或聚合物的阳离子方法的聚合和/或固化而得到的，硅氧烷涂层还包括 至少一种调节硅酮/粘合剂界面释放力的添加剂，其活性是光化学引发和调节的。

公开(公告)号：US20050020764A1

公开(公告)日：2005-01-27

申请号：US10478868

申请日：2002-06-04

申请人： Didier Dhaler ,  John White

发明人： Didier Dhaler ,  John White

IPC分类号： C09K3/00 ,  C08L83/04 ,  C08L83/05 ,  C08L83/06 ,  C08L83/07 ,  C09D183/04 ,  C09D183/05 ,  C09D183/06 ,  C09J7/02

CPC分类号： C09D183/06 ,  C08G77/12 ,  C08G77/14 ,  C08G77/16 ,  C08G77/20 ,  C08G77/80 ,  C08L83/04 ,  C08L83/06 ,  C09D183/04 ,  C08L83/00

摘要： The invention concerns a novel release regulating silicone composition, and its use for preparing curable release compositions (Si-II/Si-Vi), adapted to be applied on substrates so as to facilitate removal of adhesive materials reversibly glued on said substrates. The invention aims at providing adhesion modifiers highly efficient in terms of regulating power and without negative effect on the instantaneous tackiness of adhesive materials laminated on the release silicone coating. Therefor the invention provides a release regulating system based on: 96 to 85 parts by weight of at least a reactive polyorganosiloxane resin (A) of the type: MDViQ, MDViT, MMHexenylQ, or MMAllyloxypropylQ: 4 to 15 parts by weight of at least a non-reactive resin (B) of the type: MD′Q, MDD′Q, MDT′, MQ or MDQ. The invention also concerns the use of a regulating system for preparing release compositions containing a linear polyorganosiloxane, said regulating system, a hydrosilylation inhibitor, a linear crosslinking polyorganohalogenosiloxane and a hydrosilylation catalyst.

摘要翻译： 本发明涉及一种新型释放调节硅酮组合物及其用于制备适用于基材上的可固化脱模组合物（Si-II / Si-Vi）的用途，以便于去除可逆地胶合在所述基材上的粘合剂材料。 本发明的目的是在调节功率方面提供高效的粘合改性剂，并且不会对层压在剥离硅氧烷涂层上的粘合剂材料的瞬时粘合性产生不利影响。 因此本发明提供一种释放调节系统，其基于：96至85重量份的至少一种类型为MDViQ，MDViT，MMHexenylQ或MMAllyloxypropyl Q的反应性聚有机硅氧烷树脂（A）：4至15重量份的至少一种 非反应性树脂（B）类型：MD'Q，MDD'Q，MDT'，MQ或MDQ。 本发明还涉及调节系统用于制备含有线性聚有机硅氧烷，所述调节系统，氢化硅烷化抑制剂，线性交联聚有机卤代硅氧烷和氢化硅烷化催化剂的释放组合物的用途。

公开(公告)号：US08101241B2

公开(公告)日：2012-01-24

申请号：US12123974

申请日：2008-05-20

申请人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

发明人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

IPC分类号： B05D3/02 ,  C08L83/04

CPC分类号： D21H19/32 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C08L83/04 ,  C09D183/04 ,  D21H21/16 ,  D21H27/001 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L83/00

摘要： The invention relates to crosslinkable or crosslinked silicone compositions capable of being used to form a water-repellent and release coating for a flexible support made of paper or of polymer, in particular a heat-sensitive flexible support. These compositions are of the type of those comprising crosslinking polyorganosiloxanes carrying SiH units and unsaturated, preferably vinylated, polyorganosiloxanes capable of reacting with the crosslinking agent by polyaddition in the presence of platinum to form the release crosslinked coating on the flexible support.The targeted aim is to make possible the instantaneous crosslinking at low temperature (85-90° C.) of such silicone compositions coated on flexible supports at a very high speed.To achieve this aim, the invention provides for the use of specific crosslinking agents composed of POSs hydrogenated at the chain end and in the chain.The invention also relates to the silicone compositions of solvent-free type or of emulsion type comprising the Si-Vi POS, the SiH POS crosslinking agent α,ω-bis(hydrodimethylsiloxyl)poly(hydromethyl)-(dimethyl)siloxane, and the platinum catalyst, inter alia.Applications: release silicone coatings obtained by crosslinking/polyaddition for heat-sensitive flexible supports, for example polymeric films made of polyethylene.

