公开(公告)号：US20140014180A1

公开(公告)日：2014-01-16

申请号：US13996588

申请日：2011-11-17

申请人： Stéphane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset

发明人： Stéphane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset

IPC分类号： H01L31/048

CPC分类号： H01L31/0481 ,  B32B27/06 ,  Y02E10/50 ,  Y10T428/239 ,  Y10T428/24967 ,  Y10T428/31757

摘要： An encapsulant for a photovoltaic module, intended to coat a photovoltaic cell, including at least two adjacent thermoplastic layers forming a core-skin assembly, wherein the skin layer consists of a polyamide-grafted polymer including a polyolefin backbone, representing from 50% to 95% by weight of the polyamide-grafted polymer, containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, representing from 5% to 50% by weight of polyamide-grafted polymer, the core layer including a polyethylene chosen from a homopolymer of ethylene or a copolymer including at least 50 mol % of ethylene and one or more comonomers. Also, a photovoltaic module incorporating such an encapsulant.

摘要翻译： 一种用于光伏模块的密封剂，其用于包覆光伏电池，包括形成芯 - 皮组件的至少两个相邻的热塑性层，其中所述表层由包含聚烯烃主链的聚酰胺接枝聚合物组成，代表50％至95 含有至少一种不饱和单体（X）和至少一种聚酰胺接枝物的聚酰胺接枝聚合物的重量％，代表聚酰胺接枝聚合物重量的5％至50％，核心层包括聚乙烯 选自乙烯均聚物或包含至少50mol％乙烯和一种或多种共聚单体的共聚物。 而且，包含这种密封剂的光伏模块。

公开(公告)号：US20140026960A1

公开(公告)日：2014-01-30

申请号：US13984468

申请日：2012-01-12

申请人： Stéphane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset

发明人： Stéphane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset

IPC分类号： H01L31/048

CPC分类号： H01L31/0481 ,  B32B27/08 ,  B32B27/32 ,  B32B2457/12 ,  C08G81/028 ,  Y02E10/50 ,  Y10T428/31928

摘要： An encapsulant for a photovoltaic module, intended to coat a photovoltaic cell, including at least two adjacent thermoplastic layers together forming a core-skin assembly: the skin layer is a polyamide graft polymer including a polyolefin backbone representing 50 wt % to 95 wt % of the polyamide graft polymer, containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, representing 5 wt % to 50 wt % of said polyamide graft polymer; the polyolefin backbone and the polyamide graft of the skin layer are chosen so that the polyamide graft polymer has a flow temperature greater than or equal to 75° C. and less than or equal to 160° C., this flow temperature being defined as the highest temperature out of the melting temperature and the glass transition temperature of the polyamide graft and of the polyolefin backbone.

摘要翻译： 一种用于光伏组件的密封剂，其旨在将包括至少两个相邻的热塑性层的光伏电池包覆在一起形成芯 - 皮组件：表层是聚酰胺接枝聚合物，其包含聚烯烃主链，占50重量％至95重量％ 所述聚酰胺接枝聚合物含有至少一种不饱和单体（X）的残余物和至少一种聚酰胺接枝物，占所述聚酰胺接枝聚合物的5重量％至50重量％ 选择表面层的聚烯烃骨架和聚酰胺接枝物，使得聚酰胺接枝聚合物的流动温度大于或等于75℃且小于或等于160℃，该流动温度定义为 聚酰胺接枝物和聚烯烃主链的熔融温度和玻璃化转变温度以外的最高温度。

公开(公告)号：US20140000707A1

公开(公告)日：2014-01-02

申请号：US13984549

申请日：2012-01-12

申请人： Stephane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset ,  Gregory O'Brien ,  Amy Lefebvre

发明人： Stephane Bizet ,  Samuel Devisme ,  Thomas Fine ,  Dominique Jousset ,  Gregory O'Brien ,  Amy Lefebvre