摘要翻译： 本发明涉及可交联或交联的硅氧烷组合物，其能够用于形成由纸或聚合物，特别是热敏性柔性载体制成的柔性载体的防水和防粘涂层。 这些组合物是包含交联含有SiH单元的聚有机硅氧烷和不饱和的，优选乙烯基化的聚有机硅氧烷的那些类型的那些，其能够在铂存在下通过加聚与交联剂反应以在柔性载体上形成释放交联涂层。 目标的目标是使得可以以非常高的速度在这样的有机硅组合物的低温（85-90℃）下快速交联涂覆在柔性载体上。 为了达到这个目的，本发明提供了使用由在链末端和链中氢化的POS构成的特定交联剂。 本发明还涉及包含Si-Vi POS，SiH POS交联剂α，ω-双（氢二甲基甲硅烷氧基）聚（氢化甲基） - （二甲基）硅氧烷和铂的无溶剂型或乳液型的有机硅组合物 催化剂，特别是。 应用：通过用于热敏柔性载体的交联/加聚得到的硅氧烷涂层，例如由聚乙烯制成的聚合物膜。

公开(公告)号：US20050165194A1

公开(公告)日：2005-07-28

申请号：US10849466

申请日：2004-05-20

申请人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

发明人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

IPC分类号： C08G77/00

CPC分类号： D21H19/32 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C08L83/04 ,  C09D183/04 ,  D21H21/16 ,  D21H27/001 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L83/00

摘要： The invention relates to crosslinkable or crosslinked silicone compositions capable of being used to form a water-repellent and release coating for a flexible support made of paper or of polymer, in particular a heat-sensitive flexible support. These compositions are of the type of those comprising crosslinking polyorganosiloxanes carrying SiH units and unsaturated, preferably vinylated, polyorganosiloxanes capable of reacting with the crosslinking agent by polyaddition in the presence of platinum to form the release crosslinked coating on the flexible support. The targeted aim is to make possible the instantaneous crosslinking at low temperature (85-90° C.) of such silicone compositions coated on flexible supports at a very high speed. To achieve this aim, the invention provides for the use of specific crosslinking agents composed of POSs hydrogenated at the chain end and in the chain. The invention also relates to the silicone compositions of solvent-free type or of emulsion type comprising the Si-Vi POS, the SiH POS crosslinking agent α,ω-bis(hydrodimethylsiloxyl)poly(hydromethyl)-(dimethyl)siloxane, and the platinum catalyst, inter alia. Applications: release silicone coatings obtained by crosslinking/polyaddition for heat-sensitive flexible supports, for example polymeric films made of polyethylene.

摘要翻译： 本发明涉及可交联或交联的硅氧烷组合物，其能够用于形成由纸或聚合物，特别是热敏性柔性载体制成的柔性载体的防水和防粘涂层。 这些组合物是包含交联含有SiH单元的聚有机硅氧烷和不饱和的，优选乙烯基化的聚有机硅氧烷的那些类型的那些，其能够在铂存在下通过加聚与交联剂反应以在柔性载体上形成释放交联涂层。 目标的目标是使得可以以非常高的速度在这样的有机硅组合物的低温（85-90℃）下快速交联涂覆在柔性载体上。 为了达到这个目的，本发明提供了使用由在链末端和链中氢化的POS构成的特定交联剂。 本发明还涉及无溶剂型或包含Si-Vi POS，SiH POS交联剂α，ω-双（氢二甲基甲硅烷氧基）聚（氢化甲基） - （二甲基）硅氧烷和铂 催化剂，特别是。 应用：通过用于热敏柔性载体的交联/加聚得到的硅氧烷涂层，例如由聚乙烯制成的聚合物膜。

公开(公告)号：US20090149609A1

公开(公告)日：2009-06-11

申请号：US12123974

申请日：2008-05-20

申请人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

发明人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

IPC分类号： C08G77/04

CPC分类号： D21H19/32 ,  C08G77/12 ,  C08G77/20 ,  C08G77/70 ,  C08G77/80 ,  C08L83/04 ,  C09D183/04 ,  D21H21/16 ,  D21H27/001 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31855 ,  C08L83/00