IPC分类号： H01L31/0203

CPC分类号： H01L31/0203 ,  B32B27/08 ,  B32B27/32 ,  B32B2250/02 ,  B32B2250/24 ,  B32B2457/12 ,  C08G81/028 ,  H01L31/0481 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/3154 ,  Y10T428/31728

摘要： A double-layer thermoplastic film of a photovoltaic module, including two layers, one forms the encapsulator and the other forms the backsheet, wherein: a) the encapsulator is a layer including at least one polyolefin containing a polyethylene selected from a homopolymer of ethylene or a copolymer comprising at least 50 mol % of ethylene and at least one comonomer and between 0% and 100% of a polyamide grafted polymer comprising a polyolefin trunk that represents between 50 mass % and 95 mass % of the polyamide grafted polymer containing a radical of at least one unsaturated monomer (X) and at least one polyamide graft that represents between 5 mass % and 50 mass % of said polyamide grafted polymer; and b) the backsheet comprises a layer formed from a polyamide grafted polymer that is identical to that of the encapsulator except that it has a flow temperature higher than 160° C.

摘要翻译： 包括两层的光伏模块的双层热塑性膜形成封装体，另一层形成底片，其中：a）封装剂是包含至少一种含有聚乙烯的层，所述聚烯烃选自乙烯的均聚物或 包含至少50摩尔％乙烯和至少一种共聚单体和0％至100％的聚酰胺接枝聚合物的共聚物，所述聚酰胺接枝聚合物包含聚烯烃树脂，所述聚烯烃树脂占聚合物接枝聚合物的50质量％至95质量％ 至少一种不饱和单体（X）和至少一种代表所述聚酰胺接枝聚合物的5质量％至50质量％的聚酰胺接枝物; 和b）底片包括由与聚合物接枝的聚合物形成的层，其与除了具有高于160℃的流动温度之外的封装剂相同。

公开(公告)号：US20110315199A1

公开(公告)日：2011-12-29

申请号：US13139594

申请日：2009-12-15

申请人： Marc Vogt ,  Dominique Jousset ,  Stéphane Bizet ,  Jean-Jacques Flat

发明人： Marc Vogt ,  Dominique Jousset ,  Stéphane Bizet ,  Jean-Jacques Flat

IPC分类号： H01L31/048 ,  H01L31/0216 ,  C08L77/00 ,  C08F291/06 ,  C08L51/00 ,  B32B37/00 ,  H01L31/0203

CPC分类号： C08G81/028 ,  C08L23/0869 ,  H01L31/049 ,  Y02E10/50 ,  C08L2666/20

摘要： One subject of the invention is the use of α film as a protective backsheet in a photovoltaic module, said film comprising at least one layer of a composition containing a polyamide-grafted polymer, this polyamide-grafted polymer comprising a polyolefin backbone containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, in which: • the polyamide graft is attached to the polyolefin backbone by the residue of the unsaturated monomer (X) that comprises a functional group capable of reacting via a condensation reaction with a polyamide having at least one amine end group and/or at least one carboxylic acid end group; • the residue of the unsaturated monomer (X) is attached to the backbone by grafting or copolymerization; said polyamide-grafted polymer comprising, relative to its total weight: • from 40 to 95% by weight of the polyolefin backbone comprising the unsaturated monomer (X); and • from 5 to 60% by weight of polyamide grafts, and the melting point or glass transition temperature of the polyamide grafts being greater than or equal to 85° C. The invention also relates to a process of manufacturing a photovoltaic module, to a photovoltaic module and also to the use of this module for producing electricity.

摘要翻译： 本发明的一个主题是在光伏模块中使用α膜作为保护性底片，所述膜包括至少一层含有聚酰胺接枝聚合物的组合物，该聚酰胺接枝聚合物包含聚烯烃主链，其含有 至少一种不饱和单体（X）和至少一种聚酰胺接枝物，其中：•聚酰胺接枝物通过不饱和单体（X）的残基连接到聚烯烃主链上，该不饱和单体（X）包含能够通过缩合反应进行反应的官能团 与具有至少一个胺端基和/或至少一个羧酸端基的聚酰胺; •不饱和单体（X）的残基通过接枝或共聚连接到骨架上; 所述聚酰胺接枝聚合物相对于其总重量包含：•40至95重量％的包含不饱和单体（X）的聚烯烃主链; 和•5至60重量％的聚酰胺接枝物，并且聚酰胺接枝物的熔点或玻璃化转变温度大于或等于85℃。本发明还涉及制造光伏组件的方法， 光伏组件以及该模块用于生产电力。