摘要： The invention relates to crosslinkable or crosslinked silicone compositions capable of being used to form a water-repellent and release coating for a flexible support made of paper or of polymer, in particular a heat-sensitive flexible support. These compositions are of the type of those comprising crosslinking polyorganosiloxanes carrying SiH units and unsaturated, preferably vinylated, polyorganosiloxanes capable of reacting with the crosslinking agent by polyaddition in the presence of platinum to form the release crosslinked coating on the flexible support.The targeted aim is to make possible the instantaneous crosslinking at low temperature (85-90° C.) of such silicone compositions coated on flexible supports at a very high speed.To achieve this aim, the invention provides for the use of specific crosslinking agents composed of POSs hydrogenated at the chain end and in the chain.The invention also relates to the silicone compositions of solvent-free type or of emulsion type comprising the Si-Vi POS, the SiH POS crosslinking agent α,ω-bis(hydrodimethylsiloxyl)poly(hydromethyl)-(dimethyl)siloxane, and the platinum catalyst, inter alia.Applications: release silicone coatings obtained by crosslinking/polyaddition for heat-sensitive flexible supports, for example polymeric films made of polyethylene.

摘要翻译： 本发明涉及可交联或交联的硅氧烷组合物，其能够用于形成由纸或聚合物，特别是热敏性柔性载体制成的柔性载体的防水和防粘涂层。 这些组合物是包含交联含有SiH单元的聚有机硅氧烷和不饱和的，优选乙烯基化的聚有机硅氧烷的那些类型的那些，其能够在铂存在下通过加聚与交联剂反应以在柔性载体上形成释放交联涂层。 目标的目标是使得可以以非常高的速度在这样的有机硅组合物的低温（85-90℃）下快速交联涂覆在柔性载体上。 为了达到这个目的，本发明提供了使用由在链末端和链中氢化的POS构成的特定交联剂。 本发明还涉及无溶剂型或包含Si-Vi POS，SiH POS交联剂α，ω-双（氢二甲基甲硅烷氧基）聚（氢化甲基） - （二甲基）硅氧烷和铂 催化剂，特别是。 应用：通过用于热敏柔性载体的交联/加聚得到的硅氧烷涂层，例如由聚乙烯制成的聚合物膜。

公开(公告)号：US20050075020A1

公开(公告)日：2005-04-07

申请号：US10499671

申请日：2002-12-19

申请人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

发明人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

IPC分类号： B05D7/24 ,  C08G77/12 ,  C08J7/04 ,  C08L83/07 ,  C09D5/00 ,  C09D183/00 ,  C09D183/04 ,  C09D183/07 ,  D21H19/32 ,  D21H27/00 ,  B32B27/12

CPC分类号： C08J7/047 ,  C08G77/12 ,  C08J2483/00 ,  C09D183/04 ,  Y10T428/31663 ,  Y10T442/223 ,  Y10T442/2328 ,  C08L83/00

摘要： The invention concerns crosslinkable silicone compositions, useful for forming water-repellent and release coating for flexible heat-sensitive support. Said compositions comprise crosslinking polyorganosiloxanes (POS) bearing ≡Si—H units and unsaturated POS, for example ≡Si-Vi vinyl-containing POS, capable of reacting with the crosslinking agent by polyaddition, in the presence of platinum to form a release crosslinked coat on the flexible support. The invention aims at instantaneously enabling low platinum content crosslinking of such silicone compositions, coated at high speed. Therefor, the invention provides for the use of particular crosslinking agents consisting of hydrogenated POS comprising at least three hydrogen atoms bound to the silicon located at chain end and in the chain. The invention also concerns solvent-free or emulsion-type silicone compositions comprising the ≡Si-Vi POS (I.1), the crosslinking agent ≡Sl-H POS (l.2) and the platinum catalyst among others. The invention is useful for coating flexible supports, for example made of Lissé BEKK>1000 paper.

摘要翻译： 本发明涉及可交联的硅氧烷组合物，其可用于形成用于柔性热敏性载体的防水和脱模涂层。 所述组合物包含交联聚有机硅氧烷（POS）轴承= Si-H单元和不饱和POS，例如=含有Si-Vi乙烯基的POS，其能够在铂存在下通过加聚与交联剂反应形成释放交联涂层 在灵活的支持下。 本发明旨在瞬时实现高速涂布的这种硅氧烷组合物的低铂含量交联。 因此，本发明提供了使用由氢化POS构成的特定交联剂，所述氢化POS包含至少三个与位于链末端和链中的硅结合的氢原子。 本发明还涉及包含= Si-Vi POS（I.1），交联剂= S1-H POS（1.2）和铂催化剂等的无溶剂或乳液型有机硅组合物。 本发明可用于涂覆柔性支撑件，例如由LisséBEKK> 1000纸制成。

公开(公告)号：US20050053793A1

公开(公告)日：2005-03-10

申请号：US10493577

申请日：2002-10-24

申请人： Jean-Paul Benay-Oun ,  Didier Dhaler ,  Jacques Keiffer ,  Frederic Magd ,  John White

发明人： Jean-Paul Benay-Oun ,  Didier Dhaler ,  Jacques Keiffer ,  Frederic Magd ,  John White

IPC分类号： C08L83/07 ,  C08K5/057 ,  C08K5/5425 ,  C08K5/5435 ,  C08L83/05 ,  C09D183/04 ,  C09J7/00 ,  D06M13/513 ,  D06M15/643 ,  B32B9/04 ,  C08L83/04

CPC分类号： C09D183/04 ,  Y10T428/31663 ,  C08L2666/28 ,  C08L83/00 ,  C08L2666/52 ,  C08L2666/44

摘要： The invention relates to a liquid silicone formulation for the preparation of water-repellent and release crosslinked elastomer coatings on a solid support, for example made of paper. The targeted aim is to overcome the problem of the lack of adhesion of silicone elastomer films with a release outer face intended to be adhesively bonded to flexible supports of the following types: dense paper of glassine type or polypropylene polymer film. To achieve this aim, the liquid silicone formulation according to the invention which can be used as coating base for the preparation at very high speed of a water-repellent and release crosslinked elastomer coating on a solid support comprises: at least one crosslinkable polyorganosiloxane POS (I) (POS of SiVi type and POS of SiH type); at least one catalyst (II) (platinum-based); optionally an adhesion-adjusting system (III); an adhesion promoter (IV) comprising an epoxidized alkoxysilane and/or an alkenylated alkoxysilane, and a metal chelate and/or a metal alkoxide (GLYMO/MEMO/TiOBu4). The most viscous POS (I) has a viscosity of less than or equal to 1500 mPa·s.

摘要翻译： 本发明涉及一种用于制备在固体支持物上例如由纸制成的防水和释放交联弹性体涂层的液体硅氧烷配方。 目的在于克服以下问题：具有释放外表面的硅氧烷弹性体膜的粘合性不能与以下类型的柔性载体粘合：玻璃纤维或聚丙烯聚合物膜的致密纸。 为了达到这个目的，本发明的液体硅氧烷配方可以用作在非常高的速度下制备用于固体支持物的防水和释放交联弹性体涂层的涂布基底，包括：至少一种可交联聚有机硅氧烷POS（ I）（SiVi型POS和SiH型POS）; 至少一种催化剂（II）（基于铂）; 任选的粘合调节系统（III）; 包含环氧烷氧基硅烷和/或烯基烷氧基硅烷的粘合促进剂（IV）和金属螯合物和/或金属醇盐（GLYMO / MEMO / TiOBu4）。 最粘稠的POS（I）的粘度小于或等于1500mPa.s。

公开(公告)号：US07790785B2

公开(公告)日：2010-09-07

申请号：US11166380

申请日：2005-06-27

申请人： Francis Lafaysse ,  Pierre Luciani ,  Didier Dhaler ,  Laurent Dumont ,  Jean-Marc Frances

发明人： Francis Lafaysse ,  Pierre Luciani ,  Didier Dhaler ,  Laurent Dumont ,  Jean-Marc Frances

IPC分类号： C09D5/16 ,  C09J4/00 ,  C08K3/38

CPC分类号： C09D163/00 ,  C08G59/306 ,  C08K5/151 ,  C08K5/5435 ,  C08K5/55 ,  C09D183/06 ,  Y10T428/2962 ,  Y10T428/31663 ,  Y10T442/2525 ,  C08L2666/46

摘要： Silicone compositions particularly useful for the production of anti-fouling varnishes for application to support substrates, these providing an anti-fouling varnish for textiles covered with silicone elastomers which is economical, adhesive, non-slip and glossy; the subject varnishes comprise a crosslinkable silicone composition containing, per 100 parts by weight: 1, at least 80 parts by weight of: (1.1), 2., 0.1 to 10 parts of weight of: (1.2), 3., 0 to 10 parts by weight of at least one polydimethylisiloxane (PDMS) acrylate or epoxide, 4., 0 to 10 parts by weight of at least one silylated compound which includes at least one ultrafine filler, 7., 0 to 10 parts by weight of at least one thickener, and 8., 0 to 10 parts by weigh of at least one additional functional additive.