公开(公告)号：US08883899B2

公开(公告)日：2014-11-11

申请号：US13881491

申请日：2011-10-18

申请人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

发明人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC分类号： H01B3/44 ,  F16L57/04 ,  C08L53/00 ,  C08G81/02 ,  C08L87/00 ,  C08L33/16

CPC分类号： H01B3/447 ,  C08G81/028 ,  C08L33/16 ,  C08L53/00 ,  C08L87/005 ,  F16L57/04

摘要： A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.

摘要翻译： 一种阻燃热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物通过具有功能的不饱和单体（X）的残基连接到主链上 能够与聚酰胺反应，不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上，其中组合物包括：含有聚酰胺的接枝共聚物的60重量％至70重量％ （聚丙烯酸五溴苄酯）的22重量％至28重量％，4重量％至8重量％的协同阻燃剂，其选自三氧化锑，锡，钼和/或铋的衍生物，以及硼 和氧化锌，硼酸钙，硫酸钙和/或锡酸锌，占亲水处理粘土的0.5重量％至5重量％。

公开(公告)号：US08841542B2

公开(公告)日：2014-09-23

申请号：US13500648

申请日：2010-10-07

申请人： Pierre Gerard ,  Stephane Bizet ,  Dominique Jousset

发明人： Pierre Gerard ,  Stephane Bizet ,  Dominique Jousset

IPC分类号： H01L31/048 ,  C08F293/00 ,  C08L53/00 ,  B32B17/10

CPC分类号： C08L53/00 ,  B32B17/10743 ,  C08F293/005 ,  H01L31/048 ,  H01L31/0481 ,  Y02E10/50

摘要： The present invention relates to a photovoltaic module comprising as an encapsulant a composition comprising at least one polyacrylate- or polymethacrylate-type block copolymer with the general formula B-(A)n, n being a natural integer no lower than one, preferably 1 to 8, the block A being selected from among methacrylates having a Tg higher than 0° C., the block B being a polyacrylate or a polymethacrylate having a Tg lower than 0° C., the block B being at least 50 wt % of the total weight of the block copolymer.

摘要翻译： 本发明涉及一种光伏组件，其包含作为密封剂的组合物，该组合物包含至少一种具有通式B-（A）n的聚丙烯酸酯或聚甲基丙烯酸酯型嵌段共聚物，n为不低于1的自然整数，优选1至 如图8所示，嵌段A选自Tg高于0℃的甲基丙烯酸酯，嵌段B为Tg低于0℃的聚丙烯酸酯或聚甲基丙烯酸酯，嵌段B为至少50重量％ 嵌段共聚物的总重量。

公开(公告)号：US08779060B2

公开(公告)日：2014-07-15

申请号：US12667265

申请日：2008-07-01

申请人： Marius Hert ,  Dominique Jousset

发明人： Marius Hert ,  Dominique Jousset

IPC分类号： C08L23/08 ,  C08L23/10 ,  C08L77/00 ,  C08F255/00 ,  C08L51/06 ,  C08F255/02 ,  C09D151/06 ,  C08L23/06 ,  C08L53/00 ,  C08L23/16 ,  C08L23/12 ,  C09J151/06 ,  C08L23/22 ,  C08L23/36

CPC分类号： C08L51/06 ,  C08F255/00 ,  C08F255/02 ,  C08F255/026 ,  C08L23/06 ,  C08L23/0853 ,  C08L23/0869 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16 ,  C08L23/22 ,  C08L23/36 ,  C08L53/00 ,  C08L2205/03 ,  C08L2666/02 ,  C09D151/06 ,  C09J151/06 ,  C08L2666/24 ,  C08L2666/06

摘要： The mixture of the invention contains, for 100 parts in weight of (A)+(B): (A) 10 to 90 parts in weight of at least one non-nanostructured olefinic thermoplastic polymer; (B) 90 to 10 parts in weight of a formulation of at least one elastomer having unsaturated double bonds and capable of reacting with a cross-linking or vulcanization agent, said formulation containing a crosslinking or vulcanization system of said elastomer(s), at least one plasticizer, and the standard additives present in elastomer formulations; (C) up to 100 parts in weight, relative to (A)+(B), of at least one copolymer grafted with polyamide blocks, said copolymer comprising a polyolefin trunk and at least 1.3 polyamide grafts on said trunk in average, and having a nanostructured organization, wherein said grafts are attached to the trunk by the rest of an unsaturated monomer (X) having a function capable of reacting with a polyamide with an amine end; and rest of said unsaturated monomer (X) being attached on the trunk by grafting or copolymerization from its double bond thereof, and wherein (A) and (B) in the mixture can already have been combined together by the crosslinking or vulcanization dynamic method in order to provide a crosslinked or vulcanized thermoplastic composition.

摘要翻译： 对于100重量份的（A）+（B）：（A）10重量份的至少一种非纳米结构的烯属热塑性聚合物，本发明的混合物包含： （B）90至10份重量的至少一种具有不饱和双键且能够与交联或硫化剂反应的弹性体的制剂，所述制剂含有所述弹性体的交联或硫化体系， 至少一种增塑剂和弹性体配方中存在的标准添加剂; （C）至少一种接枝有聚酰胺嵌段共聚物的（A）+（B）至多100重量份，所述共聚物平均包含聚烯烃树干和至少1.3个聚酰胺接枝物，并且具有 纳米结构组织，其中所述移植物通过剩余的具有能够与聚酰胺与胺末端反应的功能的不饱和单体（X）连接到树干上; 并且其余所述不饱和单体（X）通过其双键接枝或共聚而附着在树干上，并且其中混合物中的（A）和（B）可以已经通过交联或硫化动力学方法组合在一起 以提供交联或硫化的热塑性组合物。

公开(公告)号：US20130247983A1

公开(公告)日：2013-09-26

申请号：US13879959

申请日：2011-10-18

申请人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

发明人： Dominique Jousset ,  Jean-Jacques Flat ,  Pierre Georlette

IPC分类号： H01L31/0203

CPC分类号： H01L31/0203 ,  C08G81/028 ,  C09K21/12 ,  H01L31/0481 ,  Y02E10/50

摘要： A transparent, fireproof thermoplastic composition which is free from halogen compounds and includes a polyamide-block graft copolymer formed by a polyolefin backbone and, on average, at least one polyamide graft. The grafts are attached to the backbone by the radicals of an unsaturated monomer (X) that has a function capable of reacting with a polyamide, and the radicals of the unsaturated monomer (X) are attached to the backbone by grafting or co-polymerisation from the double bond thereof. The composition includes, as a weight percentage of the total composition: 90 to 99 wt % of the polyamide-block graft copolymer, and 1 to 10 wt % of metal salts of phosphoric acid.

摘要翻译： 一种不含卤素化合物的透明耐火热塑性组合物，包括由聚烯烃主链和平均至少一个聚酰胺接枝物形成的聚酰胺嵌段接枝共聚物。 移植物通过具有能够与聚酰胺反应的功能的不饱和单体（X）的基团连接到主链上，并且不饱和单体（X）的基团通过接枝或共聚从 其双键。 该组合物包含总组合物的重量百分数：聚酰胺 - 嵌段共聚物的90-99重量％和磷酸金属盐的1-10重量％。