摘要翻译： 硅胶组合物特别可用于生产用于支撑基材的防污清漆，这些提供了用于经济，粘合，防滑和有光泽的硅氧烷弹性体覆盖的织物的防污清漆; 所述清漆包含每100重量份的交联性硅氧烷组合物：1，至少80重量份：（1.1），2.，0.1至10重量份：（1.2），3.，0至 10重量份的至少一种聚二甲基硅氧烷（PDMS）丙烯酸酯或环氧化物，4. 0至10重量份的至少一种甲硅烷基化合物，其包括至少一种超细填料，7. 0至10重量份的 至少一种增稠剂和8.,0至10份重量的至少一种其它功能添加剂。

公开(公告)号：US20090003633A1

公开(公告)日：2009-01-01

申请号：US12160912

申请日：2007-01-04

申请人： Valerie Thoraval ,  Didier Dhaler

发明人： Valerie Thoraval ,  Didier Dhaler

IPC分类号： H04R1/00

CPC分类号： H04R1/345 ,  H04R1/24 ,  H04R9/06 ,  H04R2201/021 ,  H04R2201/025 ,  H04R2499/13

摘要： The invention relates to a filter element comprising a support with an outside surface and at least three channels in the support. The channels comprise a peripheral wall directed towards the outside surface, the distance between the peripheral wall and the outside surface reducing on each side of the middle of the peripheral wall. The element has the advantage of improved strength when subject to severe conditions of use.

摘要翻译： 本发明涉及一种过滤器元件，其包括具有外表面的支撑件和支撑件中的至少三个通道。 通道包括指向外表面的周壁，周壁与外表面之间的距离在周壁的中间的每一侧减小。 该元件具有当受到苛刻使用条件时强度提高的优点。

公开(公告)号：US07273658B2

公开(公告)日：2007-09-25

申请号：US10499671

申请日：2002-12-19

申请人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

发明人： Jean-Paul Benayoun ,  Didier Dhaler ,  Jacques Kieffer ,  John White

IPC分类号： B32B9/04

CPC分类号： C08J7/047 ,  C08G77/12 ,  C08J2483/00 ,  C09D183/04 ,  Y10T428/31663 ,  Y10T442/223 ,  Y10T442/2328 ,  C08L83/00

摘要： The invention concerns crosslinkable silicone compositions, useful for forming water-repellent and release coating for flexible heat-sensitive support. Said compositions comprise crosslinking polyorganosiloxanes (POS) bearing ≡Si—H units and unsaturated POS, for example ≡Si-Vi vinyl-containing POS, capable of reacting with the crosslinking agent by polyaddition, in the presence of platinum to form a release crosslinked coat on the flexible support. The invention aims at instantaneously enabling low platinum content crosslinking of such silicone compositions, coated at high speed. Therefor, the invention provides for the use of particular crosslinking agents consisting of hydrogenated POS comprising at least three hydrogen atoms bound to the silicon located at chain end and in the chain. The invention also concerns solvent-free or emulsion-type silicone compositions comprising the ≡Si-Vi POS (I.1), the crosslinking agent ≡Sl-H POS (l.2) and the platinum catalyst among others. The invention is useful for coating flexible supports, for example made of Lissé BEKK>1000 paper.

摘要翻译： 本发明涉及可交联的硅氧烷组合物，其可用于形成用于柔性热敏性载体的防水和脱模涂层。 所述组合物包含具有≡Si-H单元和不饱和POS的交联聚有机硅氧烷（POS），例如≡Si-Vi含乙烯基的POS，其能够在铂存在下通过加聚与交联剂反应以形成释放交联涂层 在灵活的支持下。 本发明旨在瞬时实现高速涂布的这种硅氧烷组合物的低铂含量交联。 因此，本发明提供了使用由氢化POS构成的特定交联剂，所述氢化POS包含至少三个与位于链末端和链中的硅结合的氢原子。 本发明还涉及包含≡Si-Vi POS（I.1），交联剂≡S-H POS（1.2）和铂催化剂等的无溶剂或乳液型有机硅组合物。 本发明可用于涂覆柔性支撑件，例如由LisséBEKK> 1000纸制成。