公开(公告)号：US20100256276A1

公开(公告)日：2010-10-07

申请号：US12667259

申请日：2008-07-01

申请人： Marius Hert ,  Dominique Jousset

发明人： Marius Hert ,  Dominique Jousset

IPC分类号： C08K5/12 ,  C08L51/00 ,  C08K5/01 ,  C08K3/22 ,  C08K3/34 ,  C08K5/101

CPC分类号： C08F255/02 ,  C08F255/00 ,  C08L51/06 ,  C08L2666/04 ,  C08L2666/02

摘要： The mixture of the invention contains, for 100 parts by weight: (A) 10 to 90 parts in weight of at least one copolymer grafted to polyamide blocks, said copolymer comprising a polyolefin trunk and at least 1.3 polyamide grafts on said trunk in average, and having a nanostructured organization, wherein said grafts are attached to the trunk by the rest of an unsaturated monomer (X) having a function capable of reacting with a polyamide with an amine end; the rest of said monomer (X) being attached on the trunk by grafting or copolymerization from its double bond thereof, (A) optionally including at least one non-grafted polyolefin in a proportion such that the nano-structured organization of the compound (A) is preserved; and (B) 90 to 10 parts in weight of a formulation of at least one elastomer having unsaturated double bonds and capable of reacting with a cross-linking or vulcanization agent, said formulation containing a crosslinking or vulcanization system of said elastomer(s), at least one plasticizer and the standard additives present in elastomer formulations.

摘要翻译： 对于100重量份，本发明的混合物包含：（A）10至90重量份的至少一种接枝到聚酰胺嵌段的共聚物，所述共聚物平均包含聚烯烃树干和所述树干上至少1.3个聚酰胺接枝物， 并且具有纳米结构组织，其中所述移植物通过剩余的具有能够与聚酰胺与胺末端反应的功能的不饱和单体（X）连接到树干上; 所述单体（X）的其余部分通过从其双键接枝或共聚而附着在树干上，（A）任选地包括至少一种非接枝聚烯烃，使得化合物（A ）保存; 和（B）90至10重量份的至少一种具有不饱和双键且能与交联或硫化剂反应的弹性体的制剂，所述制剂含有所述弹性体的交联或硫化体系， 至少一种增塑剂和弹性体配方中存在的标准添加剂。

公开(公告)号：US20120298195A1

公开(公告)日：2012-11-29

申请号：US13522054

申请日：2011-01-07

申请人： Dominique Plee ,  Dominique Jousset ,  Francois Beaume ,  Anthony Bonnet

发明人： Dominique Plee ,  Dominique Jousset ,  Francois Beaume ,  Anthony Bonnet

IPC分类号： H01L31/02 ,  B32B27/08 ,  B32B27/20

CPC分类号： H01L51/448 ,  H01L31/0481 ,  H01L51/5253 ,  Y02E10/549 ,  Y10T428/24975 ,  Y10T428/256

摘要： The invention relates to a multilayer structure that includes: a layer of a composition including a fluorinated polymer and a zinc oxide (ZnO), said ZnO being present in said composition in the form of particles having a weight proportion of less than 1%, said ZnO particles having a size between 10 to 100 nm, and an adhesion promoter present in the body and/or surface of said layer; and at least one oxide layer (MOx) selected from among silicon oxide and aluminum oxide, and having a thickness of from 20 to 200 nm. Aid structure has excellent properties of transparency within the visible range, excellent properties of opacity to UV rays, as well as good mechanical resistance and aging resistance while having excellent moisture barrier properties. Said structure can thus be advantageously used in the front surface of photovoltaic panels or fro protecting organic light-emitting diodes.

摘要翻译： 本发明涉及一种多层结构，其包括：包含氟化聚合物和氧化锌（ZnO）的组合物层，所述ZnO在所述组合物中以重量比例小于1％的颗粒形式存在，所述 尺寸在10至100nm之间的ZnO颗粒和存在于所述层的主体和/或表面中的粘合促进剂; 和选自氧化硅和氧化铝中的至少一种氧化物层（MOx），其厚度为20〜200nm。 辅助结构在可见光范围内具有优异的透明性，优异的紫外线不透明性以及良好的机械阻力和耐老化性，同时具有优异的防潮性能。 因此，所述结构可有利地用于光伏面板的前表面或保护有机发光二极管。